46 1001 MOORE, FRED; RAY, ERIC; ELKINS, JAMES U.S. DEPT OF COMMERCE, NOAA / CMDL / HATS LACE/OMS SOLVE 1 1 2000 03 05 2000 08 01 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 16 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 9999 999 CCl3F (F11) MIXING RATIO (PPT) CCl3F (F11) ERROR 1-sd (PPT) N2O MIXING RATIO (PPB) N2O ERROR 1-sd (PPB) SF6 MIXING RATIO (PPT) SF6 ERROR 1-sd (PPT) CCl2F2 (F12) MIXING RATIO (PPT) CCl2F2 (F12) ERROR 1-sd (PPT) CBrClF2 (H1211) MIXING RATIO (PPT) CBrClF2 (H1211) ERROR 1-sd (PPT) H2 MIXING RATIO (PPB) H2 ERROR 1-sd (PPB) CH4 MIXING RATIO (PPB) CH4 ERROR 1-sd (PPB) CO MIXING RATIO (PPB) CO ERROR 1-sd (PPB) 15 --------------------------------------------------------------------------------- Submitted error bars include all the statistical uncertainty in going from raw data to final data. --------------------------------------------------------------------------------- An additional 1% to 2% systematic in the assigned value of our calibration standards must also be applied when comparing LACE data to other data sets. --------------------------------------------------------------------------------- H2 data with values above 575 ppb will have larger error bars until a calibration point near1000 ppb has been added to the calibration curve. --------------------------------------------------------------------------------- CO data is not submitted due to a possible systematic that will be investigated in the lab. (CO data available on request.) --------------------------------------------------------------------------------- ACATS/LACE intercomparison reveals good agreement on all molecules except for CFC-11 for mixing ratios greater than 150 ppt were ACATS numbers are approximately 5 to 10 ppt lower. --------------------------------------------------------------------------------- 1 GMTs F11 F11e N2O N2Oe SF6 SF6e F12 F12e H1211 H1211e H2 H2e CH4 CH4e CO COe 55624 268.57 3 318.11 1.9664 4.6273 0.0385 537.99 3.9299 3.9771 0.1126 9999 999 9999 999 9999 999 55694 268.46 3 316.72 1.9595 4.6041 0.0385 540.55 3.9472 4.0801 0.1135 500.41 11.988 1842.2 8.632 9999 999 55764 269.94 3 317.2 1.9619 4.6171 0.0385 538.93 3.9363 3.9494 0.1124 9999 999 9999 999 9999 999 55834 268.67 3 316.44 1.9582 4.6161 0.0385 540.69 3.9481 4.0183 0.113 503.63 12.001 1835.3 8.6233 9999 999 55904 271.69 3 317 1.9609 4.6636 0.0386 538.85 3.9357 3.8989 0.1119 9999 999 9999 999 9999 999 56044 270.94 3 316.62 1.959 4.5998 0.0385 538.19 3.9313 3.7795 0.1109 9999 999 9999 999 9999 999 