DC-8 - AFRC

HTS is composed of two instruments based on absorption of near-infrared laser radiation in high finesse optical cavities. A Picarro G2401-m analyzer based on wavelength-scanned cavity ring-down spectroscopy (CRDS) measures CO2, CH4, and CO concentrations at 2-second intervals. A Los Gatos 913-0014 EP analyzer based on off-axis integrated cavity output spectroscopy (ICOS) measures N2O and CO concentrations at 1-second intervals. Extensive modifications have been applied to these commercial analyzers for flight and include vibration isolation, temperature control, additional flow control and pumping capacity for high-altitude sampling, sample drying, and in-flight calibrations using WMO-traceable compressed gas standards to verify stable and accurate performance throughout the full DC-8 flight envelope.

The PFP whole air sampler provides a means of automated or manual filling of glass flasks, twelve per PFP. The sampler is designed to remove excess water vapor from the sampled air and compress it without contamination into ~1-liter volumes. These flasks are analyzed at the NOAA’s Global Monitoring Division laboratory for trace gasses and at  the INSTAR’s Staple Isotope Lab laboratory for isotopes of methane. More than 60 trace gases found in the global atmosphere can be measured at mole fractions that range from parts-per-million (10^-6), e.g., carbon dioxide, down to parts-per-quadrillion (10^-15), e.g., HFC-365mfc.  The chemical species monitored include N₂O, SF₆, H₂, CS₂, OCS, CO₂, CH₄, CO, CFCs, HCFCs, HFCs, Solvents, Methyl Halides, Hydrocarbons and Perfluorocarbons.

Medusa collects 32 cryogenically dried, flow and pressure controlled samples per flight. The samples are collected by an automated sampler into 1.5 L glass flasks that integrate over 25-s (1 e-fold) periods. Medusa provides discretely-sampled comparisons for onboard in situ O2/N2 ratio and CO2 measurements and unique measurements of Ar/N2 and ¹³C, ¹⁴C, and ¹⁸O isotopologues of CO2. The complementary measurements allow ground-truthing of onboard instrument measurements in a laboratory setting, where analysis conditions can often be more stringently controlled and carefully monitored. Isotope and argon measurements can provide additional information about land and ocean controls over the carbon cycle, and about the age and source of the air sampled.

Medusa consists of an onboard computer, two pressure controllers, two
 pumps, three multi-position selector
valves, and a host of other hardware that
control and direct the air samples. All air
is dried by passing it through traps
immersed in a -78 C dry ice bath, adjusted to match atmospheric pressure
at sea level, and then automatically isolated in a flask. Medusa flasks are analyzed on a sector-magnet mass spectrometer and a LiCor non-dispersive infrared CO2 analyzer by the Scripps O2 Program at Scripps Institution of Oceanography.

The NCAR Airborne Oxygen Instrument measures O2 concentration using a vacuum-ultraviolet absorption technique.
 AO2 is based on earlier ship-board and laboratory instruments using the same technique, but has been designed specifically for airborne use to minimize
motion and thermal sensitivity and with a pressure and flow controlled inlet system. To achieve the high levels of precision needed, AO2 switches between sample gas and air
from a high-pressure reference cylinder
every 2.5 seconds. Atmospheric O2 concentrations are typically reported in units
of one part in 1,000,000 relative deviations
in the O2/N2 ratio, which are referred to as
 "per meg." AO2 has a 1-sigma precision of
± 2 per meg on a 5 second measurement.
 For comparison, this is equivalent to detecting the removal of one O2 molecule
 from 2.5 million molecules of air. At typical
flight speeds of 300 kts or climb/descent
rates of 1500 fpm, 5-seconds correspond to
a horizontal resolution of 750 m and a
vertical resolution of 40 m. The instrument includes an internal single-cell CO2 sensor (LI-840), which is used to correct the O2 measurements for dilution by CO2 and for scientific purposes. To minimize inlet
surface effects, the pressure in the inlet line
is actively controlled at the aircraft bulkhead.
The sample air is cryogenically dried in a
series of electropolished stainless steel traps immersed in a dry ice Fluorinert slurry. The
 AO2 system consists of a pump module, a cylinder module, an instrument module, and a dewar.

Vacuum ultraviolet radiation produced in a low pressure plasma discharge lamp is used to induce resonance scattering in Cl and Br atoms within a flowing sample. ClO and BrO are converted to Cl and Br by the addition of NO such that the rapid bimolecular reaction ClO + NO → Cl + NO2 (BrO + NO → Br + NO2) yields one halogen atom for each halogen oxide radical present in the flowing sample. Three detection axes are used to diagnose the spatial (and thus temporal) dependence of the ClO (BrO) to Cl (Br) conversion and to detect any removal of Cl (Br) following its formation. A double duct system is used both to maintain laminar flow through the detection region and to step the flow velocity in the detection region down from free stream (200 m/sec) to 20 m/sec in order to optimize the kinetic diagnosis.

The Polarized Imaging Nephelometer is an in situ instrument designed and built at the Laboratory for Aerosols, Clouds and Optics (LACO) at the University of Maryland Baltimore County for the measurement of components of the aerosol phase matrix in high angular resolution between 2 to 178 deg scattering angles. The measured phase matrix provides extensive characterization of the scattering properties of the studied aerosols allowing for a very comprehensive set of aerosol scattering parameters. These measurements are essential for the validation of the new generation of aerosol remote sensors like the APS polarimeter in the Glory satellite, and for the construction of accurate models of real aerosol particles, specially the non-spherical ones.

