84, 1001 Montzka, S., Sweeney, C. Global Monitoring Division/ESRL/NOAA PFP; Flask measurements of trace gases from PFP flasks ATom 1,1 2017, 10, 23, 2019, 02, 27 0 Start_UTC, seconds 51 1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1 -999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 Stop_UTC, seconds, elapsed time since midnight (GMT) of the day of takeoff CO2_PFP, ppm, carbon dioxide, dry-air mole fraction, micro mole per mole (as part per million) CH4_PFP, ppb, methane, dry-air mole fraction, nano mole per mole (as part per billion) CO_PFP, ppb, carbon monoxide, dry-air mole fraction, nano mole per mole (as part per billion) N2O_PFP, ppb, nitrous oxide, dry-air mole fraction, nano mole per mole (as part per billion) SF6_CCGG_PFP, ppt, sulfur hexafluoride dry-air mole fraction, pico mole per mole (as part per trillion, or ppt), measured by electron capture detection in carbon cycle group H2_PFP, ppb, hydrogen, dry-air mole fraction, nano mole per mole (as part per billion) d13CH4_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CH4 relative to Vienna Pee Dee Belemnite d13CO2_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CO2 relative to Vienna Pee Dee Belemnite HFC134a_PFP, ppt, 1,1,1,2-tetrafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC22_PFP, ppt, chlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC12_PFP, ppt, dichlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3Cl_PFP, ppt, methyl chloride, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC142b_PFP, ppt, 1-chloro-1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H1211_PFP, ppt, bromodichlorofluoromethane (halon-1211), dry-air mole fraction, pico mole per mole (as part per trillion) CH3Br_PFP, ppt, methyl bromide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC11_PFP, ppt, trichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC141b_PFP, ppt, 1,1-chloro-1-fluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3I_PFP, ppt, methyl iodide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC113_PFP, ppt, 1,1,2-trichloro-1,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Cl2_PFP, ppt, dichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHCl3_PFP, ppt, trichloromethane (chloroform), dry-air mole fraction, pico mole per mole (as part per trillion) CH3CCl3_PFP, ppt, 1,1,1-trichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CCl4_PFP, ppt, tetrachloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Br2_PFP, ppt, dibromomethane, dry-air mole fraction, pico mole per mole (as part per trillion) C2Cl4_PFP, ppt, tetrachloroethylene, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr3_PFP, ppt, tribromomethane (bromorform), dry-air mole fraction, pico mole per mole (as part per trillion) Benzene_PFP, ppt, C6H6, dry-air mole fraction, pico mole per mole (as part per trillion) OCS_PFP, ppt, carbonyl sulfide, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC21_PFP, ppt, dichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC152a_PFP, ppt, 1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H2402_PFP, ppt, 1,2-dibromo-1,1,2,2-tetrafluoroethane (halon-2402, dry-air mole fraction, pico mole per mole (as part per trillion) HFC365mfc_PFP, ppt, 1,1,1,3,3-pentafluorobutane, dry-air mole