Instrument: Condensation Nucleus Counters (CNCs) and

Electrical Aerosol Sampler (EAS)

Principal Investigator: James C. Wilson

Organization:
University of Denver
Department of Engineering
2390 S. York Street
Denver, CO 80208

Instrument Description:
Two condensation nucleus counters (CNCs) have been developed for use on the NASA ER-2 high altitude research aircraft. One CNC measures the number concentration of aerosol particles having diameters in the 0.01 to about 1.0 micron range, while the second uses a heated (150 oC) inlet to vaporize volatile components and then measures the number concentration of residue particles. Used together, the CNCs discriminate between particles composed of volatile materials (i.e., sulfuric acid), and those containing components that are non-volatile at temperatures of 150 oC. For SPADE, the CNCs should be able to distinguish between particles containing carbon soot (an aircraft exhaust product) and background sulfate particles.

Two aerosol collectors have been developed for the SPADE mission. The first uses electrical precipitation to collect particles with diameters greater than 0.01 microns on electron microscope grids. Similar samples, but of particles with diameters greater than about 0.1 microns, are taken concurrently with an impactor. The sealed samples are then returned to the laboratory for analysis by analytical electron microscopy. Up to 25 samples may be collected by each method during a single flight.

Instrument Function: The CNCs function by saturating an aerosol sample with warm alcohol vapor and then cooling the sample so that the alcohol vapor condenses on the particles. The particles grow by vapor deposition to a size such that the individual particles are easily detected by a simple optical particle counter.

The aerosol collectors function by two different principles. In the electrical collector, a needle is forced into a corona discharge by high voltage. The sample is carried past the corona point, and unipolar ions produced by the corona attatch to the particles, causing them to become charged. The charged particles are then collected on a grounded electron microscope grid. In the impactor, the air sample is accelerated through a nozzle and forced around a sharp bend. Particles larger than about 0.1 micron diameter cannot follow the streamlines and instead impact onto an electron microscope grid located at the bend.

Accuracy: The accuracy and precision of the CNCs is highly dependent on the aerosol size distribution. For aerosols whose number distribution is dominated by particles larger than 0.01 microns in diameter, the submicron number concentration is usually measured with an uncertainty of less than 20% and a precision smaller than 10%.

Reference: Wilson, James Charles, Edmund D. Blackshear and Jong Ho Hyun. "The Function and Response of an Improved Stratospheric Condensation Nucleus Counter." J. Geophys. Res. 88 (1983): 6781-6785.

Vacuum ultraviolet radiation produced in a low pressure plasma discharge lamp is used to induce resonance scattering in Cl and Br atoms within a flowing sample. ClO and BrO are converted to Cl and Br by the addition of NO such that the rapid bimolecular reaction ClO + NO → Cl + NO2 (BrO + NO → Br + NO2) yields one halogen atom for each halogen oxide radical present in the flowing sample. Three detection axes are used to diagnose the spatial (and thus temporal) dependence of the ClO (BrO) to Cl (Br) conversion and to detect any removal of Cl (Br) following its formation. A double duct system is used both to maintain laminar flow through the detection region and to step the flow velocity in the detection region down from free stream (200 m/sec) to 20 m/sec in order to optimize the kinetic diagnosis.

The NCAR NOxyO3 instrument is a 4-channel chemiluminescence instrument for the measurement of NO, NO2, NOy, and O3. NOx (NO and NO2) is critical to fast chemical processes controlling radical chemistry and O3 production. Total reactive nitrogen (NOy = NO + NO2 + HNO3 + PANs + other organic nitrates + HO2NO2 + HONO + NO3 + 2*N2O5 + particulate NO3- + …) is a useful tracer for characterizing air masses since it has a tendency to be conserved during airmass aging, as NOx is oxidized to other NOy species.

NOx (NO and NO2), NOy (total reactive nitrogen), and O3 are measured using the NCAR 4-channel chemiluminescence instrument, previously flown on the NASA WB-57F and the NCAR C130. NO is measured via addition of reagent O3 to the sample flow to generate the chemiluminescent reaction producing excited NO2, which is detected by photon counting with a dry-ice cooled photomultiplier tube. NO2 is measured as NO following photolytic conversion of NO2, with a time response of about 3 sec due to the residence time in the photolysis cell. NO is measured with an identical time response due to use of a matching volume. NOy is measured via Au-catalyzed conversion of reactive nitrogen species to NO, in the presence of CO, with a time response of slightly better than 1 sec. O3 is measured using the same chemiluminescent reaction but with the addition of reagent NO to the sample flow. Time response for the ozone measurement is slightly better than 1 s.

The NASA Langley Airborne Differential Absorption Lidar (DIAL) system uses four lasers to make DIAL O3 profile measurements in the ultraviolet (UV) simultaneously with aerosol profile measurements in the visible and IR. Recent changes incorporate an additional laser and modifications to the receiver system that will provide aerosol backscatter, extinction, and depolarization profile measurements at three wavelengths (UV, visible, and NIR). For SEAC4RS, the DIAL instrument will include for the first time aerosol and cloud measurements implementing the High Spectral Resolution Lidar (HSRL) technique [Hair, 2008]. The modifications include integrating an additional 3-wavelength (355 nm, 532 nm, 1064 nm) narrowband laser and the receiver to make the following measurements; depolarization at all three wavelengths, aerosol/cloud backscatter and extinction at 532 nm via the HSRL technique, and aerosol/cloud backscatter at the 355 and 1064 nm via the standard backscatter lidar technique. Integration of the aerosol extinction profile at 532nm above and below the aircraft also provides aerosol optical depth (AOD) along the aircraft flight track.

