84, 1001 Montzka, S., Sweeney, C. Global Monitoring Division/ESRL/NOAA PFP; Flask measurements of trace gases from PFP flasks ATom 1,1 2017, 10, 14, 2019, 02, 27 0 Start_UTC, seconds 51 1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1 -999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 Stop_UTC, seconds, elapsed time since midnight (GMT) of the day of takeoff CO2_PFP, ppm, carbon dioxide, dry-air mole fraction, micro mole per mole (as part per million) CH4_PFP, ppb, methane, dry-air mole fraction, nano mole per mole (as part per billion) CO_PFP, ppb, carbon monoxide, dry-air mole fraction, nano mole per mole (as part per billion) N2O_PFP, ppb, nitrous oxide, dry-air mole fraction, nano mole per mole (as part per billion) SF6_CCGG_PFP, ppt, sulfur hexafluoride dry-air mole fraction, pico mole per mole (as part per trillion, or ppt), measured by electron capture detection in carbon cycle group H2_PFP, ppb, hydrogen, dry-air mole fraction, nano mole per mole (as part per billion) d13CH4_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CH4 relative to Vienna Pee Dee Belemnite d13CO2_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CO2 relative to Vienna Pee Dee Belemnite HFC134a_PFP, ppt, 1,1,1,2-tetrafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC22_PFP, ppt, chlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC12_PFP, ppt, dichlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3Cl_PFP, ppt, methyl chloride, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC142b_PFP, ppt, 1-chloro-1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H1211_PFP, ppt, bromodichlorofluoromethane (halon-1211), dry-air mole fraction, pico mole per mole (as part per trillion) CH3Br_PFP, ppt, methyl bromide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC11_PFP, ppt, trichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC141b_PFP, ppt, 1,1-chloro-1-fluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3I_PFP, ppt, methyl iodide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC113_PFP, ppt, 1,1,2-trichloro-1,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Cl2_PFP, ppt, dichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHCl3_PFP, ppt, trichloromethane (chloroform), dry-air mole fraction, pico mole per mole (as part per trillion) CH3CCl3_PFP, ppt, 1,1,1-trichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CCl4_PFP, ppt, tetrachloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Br2_PFP, ppt, dibromomethane, dry-air mole fraction, pico mole per mole (as part per trillion) C2Cl4_PFP, ppt, tetrachloroethylene, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr3_PFP, ppt, tribromomethane (bromorform), dry-air mole fraction, pico mole per mole (as part per trillion) Benzene_PFP, ppt, C6H6, dry-air mole fraction, pico mole per mole (as part per trillion) OCS_PFP, ppt, carbonyl sulfide, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC21_PFP, ppt, dichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC152a_PFP, ppt, 1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H2402_PFP, ppt, 1,2-dibromo-1,1,2,2-tetrafluoroethane (halon-2402, dry-air mole fraction, pico mole per mole (as part per trillion) HFC365mfc_PFP, ppt, 1,1,1,3,3-pentafluorobutane, dry-air mole fraction, pico mole per mole (as part per trillion) Propyne_PFP, ppt, C3H4, dry-air mole