fraction, pico mole per mole (as part per trillion) Propyne_PFP, ppt, C3H4, dry-air mole fraction, pico mole per mole (as part per trillion) C2H5Cl_PFP, prelim, chloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC227ea_PFP, ppt, 1,1,1,2,3,3,3-heptafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) nPentane_PFP, ppt, normal pentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) nHexane_PFP, ppt, normal hexane (C6H14), dry-air mole fraction, pico mole per mole (as part per trillion) HCFC133a_PFP, ppt, 1-chloro-2,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClI_PFP, ppt, chloroiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2I2_PFP, ppt, diiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrCl_PFP, ppt, bromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClCH2Cl_PFP, ppt, 1,2-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) Propane_PFP, ppt, C3H8, dry-air mole fraction, pico mole per mole (as part per trillion) iPentane_PFP, ppt, isopentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) iButane_PFP, ppt, isobutane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) nButane_PFP, ppt, normal butane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) CHBrCl2_PFP, ppt, bromodichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrI_PFP, ppt, bromoiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3CHCl2_PFP, prelim, 1,1-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr2Cl_PFP, ppt, dibromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) 0 19 PI_CONTACT_INFO: 303-497-6657 325 Broadway, Boulder CO 80305 email stephen.a.montzka@noaa.gov colm.sweeney@noaa.gov PLATFORM: NASA DC8 LOCATION: Aircraft location here with appropriate date indicated: http://espoarchive.nasa.gov/archive/fileinfo/MMS-FlightPath_DC8_YYYYMMDD.ict ASSOCIATED_DATA: See http://espoarchive.nasa.gov/archive/browse/atom INSTRUMENT_INFO: Programmable Flask Package results from multiple analysis instruments at NOAA and CU/INSTAAR DATA_INFO: N/A UNCERTAINTY: tbd ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: Steve Montzka, 303-497-6657, 325 Broadway, Boulder, CO 80305 PROJECT_INFO: ATom-2; 04-Dec-2016 to 22-Feb-2017; https://espo.nasa.gov/home/atom/content/ATom STIPULATIONS_ON_USE: Notification of S. Montzka or C. Sweeney is requested with use of data. OTHER_COMMENTS: all measurement results are given in dry-air mole fractions; results for two gases are on preliminary scales (not mole fractions) REVISION: R1 R0: preliminary data R1: final data, for public release Start_UTC,Stop_UTC,CO2_PFP,CH4_PFP,CO_PFP,N2O_PFP,SF6_CCGG_PFP,H2_PFP,d13CH4_PFP,d13CO2_PFP,HFC134a_PFP,HCFC22_PFP,CFC12_PFP,CH3Cl_PFP,HCFC142b_PFP,H1211_PFP,CH3Br_PFP,CFC11_PFP,HCFC141b_PFP,CH3I_PFP,CFC113_PFP,CH2Cl2_PFP,CHCl3_PFP,CH3CCl3_PFP,CCl4_PFP,CH2Br2_PFP,C2Cl4_PFP,CHBr3_PFP,Benzene_PFP,OCS_PFP,HCFC21_PFP,HFC152a_PFP,H2402_PFP,HFC365mfc_PFP,Propyne_PFP,C2H5Cl_PFP,HFC227ea_PFP,nPentane_PFP,nHexane_PFP,HCFC133a_PFP,CH2ClI_PFP,CH2I2_PFP,CH2BrCl_PFP,CH2ClCH2Cl_PFP,Propane_PFP,iPentane_PFP,iButane_PFP,nButane_PFP,CHBrCl2_PFP,CH2BrI_PFP,CH3CHCl2_PFP,CHBr2Cl_PFP 36238,36258,403.82,1885.61,80.64,328.86,9.45,517.41,-47.424,-8.402,102.61,249.34,507.76,545.7,22.63,3.471,6.96,229.8,25.23,0.124,70.54,51.09,11.7,2.088,80.44,0.843,-999.99,0.62,8.27,484.4,0.373,8.13,0.408,1.018,0.09,0.23,-999.99,0.4,0.41,0.486,0.016,0,0.136,8.57,76.47,1.05,4.28,8.36,0.197,0.002,0.308,0.147 