Ozone Profile Climatology for Remote Sensing Retrieval Algorithms

New ozone (O3 ) profile climatologies are created from the Modern-Era Retrospective Analysis for Research and Applications version 2 (MERRA-2) O3 record between 2005 and 2016, within the period of Aura Microwave Limb Sounder (MLS) and Aura Ozone Monitoring Instrument (OMI) assimilation. These two climatologies consist of local solar time, longitudinal (15◦ ), and latitudinal (10◦ ) dependent monthly mean O3 profiles and the corresponding covariances, which are parameterized respectively by tropopause pressure and total O3 column. They are validated through comparisons, which show good agreements with previous O3 profile climatologies. Compared to a monthly zonal mean climatology, both tropopause- and column-dependent climatologies provide improved a priori information for profile and total O3 retrievals from remote sensing measurements. Furthermore, parameterization of O3 profile with total column usually reduces the natural variability of the resulting climatological profile in the upper stratosphere further than the tropopause parameterization, which usually performs better in the upper troposphere and lower stratosphere (UTLS). Therefore tropopause-dependent climatology is more appropriate for profile O3 retrieval for complementing the vertical resolution of backscattered ultraviolet (UV) spectra, while the column-dependent climatology is more suited for use in total O3 retrieval algorithms, with an advantage of complete profile specification without requiring ancillary information. Compared to previous column-dependent climatologies, the new MERRA-2 column-dependent climatology better captures the diurnal, seasonal, and spatial variations and dynamical changes of O3 profiles with higher resolutions in O3 , latitude, longitude, and season. The new MERRA-2 climatologies contain first quantitative characterization of O3 profile covariances, which facilitate a new approach to improve O3 profiles using the most probable patterns of profile adjustments represented by the empirical orthogonal functions (EOFs) of the covraniance matrices. The MERRA-2 daytime column-dependent climatology is used in the combo O3 and SO2 algorithm for retrieval from the Earth Polychromatic Imaging Camera (EPIC) onboard the Deep Space Climate Observatory (DSCOVR) satellite, the Ozone Mapping and Profiler Suite Nadir Mapper (OMPS-NM) on the Suomi National Polar Partnership (SNPP), and the Ozone Monitoring Instrument (OMI) on the Aura spacecraft.