Bromine and iodine chemistry in a global chemistry-climate model: description...

Ordóñez, C., J. Lamarque, S. Tilmes, D. Kinnison, E. Atlas, D. R. Blake, G. S. Santos, G. Brasseur, and A. Saiz-Lopez (2012), Bromine and iodine chemistry in a global chemistry-climate model: description and evaluation of very short-lived oceanic sources, Atmos. Chem. Phys., 12, 1423-1447, doi:10.5194/acp-12-1423-2012.
Abstract: 

The global chemistry-climate model CAMChem has been extended to incorporate an expanded bromine and iodine chemistry scheme that includes natural oceanic sources of very short-lived (VSL) halocarbons, gas-phase photochemistry and heterogeneous reactions on aerosols. Ocean emissions of five VSL bromocarbons (CHBr3 , CH2 Br2 , CH2 BrCl, CHBrCl2 , CHBr2 Cl) and three VSL iodocarbons (CH2 ICl, CH2 IBr, CH2 I2 ) have been parameterised by a biogenic chlorophyll-a (chl-a) dependent source in the tropical oceans (20◦ N–20◦ S). Constant oceanic fluxes with 2.5 coast-to-ocean emission ratios are separately imposed on four different latitudinal bands in the extratropics (20◦ –50◦ and above 50◦ in both hemispheres). Top-down emission estimates of bromocarbons have been derived using available measurements in the troposphere and lower stratosphere, while iodocarbons have been constrained with observations in the marine boundary layer (MBL). Emissions of CH3 I are based on a previous inventory and the longer lived CH3 Br is set to a surface mixing ratio boundary condition. The global oceanic emissions estimated for the most abundant VSL bromocarbons – 533 Gg yr−1 for CHBr3 and 67.3 Gg yr−1 for CH2 Br2 – are within the range of previous estimates. Overall the latitudinal and vertical distributions of modelled bromocarbons are in good agreement with observations. Nevertheless, we identify some issues such as the reduced number of aircraft observations to validate models in the Southern Hemisphere, the overestimation of CH2 Br2 in the upper troposphere – lower stratosphere and the underestimation of CH3 I in the same region. Despite the difficulties involved in the global modelling of the shortest lived iodocarbons (CH2 ICl, CH2 IBr, CH2 I2 ), modelled results are in good agreement with published observations in the MBL. Finally, sensitivity simulations show that knowledge of the diurnal emission cycle for these species, in particular for CH2 I2 , is key to assess their global source strength.

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Research Program: 
Atmospheric Composition Modeling and Analysis Program (ACMAP)