The Harvard Water Vapor (HWV) instrument combines two independent measurement methods for the simultaneous in situ detection of ambient water vapor mixing ratios in a single duct. This dual axis instrument combines the heritage of the Harvard Lyman-α photo-fragment fluorescence instrument (LyA) with the newly designed tunable diode laser direct absorption instrument (HHH). The Lyman-α detection axis functions as a benchmark measurement, and provides a requisite link to the long measurement history of Harvard Lyman-α aboard NASA’s WB-57 and ER-2 aircraft [Weinstock et al., 1994; Hintsa et al., 1999; Weinstock et al., 2009]. The inclusion of HHH provides a second high precision measurement that is more robust than LyA to changes in its measurement sensitivity [Smith et al., in preparation]. The simultaneous utilization of radically different measurement techniques facilitates the identification, diagnosis, and constraint of systematic errors both in the laboratory and in flight. As such, it constitutes a significant step toward resolving the controversy surrounding water vapor measurements in the upper troposphere and lower stratosphere.

The Multiple-Angle Aerosol Spectrometer Probe (MASP) determines the size and concentration of particles from about 0.3 to 20 microns in diameter and the index of refraction for selected sizes. Size is determined by measuring the light intensity scattered by individual particles as they transit a laser beam of 0.780µm wavelength. Light scattered from particles into a cone from 30 to 60 degrees forward and 120 to 150 degrees backwards is reflected by a mangin mirror through a condensing lens to the detectors. A comparison of the signals from the open aperture detector and the masked aperture detector is used to accept only those particles passing through the center of the laser beam. The size of the particle is determined from the total scattered light. The index of refraction of particles can be estimated from the ratio of the forward to back scatter signals. A calibration diode laser is pulsed periodically during flight to ensure proper operation of the electronics. The shrouded inlet minimizes angle of attack effects and maintains isokinetic flow through the sensing volume so that volatilization of particles is eliminated.

The Multiple Aerosol Collection System contains an impactor collector which permits the collection of particles on electron microscope grids for later chemical-constituent analysis. The collector consists of a two stages. In the first stage the pressure of the sample is reduced by a factor of two without loosing particles by impaction on walls. The second stage consists of a thin plate impactor which collects efficiently even at small Reynolds numbers. The system collects particles as small as 0.02 micron at WB-57 cruise altitudes. As many as 24 samples can be collected in a flight.

OH is detected by direct laser induced fluorescence in the (0-1) band of the 2?-2? electronic transition. A pulsed dye-laser system produces frequency tunable laser light at 282 nm. An on-board frequency reference cell is used by a computer to lock the laser to the appropriate wavelength. Measurement of the signal is then made by tuning the laser on and off resonance with the OH transition.

Stratospheric air is channeled into the instrument using a double-ducted system that both maintains laminar flow through the detection region and slows the flow from free stream velocity (200 m/s) to 40 m/s. The laser light is beam-split and directed to two detection axes where it passes through the stratospheric air in multipass White cells.

Fluorescence from OH (centered at 309 nm) is detected orthogonal to both the flow and the laser propagation using a filtered PMT assembly. Optical stability is checked periodically by exchanging the 309 nm interference filter with a filter centered at 302 nm, where Raman scattering of N2 is observed.

HO2 is measured as OH after chemical titration with nitric oxide: HO2 + NO → OH + NO2. Variation of added NO density and flow velocity as well as the use of two detection axes aid in diagnosis of the kinetics of this titration. Measurements of ozone (by uv absorption) and water vapor (by photofragment fluorescence) are made as diagnostics of potential photochemical interference from the mechanism: O3 + hv (282 nm) → O(1D) + O2, followed by: O(1D) + H2O → OH + OH

The FCAS II sizes particles in the approximate diameter range from 0.07 mm to 1 mm. Particles are sampled from the free stream with a near isokinetic sampler and are transported to the instrument. They are then passed through a laser beam and the light scattered by individual particles is measured. Particle size is related to the scattered light. The data reduction for the FCAS II takes into account the water which is evaporated from the particle in sampling and the effects of anisokinetic sampling (Jonsson et al., 1995).

The FCAS II and its predecessors have provided accurate aerosol size distribution measurements throughout the evolution of the volcanic cloud produced by the eruption of Mt. Pinatubo. (Wilson et al., 1993). Near co-incidences between FCAS II and SAGE II measurements show good agreement between optical extinctions calculated from FCAS size distributions and extinctions measured by SAGE II.

Accuracy: The instrument has been calibrated with monodisperse aerosol carrying a single charge. The FCAS III and the electrometer agree to within 10%. Sampling errors may increase the uncertainty but a variety of comparisons suggests that total uncertainties in aerosol surface are near 30% (Jonsson, et al., 1995).

Precision: The precision equals 1/ÖN where N is the number of particles counted. In many instances the precision on concentration measurements may reach 7% for 0.1 Hz data. If better precision is desired, it is necessary only to accumulate over longer time intervals.

