84, 1001 Montzka, S., Sweeney, C. Global Monitoring Division/ESRL/NOAA PFP; Flask measurements of trace gases from PFP flasks ATom 1,1 2017, 10, 08, 2019, 02, 27 0 Start_UTC, seconds 51 1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1 -999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 Stop_UTC, seconds, elapsed time since midnight (GMT) of the day of takeoff CO2_PFP, ppm, carbon dioxide, dry-air mole fraction, micro mole per mole (as part per million) CH4_PFP, ppb, methane, dry-air mole fraction, nano mole per mole (as part per billion) CO_PFP, ppb, carbon monoxide, dry-air mole fraction, nano mole per mole (as part per billion) N2O_PFP, ppb, nitrous oxide, dry-air mole fraction, nano mole per mole (as part per billion) SF6_CCGG_PFP, ppt, sulfur hexafluoride dry-air mole fraction, pico mole per mole (as part per trillion, or ppt), measured by electron capture detection in carbon cycle group H2_PFP, ppb, hydrogen, dry-air mole fraction, nano mole per mole (as part per billion) d13CH4_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CH4 relative to Vienna Pee Dee Belemnite d13CO2_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CO2 relative to Vienna Pee Dee Belemnite HFC134a_PFP, ppt, 1,1,1,2-tetrafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC22_PFP, ppt, chlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC12_PFP, ppt, dichlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3Cl_PFP, ppt, methyl chloride, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC142b_PFP, ppt, 1-chloro-1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H1211_PFP, ppt, bromodichlorofluoromethane (halon-1211), dry-air mole fraction, pico mole per mole (as part per trillion) CH3Br_PFP, ppt, methyl bromide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC11_PFP, ppt, trichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC141b_PFP, ppt, 1,1-chloro-1-fluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3I_PFP, ppt, methyl iodide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC113_PFP, ppt, 1,1,2-trichloro-1,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Cl2_PFP, ppt, dichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHCl3_PFP, ppt, trichloromethane (chloroform), dry-air mole fraction, pico mole per mole (as part per trillion) CH3CCl3_PFP, ppt, 1,1,1-trichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CCl4_PFP, ppt, tetrachloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Br2_PFP, ppt, dibromomethane, dry-air mole fraction, pico mole per mole (as part per trillion) C2Cl4_PFP, ppt, tetrachloroethylene, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr3_PFP, ppt, tribromomethane (bromorform), dry-air mole fraction, pico mole per mole (as part per trillion) Benzene_PFP, ppt, C6H6, dry-air mole fraction, pico mole per mole (as part per trillion) OCS_PFP, ppt, carbonyl sulfide, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC21_PFP, ppt, dichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC152a_PFP, ppt, 1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H2402_PFP, ppt, 1,2-dibromo-1,1,2,2-tetrafluoroethane (halon-2402, dry-air mole fraction, pico mole per mole (as part per trillion) HFC365mfc_PFP, ppt, 1,1,1,3,3-pentafluorobutane, dry-air mole fraction, pico mole per mole (as part per trillion) Propyne_PFP, ppt, C3H4, dry-air mole fraction, pico mole per mole (as part per trillion) C2H5Cl_PFP, prelim, chloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC227ea_PFP, ppt, 1,1,1,2,3,3,3-heptafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) nPentane_PFP, ppt, normal pentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) nHexane_PFP, ppt, normal hexane (C6H14), dry-air mole fraction, pico mole per mole (as part per trillion) HCFC133a_PFP, ppt, 