54 1001 Ridley, B.A.; Weinheimer, A.J.; Montzka, D.D.; Knapp, D.J. National Center for Atmospheric Research WB-57 in situ NO, NOy, NOy-fore, NOy-coPh CRYSTAL-FACE 1 1 2002 05 11 2003 02 04 0.0 Time (seconds past 0 UT of flight day in line 7) 4 1.0 1.0 1.0 1.0 999999.9 999999.9 999999.9 999999.9 NO (pptv) NOy (pptv) NOy-fore (pptv) NOy-coPh (pptv) 0 Flight-specific comment lines: None 36 General comment lines: The instrument uses 3 channels for the measurement of reactive nitrogen species via chemiluminescence: NO, NOy, NOy-fore. NOy-fore is NOy sampled through a forward-facing inlet to enhance the sampling of particulate NOy relative to that in the gas phase. NOy is sampled through an inlet that is in fact forward-facing but is shielded from particles larger than about 3-4 microns. Thus both inlets give a signal that is the sum of gas phase NOy plus and an enhanced signal from NOy on particles. NOy-fore includes all particles, and NOy includes an enhanced signal from particles smaller than about 3-4 microns. The difference in mixing ratios between the two NOy channels is divided by the high-mass limit enhancement factor to obtain the condensed-phase NOy mixing ratio (NOy-coPh) that resides on particles larger than about 3-4 microns. The NOy-fore data have been corrected for the effect of water vapor on the sensitivity of the instrument, using 10-sec Harvard ice water content data. For 3 flights (0707, 0716, 0729), a small amount of NOy data have been deleted in association with transects through particularly heavy cloud, when the NOy mixing ratio would signficantly exceed NOy-fore for reasons that are not understood. For the flight of 0707, all data have been deleted for the period of 72440-72700 sec, during which huge, short-term variations were seen. These were originally thought to be due to natural lightning but are now considered to be of unknown origin. In the early portion of the project (thru 20020713), a small oscillation is discernible in the NOy channels. This is not real and is due to an oscillation in the converter temperature. It has a period of about 85 sec. Time has been corrected to the time in the WB57 nav stream. It is good to about 1 second. ************************************** ********** PRELIMINARY DATA ********** ************************************** Time_(UT_sec) NO_(pptv) NOy_(pptv) NOy-fore_(pptv) NOy-coPh_(pptv) 65802.4 999999.9 999999.9 999999.9 999999.9 65805.9 999999.9 999999.9 999999.9 999999.9 65808.3 999999.9 999999.9 999999.9 999999.9 65810.8 999999.9 999999.9 999999.9 999999.9 65813.1 999999.9 999999.9 999999.9 999999.9 65815.5 999999.9 999999.9 999999.9 999999.9 65817.9 999999.9 999999.9 999999.9 999999.9 65820.3 999999.9 999999.9 999999.9 999999.9 65822.7 999999.9 999999.9 999999.9 999999.9 65825.1 999999.9 999999.9 999999.9 999999.9 65827.5 999999.9 999999.9 999999.9 999999.9 65829.9 999999.9 999999.9 999999.9 999999.9 65832.3 999999.9 999999.9 999999.9 999999.9 65834.7 999999.9 999999.9 999999.9 999999.9 65837.1 999999.9 999999.9 999999.9 999999.9 65839.5 999999.9 999999.9 999999.9 999999.9 65841.9 999999.9 999999.9 999999.9 999999.9 65844.4 999999.9 999999.9 999999.9 999999.9 65846.7 999999.9 999999.9 999999.9 999999.9 65849.1 999999.9 999999.9 999999.9 999999.9 65851.6 999999.9 999999.9 