Vladimir L. Orkin

Organization

NIST

Email

Contact person by email

Business Phone

Work

:

(301) 975-4418

Business Address

NIST
100 Bureau Drive, Stop 8320
Bldg. 221, Room A-111
Gaithersburg, MD 20899
United States

First Author Publications

Orkin, V.L., et al. (2023), Experimental kinetic study of the reactions between OH radicals and three 2-butenes over the temperature range 220-370 K and pressure range 0.67-40 kPa (5-300 Torr), Int. J. Chem. Kinet., 55, 221-237, doi:10.1002/kin.21630.
Orkin, V.L., et al. (2020), Atmospheric Lifetimes of Halogenated Hydrocarbons: Improved Estimations From an Analysis of Modeling Results, J. Geophys. Res., 125, 1-13, doi:10.1029/2019JD032243.
Orkin, V.L., et al. (2017), Photochemical Properties of CH2HCH-CFCl-CF2Br (4-Bromo-3-chloro3,4,4-trifluoro-1-butene) and CH3‑O-CH(CF3)2 (Methyl Hexafluoroisopropyl Ether): OH Reaction Rate Constants and UV and IR Absorption Spectra, J. Phys. Chem. A, doi:10.1021/acs.jpca.7b04256.
Orkin, V.L., et al. (2014), Photochemical Properties of trans-1-Chloro-3,3,3-trifluoropropene (trans-CHClHCHCF3): OH Reaction Rate Constant, UV and IR Absorption Spectra, Global Warming Potential, and Ozone Depletion Potential, J. Phys. Chem. A, 118, 5263-5271, doi:10.1021/jp5018949.
Orkin, V.L., et al. (2014), Photochemical Properties of Hydrofluoroethers CH3OCHF2, CH3OCF3, and CHF2OCH2CF3: Reactivity toward OH, IR Absorption Cross Sections, Atmospheric Lifetimes, and Global Warming Potentials, J. Phys. Chem. A, 118, 10770-10777, doi:10.1021/jp506377w.
Orkin, V.L., et al. (2013), Photochemical Properties of Some Cl-Containing Halogenated Alkanes, J. Phys. Chem. A, 117, 5483-5490, doi:10.1021/jp400408y.
Orkin, V.L., et al. (2013), Measurements of Rate Constants for the OH Reactions with Bromoform (CHBr3), CHBr2Cl, CHBrCl2, and Epichlorohydrin (C3H5ClO), J. Phys. Chem. A, 117, 3809-3818, doi:10.1021/jp3128753.
Orkin, V.L., et al. (2012), High Accuracy Measurements of OH Reaction Rate Constants and IR Absorption Spectra: Substituted 2-Propanols, J. Phys. Chem. A, 116, 6188-6198, doi:10.1021/jp211534n.
Orkin, V.L., et al. (2011), High-Accuracy Measurements of OH• Reaction Rate Constants and IR and UV Absorption Spectra: Ethanol and Partially Fluorinated Ethyl Alcohols, J. Phys. Chem. A, 115, 8656-8668, doi:10.1021/jp202099t.
Orkin, V.L., et al. (2011), Rate Constants for the Reactions between OH and Perfluorinated Alkenes, J. Phys. Chem. A, 115, 6568-6574, doi:10.1021/jp201663j.
Orkin, V.L., et al. (2010), High-Accuracy Measurements of OH Reaction Rate Constants and IR Absorption Spectra: CH2=CF-CF3 and trans-CHF=CH-CF3, J. Phys. Chem. A, 114, 5967-5979, doi:10.1021/jp9092817.
Orkin, V.L., et al. (2006), Rate Constant for the Reaction of OH with H2 between 200 and 480 K, J. Phys. Chem. A, 110, 6978-6985, doi:10.1021/jp057035b.
Orkin, V.L., et al. (2003), Measurements of the infrared absorption cross-sections of haloalkanes and their use in a simplified calculational approach for estimating direct global warming potentials, Journal of Photochemistry and Photobiology A: Chemistry, 157, 211-222, doi:10.1016/S1010-6030.
Orkin, V.L., et al. (2002), Photochemistry of Bromine-Containing Fluorinated Alkenes: Reactivity toward OH and UV Spectra, J. Phys. Chem. A, 106, 10195-10199, doi:10.1021/jp014436s.
Orkin, V.L., et al. (1999), Atmospheric Lifetimes and Global Warming Potentials of Hydrofluoroethers: Reactivity toward OH, UV Spectra, and IR Absorption Cross Sections, J. Phys. Chem. A, 103, 9770-9779, doi:10.1021/jp991741t.
Orkin, V.L., et al. (1997), Atmospheric Fate of Chlorobromomethane: Rate Constant for the Reaction with OH, UV Spectrum, and Water Solubility, J. Phys. Chem. A, 101, 174-178.
Orkin, V.L., et al. (1997), Rate Constants for the Reactions of OH with HFC-245cb (CH3CF2CF3) and Some Fluoroalkenes (CH2CHCF3, CH2CFCF3, CF2CFCF3, and CF2CF2), J. Phys. Chem. A, 101, 9118-9124.

