WB-57 - JSC

The JPL Laser Hygrometer (JLH) is an autonomous spectrometer to measure atmospheric water vapor from airborne platforms. It is designed for high-altitude scientific flights of the NASA ER-2 aircraft to monitor upper tropospheric (UT) and lower stratospheric (LS) water vapor for climate studies, atmospheric chemistry, and satellite validation. JLH will participate in the NASA SEAC4RS field mission this year. The light source for JLH is a near-infrared distributed feedback (DFB) tunable diode laser that scans across a strong water vapor vibrational-rotational combination band absorption line in the 1.37 micrometer band. Both laser and detector are temperature‐stabilized on a thermoelectrically-cooled aluminum mount inside an evacuated metal housing. A long optical path is folded within a Herriott Cell for sensitivity to water vapor in the UT and LS. A Herriott cell is an off-axis multipass cell using two spherical mirrors [Altmann et al., 1981; Herriott et al., 1964]. The laser beam enters the Herriott cell through a hole in the mirror that is closest to the laser. The laser beam traverses many passes of the Herriott cell and then returns through the same mirror hole to impinge on a detector.

IRIS is an ultra sensive laser spectrometer for in situ detection of the isotopic composition of water vapor in the higher tropopause and the lower stratosphere. The isotope signals may be used to quantify troposphere-stratosphere exchange, and to study the water chemistry in the stratosphere. IRIS is based on the technique of optical-feedback cavity enhanced absorption spectroscopy. It uses a room temperature infrared laser, needing no crygens. The instrument combines a low weight (< 50 kg) and volume (< 50 L) with a low power consumption (< 200 W), making it uniquely suitable for future deployment on an Unmanned Aerial Vehicle.

The Harvard CRDS/ICOS instrument is an absorption spectrometer that uses the relatively new and highly sensitive techniques of integrated cavity output spectroscopy (ICOS) and cavity ringdown spectroscopy (CRDS) with a high-finesse optical cavity and a cw quantum cascade laser (QCL) source. The primary spectroscopic technique employed is ICOS, in which intra-cavity absorption is measured from the steady-state output of the cavity. Light from a high power, tunable, single mode, solid-state laser source is coupled into a cavity consisting of two concave, highly reflective mirrors (R ≈ 0.9999), through which air continuously flows. The laser is scanned over a spectral region of 1–2 cm-1 containing an absorption feature, and the cavity output is detected by an LN2-cooled HgCdTe detector. The resultant output approximates an absorption spectrum with an effective pathlength of > 5 km, far greater than that of standard multipass Herriott or White cells.

The Harvard CRDS/ICOS instrument is an absorption spectrometer that uses the relatively new and highly sensitive techniques of integrated cavity output spectroscopy (ICOS) and cavity ringdown spectroscopy (CRDS) with a high-finesse optical cavity and a cw quantum cascade laser (QCL) source. The primary spectroscopic technique employed is ICOS, in which intra-cavity absorption is measured from the steady-state output of the cavity. Light from a high power, tunable, single mode, solid-state laser source is coupled into a cavity consisting of two concave, highly reflective mirrors (R ≈ 0.9999), through which air continuously flows. The laser is scanned over a spectral region of 1–2 cm-1 containing an absorption feature, and the cavity output is detected by an LN2-cooled HgCdTe detector. The resultant output approximates an absorption spectrum with an effective pathlength of > 5 km, far greater than that of standard multipass Herriott or White cells.

The design of the newly developed total water instrument is based on the same principles as the water vapor instrument, and is intended to fly in conjunction with it. Conceptually, the total water instrument can be thought of as containing four subsystems:
1. An inlet through which liquid and/or solid water particles can be brought into an instrument duct without perturbing the ambient particle density.
2. A heater that efficiently evaporates the liquid/solid water before it reaches the detection axis.
3. Ducting through which the air flows to the detection axis without perturbing the (total) water vapor mixing ratio.
4. A water vapor detection axis that accurately and precisely measures the total water content of the ambient air.