56114 264.8 3 312.98 1.9413 4.4419 0.0384 532.93 3.8958 3.807 0.1111 524.7 12.091 1775.5 8.5499 9999 999 56184 269.65 3 313.6 1.9443 4.526 0.0384 535.25 3.9115 3.7406 0.1106 9999 999 9999 999 9999 999 56254 262.45 3 310.24 1.9281 4.4066 0.0383 530.65 3.8804 3.7944 0.111 528.25 12.107 1761.7 8.5332 9999 999 56324 268.54 3 310.74 1.9305 4.4915 0.0384 534.56 3.9068 3.7586 0.1107 9999 999 9999 999 9999 999 56464 267.05 3 309.04 1.9223 4.4117 0.0383 529.65 3.8737 3.6864 0.1102 9999 999 9999 999 9999 999 56534 257.87 3 305.43 1.9052 4.3424 0.0383 525.28 3.8442 3.7073 0.1103 535.2 12.137 1739.9 8.507 9999 999 56604 259.7 3 303.91 1.8981 4.3269 0.0383 520.46 3.8117 3.5747 0.1093 9999 999 9999 999 9999 999 56674 252.79 3 301.68 1.8878 4.2622 0.0382 517.42 3.7911 3.5519 0.1091 526.27 12.098 1693.6 8.4522 9999 999 56744 255.97 3 300.94 1.8844 4.2591 0.0382 514.54 3.7717 3.4886 0.1087 9999 999 9999 999 9999 999 56884 249.91 3 298.33 1.8725 4.2121 0.0381 511.05 3.7482 3.3978 0.108 9999 999 9999 999 9999 999 56954 244.95 3 295.45 1.8594 4.2254 0.0382 505.48 3.7107 3.347 0.1077 536.92 12.145 1693.6 8.4522 9999 999 57024 239.77 3 293.42 1.8503 4.169 0.0381 500.5 3.6771 3.2285 0.1069 9999 999 9999 999 9999 999 57094 237.91 3 293 1.8485 4.1509 0.0381 499.57 3.6709 3.221 0.1069 537.1 12.146 1656.4 8.4091 9999 999 57164 226.04 3 285.9 1.8175 4.0835 0.038 484.26 3.5683 2.9839 0.1054 9999 999 9999 999 9999 999 57304 259.36 3 304.52 1.901 4.3156 0.0382 522.02 3.8222 3.5717 0.1093 9999 999 9999 999 9999 999 57374 224.76 3 283.28 1.8063 4.0807 0.038 484.96 3.573 3.0088 0.1056 9999 999 1624.1 8.3721 9999 999 57444 208.15 3 273.98 1.7677 3.9273 0.0379 460.06 3.4082 2.5544 0.1033 9999 999 9999 999 9999 999 57514 199.19 3 268.47 1.7457 3.9251 0.0379 452.18 3.3567 2.4715 0.1029 543.61 12.175 1557.2 8.2975 9999 999 57584 191.75 3 264.6 1.7306 3.8701 0.0378 439.9 3.2774 2.3089 0.1023 9999 999 9999 999 9999 999 57724 163.6 3 250.1 1.6768 3.7638 0.0378 405.2 3.0603 1.8251 0.1008 9999 999 9999 999 9999 999 57794 154.26 3 245.2 1.6596 3.7454 0.0377 400.47 3.0317 1.7611 0.1007 544.23 12.178 1462.8 8.1965 9999 999 57864 153.7 3 245.17 1.6595 3.7238 0.0377 394.66 2.9968 1.6892 0.1005 9999 999 9999 999 9999 999 57934 122.79 3 227.19 1.6005 3.6008 0.0376 359.33 2.7939 1.266 0.0998 541.08 12.164 1380.6 8.1127 9999 999 58004 114.84 3 218.36 1.5739 3.5627 0.0376 341.52 2.6981 1.1115 0.0996 9999 999 9999 999 9999 999 58144 101.16 3 208.8 1.5469 3.5154 0.0376 322.23 2.5998 0.8519 0.0994 9999 999 9999 999 9999 999 58214 97.602 3 