The single mass analyzer CIMS (S-CIMS) was developed for use on NASA’s ER-2 aircraft. Its first measurements were made in 2000 (SOLVE, see photo). Subsequently, it has flown on the NASA DC-8 aircraft for INTEX-NA, DICE, TC4, ARCTAS, ATom, KORUS, FIREX, as well as on the NCAR C-130 during MILAGRO/INTEX-B. HNO3 is measured by selective ion chemical ionization via the fluoride transfer reaction: CF3O^- + HNO3 → HF • NO3^- + CF2O In addition to its fast reaction rate with HNO3, CF3O^- can be used to measure additional acids and nitrates as well as SO2 [Amelynck et al., 2000; Crounse et al., 2006; Huey et al., 1996]. We have further identified CF3O^- chemistry as useful for the measurement of less acidic species via clustering reactions [Crounse et al., 2006; Paulot et al., 2009a; Paulot et al., 2009b; St. Clair et al., 2010]: CF3O^- + HX → CF3O^- • HX where, e.g., HX = HCN, H2O2, CH3OOH, CH3C(O)OOH (PAA) The mass analyzer of the S-CIMS instrument was first upgraded from a quadrupole to a unit-mass resolution time-of-flight (ToF) analyzer. In 2023, the mass filter was again upgraded to an 1m flight path (~5000 deltaM/M).  The ToF admits the sample ion beam to the ion extractor, where a pulse of high voltage orthogonally deflects and accelerates the ions into the reflectron, which in turn redirects the ions toward the multichannel plate detector. Ions in the ToF follow a V-shaped from the extractor to detector, separating by mass as the smaller ions are accelerated to greater velocities by the high voltage pulse. The detector collects the ions as a function of time following each extractor pulse. The rapid-scan collection of the ToF guarantees a high temporal resolution (1 Hz or faster) and simultaneous data products from the S-CIMS instrument for all mass channels [Drewnick et al., 2005]. We have flown a tandem CIMS (TCIMS) instrument in addition to the SCIMS since INTEX-B (2006). The T-CIMS provides parent-daughter mass analysis, enabling measurement of compounds precluded from quantification by the S-CIMS due to mass interferences (e.g. MHP) or the presence of isobaric compounds (e.g. isoprene oxidation products) [Paulot et al., 2009b; St. Clair et al., 2010]. Calibrations of both CIMS instruments are performed in flight using isotopically-labeled reagents evolved from a gas cylinders or from a thermally-stabilized permeation tube oven [Washenfelder et al., 2003]. By using an isotopically labeled standard, the product ion signals are distinct from the natural analyte and calibration can be performed at any time without adversely affecting the ambient measurement.

The Multiangle SpectroPolarimetric Imager, or AirMSPI, was a candidate for the multi-directional, multi-wavelength, high-accuracy polarization imager identified by the National Research Council's Earth Sciences Decadal Survey as one component of the notional Aerosol-Cloud-Ecosystem, or ACE, mission. The ACE spacecraft was planned to characterize the role of aerosols in climate forcing, especially their impact on precipitation and cloud formation. Forcing is the process by which natural mechanisms or human activities alter the global energy balance and “force” the climate to change. The unresolved effects of aerosols on clouds are among the greatest uncertainties in predicting global climate change. AirMSPI is conceptually similar to JPL’s Multiangle Imaging SpectroRadiometer, or MISR, carried on NASA’s EOS Terra spacecraft, but with some important additions. The new camera design extends the spectral range to the ultraviolet and shortwave infrared (from 446–866 nm to 355–2130 nm), increases the image swath (from 360 km to 680 km) to achieve more rapid global coverage (from 9 days to 4 days), and adds high-accuracy polarimetry in selected spectral bands. Like MISR, a suite of AirMSPI cameras would view Earth at a variety of angles, with an intrinsic pixel size of a few hundred meters, which for certain channels would be averaged up to about 1 kilometer.
An advanced version of this instrument is currently in development, called AirMSPI-2. 

The NOAA chemical ionization mass spectrometer (CIMS) instrument was developed for high-precision measurements of gaseous nitric acid (HNO3) specifically under high- and variable-humidity conditions in the boundary layer. The instrument’s background signals (i.e., signals detected when HNO3-free air is measured), which depend on the humidity and HNO3 concentration of the sample air, are the most important factor affecting the limit of detection (LOD). A new system to provide HNO3-free air without changing both the humidity and the pressure of the sampled air was developed to measure the background level accurately. The detection limit was about 23 parts per trillion by volume (pptv) for 50-s averages. Field tests, including an intercomparison with the diffusion scrubber technique, were carried out at a surface site in Tokyo, Japan, in October 2003 and June 2004. A comparison between the measured concentrations of HNO3 and particulate nitrate indicated that the interference from particulate nitrate was not detectable (i.e., less than about 1%). The intercomparison indicated that the two independent measurements of HNO3 agreed to within the combined uncertainties of these measurements.

AVIRIS is the second in a series of imaging spectrometer instruments developed at the Jet Propulsion Laboratory (JPL) for earth remote sensing. It is a unique optical sensor that delivers calibrated images of the upwelling spectral radiance in 224 contiguous spectral channels (bands) with wavelengths from 380 to 2510 nanometers. It uses scanning optics and four spectrometers to image a 677 pixel swath simultaneously in all 224 bands. AVIRIS has flown in North America, Europe, and portions of South America.

The AVIRIS sensor collects data that can be used for characterization of the Earth's surface and atmosphere from geometrically coherent spectroradiometric measurements. This data can be applied to studies in the fields of oceanography, environmental science, snow hydrology, geology, volcanology, soil and land management, atmospheric and aerosol studies, agriculture, and limnology. Applications under development include the assessment and monitoring of environmental hazards such as toxic waste, oil spills, and land/air/water pollution. With proper calibration and correction for atmospheric effects, the measurements can be converted to ground reflectance data which can then be used for quantitative characterization of surface features.