999999.9 999999.9 65853.9 999999.9 999999.9 999999.9 999999.9 65856.3 999999.9 999999.9 999999.9 999999.9 65858.8 999999.9 999999.9 999999.9 999999.9 65861.1 999999.9 999999.9 999999.9 999999.9 65863.5 999999.9 999999.9 999999.9 999999.9 65866.0 999999.9 999999.9 999999.9 999999.9 65868.4 999999.9 999999.9 999999.9 999999.9 65870.7 999999.9 999999.9 999999.9 999999.9 65873.2 999999.9 999999.9 999999.9 999999.9 65875.5 999999.9 999999.9 999999.9 999999.9 65877.9 999999.9 999999.9 999999.9 999999.9 65880.4 999999.9 999999.9 999999.9 999999.9 65882.7 999999.9 999999.9 999999.9 999999.9 65885.1 999999.9 999999.9 999999.9 999999.9 65887.5 999999.9 999999.9 999999.9 999999.9 65889.9 999999.9 999999.9 999999.9 999999.9 65892.3 999999.9 999999.9 999999.9 999999.9 65894.8 999999.9 999999.9 999999.9 999999.9 65897.1 999999.9 999999.9 999999.9 999999.9 65899.5 999999.9 999999.9 999999.9 999999.9 65901.9 999999.9 999999.9 999999.9 999999.9 65904.3 999999.9 999999.9 999999.9 999999.9 65906.7 999999.9 999999.9 999999.9 999999.9 65909.1 999999.9 999999.9 999999.9 999999.9 65911.5 999999.9 999999.9 999999.9 999999.9 65913.9 999999.9 999999.9 999999.9 999999.9 65916.3 999999.9 999999.9 999999.9 999999.9 65918.7 999999.9 999999.9 999999.9 999999.9 65921.1 999999.9 999999.9 999999.9 999999.9 65923.5 999999.9 999999.9 999999.9 999999.9 65925.9 999999.9 999999.9 999999.9 999999.9 65928.4 999999.9 999999.9 999999.9 999999.9 65930.7 999999.9 999999.9 999999.9 999999.9 65933.1 999999.9 999999.9 999999.9 999999.9 65935.6 999999.9 999999.9 999999.9 999999.9 65937.9 999999.9 999999.9 999999.9 999999.9 65940.3 999999.9 999999.9 999999.9 999999.9 65942.8 999999.9 999999.9 999999.9 999999.9 65945.1 999999.9 999999.9 999999.9 999999.9 65947.5 999999.9 999999.9 999999.9 999999.9 65950.0 999999.9 999999.9 999999.9 999999.9 65952.3 999999.9 999999.9 999999.9 999999.9 65954.7 999999.9 999999.9 999999.9 999999.9 65957.1 999999.9 999999.9 999999.9 999999.9 65959.5 999999.9 999999.9 999999.9 999999.9 65961.9 999999.9 999999.9 999999.9 999999.9 65964.3 999999.9 999999.9 999999.9 999999.9 65966.7 999999.9 999999.9 999999.9 999999.9 65969.1 999999.9 999999.9 999999.9 999999.9 65971.5 999999.9 999999.9 999999.9 999999.9 65973.9 999999.9 999999.9 999999.9 999999.9 65976.4 999999.9 999999.9 999999.9 999999.9 65978.7 999999.9 999999.9 999999.9 999999.9 65981.1 999999.9 999999.9 999999.9 999999.9 65983.6 999999.9 999999.9 999999.9 999999.9 65985.9 999999.9 999999.9 999999.9 999999.9 65988.3 999999.9 999999.9 999999.9 999999.9 65990.8 999999.9 999999.9 999999.9 999999.9 65993.1 999999.9 999999.9 999999.9 999999.9 65995.5 999999.9 999999.9 999999.9 999999.9 65998.0 999999.9 999999.9 999999.9 999999.9 66000.3 999999.9 999999.9 999999.9 999999.9 66002.7 999999.9 999999.9 999999.9 999999.9 66005.2 999999.9 999999.9 999999.9 999999.9 66007.5 999999.9 999999.9 999999.9 999999.9 66009.9 999999.9 999999.9 999999.9 999999.9 66012.4 999999.9 999999.9 999999.9 999999.9 66014.7 999999.9 999999.9 999999.9 999999.9 66017.1 999999.9 999999.9 999999.9 999999.9 66019.5 999999.9 999999.9 999999.9 999999.9 66021.9 999999.9 999999.9 999999.9 999999.9 66024.3 999999.9 999999.9 999999.9 999999.9 66026.7 999999.9 999999.9 999999.9 999999.9 66029.1 999999.9 999999.9 999999.9 999999.9 66031.5 999999.9 