fraction, pico mole per mole (as part per trillion) C2H5Cl_PFP, prelim, chloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC227ea_PFP, ppt, 1,1,1,2,3,3,3-heptafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) nPentane_PFP, ppt, normal pentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) nHexane_PFP, ppt, normal hexane (C6H14), dry-air mole fraction, pico mole per mole (as part per trillion) HCFC133a_PFP, ppt, 1-chloro-2,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClI_PFP, ppt, chloroiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2I2_PFP, ppt, diiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrCl_PFP, ppt, bromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClCH2Cl_PFP, ppt, 1,2-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) Propane_PFP, ppt, C3H8, dry-air mole fraction, pico mole per mole (as part per trillion) iPentane_PFP, ppt, isopentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) iButane_PFP, ppt, isobutane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) nButane_PFP, ppt, normal butane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) CHBrCl2_PFP, ppt, bromodichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrI_PFP, ppt, bromoiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3CHCl2_PFP, prelim, 1,1-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr2Cl_PFP, ppt, dibromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) 0 19 PI_CONTACT_INFO: 303-497-6657 325 Broadway, Boulder CO 80305 email stephen.a.montzka@noaa.gov colm.sweeney@noaa.gov PLATFORM: NASA DC8 LOCATION: Aircraft location here with appropriate date indicated: http://espoarchive.nasa.gov/archive/fileinfo/MMS-FlightPath_DC8_YYYYMMDD.ict ASSOCIATED_DATA: See http://espoarchive.nasa.gov/archive/browse/atom INSTRUMENT_INFO: Programmable Flask Package results from multiple analysis instruments at NOAA and CU/INSTAAR DATA_INFO: N/A UNCERTAINTY: tbd ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: Steve Montzka, 303-497-6657, 325 Broadway, Boulder, CO 80305 PROJECT_INFO: ATom-2; 04-Dec-2016 to 22-Feb-2017; https://espo.nasa.gov/home/atom/content/ATom STIPULATIONS_ON_USE: Notification of S. Montzka or C. Sweeney is requested with use of data. OTHER_COMMENTS: all measurement results are given in dry-air mole fractions; results for two gases are on preliminary scales (not mole fractions) REVISION: R1 R0: preliminary data R1: final data, for public release Start_UTC,Stop_UTC,CO2_PFP,CH4_PFP,CO_PFP,N2O_PFP,SF6_CCGG_PFP,H2_PFP,d13CH4_PFP,d13CO2_PFP,HFC134a_PFP,HCFC22_PFP,CFC12_PFP,CH3Cl_PFP,HCFC142b_PFP,H1211_PFP,CH3Br_PFP,CFC11_PFP,HCFC141b_PFP,CH3I_PFP,CFC113_PFP,CH2Cl2_PFP,CHCl3_PFP,CH3CCl3_PFP,CCl4_PFP,CH2Br2_PFP,C2Cl4_PFP,CHBr3_PFP,Benzene_PFP,OCS_PFP,HCFC21_PFP,HFC152a_PFP,H2402_PFP,HFC365mfc_PFP,Propyne_PFP,C2H5Cl_PFP,HFC227ea_PFP,nPentane_PFP,nHexane_PFP,HCFC133a_PFP,CH2ClI_PFP,CH2I2_PFP,CH2BrCl_PFP,CH2ClCH2Cl_PFP,Propane_PFP,iPentane_PFP,iButane_PFP,nButane_PFP,CHBrCl2_PFP,CH2BrI_PFP,CH3CHCl2_PFP,CHBr2Cl_PFP 45404,45428,404.36,1814.45,69.97,326.12,9.1,532.73,-47.2,-8.497,92.34,233.41,502.88,560.63,21.61,3.368,6.31,222.66,22.59,0.036,67.23,15.82,2.41,1.419,72.32,0.103,-999.99,0.01,0.49,446.2,0.258,4.91,0.37,0.601,0.15,0.09,-999.99,0.87,0.52,0.417,-0.001,-0.001,0.033,0.2,9.37,0.06,0.29,0.63,0.016,0.015,0.101,0.004 