Crounse, J.D., F. Paulot, H.G. Kjaergaard, and P. Wennberg (2011), Peroxy radical isomerization in the oxidation of isoprene, Phys. Chem. Chem. Phys., 13, 13607-13613, doi:10.1039/c1cp21330j.
Abstract
We report experimental evidence for the formation of C5-hydroperoxyaldehydes (HPALDs) from 1,6-H-shift isomerizations in peroxy radicals formed from the hydroxyl radical (OH) oxidation of 2-methyl-1,3-butadiene (isoprene).
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