999999.9 999999.9 999999.9 66033.9 999999.9 999999.9 999999.9 999999.9 66036.3 999999.9 999999.9 999999.9 999999.9 66038.7 999999.9 999999.9 999999.9 999999.9 66041.1 999999.9 999999.9 999999.9 999999.9 66043.5 999999.9 999999.9 999999.9 999999.9 66045.9 999999.9 999999.9 999999.9 999999.9 66048.3 999999.9 999999.9 999999.9 999999.9 66050.7 999999.9 999999.9 999999.9 999999.9 66053.1 999999.9 999999.9 999999.9 999999.9 66055.5 999999.9 999999.9 999999.9 999999.9 66057.9 999999.9 999999.9 999999.9 999999.9 66060.4 999999.9 999999.9 999999.9 999999.9 66062.7 999999.9 999999.9 999999.9 999999.9 66065.1 999999.9 999999.9 999999.9 999999.9 66067.6 999999.9 999999.9 999999.9 999999.9 66069.9 999999.9 999999.9 999999.9 999999.9 66072.3 999999.9 999999.9 999999.9 999999.9 66074.8 999999.9 999999.9 999999.9 999999.9 66077.1 999999.9 999999.9 999999.9 999999.9 66079.5 999999.9 999999.9 999999.9 999999.9 66082.0 999999.9 999999.9 999999.9 999999.9 66084.3 999999.9 999999.9 999999.9 999999.9 66086.7 999999.9 999999.9 999999.9 999999.9 66089.1 999999.9 999999.9 999999.9 999999.9 66091.5 999999.9 999999.9 999999.9 999999.9 66093.9 999999.9 999999.9 999999.9 999999.9 66096.4 999999.9 999999.9 999999.9 999999.9 66098.7 999999.9 999999.9 999999.9 999999.9 66101.1 999999.9 999999.9 999999.9 999999.9 66103.5 999999.9 999999.9 999999.9 999999.9 66105.9 999999.9 999999.9 999999.9 999999.9 66108.3 999999.9 999999.9 999999.9 999999.9 66110.7 999999.9 999999.9 999999.9 999999.9 66113.1 999999.9 999999.9 999999.9 999999.9 66115.6 999999.9 999999.9 999999.9 999999.9 66117.9 999999.9 999999.9 999999.9 999999.9 66120.3 999999.9 999999.9 999999.9 999999.9 66122.8 999999.9 999999.9 999999.9 999999.9 66125.1 999999.9 999999.9 999999.9 999999.9 66127.5 999999.9 999999.9 999999.9 999999.9 66129.9 999999.9 999999.9 999999.9 999999.9 66132.3 999999.9 999999.9 999999.9 999999.9 66134.7 999999.9 999999.9 999999.9 999999.9 66137.2 999999.9 999999.9 999999.9 999999.9 66139.5 999999.9 999999.9 999999.9 999999.9 66141.9 999999.9 999999.9 999999.9 999999.9 66144.4 999999.9 999999.9 999999.9 999999.9 66146.7 999999.9 999999.9 999999.9 999999.9 66149.1 999999.9 999999.9 999999.9 999999.9 66151.6 999999.9 999999.9 999999.9 999999.9 66153.9 999999.9 999999.9 999999.9 999999.9 66156.3 999999.9 999999.9 999999.9 999999.9 66158.7 999999.9 999999.9 999999.9 999999.9 66161.1 999999.9 999999.9 999999.9 999999.9 66163.5 999999.9 999999.9 999999.9 999999.9 66165.9 999999.9 999999.9 999999.9 999999.9 66168.3 999999.9 999999.9 999999.9 999999.9 66170.7 999999.9 999999.9 999999.9 999999.9 66173.1 999999.9 999999.9 999999.9 999999.9 66175.5 999999.9 999999.9 999999.9 999999.9 66177.9 999999.9 999999.9 999999.9 999999.9 66180.3 999999.9 999999.9 999999.9 999999.9 66182.7 999999.9 999999.9 999999.9 999999.9 66185.1 999999.9 999999.9 999999.9 999999.9 66187.5 999999.9 999999.9 999999.9 999999.9 66189.9 999999.9 999999.9 999999.9 999999.9 66192.4 999999.9 999999.9 999999.9 999999.9 66194.7 999999.9 999999.9 999999.9 999999.9 66197.1 999999.9 999999.9 999999.9 999999.9 66199.6 999999.9 999999.9 999999.9 999999.9 66201.9 999999.9 999999.9 999999.9 999999.9 66204.3 999999.9 999999.9 999999.9 999999.9 66206.8 999999.9 999999.9 999999.9 999999.9 66209.1 999999.9 999999.9 999999.9 999999.9 66211.5 