46601,46608,404.15,1816.41,59.36,328.93,9.1,519.88,-47.309,-8.477,91.9,232.4,507.88,538.14,21.52,3.439,5.94,227.52,23.8,0.087,70.87,20.4,7.21,2.186,78.79,0.993,-999.99,1.15,6.31,483,0.266,4.85,0.408,0.854,0.33,0.19,1.29,1.77,0.63,0.414,-0.002,0.009,0.113,1.93,19.88,1,2.86,3.25,0.203,-0.011,0.074,0.204 47358,47367,404.12,1818.21,64.01,329.67,9.17,521.92,-47.309,-8.475,92.49,233.75,506.49,552.54,21.7,3.41,6.22,227.36,23.87,0.039,70.79,20.79,7.36,2.146,78.92,0.938,-999.99,0.62,4.65,482.8,0.262,4.87,0.408,0.859,0.1,0.11,-999.99,0.95,0.55,0.424,0.003,-0.005,0.124,1.88,16.61,0.6,2.24,2.58,0.194,0.008,0.094,0.142 47520,47533,404.14,1817.36,66.45,329.28,9.15,524.54,-47.255,-8.499,92.49,233.45,505.82,557.17,21.57,3.405,6.29,226.72,24.05,0.031,70.56,21.34,6.87,2.109,79.05,0.909,-999.99,0.39,3.4,478.6,0.259,4.89,0.407,0.883,0.11,0.11,-999.99,0.64,0.78,0.42,-0.002,0.003,0.107,1.93,16.91,0.42,1.02,1.82,0.172,0.009,0.061,0.138 48094,48111,404.25,1810.99,59.54,326.37,9.17,530.43,-47.227,-8.486,91.6,233.03,502.18,555.16,21.45,3.315,6.55,223.2,24.04,0.027,69.22,19.67,4.42,1.748,76.19,0.267,-999.99,0.03,1.26,452.2,0.253,4.99,0.395,0.802,1.72,0.1,-999.99,0.66,0.72,0.424,0.002,0,0.073,0.51,11.15,0.3,1.03,1.53,0.055,0.035,0.081,0.017 49001,49026,404.76,1814.09,76.39,325.28,9.14,534.93,-47.225,-8.489,92.1,233.49,500.97,559.71,21.57,3.342,6.47,223.05,23.1,0.028,68.11,19.31,3.68,1.614,74.15,0.207,-999.99,0.01,0.69,446.7,0.249,4.95,0.377,0.816,0.11,0.08,-999.99,0.59,0.79,0.429,0.001,0,0.058,0.49,15.15,0.14,1.28,1.09,0.031,-0.011,0.094,0.018 52668,52702,404.66,1826.32,86.65,328.21,9.15,533.62,-47.259,-8.488,93.55,234.84,505.87,576.7,21.63,3.362,6.64,225.83,23.32,0.028,68.5,20.79,4.21,1.71,74.97,0.315,-999.99,0.03,1.22,465.9,0.259,5.01,0.377,0.765,0.05,0.11,-999.99,0.77,0.82,0.416,0.004,0,0.071,0.8,20.77,0.23,1.13,1.99,0.052,0.005,0.118,0.016 54749,54757,403.99,1816.75,59.68,328.99,9.16,521.46,-47.242,-8.463,91.84,232.4,505.34,543.55,21.73,3.405,6.06,226.54,23.59,0.049,70.4,20.47,7.22,2.19,78.6,1.005,-999.99,1.31,6.25,485.4,0.254,4.87,0.395,0.865,-0.03,0.17,1.32,0.98,0.65,0.416,-0.003,0,0.105,2,17.15,0.57,2.07,2.32,0.196,-0.01,0.115,0.198 55491,55501,403.94,1818.3,66.99,329.22,9.11,524.31,-47.281,-8.462,92.63,232.96,505.63,553.42,21.72,3.38,6.25,226.7,23.72,0.023,70.57,20.78,6.83,2.062,78.56,0.875,-999.99,0.35,3.4,485.4,0.263,4.95,0.412,0.858,1.5,0.11,-999.99,1.36,0.87,0.417,-0.002,-0.001,0.103,1.76,19.63,0.7,2.06,3.54,0.17,0.003,0.065,0.121 57620,57652,404.53,1820.29,78.72,328.07,9.2,532.17,-47.233,-8.465,92.59,233.55,504.6,565.11,21.59,3.354,6.41,224.2,23.02,0.026,67.65,19.75,3.81,1.664,73.79,0.273,-999.99,0.02,0.79,462.7,0.265,4.87,0.382,0.719,0.15,0.11,-999.99,0.76,0.52,0.409,-0.002,0.003,0.076,0.59,16,0.2,1.13,1.65,0.041,-0.005,0.061,0.013 61176,61206,404.08,1809.07,62.87,326.1,9.1,531.72,-47.212,-8.486,91.67,232.86,500.35,553.67,21.49,3.309,6.38,222.36,22.6,0.026,67.53,18.76,3.35,1.61,72.82,0.185,-999.99,0.02,0.54,457.4,0.252,5,0.372,0.729,-0.04,0.09,-999.99,0.64,0.84,0.406,0.002,-0.001,0.059,0.43,7.37,0.25,0.83,0.95,0.042,0,0.045,0.164 65141,65153,404.03,1816.73,65.92,328.59,9.09,524.1,-47.303,-8.476,92.49,233.72,508.66,552.5,21.67,3.433,6.19,227.64,23.64,0.047,70.51,20.7,7.01,2.165,79.07,0.959,-999.99,0.54,4.88,479.1,0.26,4.85,0.408,0.877,0.09,0.1,-999.99,0.97,0.55,0.41,0,-0.003,0.106,1.94,14.53,0.55,1.78,3.07,0.175,0,0.127,0.003 