37159,37166,406.01,1926,108.85,329.61,9.54,492.46,-47.67,-8.532,106.51,254.65,507.16,516.9,23.04,3.441,6.85,230.18,25.94,0.468,70.52,63.36,17.44,2.106,80.3,1.027,-999.99,1.58,34.64,454,0.439,10.71,0.413,1.122,1.77,0.38,1.43,15.02,2.89,0.497,0.134,0,0.16,12.39,310.99,20.37,37.79,71.35,0.27,0.008,0.566,0.218 37350,37357,406.44,1933.72,113.5,329.76,9.52,490.15,-47.649,-8.541,110.37,258.24,509.09,521.03,23.41,3.442,6.91,231.49,26.49,0.715,70.92,65.21,18.03,2.131,80.76,1.161,-999.99,1.68,36.18,455.2,0.451,14.5,0.407,1.209,1.55,0.4,1.46,18.85,3.07,0.505,0.478,0.011,0.133,12.35,402.85,25.47,45.61,89.79,0.285,0.01,0.556,0.243 38373,38385,404.08,1889.06,81.14,330.54,9.53,521,-47.483,-8.398,101.28,249.34,505.24,546.46,22.52,3.461,7.04,229.45,25.36,0.04,70.33,64.74,13.18,2.055,80.15,0.748,-999.99,0.37,9.69,485.8,0.383,7.45,0.411,1.015,0.3,0.37,-999.99,2.12,0.52,0.5,0.001,-0.001,0.11,13.34,64.49,1.44,4.95,7.25,0.183,-0.014,0.374,0.115 40262,40270,405.43,1934.11,112.81,330.16,9.58,468.49,-47.731,-8.523,105.87,254.38,509.57,492.46,23.12,3.433,6.43,230.78,25.9,0.421,70.51,61.52,19.34,2.156,80.39,1.263,-999.99,2.66,38.93,418.7,0.44,9.8,0.424,1.12,2.36,0.43,1.46,16.97,4.41,0.499,0.135,0.003,0.14,11.74,312.59,24.67,39.93,76.85,0.277,-0.019,0.607,0.284 40566,40573,404.23,1928.86,111.32,329.86,9.46,480.56,-47.726,-8.469,105.64,253.3,506.84,499.87,23.05,3.467,6.58,230.43,25.79,0.419,70.4,62.54,18.49,2.154,80.23,1.241,-999.99,2.25,36.17,438.4,0.439,9.72,0.419,1.114,1.88,0.38,1.44,11.76,3.2,0.506,0.256,0.007,0.142,11.88,262.62,19.01,32.82,59.36,0.265,0.01,0.593,0.244 42966,42978,405.12,1909.54,98.12,330.1,9.51,493.53,-47.639,-8.485,104.18,252.84,505.86,519.7,22.81,3.428,6.97,229.74,25.7,0.151,70.36,61.58,16.04,2.108,79.96,0.992,-999.99,1.16,22.01,454.5,0.425,9.25,0.408,1.083,0.82,0.9,-999.99,7.55,1.69,0.501,0.006,0.001,0.148,11.48,222.5,10.66,23.57,46.72,0.228,0.015,0.523,0.178 43778,43785,405.9,1931.91,112.36,332.37,9.61,478.2,-47.782,-8.53,105.81,253.82,506.17,495.9,23,3.442,6.47,230.06,25.84,0.552,70.57,63.74,18.67,2.139,80.37,1.246,-999.99,1.97,38.48,433.7,0.439,10.27,0.414,1.13,2.61,0.41,1.45,18.31,4.51,0.5,0.169,0.004,0.135,12.32,332.33,25.1,42.01,83.49,0.272,-0.026,0.594,0.249 44118,44124,406.21,1939.32,116.07,330.63,9.67,468.63,-47.805,-8.555,106.22,254.16,506.5,487.19,23.14,3.406,6.36,230.46,25.94,0.588,70.54,62.57,19.25,2.145,80.04,1.28,-999.99,2.13,42.23,420.7,0.446,10.5,0.425,1.146,3.11,0.41,1.44,22.23,5.61,0.511,0.262,0.005,0.14,11.82,378.35,31.85,50.67,99.04,0.284,-0.012,0.606,0.264 44940,44952,405.15,1906.55,98.88,329.27,9.74,503.62,-47.652,-8.454,104.11,252.52,505.08,524.7,22.89,3.439,6.99,229.2,25.68,0.138,70.29,66.29,16.14,2.084,80.11,0.91,-999.99,1.04,22.99,469.6,0.429,9.23,0.41,1.085,1.26,0.43,-999.99,6.74,1.77,0.505,0.004,0.007,0.131,13.25,209.66,10.22,21.84,44.33,0.234,0.006,0.546,0.171 45329,45342,405.19,1923.35,109.54,329.5,9.55,484.03,-47.703,-8.479,105.9,254.96,509.06,505.51,23.11,3.449,6.71,231.19,25.96,0.155,70.54,63.58,18.12,2.111,80.73,1.156,-999.99,1.5,27.99,445.3,0.439,10.1,0.414,1.121,1.15,0.42,-999.99,10.66,2.23,0.506,0.009,0.003,0.13,12.07,276.8,14.63,29.82,60.15,0.253,0.012,0.605,0.211 