999999.9 999999.9 999999.9 999999.9 66214.0 999999.9 999999.9 999999.9 999999.9 66216.3 999999.9 999999.9 999999.9 999999.9 66218.7 999999.9 999999.9 999999.9 999999.9 66221.2 999999.9 999999.9 999999.9 999999.9 66223.5 999999.9 999999.9 999999.9 999999.9 66225.9 999999.9 999999.9 999999.9 999999.9 66228.3 999999.9 999999.9 999999.9 999999.9 66230.7 999999.9 999999.9 999999.9 999999.9 66233.1 999999.9 999999.9 999999.9 999999.9 66235.5 999999.9 999999.9 999999.9 999999.9 66237.9 999999.9 999999.9 999999.9 999999.9 66240.3 999999.9 999999.9 999999.9 999999.9 66242.7 999999.9 999999.9 999999.9 999999.9 66245.1 999999.9 999999.9 999999.9 999999.9 66247.6 999999.9 999999.9 999999.9 999999.9 66249.9 999999.9 999999.9 999999.9 999999.9 66252.3 999999.9 999999.9 999999.9 999999.9 66254.8 999999.9 999999.9 999999.9 999999.9 66257.1 999999.9 999999.9 999999.9 999999.9 66259.5 999999.9 999999.9 999999.9 999999.9 66261.9 999999.9 999999.9 999999.9 999999.9 66264.3 999999.9 999999.9 999999.9 999999.9 66266.7 999999.9 999999.9 999999.9 999999.9 66269.2 999999.9 999999.9 999999.9 999999.9 66271.5 999999.9 999999.9 999999.9 999999.9 66273.9 999999.9 999999.9 999999.9 999999.9 66276.4 999999.9 999999.9 999999.9 999999.9 66278.7 999999.9 999999.9 999999.9 999999.9 66281.1 999999.9 999999.9 999999.9 999999.9 66283.6 999999.9 999999.9 999999.9 999999.9 66285.9 999999.9 999999.9 999999.9 999999.9 66288.3 999999.9 999999.9 999999.9 999999.9 66290.8 999999.9 999999.9 999999.9 999999.9 66293.1 999999.9 999999.9 999999.9 999999.9 66295.5 999999.9 999999.9 999999.9 999999.9 66297.9 999999.9 999999.9 999999.9 999999.9 66300.3 999999.9 999999.9 999999.9 999999.9 66302.7 999999.9 999999.9 999999.9 999999.9 66305.2 999999.9 999999.9 999999.9 999999.9 66307.5 999999.9 999999.9 999999.9 999999.9 66309.9 999999.9 999999.9 999999.9 999999.9 66312.3 999999.9 999999.9 999999.9 999999.9 66314.7 999999.9 999999.9 999999.9 999999.9 66317.1 999999.9 999999.9 999999.9 999999.9 66319.5 999999.9 999999.9 999999.9 999999.9 66321.9 999999.9 999999.9 999999.9 999999.9 66324.4 999999.9 999999.9 999999.9 999999.9 66326.7 999999.9 999999.9 999999.9 999999.9 66329.1 999999.9 999999.9 999999.9 999999.9 66331.6 999999.9 999999.9 999999.9 999999.9 66333.9 999999.9 999999.9 999999.9 999999.9 66336.3 999999.9 999999.9 999999.9 999999.9 66338.8 999999.9 999999.9 999999.9 999999.9 66341.1 999999.9 999999.9 999999.9 999999.9 66343.5 999999.9 999999.9 999999.9 999999.9 66346.0 999999.9 999999.9 999999.9 999999.9 66348.3 999999.9 999999.9 999999.9 999999.9 66350.7 999999.9 999999.9 999999.9 999999.9 66353.2 999999.9 999999.9 999999.9 999999.9 66355.5 999999.9 999999.9 999999.9 999999.9 66357.9 999999.9 999999.9 999999.9 999999.9 66360.3 999999.9 999999.9 999999.9 999999.9 66362.7 999999.9 999999.9 999999.9 999999.9 66365.1 999999.9 999999.9 999999.9 999999.9 66367.5 999999.9 999999.9 999999.9 999999.9 66369.9 999999.9 999999.9 999999.9 999999.9 66372.3 999999.9 999999.9 999999.9 999999.9 66374.7 999999.9 999999.9 999999.9 999999.9 66377.1 999999.9 999999.9 999999.9 999999.9 66379.5 999999.9 999999.9 999999.9 999999.9 66381.9 999999.9 999999.9 999999.9 999999.9 66384.3 999999.9 999999.9 999999.9 999999.9 66386.8 999999.9 999999.9 999999.9 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