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O3 Photometer - UAS (NOAA)

Ozone (O3) in the lower stratosphere (LS) is responsible for absorbing much of the biologically damaging ultraviolet (UV) radiation from the sunlight, and thus plays a critical role in protecting Earth's environment. By absorbing UV light, O3 heats the surrounding air, leading to the vertical stratification and dynamic stability that define the stratosphere. Halogen species from anthropogenic compounds such as CFCs can cause significant damage to the O3 layer in the LS and have led to the formation of the Antarctic ozone hole. Accurate measurement of O3 in the LS is the first step toward understanding and protecting stratospheric O3. The UAS Ozone Photometer was designed specifically for autonomous, precise, and accurate O3 measurements in the upper troposphere and lower stratosphere (UT/LS) onboard the NASA Global Hawk Unmanned Aircraft System (GH UAS) and other high altitude research platforms such as the ER-2 and WB-57. With a data rate of 2 Hz, the instrument can provide high-time-resolution, detailed information for studies of O3 photochemistry, radiation balance, stratosphere-troposphere exchange, and air parcel mixing in the UT/LS. Furthermore, its accurate data are useful for satellite retrieval validation.  Contacts: Troy Thornberry, Ru-Shan Gao

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Whole Air Sampler

The Whole Air Sampler (WAS) collects samples from airborne platforms for detailed analysis of a wide range of trace gases. The compounds that are typically measured from the WAS includes trace gases with sources from industrial midlatitude emissions, from biomass burning, and from the marine boundary layer, with certain compounds (e.g. organic nitrates) that have a unique source in the equatorial surface ocean. The use of a broad suite of tracers with different sources and lifetimes provides powerful diagnostic information on air mass history and chemical processing that currently is only available from measurements from whole air samples. Previous deployments of the whole air sampler have shown that the sampling and analytical procedures employed by our group are capable of accessing the wide range of mixing ratios at sufficient precision to be used for tracer studies. Thus, routine measurement of species, such as methyl iodide, at <= 0.1 x 10-12 mole fraction, or NMHC at levels of a few x 10-12 mole fraction are possible. In addition to the tracer aspects of the whole air sampler measurements, we measure a full suite of halocarbon species that provide information on the role of short-lived halocarbons in the tropical UT/LS region, on halogen budgets in the UT/LS region, and on continuing increasing temporal trends of HFCs (such as 134a), HCFCs (such as HCFC 141b), PFCs (such as C2F6), as well as declining levels of some of the major CFCs and halogenated solvents. The measurements of those species that are changing rapidly in the troposphere also give direct indications of the age and origin of air entering the stratosphere.

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Single Particle Soot Photometer (NOAA)

The SP2 is a laser-induced incandescence instrument primarily used for measuring the refractory BC  (rBC) mass content of individual accumulation-mode aerosol particles. It is able to provide this data product independently of the total particle morphology and mixing state, and thus delivers detailed information not only about BC loadings, but also size distributions, even in exceptionally clean air. The instrument can also provide the optical size of individual particles containing rBC, and identify the presence of materials associated with the BC fraction (i.e. identify the rBC’s mixing state). Since its introduction in 2003, the SP2 has been substantially improved, and now can be considered a highly competent instrument for assessing BC loadings and mixing state in situ.  NOAA deploys multiple SP2s with different designs: the first was built for the WB-57F research aircraft. Two others are rack-mounted units customized at NOAA; one of the rack mounted units can be humidified, and has been deployed with a paired dry rack-mounted SP2 as the "Humidified-Dual SP2" (HD-SP2). The rack mounted units are suitable for in-cabin operations.

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Particle Analysis By Laser Mass Spectrometry

The NOAA PALMS instrument measures single-particle aerosol composition using UV laser ablation to generate ions that are analyzed with a time-of-flight mass spectrometer.  The PALMS size range is approximately 150 to >3000 nm and encompasses most of the accumulation and coarse mode aerosol volume. Individual aerosol particles are classified into compositional classes.  The size-dependent composition data is combined with aerosol counting instruments from Aerosol Microphysical Properties (AMP), the Langley Aerosol Research Group Experiment (LARGE), and other groups to generate quantitative, composition-resolved aerosol concentrations.  Background tropospheric concentrations of climate-relevant aerosol including mineral dust, sea salt, and biomass burning particles are the primary foci for the ATom campaigns.  PALMS also provides a variety of compositional tracers to identify aerosol sources, probe mixing state, track particle aging, and investigate convective transport and cloud processing.