65944,65951,404.07,1815.46,58.26,328.42,9.09,520.38,-47.24,-8.475,91.62,232.24,507.7,539.68,21.58,3.401,5.92,227.15,23.58,0.041,70.69,19.98,7.2,2.183,78.82,0.973,-999.99,1.97,5.21,480.3,0.255,4.93,0.416,0.855,0.03,0.31,1.31,0.77,0.42,0.396,0.001,0.001,0.135,1.87,14.12,0.53,1.9,2.28,0.207,-0.004,0.081,0.131 66454,66463,404.06,1815.36,62.84,329.46,9.14,519.79,-47.178,-8.469,92.21,233.38,506.65,549.88,21.63,3.407,6.17,228.07,23.71,0.06,70.85,20.68,7.18,2.166,79.16,0.972,-999.99,0.66,5.51,482.9,0.252,4.94,0.421,0.866,0.51,0.1,-999.99,1.79,0.67,0.409,-0.001,-0.001,0.128,1.98,20.65,1.13,3.12,4.83,0.173,-0.017,0.092,0.271 66942,66958,404.09,1821.48,73.63,329.34,9.18,526.17,-47.303,-8.463,92.72,233.8,507.13,561.09,21.7,3.37,6.38,227.41,23.6,0.02,70.45,21,6.92,1.989,78.7,0.755,-999.99,0.15,1.91,472.6,0.25,4.96,0.402,0.883,0.21,0.1,-999.99,0.57,0.57,0.409,0.001,-0.002,0.109,1.52,20.93,0.5,1.69,3.27,0.147,0.011,0.058,0.144 67661,67692,404.59,1816.03,69.92,326.67,9.15,531.7,-47.266,-8.506,92.28,234.05,504.27,562.53,21.65,3.339,6.56,224.95,23.47,0.024,69.81,20.66,4.79,1.883,77.42,0.359,-999.99,0.03,0.69,462.2,0.257,4.97,0.402,0.901,0.28,0.09,-999.99,0.67,0.72,0.43,0.001,0.002,0.079,0.77,14.18,0.17,1.18,1.59,0.057,0.002,0.064,0.081 68810,68816,404.09,1815.55,57.42,329.41,9.14,519.42,-47.295,-8.495,91.36,231.98,505.27,539.23,21.52,3.374,5.93,226.71,23.54,0.037,70.44,20.18,6.97,2.189,78.68,0.992,-999.99,1.44,5.3,477.9,0.258,4.82,0.42,0.855,-0.1,0.1,1.26,1.47,1.56,0.419,0.002,-0.001,0.115,1.89,14.57,0.53,1.71,2.36,0.203,-0.013,0.121,0.02 69582,69596,404.04,1817.14,64.63,329.08,9.22,523.07,-47.27,-8.472,92.26,233.61,509.2,548.18,21.61,3.364,6.11,227.51,23.6,0.027,70.7,20.39,6.94,2.097,79,0.92,-999.99,0.43,3.39,477.3,0.257,4.91,0.414,0.875,0.07,0.11,-999.99,0.6,0.64,0.414,0.001,0.003,0.114,1.76,14.91,0.38,1.41,2.6,0.178,0.011,0.049,0.224 73139,73180,403.24,1758.83,34.68,313.37,8.88,540.03,-46.827,-8.487,87.71,227.78,484.56,506.51,21.21,2.967,5.6,206.42,20.79,0.034,62.29,13.71,1.29,1.282,63.1,0.068,-999.99,0.02,0.92,419.5,0.248,4.87,0.311,0.526,0.16,0.06,-999.99,0.69,0.82,0.395,0.003,0.001,0.019,0.19,2.75,0.32,1.65,1.73,0.003,0.018,0.107,0.122 73417,73439,404.37,1816.11,72.08,326.66,9.08,532.72,-47.252,-8.488,92.03,233.07,501.64,561.47,21.58,3.366,6.52,224.26,23.34,0.026,69.3,20.29,3.65,1.868,76.32,0.298,-999.99,0.03,0.69,463.5,0.258,5.08,0.41,0.876,0.71,0.1,-999.99,0.7,1.01,0.42,0.002,-0.002,0.086,0.72,16.7,0.34,1.22,2.32,0.035,-0.013,0.046,0 73649,73664,404.29,1819.37,75.48,329.05,9.16,529.42,-47.24,-8.473,93.18,234.63,508.33,569.06,21.74,3.393,6.6,228.33,23.72,0.033,70.75,21.22,6.6,2.123,79.6,0.903,-999.99,0.33,5.04,481.8,0.26,5.08,0.42,0.907,0.48,0.09,-999.99,0.85,0.67,0.413,0.001,0.005,0.112,2.03,14.04,0.52,1.81,2.95,0.168,-0.009,0.087,0.016 73995,74003,404.05,1818.6,62.77,328.28,9.1,523.09,-47.418,-8.486,92.06,232.94,507.74,547.95,21.64,3.404,6.14,227.02,23.65,0.047,70.39,20.9,7.02,2.166,78.97,0.989,-999.99,0.54,5.06,479.2,0.259,5.02,0.408,0.864,0.35,0.1,-999.99,1.36,0.83,0.421,0,-0.004,0.126,2.01,19.91,0.78,2.71,3.9,0.172,-0.004,0.119,0.109 74503,74511,403.98,1816.59,59.68,328.93,9.12,519.86,-47.288,-8.473,91.94,231.8,506.89,537.89,21.45,3.387,5.88,227.08,23.71,0.069,70.58,20.19,7.15,2.134,78.92,0.96,-999.99,1.09,5.8,478.9,0.255,4.95,0.407,0.869,1.29,0.19,1.36,1.63,0.78,0.411,0,0.004,0.12,1.82,19.56,0.99,2.62,3.52,0.205,-0.003,0.062,0.142