Note: Only publications that have been uploaded to the ESD Publications database are listed here.

Co-Authored Publications

Khamaganov, V.G., et al. (2020), Study of the reactions of OH with HCl, HBr, and HI between 298 K and 460 K, Int. J. Chem. Kinet., 52, 852-860, doi:10.1002/kin.21404.
Liang, Q., et al. (2017), Deriving Global OH Abundance and Atmospheric Lifetimes for Long-Lived Gases: A Search for CH3CCl3 Alternatives, J. Geophys. Res., 122, 11,914-11,933, doi:10.1002/2017JD026926.
Fleming, E., et al. (2015), The impact of current CH4 and N2O atmospheric loss process uncertainties on calculated ozone abundances and trends, J. Geophys. Res., 120, 5267-5293, doi:10.1002/2014JD022067.
Patten, K.O., et al. (2012), Correction to “OH reaction rate constant, IR absorption spectrum, ozone depletion potentials and global warming potentials of 2-bromo-3,3,3-trifluoropropene”, J. Geophys. Res., 117, D22301, doi:10.1029/2012JD019051.
Patten, K.O., et al. (2011), OH reaction rate constant, IR absorption spectrum, ozone depletion potentials and global warming potentials of 2-bromo-3,3,3-trifluoropropene, J. Geophys. Res., 116, D24307, doi:10.1029/2011JD016518.
Kozlov, S.N., et al. (2003), An Investigation of the Reactivity of OH with Fluoroethanes: CH3CH2F (HFC-161), CH2FCH2F (HFC-152), and CH3CHF2 (HFC-152a), J. Phys. Chem. A, 107, 2239-2246, doi:10.1021/jp022087b.
Kozlov, S.N., et al. (2003), OH Reactivity and UV Spectra of Propane, n-Propyl Bromide, and Isopropyl Bromide, J. Phys. Chem. A, 107, 1333-1338, doi:10.1021/jp021806j.
Kurylo, M., and V.L. Orkin (2003), Determination of Atmospheric Lifetimes via the Measurement of OH Radical Kinetics, Chem. Rev., 103, 5049-5076.
Wallington, T.J., et al. (2001), Atmospheric Oxidation Mechanism of Methyl Pivalate, (CH3)3CC(O)OCH3, J. Phys. Chem. A, 105, 7225-7235, doi:10.1021/jp010308s.
Villenave, E., et al. (1997), Rate Constant for the Reaction of OH Radicals with Dichloromethane, J. Phys. Chem. A, 101, 8513-8517.

Note: Only publications that have been uploaded to the ESD Publications database are listed here.

Vladimir L. Orkin

National Aeronautics and Space Administration

National Aeronautics and
Space Administration