207.65 1.5438 3.4937 0.0375 318.5 2.5815 0.785 0.0994 550.46 12.206 1314.6 8.0484 9999 999 58284 64.952 3 179.38 1.4751 3.3644 0.0374 263.76 2.3399 0.3377 0.0995 9999 999 9999 999 9999 999 58354 48.089 3 162.54 1.4414 3.3074 0.0374 233.06 2.2276 0.197 0.0996 542.25 12.169 1135.9 7.8877 9999 999 58424 37.074 3 149.67 1.419 3.2887 0.0374 206.74 2.1449 0.0984 0.0997 9999 999 9999 999 9999 999 58564 28.398 3 136.49 1.3991 3.2156 0.0373 183.52 2.082 -0.0219 0.0999 9999 999 9999 999 9999 999 58634 23.399 3 126.82 1.3864 3.2005 0.0373 166.03 2.0408 -0.0177 0.0999 534.59 12.135 994.74 7.7755 9999 999 58704 21.548 3 122 1.3806 3.2037 0.0373 157.64 2.0228 -0.0023 0.0998 9999 999 9999 999 9999 999 58844 11.476 3 91.037 1.352 3.1226 0.0373 107.36 1.9382 -0.0118 0.0998 9999 999 9999 999 9999 999 58984 5.8036 3 72.011 1.3413 3.0513 0.0372 73.052 1.9013 -0.0172 0.0999 9999 999 9999 999 9999 999 59054 3.9379 3 57.692 1.3364 3.0311 0.0372 54.093 1.8875 -0.0041 0.0998 524.89 12.092 710.41 7.591 9999 999 59124 2.7465 3 50.186 1.335 3.0617 0.0372 41.695 1.8809 9999 999 9999 999 9999 999 9999 999 59194 1.8733 3 41.271 1.3342 3.0124 0.0372 29.219 1.8761 9999 999 513.23 12.042 623.33 7.5462 9999 999 59264 1.4824 3 35.234 1.3342 2.9287 0.0371 21.874 1.8741 9999 999 9999 999 9999 999 9999 999 59404 1.2914 3 26.222 1.335 2.8927 0.0371 11.493 1.8723 9999 999 9999 999 9999 999 9999 999 59474 0.9883 3 21.701 1.3359 2.9229 0.0371 7.9533 1.872 9999 999 502.72 11.998 492.2 7.4893 9999 999 59544 1.5832 3 20.123 1.3362 2.9218 0.0371 9.7042 1.8722 9999 999 9999 999 9999 999 9999 999 59614 1.0701 3 18.008 1.3367 2.9765 0.0372 5.199 1.8719 9999 999 489.62 11.943 441.84 7.4709 9999 999 59684 0.9581 3 17.721 1.3368 2.8388 0.0371 5.3028 1.8719 9999 999 9999 999 9999 999 9999 999 59824 1.0389 3 14.888 1.3376 2.8253 0.0371 4.0516 1.8718 9999 999 9999 999 9999 999 9999 999 59894 1.0598 3 14.721 1.3376 2.7757 0.037 4.3956 1.8718 9999 999 481.36 11.91 416.1 7.4623 9999 999 59964 1.1124 3 14.22 1.3378 2.8286 0.0371 4.4935 1.8718 9999 999 9999 999 9999 999 9999 999 60034 1.0369 3 15.739 1.3373 2.8424 0.0371 6.0553 1.8719 9999 999 477.98 11.896 422.36 7.4644 9999 999 60104 1.1058 3 15.496 1.3374 2.7946 0.0371 6.6351 1.8719 9999 999 9999 999 9999 999 9999 999 60244 1.1733 3 15.366 1.3374 2.774 0.037 7.4869 1.872 9999 999 9999 999 9999 999 9999 999 60314 1.1831 3 16.059 1.3373 2.773 0.037 8.6679 1.8721 9999 999 443.33 11.761 357.57 7.4445 9999 999 60384 1.6477 3 16.683 1.3371 2.8133 0.0371 9.917 1.8722 9999 999 9999 999 9999 999 