Total water is measured in situ as vapor with a Lyman-Alpha hygrometer. High ambient sample flows through a closed cell minimize the effect of trapped water. Lyman-a light (121.6 nm) photodissociates water to produce an excited OH radical. The fluorescence from this radical at 309 nm is detected with a phototube and counting system. At aircraft pressures the fluorescence signal is quenched by air which gives a signal that is proportional to mixing ratio. The Lyman-Alpha radiation produced with a DC-discharge lamp is monitored with an iodine ionization cell that is sensitive from 115 nm to 135 nm. Calibration occurs in flight by injecting water vapor directly into the ambient sample flow.

The NOy instrument has three independent chemiluminescence detectors for simultaneous measurements of NOy, NO2, and NO. Each detector utilizes the reaction between NO in the sample with reagent O3. The NO/O3 reaction produces excited state NO2 which emits light of near 1µ m wavelength. Emitted photons are detected with a cooled photomultiplier tube.

Because NOy species other than NO do not respond in the chemiluminescence detector, NOy component species are reduced to NO by catalytic reduction on a gold surface with carbon monoxide (CO) acting as a reducing agent. Conversion efficiencies are > 90% at surface temperatures of 300°C. An NO signal representing NOy is then detected by chemiluminescence in the detector module. The catalyst is located outside the aircraft fuselage in order to avoid inlet line losses. NO2 is photolytically converted to NO in a glass cell in the presence of intense UV light between 300 and 400 nm. The conversion fraction is > 50% for a residence time of 1 s. The chemiluminescence detector detects NO as well as the additional NO from NO2. The third channel measures NO directly by passing the ambient sample through the detector module.

The response of each detector is checked several times in flight by standard addition of NO or NO2 calibration gas. The baseline of each measurement is determined in part by the addition of synthetic air that contains no reactive nitrogen. A continuous flow of water vapor is added directly to the sample flow in order to reduce the background signal in the detectors.

The sampling inlet for NOy is located outside the fuselage of the aircraft in a separate football-shaped housing. The shape of the housing allows for the inertial separation of large aerosols (> 5 µm diameter) from the NOy inlet at the downstream end of the housing.

The FSSP is of that general class of instruments called optical particle counters (OPCs) that detect single particles and size them by measuring the intensity of light that the particle scatters when passing through a light beam. A Helium Neon laser beam is focused to a diameter of 0.2 mm at the center of an inlet that faces into the oncoming airstream. This laser beam is blocked on the opposite side of the inlet with an optical stop, a "dump spot" to prevent the beam from entering the collection optics. Particles that encounter this beam scatter light in all directions and some of that scattered in the forward direction is directed by a right angle prism though a condensing lens and onto a beam splitter. The "dump spot" on the prism and aperture of the condensing lens define a collection angle from about 4º - 12º.

The beam splitter divides the scattered light into two components, each of which impinge on a photodetector. One of these detectors, however, is optically masked to receive only scattered light when the particles pass through the laser beam displaced greater than approximately 1.5 mm either side of the center of focus. Particles that fall in that region are rejected when the signal from the masked detector exceeds that from the unmasked detector. This defines the sample volume needed to calculate particle concentrations.

The absorption of infrared solar radiation along a slant path to the sun is recorded from 2 to 15 micrometers. Six spectral filters are used to cover the region from 2-15 microns. An interferogram is recorded in about 10 seconds. Interferograms are transformed to produce spectra. Column amounts are retrieved by fitting the observed spectra using the non-linear least squares fitting code SFIT2 that employs an Optimal Estimation retrieval algorithm.

The major chlorine reservoirs (HCl and ClONO2), the important nitrogen-containing gases in the stratosphere (N2O, NO, NO2, and HNO3), stratospheric and tropospheric tracers (HF, CH4, C2H6, H2O, CO2), a major source CFC (CF2Cl2) and ozone may be routinely retrieved.

The UC-Irvine research group collected whole air samples aboard the NASA DC-8 aircraft during the summer 2019 NASA Fire Influence on Regional to Global Environments Experiment - Air Quality (FIREX-AQ) field mission. More than 70 trace gases were identified and quantified at our Irvine laboratory, including C2-C10 NMHCs, C1-C2 halocarbons, C1-C5 alkyl nitrates, and selected sulfur compounds using our established technique of airborne whole air sampling followed by laboratory analysis using gas chromatography (GC) with flame ionization detection (FID), electron capture detection (ECD), and mass spectrometric detection (MSD). Our experimental procedures build on those that have been successfully employed for numerous prior NASA field missions, for example PEM Tropics A and B, TRACE-P, INTEX-A and B, ARCTAS, DC-3, SEAC4RS, ATom, KORUS-AQ, FIREX-AQ, and SARP.