Response Time: Data are processed at 0.1 Hz. However, the response time depends upon the precision required to detect the change in question. Small changes may require longer times to detect. Plume measurements may be processed with 1 s resolution.

Weight: Approximately 50 lbs.

The instrument used for the CPFM is a spectroradiometer based on a concave, holographic diffraction grating and a 1024-element diode array detector. It measures the intensities of the two linear polarization components of radiation propagating upward at the aircraft location from a range of elevation angles near the horizon. In addition, a measurement of the intensity of the direct solar beam is made by viewing a horizontal diffusing surface mounted under a quartz dome on board the aircraft. These measurements are used to verify atmospheric light-scattering calculations, which are essential for the accurate modeling of the chemistry of the stratosphere where POLARIS makes its measurements.

The CNC counts particles in the approximate diameter range from 0.006 m to 2 m. The instrument operates by exposing the articles to saturated Flourinert vapor at 28 C and then cooling the sample in a condenser at 5 C. The supersaturation of the vapor increases as it is cooled and the vapor condenses on the particles causing them to grow to sizes which are easily detected. The resulting droplets are passed through a laser beam and the scattered light is detected. Individual particles are counted and are referred to as condensation nuclei (CN). Two CN Counters are provided in the instrument. One counts the particles after sampling from the atmosphere and the second counts particles that have survived heating to 192C. Lab experiments show that pure sulfuric acid particles smaller than 0.05 mm are volatilized in the heater. The heated channel detects when small particles are volatile and permits speculation about the composition. The CNC II contains an impactor collector which permits the collection of particles on electron microscope grids for later analysis. The collector consists of a two stages. In the first stage the pressure of the sample is reduced by a factor of two without loosing particles by impaction on walls. The second stage consists of a thin plate impactor which collect efficiently even at small Reynolds numbers. The system collects particles as small as 0.02 m at WB-57 cruise altitudes. As many as 25 samples can be collected in a flight.

ATLAS uses a tunable laser to detect an infrared-active target gas such as N2O, methane, carbon monoxide, or ozone. The laser source is tuned to an individual roto-vibrational line in an infrared absorption band of the target gas, and is frequency modulated at 2 kHz. The instrument detects the infrared target gas by measuring the fractional absorption of the infrared beam from the tunable diode laser as it traverses a multipass White cell containing an atmospheric sample at ambient pressure.

Synchronous detection of the resultant amplitude modulation at 2kHz and 4kHz yields the first and second harmonics of the generally weak absorption feature with high sensitivity (DI/I < 1E-5). Part of the main beam is split off through a short cell containing a known amount of the target gas to a reference detector. The reference first harmonic signal is used to lock the laser frequency to the absorption line center, while the second harmonic signal is used to derive the calibration factor needed to convert the measurement beam second harmonic amplitude into absolute gas concentration. A zero beam is included to correct for background gas absorption occurring outside the multipass cell. The response time of the instrument is set by the gas flow rate through the White cell, which is normally adjusted to give a new sample every second. Periodic standard additions of the target gas are injected into the sample stream as a second method to calibrate the measurement technique and as an overall instrument diagnostic.

ACATS-IV is a 4-channel gas chromatograph with electron capture detection (ECD) that measures a variety of halocarbons and other long-lived trace gases in the stratosphere. The instrument is currently configured to measure CFC-11 (CCl3F), CFC-12 (CCl2F2), CFC-113 (CCl2FCClF2), methyl chloroform (CH3CCl3), carbon tetrachloride (CCl4), halon-1211 (CBrClF2), chloroform (CHCl3), methane (CH4), and hydrogen (H2) every 125 s, and nitrous oxide (N2O) and sulfur hexafluoride (SF6) every 250 s. Each channel is comprised of a sample loop (2-10 cm3 volume), gas sampling valve (GSV), chromatographic column pair, ECD, electrometer, and several flow, temperature, and pressure controllers. In-flight calibration is carried out every 625 s (1250 s for N2O and SF6) by injecting a dried, whole air standard containing approximately 80% of tropospheric mixing ratios.

ALIAS (Aircraft Laser Infrared Absorption Spectrometer) measures total water, total water isotopes, carbon monoxide, and carbon dioxide isotope ratios. No other instrument provides real-time measurements of carbon dioxide isotope ratios which are clear identifiers of atmospheric transport (18O/17O/16O for stratospheric intrusion, 13C/12C for anthropogenic signals). ALIAS easily adapts to changing mission priorities and can be configured to measure HCl, CH4, SO2, and N2O by simply replacing a semiconductor laser. These measurements contribute to Atmospheric Composition Focus Area research by providing key data on how convective processes affect stratospheric composition, the development of cirrus particles and their affect on Earth's radiative balance, and health of the ozone layer through measurement of chlorine partitioning.