The Harvard Water Vapor (HWV) instrument combines two independent measurement methods for the simultaneous in situ detection of ambient water vapor mixing ratios in a single duct. This dual axis instrument combines the heritage of the Harvard Lyman-α photo-fragment fluorescence instrument (LyA) with the newly designed tunable diode laser direct absorption instrument (HHH). The Lyman-α detection axis functions as a benchmark measurement, and provides a requisite link to the long measurement history of Harvard Lyman-α aboard NASA’s WB-57 and ER-2 aircraft [Weinstock et al., 1994; Hintsa et al., 1999; Weinstock et al., 2009]. The inclusion of HHH provides a second high precision measurement that is more robust than LyA to changes in its measurement sensitivity [Smith et al., in preparation]. The simultaneous utilization of radically different measurement techniques facilitates the identification, diagnosis, and constraint of systematic errors both in the laboratory and in flight. As such, it constitutes a significant step toward resolving the controversy surrounding water vapor measurements in the upper troposphere and lower stratosphere.

The high-sensitivity fast response CO2 instrument measures CO2 concentrations in situ using the light source, gas cells, and solid-state detector from a modified nondispersive infrared CO2 analyzer (Li-Cor, Inc., Lincoln, NE). These components are stabilized along the detection axis, vibrationally isolated, and housed in a temperature-controlled pressure vessel. Sample air enters a rear-facing inlet, is preconditioned using a Nafion drier (to remove water vapor), then is compressed by a Teflon diaphragm pump. A second water trap, using dry ice, reduces the sample air dewpoint to less than 70C prior to detection. The CO2 mixing ratio of air flowing through the sample gas cell is determined by measuring absorption at 4.26 microns relative to a reference gas of known concentration. In-flight calibrations are performed by replacing the air sample with reference gas every 10 minutes, with a low-span and a high-span gas every 20 minutes, and with a long-term primary standard every 2 hours. The long-term standard is used sparingly and serves as a check of the flight-to-flight accuracy and precision of the measurements, augmented by ground-based calibrations before and after flights.

The HyMap scanner, built by Integrated Spectronics Inc of Sydney, Australia, has four spectrometers in the interval 0.45 to 2.45 micrometers excluding the two major atmospheric water absorption windows. The bandwidths are not constant, but vary between 15 and 18 nanometers. The scanner also has an on-board bright source calibration system, which is used to monitor the stability of the signal. The signal/noise ratio measured outside the aircraft with a sun angle of 30° and a 50% reflectance standard is more than 500/1 except near the major atmospheric water absorption bands. The scanner is mounted on a hydraulically actuated Zeiss-Jena SM 2000 stabilized platform. The platform provides +/- 5 degrees of pitch and roll correction. The yaw can be offset by +/- 20 degrees with +/- 8 degrees of stabilization. The platform provides a residual error in nadir pointing of less than 1 degree and reduces aircraft motion effects by a factor ranging from 10:1 to 30:1.

The basic HyMap specifications are:

IFOV: 2.5 mr along track, 2.0 mr across track (Spatial resolution 3.5–10 m)
FOV: 62 degrees (512 pixels)

<p>OH is detected by direct laser induced fluorescence in the (0-1) band of the 2?-2? electronic transition. A pulsed dye-laser system produces frequency tunable laser light at 282 nm. An on-board frequency reference cell is used by a computer to lock the laser to the appropriate wavelength. Measurement of the signal is then made by tuning the laser on and off resonance with the OH transition.</p>
<p>Stratospheric air is channeled into the instrument using a double-ducted system that both maintains laminar flow through the detection region and slows the flow from free stream velocity (200 m/s) to 40 m/s. The laser light is beam-split and directed to two detection axes where it passes through the stratospheric air in multipass White cells.</p>
<p>Fluorescence from OH (centered at 309 nm) is detected orthogonal to both the flow and the laser propagation using a filtered PMT assembly. Optical stability is checked periodically by exchanging the 309 nm interference filter with a filter centered at 302 nm, where Raman scattering of N2 is observed.</p>
<p>HO2 is measured as OH after chemical titration with nitric oxide: HO2 + NO → OH + NO2. Variation of added NO density and flow velocity as well as the use of two detection axes aid in diagnosis of the kinetics of this titration. Measurements of ozone (by uv absorption) and water vapor (by photofragment fluorescence) are made as diagnostics of potential photochemical interference from the mechanism: O3 + hv (282 nm) → O(1D) + O2, followed by: O(1D) + H2O → OH + OH</p>