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NOAA Nitrogen Oxides and Ozone

The NOAA NOyO3 4-channel chemiluminescence (CL) instrument will provide in-situ measurements of nitric oxide (NO), nitrogen dioxide (NO2), total reactive nitrogen oxides (NOy), and ozone (O3) on the NASA DC-8 during the FIREX-AQ project. Different versions of this instrument have flown on the NASA DC-8 and NOAA WP-3D research aircraft on field projects since 1995. It provides fast-response, specific, high precision, and calibrated measurements of nitrogen oxides and ozone at a spatial resolution of better than 100m at typical DC-8 research flight speeds. Detection is based on the gas-phase CL reaction of NO with O3 at low pressure, resulting in photoemission from electronically excited NO2. Photons are detected and quantified using pulse counting techniques, providing ~5 to 10 part-per-trillion by volume (pptv) precision at 1 Hz data rates. One detector of the integrated 4-channel instrument is used to measure ambient NO directly, a second detector is equipped with a UV-LED converter to photodissociate ambient NO2 to NO, and a third detector is equipped with a heated gold catalyst to reduce ambient NOy species to NO. Reagent ozone is added to these sample streams to drive the CL reactions with NO. Ambient O3 is detected in the fourth channel by adding reagent NO.

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Quantum Cascade Laser System

The Harvard QCLS (DUAL and CO2) instrument package contains 2 separate optical assemblies and calibration systems, and a common data system and power supply. The two systems are mounted in a single standard HIAPER rack, and are described separately below:

The Harvard QCL DUAL instrument simultaneously measures CO, CH4, and N2O concentrations in situ using two thermoelectrically cooled pulsed-quantum cascade lasers (QCL) light sources, a multiple pass absorption cell, and two liquid nitrogen-cooled solid-state detectors. These components are mounted on a temperature-stabilized, vibrationally isolated optical bench with heated cover. The sample air is preconditioned using a Nafion drier (to remove water vapor), and is reduced in pressure to 60 mbar using a Teflon diaphragm pump. The trace gas mixing ratios of air flowing through the multiple pass absorption cell are determined by measuring absorption from their infrared transition lines at 4.59 microns for CO and 7.87 microns for CH4 and N2O using molecular line parameters from the HITRAN data base. In-flight calibrations are performed by replacing the air sample with reference gas every 10 minutes, with a low-span and a high-span gas every 20 minutes. A prototype of this instrument was flown on the NOAA P3 in the summer of 2004.

The Harvard QCL CO2 instrument measures CO2 concentrations in situ using a thermoelectrically cooled pulsed-quantum cascade laser (QCL) light source, gas cells, and liquid nitrogen cooled solid-state detectors. These components are stabilized along the detection axis, vibrationally isolated, and housed in a temperature-controlled pressure vessel. Sample air enters a rear-facing inlet, is preconditioned using a Nafion drier (to remove water vapor), then is reduced in pressure to 60 mbar using a Teflon diaphragm pump. A second water trap, using dry ice, reduces the sample air dewpoint to less than –70C prior to detection. The CO2 mixing ratio of air flowing through the sample gas cell is determined by measuring absorption from a single infrared transition line at 4.32 microns relative to a reference gas of known concentration. In-flight calibrations are performed by replacing the air sample with reference gas every 10 minutes, and with a low-span and a high-span gas every 20 minutes.

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Trace Organic Gas Analyzer

TOGA measures volatile organic compounds (VOCs). Specific data will be obtained for radical precursors, tracers of anthropogenic and biogenic activities, tracers of urban and biomass combustion emissions, products of oxidative processing, precursors to aerosol formation, and compounds important for aerosol modification and transformation. TOGA measures a wide range of VOCs with high sensitivity (ppt or lower), frequency (2.0 min.), accuracy (15% or better), and precision (<3%). Over 50 species are routinely measured (see PDF for full table) throughout the full DC-8 altitude range. TOGA is contained in a standard DC-8 rack, weighs less than 200 kg and consumes ~1 kW of power. The major components of the instrument are the inlet, cryogenic preconcentrator, gas chromatograph, mass spectrometer detector, zero air/calibration system, and the control/data acquisition system. All processes and data acquisition are computer controlled.