9999 999 60454 1.0585 3 11.59 1.3386 2.6856 0.037 5.5132 1.8719 9999 999 416.99 11.664 298.62 7.4293 9999 999 60524 2.3661 3 10.182 1.3391 2.5753 0.0369 10.038 1.8722 9999 999 9999 999 9999 999 9999 999 60664 1.1341 3 9.2802 1.3394 2.5889 0.0369 3.1918 1.8718 9999 999 9999 999 9999 999 9999 999 60734 1.0647 3 8.7536 1.3396 2.5438 0.0369 2.4092 1.8718 9999 999 433.61 11.725 275.51 7.4241 9999 999 60804 1.232 3 7.363 1.3402 2.412 0.0368 1.3096 1.8718 9999 999 9999 999 9999 999 9999 999 60874 1.4601 3 9999 999 2.4357 0.0369 2.1468 1.8718 9999 999 539.94 12.158 262.63 7.4214 9999 999 60944 1.1764 3 6.4981 1.3405 2.3999 0.0368 1.1195 1.8718 9999 999 9999 999 9999 999 9999 999 61084 1.1867 3 6.9869 1.3403 2.4275 0.0368 1.05 1.8718 9999 999 9999 999 9999 999 9999 999 61154 1.3065 3 7.3319 1.3402 2.4482 0.0369 0.9897 1.8718 9999 999 558.06 12.24 270.07 7.423 9999 999 61224 1.4415 3 8.0963 1.3399 2.43 0.0368 1.8985 1.8718 9999 999 9999 999 9999 999 9999 999 61294 2.1896 3 11.656 1.3386 2.4633 0.0369 5.7494 1.8719 9999 999 585.29 12.367 284.67 7.4261 9999 999 61364 1.2608 3 6.6088 1.3405 2.4846 0.0369 0.9243 1.8718 9999 999 9999 999 9999 999 9999 999 61504 1.2809 3 6.8661 1.3404 2.3902 0.0368 0.8647 1.8718 9999 999 9999 999 9999 999 9999 999 61574 1.3295 3 6.2838 1.3406 2.3512 0.0368 0.6776 1.8718 9999 999 688.43 12.887 270.47 7.423 9999 999 61644 1.9927 3 7.0219 1.3403 2.3125 0.0368 3.682 1.8718 9999 999 9999 999 9999 999 9999 999 61714 1.2192 3 5.1147 1.3411 2.3074 0.0368 0.5971 1.8718 9999 999 716.8 13.041 261.05 7.4211 9999 999 61784 1.2218 3 4.8406 1.3412 2.2622 0.0368 -0.0248 1.8718 9999 999 9999 999 9999 999 9999 999 61924 1.4176 3 5.2311 1.341 2.0045 0.0366 0.4992 1.8718 9999 999 9999 999 9999 999 9999 999 61994 1.4086 3 5.0828 1.3411 1.9587 0.0366 0.5492 1.8718 9999 999 934.66 14.355 225.53 7.4143 9999 999 62064 1.2885 3 4.9081 1.3412 1.9216 0.0366 0.5263 1.8718 9999 999 9999 999 9999 999 9999 999 62134 1.3919 3 3.8359 1.3416 1.8668 0.0366 -0.0594 1.8718 9999 999 985.88 14.694 190.08 7.4084 9999 999 62204 1.5018 3 3.9746 1.3415 1.829 0.0366 0.4565 1.8718 9999 999 9999 999 9999 999 9999 999 62344 1.4447 3 4.0781 1.3415 1.8519 0.0366 0.4565 1.8718 9999 999 9999 999 9999 999 9999 999 62414 1.3902 3 4.0043 1.3415 1.8135 0.0366 -0.0014 1.8718 9999 999 1013.7 14.882 186.01 7.4078 9999 999 62484 2.1172 3 9999 999 1.9696 0.0366 2.8541 1.8718 9999 999 9999 999 9999 999 9999 999 62554 1.3684 3 4.2784 1.3414 1.9202 0.0366 -0.025 1.8718 9999 999 972.09 14.602 200.86 7.4101 9999 999 62624 1.492 3 