HOx chemistry during INTEX-A 2004: Observation, model calculation, and...

Ren, X., J. Olson, J. Crawford, W. H. Brune, J. Mao, R. B. Long, Z. Chen, G. Chen, M. Avery, G. Sachse, J. Barrick, G. S. Diskin, L. G. Huey, A. Fried, R. C. Cohen, B. Heikes, P. Wennberg, H. Singh, D. R. Blake, and R. E. Shetter (2008), HOx chemistry during INTEX-A 2004: Observation, model calculation, and comparison with previous studies, J. Geophys. Res., 113, D05310, doi:10.1029/2007JD009166.

OH and HO2 were measured with the Airborne Tropospheric Hydrogen Oxides Sensor (ATHOS) as part of a large measurement suite from the NASA DC-8 aircraft during the Intercontinental Chemical Transport Experiment-A (INTEX-A). This mission, which was conducted mainly over North America and the western Atlantic Ocean in summer 2004, was an excellent test of atmospheric oxidation chemistry. The HOx results from INTEX-A are compared to those from previous campaigns and to results for other related measurements from INTEX-A. Throughout the troposphere, observed OH was generally 0.95 of modeled OH; below 8 km, observed HO2 was generally 1.20 of modeled HO2. This observed-to-modeled comparison is similar to that for TRACE-P, another midlatitude study for which the median observed-to-modeled ratio was 1.08 for OH and 1.34 for HO2, and to that for PEM-TB, a tropical study for which the median observed-tomodeled ratio was 1.17 for OH and 0.97 for HO2. HO2 behavior above 8 km was markedly different. The observed-to-modeled HO2 ratio increased from ~1.2 at 8 km to ~3 at 11 km with the observed-to-modeled ratio correlating with NO. Above 8 km, the observed-to-modeled HO2 and observed NO were both considerably greater than observations from previous campaigns. In addition, the observed-to-modeled HO2/OH, which is sensitive to cycling reactions between OH and HO2, increased from ~1.5 at 8 km to almost 3.5 at 11 km. These discrepancies suggest a large unknown HOx source and additional reactants that cycle HOx from OH to HO2. In the continental planetary boundary layer, the observed-to-modeled OH ratio increased from 1 when isoprene was less than 0.1 ppbv to over 4 when isoprene was greater than 2 ppbv, suggesting that forests throughout the United States are emitting unknown HOx sources. Progress in resolving these discrepancies requires a focused research activity devoted to further examination of possible unknown OH sinks and HOx sources.

PDF of Publication: 
Download from publisher's website.
Research Program: 
Tropospheric Composition Program (TCP)