*_Standard data products_**: *

Particle type number fractions: sulfate/organic/nitrate mixtures, biomass burning, EC, sea salt, mineral dust, meteoric, alkali salts, heavy fuel combustion, and other. Sampling times range from 1-5 mins.

*_Advanced data products_**:*

Number, surface area, volume, and mass concentrations of the above particle types. Total sulfate and organic mass concentrations. Relative and absolute abundance of various chemical markers and aerosol sub-components: methanesulfonic acid, sulfate acidity, organic oxidation level, iodine, bromine, organosulfates, pyridine, and other species.

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Meteorological Measurement System

The Meteorological Measurement System (MMS) is a state-of-the-art instrument for measuring accurate, high resolution in situ airborne state parameters (pressure, temperature, turbulence index, and the 3-dimensional wind vector). These key measurements enable our understanding of atmospheric dynamics, chemistry and microphysical processes. The MMS is used to investigate atmospheric mesoscale (gravity and mountain lee waves) and microscale (turbulence) phenomena. An accurate characterization of the turbulence phenomenon is important for the understanding of dynamic processes in the atmosphere, such as the behavior of buoyant plumes within cirrus clouds, diffusions of chemical species within wake vortices generated by jet aircraft, and microphysical processes in breaking gravity waves. Accurate temperature and pressure data are needed to evaluate chemical reaction rates as well as to determine accurate mixing ratios. Accurate wind field data establish a detailed relationship with the various constituents and the measured wind also verifies numerical models used to evaluate air mass origin. Since the MMS provides quality information on atmospheric state variables, MMS data have been extensively used by many investigators to process and interpret the in situ experiments aboard the same aircraft.

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Diode Laser Hygrometer

The DLH has been successfully flown during many previous field campaigns on several aircraft, most recently ACTIVATE (Falcon); FIREX-AQ, ATom, KORUS-AQ, and SEAC4RS (DC-8); POSIDON (WB-57); CARAFE (Sherpa); CAMP2Ex and DISCOVER-AQ (P-3); and ATTREX (Global Hawk). This sensor measures water vapor (H2O(v)) via absorption by one of three strong, isolated spectral lines near 1.4 μm and is comprised of a compact laser transceiver and a sheet of high grade retroflecting road sign material to form the optical path. Optical sampling geometry is aircraft-dependent, as each DLH instrument is custom-built to conform to aircraft geometric constraints. Using differential absorption detection techniques, H2O(v) is sensed along the external path negating any potential wall or inlet effects inherent in extractive sampling techniques. A laser power normalization scheme enables the sensor to accurately measure water vapor even when flying through clouds. An algorithm calculates H2O(v) concentration based on the differential absorption signal magnitude, ambient pressure, and temperature, and spectroscopic parameters found in the literature and/or measured in the laboratory. Preliminary water vapor mixing ratio and derived relative humidities are provided in real-time to investigators.

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BroadBand Radiometers

The Broadband Radiometers (BBR) consist of modified Kipp & Zonen CM-22 pyranometers (to measure solar irradiance) and CG-4 pyrgeometers (to measure IR irradiance) (see http://www.kippzonen.com/). The modifications to make these instruments more suitable for aircraft use include new instrument housings and amplification of the signal at the sensor. The instruments are run in current-loop mode to minimize the effects of noise in long signal cables. The housing is sealed and evacuated to prevent condensation or freezing inside the instrument. Each BBR has the following properties: Field-of-view: Hemispheric Temperature Range: -65C to +80C Estimated Accuracy: 3-5% Data Rate: 1Hz

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Cloud, Aerosol, and Precipitation Spectrometer

The CAPS is a combination probe designed around the newest technologies and the experience gained with over 20 years of using similar probes. It meets the goals of measuring a large range of particle sizes--0.5μm to 1.55mm--with one probe, thus minimizing space, cable connections, and data systems necessary for measurement of this range. Today's technology also provides the CAPS the processing power necessary to perform at speeds up to 200m/s. An intuitive graphical user interface, the Particle Analysis and Collection System (PACS), at the host computer, provides simple but powerful control of measurement parameters, while simultaneously displaying on-the-fly size distributions and derived parameters. All data interfaces are done via line drivers meeting the RS-422 electrical specification, allowing cable lengths of up to 100 meters--an improvement over RS-232 lines capable of only 15-meter cable lengths.

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