3.746 1.3416 1.8492 0.0366 -0.0055 1.8718 9999 999 9999 999 9999 999 9999 999 62764 1.9042 3 5.6173 1.3409 1.9493 0.0366 3.1298 1.8718 9999 999 9999 999 9999 999 9999 999 62834 1.527 3 3.8113 1.3416 1.9289 0.0366 -0.025 1.8718 9999 999 968.17 14.576 211.69 7.4119 9999 999 62904 1.4572 3 3.7442 1.3416 1.9333 0.0366 0 1.8718 9999 999 9999 999 9999 999 9999 999 63044 1.5261 3 4.0909 1.3415 1.9531 0.0366 0.462 1.8718 9999 999 9999 999 9999 999 9999 999 63184 1.5008 3 3.9458 1.3416 1.9944 0.0366 -0.0251 1.8718 9999 999 9999 999 9999 999 9999 999 63254 1.8756 3 7.1344 1.3402 1.854 0.0366 2.1247 1.8718 9999 999 1002.4 14.806 209.66 7.4115 9999 999 63324 1.8886 3 5.5574 1.3409 1.8842 0.0366 2.53 1.8718 9999 999 9999 999 9999 999 9999 999 63394 1.8446 3 7.3028 1.3402 1.8959 0.0366 3.1503 1.8718 9999 999 1032.4 15.011 197.16 7.4095 9999 999 63464 1.5805 3 3.2139 1.3419 1.8391 0.0366 -0.0251 1.8718 9999 999 9999 999 9999 999 9999 999 63604 1.7006 3 4.5581 1.3413 1.8592 0.0366 0.0006 1.8718 9999 999 9999 999 9999 999 9999 999 63674 1.6378 3 5.3803 1.341 1.8737 0.0366 0.6349 1.8718 9999 999 1027 14.973 195.61 7.4093 9999 999 63744 2.8737 3 4.8612 1.3412 1.8569 0.0366 9999 999 9999 999 9999 999 9999 999 9999 999 63814 1.6756 3 3.1552 1.3419 1.8307 0.0366 0.9412 1.8718 9999 999 1038.8 15.055 189.92 7.4084 9999 999 63884 1.5444 3 5.1566 1.341 1.7853 0.0365 -0.0034 1.8718 9999 999 9999 999 9999 999 9999 999 64024 1.4799 3 3.5039 1.3418 1.8598 0.0366 -4.5271 1.8719 9999 999 9999 999 9999 999 9999 999 64094 1.5016 3 2.9071 1.342 1.8139 0.0366 -0.0252 1.8718 9999 999 1056.7 15.179 191.68 7.4087 9999 999 64164 1.4992 3 3.1843 1.3419 1.8442 0.0366 -0.0252 1.8718 9999 999 9999 999 9999 999 9999 999 64234 1.486 3 2.931 1.342 1.8352 0.0366 -0.0252 1.8718 9999 999 1046.9 15.11 199.48 7.4099 9999 999 64304 1.5326 3 2.73 1.3421 1.8088 0.0366 -0.0252 1.8718 9999 999 9999 999 9999 999 9999 999 64444 1.4654 3 3.0748 1.3419 1.8663 0.0366 -4.9245 1.872 9999 999 9999 999 9999 999 9999 999 64514 1.5584 3 3.134 1.3419 1.8322 0.0366 -0.0253 1.8718 9999 999 1002.9 14.809 209.59 7.4115 9999 999 64584 1.5242 3 3.99 1.3415 1.9177 0.0366 0.4885 1.8718 9999 999 9999 999 9999 999 9999 999 64654 1.5206 3 4.0107 1.3415 1.9316 0.0366 0.4612 1.8718 9999 999 962.24 14.536 225.64 7.4143 9999 999 64724 1.5873 3 4.0173 1.3415 1.9135 0.0366 -0.0253 1.8718 9999 999 9999 999 9999 999 9999 999 64864 1.447 3 4.9096 1.3412 2.0103 0.0366 0.7396 1.8718 9999 999 9999 999 9999 999 9999 999 64934 1.5095 3 5.0096 1.3411 2.0205 0.0366 3.1563 1.8718 