4STAR (Spectrometers for Sky-Scanning Sun-Tracking Atmospheric Research; Dunagan et al., 2013) is an airborne sun-sky spectrophotometer measuring direct solar beam transmittance (i.e., 4STAR determines direct solar beam transmission by detecting direct solar irradiance) and narrow field-of-view sky radiance to retrieve and remotely sense column-integrated and, in some cases, vertically resolved information on aerosols, clouds, and trace gases. The 4STAR team is a world leader in airborne sun-sky photometry, building on 4STAR’s predecessor instrument, AATS-14 (the NASA Ames Airborne Tracking Sun photometers; Matsumoto et al., 1987; Russell et al. 1999, and cited in more than 100 publication) and greatly expanding aerosol observations from the ground-based AERONET network of sun-sky photometers (Holben et al., 1998) and the Pandora network of ground-based direct-sun and sky spectrometer (e.g, Herman et al., 2009).

4STAR is used to quantify the attenuated solar light (from 350 to 1650 nm) and retrieve properties of various atmospheric constituents: spectral Aerosol Optical Depth (AOD) from ultraviolet to the shortwave infrared (e.g., LeBlanc et al., 2020, Shinozuka et al., 2013); aerosol intensive properties - Single Scattering Albedo (SSA; e.g., Pistone et al., 2019), asymmetry parameter, scattering phase function, absorption angstrom exponent, size distribution, and index of refraction; various column trace gas components (NO₂, Ozone, Water Vapor; e.g., Segal-Rosenheimer et al., 2014, with potential for SO₂ and CH₂O); and cloud optical depth, effective radius and thermodynamic phase (e.g., LeBlanc et al., 2015).

Some examples of the science questions that 4STAR have pursued in the past and will continue to address:

• What is the Direct Aerosol Radiative Effect on climate and its uncertainty? (1)
• How much light is absorbed by aerosol emitted through biomass burning? (1)
• How does heating of the atmosphere by absorbing aerosol impact large scale climate and weather patterns? (1)
• How does aerosol spatial consistency of extensive and intensive properties compare? (2)
• How does the presence of aerosol impact Earth’s radiative transfer, with co-located high concentration of trace gas? (3, 5)
• What is the impact of air quality from long-range transport of both aerosol particulates and column NO2 and Ozone, and their evolution? (3, 6)
• What are the governing properties and spatial patterns of local and transported aerosol? (1)
• How are cloud properties impacted near the sea-ice edge? (4)
• In heterogeneous environments where clouds and aerosols are present, how much solar radiation is impacted by 3D radiative transfer? And how does that impact the aerosol properties? (5)

(1) ORACLES: Zuidema et al., doi:10.1175/BAMS-D-15-00082.1., 2016; LeBlanc et al., doi:10.5194/acp-20-1565-2020, 2020; Pistone et al., https://doi.org/10.5194/acp-2019-142, 2019;Cochrane et al., https://doi.org/10.5194/amt-12-6505-2019, 2019; Shinozuka et al., https://doi.org/10.5194/acp-20-11275-2020, 2020; Shinozuka et al., https://doi.org/10.5194/acp-20-11491-2020, 2020
(2) KORUS-AQ:  LeBlanc et al., doi:https://doi.org/10.5194/acp-22-11275-2022, 2022

(3) KORUS-AQ: Herman et al., doi:10.5194/amt-11-4583-2018, 2018
(4) ARISE: Smith et al., https://doi.org/10.1175/BAMS-D-14-00277.1, 2017; Segal-Rosenheimer et al., doi:10.1029/2018JD028349, 2018
(5) SEAC4RS: Song et al., doi: 10.5194/acp-16-13791-2016, 2016; Toon et al., https://doi.org/10.1002/2015JD024297, 2016
(6) TCAP: Shinozuka et al., doi:10.1002/2013JD020596, 2013; Segal-Rosenheimer et al., doi:10.1002/2013JD020884, 2014

The Advanced Vertical Atmospheric Profiling System (AVAPS) is the dropsonde system for the Global Hawk. The Global Hawk dropsonde is a miniaturized version of standard RD-93 dropsondes based largely on recent MIST driftsondes deployed from balloons. The dropsonde provides vertical profiles of pressure, temperature, humidity, and winds. Data from these sondes are transmitted in near real-time via Iridium or Ku-band satellite to the ground-station, where additional processing will be performed for transmission of the data via the Global Telecommunications System (GTS) for research and operational use. The dispenser is located in zone 61 in the Global Hawk tail and is capable of releasing up to 88 sondes in a single flight.

The NASA GSFC In Situ Airborne Formaldehyde (ISAF) instrument measures formaldehyde (CH2O) on both pressurized and unpressurized (high-altitude) aircraft. Using laser induced fluorescence (LIF), ISAF possesses the high sensitivity, fast time response, and dynamic range needed to observe CH2O throughout the troposphere and lower stratosphere, where concentrations can range from 10 pptv to hundreds of ppbv.

Formaldehyde is produced via the oxidation of hydrocarbons, notably methane (a ubiquitous greenhouse gas) and isoprene (the primary hydrocarbon emitted by vegetation). Observations of CH2O can thus provide information on many atmospheric processes, including:
- Convective transport of air from the surface to the upper troposphere
- Emissions of reactive hydrocarbons from cities, forests, and fires
- Atmospheric oxidizing capacity, which relates to formation of ozone and destruction of methane
In situ observations of CH2O are also crucial for validating retrievals from satellite instruments, such as OMI, TROPOMI, and TEMPO.