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New observations of the vertically integrated CO2 mixing ratio, CO2 , from ground-based remote sensing show that variations in CO2 are primarily determined by large-scale flux patterns. They therefore provide fundamentally different information than observations made within the boundary layer, which reflect the combined influence of large-scale and local fluxes. Observations of both CO2 and CO2 concentrations in the free troposphere show that large-scale spatial gradients induce synoptic-scale temporal variations in CO2 in the Northern Hemisphere midlatitudes through horizontal advection. Rather than obscure the signature of surface fluxes on atmospheric CO2 , these synopticscale variations provide useful information that can be used to reveal the meridional flux distribution. We estimate the meridional gradient in CO2 from covariations in CO2 and potential temperature, θ, a dynamical tracer, on synoptic timescales to evaluate surface flux estimates commonly used in carbon cycle models. We find that simulations using Carnegie Ames Stanford Approach (CASA) biospheric fluxes underestimate both the CO2 seasonal cycle amplitude throughout the Northern Hemisphere midlatitudes and the meridional gradient during the growing season. Simulations using CASA net ecosystem exchange (NEE) with increased and phase-shifted boreal fluxes better fit the observations. Our simulations suggest that climatological mean CASA fluxes underestimate boreal growing season NEE (between 45–65◦ N) by ∼40 %. We describe the implications for this large seasonal exchange on inference of the net Northern Hemisphere terrestrial carbon sink.