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DC-8 - AFRC, NSF G-V
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CU Aircraft High-Resolution Time-of-Flight Aerosol Mass Spectrometer

Principle: The CU aircraft version of the Aerodyne High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) detects non-refractory submicron aerosol composition by impaction on a vaporizer at 600°C, followed by electron ionization and time-of-flight mass spectral analysis. Size-resolved composition can be quantified by measuring the arrival times of the aerosol at the vaporizer.

Aircraft Operation: (1 min cycles, can be adjusted to meet mission goals):
46 s total concentration measurements (1 s resolution, can be increased to up to 10 Hz upon request)
5 s speciated size distribution measurements (with improved S/N detection due to ePToF acquisition)
9 s Background + Overhead
Higher accuracy due to flight day calibrations using built-in system
Custom pressure controlled inlet with confirmed performance up to 41 kft

Real Time Data Products: 
PM1 Aerosol Mass Concentrations:
Organic aerosol (OA) , SO4, NO3, NH4, Chloride 
OA Chemical Markers: f44 (Secondary OA), f57 (hydrocarbon-like OA), f60 (biomass burning OA), f82 (isoprene epoxide-SOA), other fx upon request

More Advanced Products:
- PM1 Seasalt, ClO4, total I, total Br, MSA concentrations
- O/C, H/C, OA/OC, OSc
- Particle organic nitrates (pRONO2)
- Ammonium Balance, estimated pH
- OA components by positive matrix factorization (PMF)
- Particle eddy covariance fluxes of all species

Detection Limits (1s, ng sm-3), (1 min, ng sm-3) from start of the flight (due to custom cyropump):
Sulfate: 40, 15
Nitrate: 15, 6
Ammonium: 3, 1
Chloride: 30, 12
OA: 200, 80
For detailed OA analysis, longer averaging (3-30 s, depending on OA concentration) is needed. A 1 min product is hence provided as well.

 

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UAS Chromatograph for Atmospheric Trace Species

The Unmanned Aircraft Systems (UAS) Chromatograph for Atmospheric Trace Species (UCATS) was designed and built for autonomous operation on pilotless aircraft. It uses chromatography to separate atmospheric trace gases along a narrow heated column, followed by precise and accurate detection with electron capture detectors. There are two chromatographs on UCATS, one of which measures nitrous oxide and sulfur hexafluoride, the other of which measures methane, hydrogen, and carbon monoxide. In addition, there is a small ozone instrument and a tunable diode laser instrument for water vapor. Gas is pumped into the instruments from an inlet below the GV, measured, and vented. UCATS has flown on the Altair UAS, the GV during HIPPO I and II, and most recently on the NASA/NOAA Global Hawk UAS during the Global Hawk Pacific (GloPac) mission, where a record was set for the longest duration research flight (more than 28 hours). UCATS is relatively lightweight and compact, making it ideal for smaller platforms, but it is easily adaptable to a mid-size platform like the GV for HIPPO. The data are used to measure sources and sinks of trace gases involved in climate and air quality, as well as transport through the atmosphere.

UCATS is three different instruments in one enclosure:

1. 2-channel gas chromatograph (GC)
2. Dual-beam ozone photometer (OZ)
3. Tunable diode laser (TDL) spectrometer for water vapor (WV)

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N2O, SF6, CH4, CO, O3, H2, H2O
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Soluble Acidic Gases and Aerosols

As part of the measurement team on the NASA DC-8 we operate two related installations: a mist chamber/ion chromatograph (MC/IC) sampling/analysis system providing near real time results for selected species, and a bulk aerosol system that collects particulates onto filters for subsequent analysis. We use ion chromatography on aqueous extracts of the bulk aerosol samples collected on Teflon filters to quantify soluble ions (Cl-, Br-, NO3-, SO42-, C2O42-, Na+, NH4+, K+, Ca+, and Mg+). Filters are exposed on all level flight legs. Below 3 km exposure times are 5 minutes or less, increasing at higher altitudes to a maximum sample time of 15 minutes. Aerosols participate in heterogeneous chemistry, impact radiative transfer, and can be detected from space. Our measurements help to validate and extend retrievals of aerosol distributions and properties by MODIS, MISR and CALIPSO. In addition, several of the particle-associated ions are tracers of sources of gas and aerosol pollutants (e.g., SO42- from industrial emissions of SO2, enhancements of C2O42-, K+, and NH4+ indicate encounters with biomass burning plumes, Na+, and Cl- are tracers of seasalt, Mg2+ and Ca2+ are tracers of dust). Our system has two inlets, allowing collection of paired samples simultaneously.

