The NCAR NOxyO3 instrument is a 4-channel chemiluminescence instrument for the measurement of NO, NO2, NOy, and O3. NOx (NO and NO2) is critical to fast chemical processes controlling radical chemistry and O3 production. Total reactive nitrogen (NOy = NO + NO2 + HNO3 + PANs + other organic nitrates + HO2NO2 + HONO + NO3 + 2*N2O5 + particulate NO3- + …) is a useful tracer for characterizing air masses since it has a tendency to be conserved during airmass aging, as NOx is oxidized to other NOy species.

NOx (NO and NO2), NOy (total reactive nitrogen), and O3 are measured using the NCAR 4-channel chemiluminescence instrument, previously flown on the NASA WB-57F and the NCAR C130. NO is measured via addition of reagent O3 to the sample flow to generate the chemiluminescent reaction producing excited NO2, which is detected by photon counting with a dry-ice cooled photomultiplier tube. NO2 is measured as NO following photolytic conversion of NO2, with a time response of about 3 sec due to the residence time in the photolysis cell. NO is measured with an identical time response due to use of a matching volume. NOy is measured via Au-catalyzed conversion of reactive nitrogen species to NO, in the presence of CO, with a time response of slightly better than 1 sec. O3 is measured using the same chemiluminescent reaction but with the addition of reagent NO to the sample flow. Time response for the ozone measurement is slightly better than 1 s.

The NASA Langley Airborne Differential Absorption Lidar (DIAL) system uses four lasers to make DIAL O3 profile measurements in the ultraviolet (UV) simultaneously with aerosol profile measurements in the visible and IR. Recent changes incorporate an additional laser and modifications to the receiver system that will provide aerosol backscatter, extinction, and depolarization profile measurements at three wavelengths (UV, visible, and NIR). For SEAC4RS, the DIAL instrument will include for the first time aerosol and cloud measurements implementing the High Spectral Resolution Lidar (HSRL) technique [Hair, 2008]. The modifications include integrating an additional 3-wavelength (355 nm, 532 nm, 1064 nm) narrowband laser and the receiver to make the following measurements; depolarization at all three wavelengths, aerosol/cloud backscatter and extinction at 532 nm via the HSRL technique, and aerosol/cloud backscatter at the 355 and 1064 nm via the standard backscatter lidar technique. Integration of the aerosol extinction profile at 532nm above and below the aircraft also provides aerosol optical depth (AOD) along the aircraft flight track.

The FSSP is of that general class of instruments called optical particle counters (OPCs) that detect single particles and size them by measuring the intensity of light that the particle scatters when passing through a light beam. A Helium Neon laser beam is focused to a diameter of 0.2 mm at the center of an inlet that faces into the oncoming airstream. This laser beam is blocked on the opposite side of the inlet with an optical stop, a "dump spot" to prevent the beam from entering the collection optics. Particles that encounter this beam scatter light in all directions and some of that scattered in the forward direction is directed by a right angle prism though a condensing lens and onto a beam splitter. The "dump spot" on the prism and aperture of the condensing lens define a collection angle from about 4º - 12º.

The beam splitter divides the scattered light into two components, each of which impinge on a photodetector. One of these detectors, however, is optically masked to receive only scattered light when the particles pass through the laser beam displaced greater than approximately 1.5 mm either side of the center of focus. Particles that fall in that region are rejected when the signal from the masked detector exceeds that from the unmasked detector. This defines the sample volume needed to calculate particle concentrations.