9999 999 879.97 14.005 240.62 7.417 9999 999 65004 1.5407 3 3.8401 1.3416 2.0457 0.0367 -0.0253 1.8718 9999 999 9999 999 9999 999 9999 999 65074 1.5518 3 3.9168 1.3416 2.1566 0.0367 -0.7299 1.8718 9999 999 822.69 13.652 245.55 7.418 9999 999 65144 1.4481 3 4.2416 1.3414 2.2859 0.0368 -0.0254 1.8718 9999 999 9999 999 9999 999 9999 999 65284 1.6117 3 7.6343 1.3401 2.4003 0.0368 9999 999 9999 999 9999 999 9999 999 9999 999 65354 1.4227 3 5.7217 1.3408 2.3789 0.0368 0.7989 1.8718 9999 999 684.89 12.868 284.37 7.4261 9999 999 65424 1.3483 3 5.1364 1.3411 2.4581 0.0369 0.5011 1.8718 9999 999 9999 999 9999 999 9999 999 65494 1.3973 3 5.3282 1.341 2.433 0.0368 -0.004 1.8718 9999 999 627.1 12.57 284.65 7.4261 9999 999 65564 1.564 3 8.7861 1.3396 2.4462 0.0369 9999 999 9999 999 9999 999 9999 999 9999 999 65704 1.5208 3 6.6869 1.3404 2.4436 0.0369 1.005 1.8718 9999 999 9999 999 9999 999 9999 999 65774 1.3722 3 6.0168 1.3407 2.4152 0.0368 0.803 1.8718 9999 999 610.32 12.487 293.97 7.4283 9999 999 65844 1.45 3 6.0322 1.3407 2.3796 0.0368 0.7279 1.8718 9999 999 9999 999 9999 999 9999 999 65914 1.3951 3 6.2143 1.3406 2.4022 0.0368 0.9506 1.8718 9999 999 552.2 12.213 283.89 7.426 9999 999 65984 1.4792 3 6.3885 1.3405 2.3974 0.0368 1.114 1.8718 9999 999 9999 999 9999 999 9999 999 66124 1.4261 3 8.3161 1.3398 2.5522 0.0369 2.1003 1.8718 9999 999 9999 999 9999 999 9999 999 66194 1.3316 3 9.3554 1.3394 2.6243 0.037 2.975 1.8718 9999 999 438.37 11.742 303.08 7.4304 9999 999 66264 1.4989 3 9.9935 1.3392 2.6283 0.037 3.5981 1.8718 9999 999 9999 999 9999 999 9999 999 66334 1.4411 3 10.454 1.339 2.6533 0.037 4.1532 1.8718 9999 999 435.9 11.733 309.46 7.4319 9999 999 66404 1.4729 3 14.495 1.3377 2.7538 0.037 7.4878 1.872 9999 999 9999 999 9999 999 9999 999 66544 1.481 3 14.464 1.3377 2.7632 0.037 6.5727 1.8719 9999 999 9999 999 9999 999 9999 999 66614 1.2666 3 14.401 1.3377 2.8607 0.0371 3.8929 1.8718 9999 999 501.56 11.993 443.13 7.4714 9999 999 66684 2.6942 3 47.376 1.3346 3.0524 0.0372 35.511 1.8783 9999 999 9999 999 9999 999 9999 999 66754 17.478 3 113 1.3708 3.1811 0.0373 136.04 1.9817 9999 999 536.9 12.145 964.49 7.7532 9999 999 66824 36.708 3 150.94 1.4211 3.3324 0.0374 201.71 2.1304 9999 999 9999 999 9999 999 9999 999 66964 143.29 3 243.82 1.6548 3.7779 0.0378 380.78 2.9152 9999 999 9999 999 9999 999 9999 999 67034 195.86 3 273.68 1.7665 3.9858 0.0379 448.97 3.3359 9999 999 546.24 12.187 1568 8.3094 9999 999 67104 210.26 3 282.18 1.8016 4.0404 0.038 461.39 3.4169 9999 999 9999 999 9999 999 9999 999