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Chemical Ionization Mass Spectrometer

The CIMS instrument consists of a low pressure ion molecule reactor (IMR) coupled to a quadrupole mass filter by an actively pumped collisional dissociation chamber (CDC) and an octopole ion guide. The vacuum system is a 100 mm outer diameter stainless steel chamber evacuated with two small turbo pumps (70 l s-1). The mass filter is a set of 9.5 mm diameter quadrupole rods housed in the main vacuum chamber. The CDC is a short 80 mm diameter chamber that houses an octopole ion guide and is evacuated with a hybrid molecular drag pump. The IMR is evacuated with a scroll pump (300 l min-1) that also serves as the backing pump for the mass spectrometer.

Click here for the Collaborative Ground and Airborne Observations description page.

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DC-8 - AFRC, NSF G-V
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Single Particle Soot Photometer (NOAA)

The SP2 is a laser-induced incandescence instrument primarily used for measuring the BC mass content of individual particles. It is able to provide this data product independently of the total particle morphology and mixing state, and thus delivers detailed information not only about BC loadings, but also size distributions, even in exceptionally clean air. The instrument can also provide the optical size of individual particles containing BC, and identify the presence of coatings associated with the BC fraction (i.e. identify the BC’s mixing state). Since its introduction in 2003, the SP2 has been substantially improved, and now can be considered a highly competent instrument for assessing BC loadings and mixing state in situ.

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Whole Air Sampler

The UC-Irvine research group proposes to collect whole air samples aboard the NASA DC-8 aircraft during the 2012 campaign of the Southeast Asia Composition, Cloud, Climate Coupling Regional Study (SEAC4RS) field mission. More than 70 trace gases will be identified and quantified at our Irvine laboratory, including C2-C10 NMHCs, C1-C2 halocarbons, C1-C5 alkyl nitrates, and selected sulfur compounds. This will be achieved using our established technique of airborne whole air sampling followed by laboratory analysis using gas chromatography (GC) with flame ionization detection (FID), electron capture detection (ECD), and mass spectrometric detection (MSD). Our experimental procedures will build on those that have been successfully employed for numerous prior NASA field missions, for example PEMTropics B, TRACE-P, INTEX-A and B, and ARCTAS.

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Particle Analysis By Laser Mass Spectrometry

The NOAA PALMS instrument measures single-particle aerosol composition using UV laser ablation to generate ions that are analyzed with a time-of-flight mass spectrometer.  The PALMS size range is approximately 150 to >3000 nm and encompasses most of the accumulation and coarse mode aerosol volume. Individual aerosol particles are classified into compositional classes.  The size-dependent composition data is combined with aerosol counting instruments from Aerosol Microphysical Properties (AMP), the Langley Aerosol Research Group Experiment (LARGE), and other groups to generate quantitative, composition-resolved aerosol concentrations.  Background tropospheric concentrations of climate-relevant aerosol including mineral dust, sea salt, and biomass burning particles are the primary foci for the ATom campaigns.  PALMS also provides a variety of compositional tracers to identify aerosol sources, probe mixing state, track particle aging, and investigate convective transport and cloud processing.

*_Standard data products_**: *

Particle type number fractions: sulfate/organic/nitrate mixtures, biomass burning, EC, sea salt, mineral dust, meteoric, alkali salts, heavy fuel combustion, and other. Sampling times range from 1-5 mins.

*_Advanced data products_**:*

Number, surface area, volume, and mass concentrations of the above particle types. Total sulfate and organic mass concentrations. Relative and absolute abundance of various chemical markers and aerosol sub-components: methanesulfonic acid, sulfate acidity, organic oxidation level, iodine, bromine, organosulfates, pyridine, and other species.

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