The Microwave Temperature Profiler (MTP) is a passive microwave radiometer, which measures the natural thermal emission from oxygen molecules in the earth’s atmosphere for a selection of elevation angles between zenith and nadir. The current observing frequencies are 55.51, 56.65 and 58.80 GHz. The measured "brightness temperatures" versus elevation angle are converted to air temperature versus altitude using a quasi-Bayesian statistical retrieval procedure. The MTP has no ITAR restrictions, has export compliance classification number EAR99/NLR. An MTP generally consists of two assemblies: a sensor unit (SU), which receives and detects the signal, and a data unit (DU), which controls the SU and records the data. In addition, on some platforms there may be a third element, a real-time analysis computer (RAC), which analyzes the data to produce temperature profiles and other data products in real time. The SU is connected to the DU with power, control, and data cables. In addition the DU has interfaces to the aircraft navigation data bus and the RAC, if one is present. Navigation data is needed so that information such as altitude, pitch and roll are available. Aircraft altitude is needed to perform retrievals (which are altitude dependent), while pitch and roll are needed for controlling the position of a stepper motor which must drive a scanning mirror to predetermined elevation angles. Generally, the feed horn is nearly normal to the flight direction and the scanning mirror is oriented at 45-degrees with respect to receiving feed horn to allow viewing from near nadir to near zenith. At each viewing position a local oscillator (LO) is sequenced through two or more frequencies. Since a double sideband receiver is used, the LO is generally located near the "valley" between two spectral lines, so that the upper and lower sidebands are located near the spectral line peaks to ensure the maximum absorption. This is especially important at high altitudes where "transparency" corrections become important if the lines are too "thin." Because each frequency has a different effective viewing distance, the MTP is able to "see" to different distances by changing frequency. In addition, because the viewing direction is also varied and because the atmospheric opacity is temperature and pressure dependent, different effective viewing distances are also achieved through scanning in elevation . If the scanning is done so that the applicable altitudes (that is, the effective viewing distance times the sine of the elevation angle) at different frequencies and elevation angles are the same, then inter-frequency calibration can also be done, which improves the quality of the retrieved profiles. For a two-frequency radiometer with 10 elevation angles, each 15-second observing cycle produces a set of 20 brightness temperatures, which are converted by a linear retrieval algorithm to a profile of air temperature versus altitude, T(z). Finally, radiometric calibration is performed using the outside air temperature (OAT) and a heated reference target to determine the instrument gain. However, complete calibration of the system to include "window corrections" and other effects, requires tedious analysis and comparison with radiosondes near the aircraft flight path. This is probably the most important single factor contributing to reliable calibration. For stable MTPs, like that on the DC8, such calibrations appear to be reliable for many years. Such analysis is always performed before MTP data are placed on mission archive computers.

The Multiple-Angle Aerosol Spectrometer Probe (MASP) determines the size and concentration of particles from about 0.3 to 20 microns in diameter and the index of refraction for selected sizes. Size is determined by measuring the light intensity scattered by individual particles as they transit a laser beam of 0.780µm wavelength. Light scattered from particles into a cone from 30 to 60 degrees forward and 120 to 150 degrees backwards is reflected by a mangin mirror through a condensing lens to the detectors. A comparison of the signals from the open aperture detector and the masked aperture detector is used to accept only those particles passing through the center of the laser beam. The size of the particle is determined from the total scattered light. The index of refraction of particles can be estimated from the ratio of the forward to back scatter signals. A calibration diode laser is pulsed periodically during flight to ensure proper operation of the electronics. The shrouded inlet minimizes angle of attack effects and maintains isokinetic flow through the sensing volume so that volatilization of particles is eliminated.

The in‐situ diode laser spectrometer system, referred to by its historical name DACOM, includes three tunable diode lasers providing 4.7, 4.5, and 3.3 μm radiation for accessing CO, N2O, and CH4 absorption lines, respectively. The three laser beams are combined by the use of dichroic filters and are then directed through a small volume (0.3 liter) Herriott cell enclosing a 36 meter optical path. As the three coincident laser beams exit the absorption cell, they are spectrally isolated using dichroic filters and are then directed to individual detectors, one for each laser wavelength. Wavelength reference cells containing CO, CH4, and N2O are used to wavelength lock the operation of the three lasers to the appropriate absorption lines. Ambient air is continuously drawn through a Rosemount inlet probe and a permeable membrane dryer which removes water vapor before entering the Herriott cell and subsequently being exhausted via a vacuum pump to the aircraft cabin. To minimize potential spectral overlap from other atmospheric species, the Herriott cell is maintained at a reduced pressure of ~90 Torr. At 5 SLPM mass flow rate, the absorption cell volume is exchanged nominally twice per second. Frequent but short calibrations with well documented and stable reference gases are critical to achieving both high precision and accuracy. Calibration for all species is accomplished by periodically (~4 minutes) flowing calibration gas through this instrument. Measurement accuracy is closely tied to the accuracy of the reference gases obtained from NOAA/ESRL, Boulder, CO. Both CO and CH4 mixing ratios are provided in real-time to investigators aboard the DC‐8.