Status
The operating principle of the O3 instrument is the measurement of chemiluminescence from the reaction of nitric oxide (NO) with ambient O3 using a dry-ice cooled, red-sensitive photomultiplier employing photon counting electronics. The reagent NO (grade > 99%) is supplied from a commercially purchased lecture bottle filled to a maximum pressure of 500 psig. Since NO is a toxic gas, the small high pressure cylinder, its regulator, and several safety features are contained inside a specially designed pressure safe vessel that is vented overboard the aircraft. Ambient air is sampled through a standard HIMIL inlet protruding outside the aircraft boundary layer. Ambient air sample flow is controlled to 500 sccm, while the NO reagent is introduced to the reaction vessel in near-excess flow of ~ 4 sccm. Gas flows as well as the reaction vessel temperature (35 ± 0.1°C) and pressure (10 ± 0.05 torr) are all controlled at constant conditions resulting in maximum stability of the detected signal and instrument sensitivity. The instrument sensitivity (~2000 cps/ppbv) is determined from calibrations performed on the ground before and after each flight or set of back-to-back flights using a UV absorption based calibrator (TECO model 49PS) operated with high-quality ultra-pure air. A near-linear calibration curve is generated in 100 ppb intervals from 0 to 1 ppm. This calibration range is sufficient to measure O3 mixing ratios over the altitude range of the aircraft.