47890,47902,404.17,-999.99,75.27,328.13,-999.99,-999.99,-47.401,-8.426,100.82,247.7,501.18,540.42,22.41,3.403,7.21,226.33,25.06,0.058,69.97,58,12.05,2.047,79.51,0.656,-999.99,0.22,4.23,490,0.387,8.03,0.41,1.019,0.11,0.43,-999.99,3.03,0.44,0.494,-0.004,-0.003,0.107,10.04,108.94,2.14,7.86,15.35,0.163,0,0.445,0.088 48661,48671,406.21,-999.99,114.48,331.7,-999.99,-999.99,-47.731,-8.536,108.35,254.96,509.35,511.52,23.15,3.445,6.75,231.6,26,0.536,70.82,68.98,18.43,2.167,80.86,1.378,-999.99,2.4,44.23,450.4,0.454,10.12,0.431,1.234,1.93,0.45,-999.99,32.58,6.67,0.51,0.051,-0.001,0.167,12.58,338.28,35.67,54.05,100.62,0.317,0.013,0.668,0.32 50451,50464,404.79,-999.99,95.15,330.33,-999.99,-999.99,-47.534,-8.453,104.13,251.78,506.99,532.91,22.69,3.457,7.08,229.68,25.7,0.136,70.59,64.56,15.09,2.111,80.43,0.879,-999.99,0.78,20.23,480.2,0.414,9.46,0.413,1.085,0.86,0.45,-999.99,8.26,1.35,0.511,0.003,0.002,0.134,13.09,165.44,7.12,15.79,30.36,0.229,0.007,0.517,0.152 51777,51787,406.49,-999.99,120.56,330.92,-999.99,-999.99,-47.755,-8.538,109.1,254.78,507.48,518.27,23.12,3.492,6.92,230.73,26.01,0.345,70.5,70.39,18.62,2.168,80.49,1.225,-999.99,1.94,48.13,448.1,0.448,10.74,0.418,1.256,2.3,0.55,-999.99,37.85,8.39,0.525,0.009,0.002,0.171,12.63,399.77,40.68,66.66,127.48,0.292,-0.003,0.663,0.259 53613,53630,405.37,-999.99,96.18,330.58,-999.99,-999.99,-47.48,-8.476,104.41,251.37,505.07,558.97,22.58,3.45,7.21,230.13,25.56,0.1,70.83,61.32,12.93,2.11,80.66,0.784,-999.99,0.43,24.65,477.9,0.393,10.13,0.42,1.046,1.1,0.49,-999.99,41.44,8.26,0.504,-0.001,0.002,0.145,11.9,515,39.27,61.9,144.79,0.22,-0.016,0.42,0.141 54251,54261,406.66,-999.99,111.71,330.93,-999.99,-999.99,-47.511,-8.511,108.84,255.52,505.65,554.74,22.92,3.454,7.32,230.1,25.94,0.261,70.41,63.79,15.48,2.39,80.55,0.804,-999.99,0.63,58.06,478.2,0.423,12.17,0.418,1.086,2.8,0.49,-999.99,203.61,45.29,0.504,0.004,0.002,0.191,13.99,1902.85,174.52,252.52,651.93,0.278,0.003,0.681,0.168 55286,55294,404.48,-999.99,115,329.98,-999.99,-999.99,-47.75,-8.492,106.58,254.84,508.1,486.4,23.33,3.493,6.48,231.06,26.12,0.447,70.66,64.94,19.55,2.186,80.56,1.776,-999.99,5.47,54.52,434.6,0.441,10.18,0.42,1.133,2.26,0.41,1.44,29.68,6.04,0.51,0.174,0.008,0.154,12.09,318.92,38.37,64.22,98.22,0.314,0.009,0.657,0.399 55879,55888,408.86,-999.99,133.99,330.55,-999.99,-999.99,-47.739,-8.627,114.72,260.55,504.64,524.1,23.52,3.484,7.19,230.65,26.88,0.35,70.55,69.06,18.4,2.389,80.34,0.914,-999.99,0.97,65.31,442.7,0.458,18.91,0.422,1.226,4.4,0.51,-999.99,114.62,23.62,0.514,0.002,0.003,0.246,14.27,1307.92,117.39,162.37,396.38,0.322,0.001,0.698,0.221 58313,58330,404.23,-999.99,87.11,330.87,-999.99,-999.99,-47.503,-8.429,102.37,251.9,508.49,551.03,22.55,3.431,7.1,230.66,25.59,0.125,70.9,70.37,13.92,2.076,80.78,0.803,-999.99,0.47,15.45,487.8,0.4,7.74,0.42,1.058,0.31,0.43,-999.99,2.4,0.69,0.53,-0.001,0.002,0.12,15.13,82.33,2.39,8.14,11.14,0.188,0.002,0.535,0.126 58706,58715,405.95,-999.99,105.36,331.23,-999.99,-999.99,-47.534,-8.497,107.64,254.81,505.06,552.86,22.75,3.442,7.26,230.41,26,0.245,70.59,62.98,14.43,2.364,80.62,0.823,-999.99,0.58,43.51,480.3,0.416,12.09,0.417,1.094,2.17,0.47,-999.99,95.09,22.09,0.516,-0.001,-0.001,0.212,13.69,977.8,93.06,130.17,318.09,0.276,0.003,0.524,0.159