1-chloro-2,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClI_PFP, ppt, chloroiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2I2_PFP, ppt, diiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrCl_PFP, ppt, bromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClCH2Cl_PFP, ppt, 1,2-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) Propane_PFP, ppt, C3H8, dry-air mole fraction, pico mole per mole (as part per trillion) iPentane_PFP, ppt, isopentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) iButane_PFP, ppt, isobutane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) nButane_PFP, ppt, normal butane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) CHBrCl2_PFP, ppt, bromodichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrI_PFP, ppt, bromoiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3CHCl2_PFP, prelim, 1,1-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr2Cl_PFP, ppt, dibromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) 0 19 PI_CONTACT_INFO: 303-497-6657 325 Broadway, Boulder CO 80305 email stephen.a.montzka@noaa.gov colm.sweeney@noaa.gov PLATFORM: NASA DC8 LOCATION: Aircraft location here with appropriate date indicated: http://espoarchive.nasa.gov/archive/fileinfo/MMS-FlightPath_DC8_YYYYMMDD.ict ASSOCIATED_DATA: See http://espoarchive.nasa.gov/archive/browse/atom INSTRUMENT_INFO: Programmable Flask Package results from multiple analysis instruments at NOAA and CU/INSTAAR DATA_INFO: N/A UNCERTAINTY: tbd ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: Steve Montzka, 303-497-6657, 325 Broadway, Boulder, CO 80305 PROJECT_INFO: ATom-2; 04-Dec-2016 to 22-Feb-2017; https://espo.nasa.gov/home/atom/content/ATom STIPULATIONS_ON_USE: Notification of S. Montzka or C. Sweeney is requested with use of data. OTHER_COMMENTS: all measurement results are given in dry-air mole fractions; results for two gases are on preliminary scales (not mole fractions) REVISION: R1 R0: preliminary data R1: final data, for public release Start_UTC,Stop_UTC,CO2_PFP,CH4_PFP,CO_PFP,N2O_PFP,SF6_CCGG_PFP,H2_PFP,d13CH4_PFP,d13CO2_PFP,HFC134a_PFP,HCFC22_PFP,CFC12_PFP,CH3Cl_PFP,HCFC142b_PFP,H1211_PFP,CH3Br_PFP,CFC11_PFP,HCFC141b_PFP,CH3I_PFP,CFC113_PFP,CH2Cl2_PFP,CHCl3_PFP,CH3CCl3_PFP,CCl4_PFP,CH2Br2_PFP,C2Cl4_PFP,CHBr3_PFP,Benzene_PFP,OCS_PFP,HCFC21_PFP,HFC152a_PFP,H2402_PFP,HFC365mfc_PFP,Propyne_PFP,C2H5Cl_PFP,HFC227ea_PFP,nPentane_PFP,nHexane_PFP,HCFC133a_PFP,CH2ClI_PFP,CH2I2_PFP,CH2BrCl_PFP,CH2ClCH2Cl_PFP,Propane_PFP,iPentane_PFP,iButane_PFP,nButane_PFP,CHBrCl2_PFP,CH2BrI_PFP,CH3CHCl2_PFP,CHBr2Cl_PFP 74192,74210,405.57,1829.7,116.63,329.24,9.2,534.94,-47.35,-8.474,94.21,236.25,509.1,600.87,21.64,3.411,7.18,227.67,23.76,0.082,70.37,23.35,6.33,2.023,79.19,0.816,-999.99,0.51,15.48,491.5,0.273,4.97,0.409,0.872,1.43,0.15,-999.99,3.28,0.65,0.415,0,0.005,0.105,2.43,26.49,0.45,0.92,2.29,0.18,-0.003,0.065,0.135 75040,75049,404.5,1821.37,87.5,329.39,9.21,528.45,-47.365,-8.46,93.71,234.62,506.78,572.38,21.58,3.366,6.73,227.16,23.87,0.037,70.62,22.22,6.37,2.077,78.73,0.798,-999.99,0.32,6.91,489,0.259,5.17,0.396,0.869,0.4,0.13,-999.99,1.42,0.74,0.431,-0.001,0.001,0.104,2.22,19.23,0.28,0.71,1.43,0.168,-0.016,0.052,0.119 75461,75469,403.4,1811.98,69.59,329.1,9.22,527.68,-47.276,-8.418,93.06,233.94,508.59,559.45,21.58,3.365,6.3,228.42,23.98,0.628,70.99,20.72,6.97,2.09,79.13,0.916,-999.99,0.53,6.15,494.3,0.25,4.84,0.396,0.856,0.43,0.14,1.37,4.98,0.79,0.408,0.022,0.003,0.115,2,9.23,2.62,5.56,0.96,0.179,-0.019,0.061,0.143 76496,76509,405.86,1832.85,120.55,329.43,9.21,538.89,-47.343,-8.466,94.4,236.03,508.1,599.01,21.73,3.415,7.04,227.82,24.31,0.07,70.74,23.41,6.27,2.027,79.16,0.797,-999.99,0.4,19.78,492.5,0.255,5.05,0.418,0.883,1.22,0.23,-999.99,3.99,0.69,0.429,0.005,0.002,0.1,2.43,31.31,0.69,1.59,2.3,0.172,-0.001,0.05,0.119 77137,77153,405.89,1829.44,120.59,329.35,9.24,538.86,-47.263,-8.49,94.16,236.09,505.68,600.09,21.75,3.367,7.04,227,23.99,0.054,70.5,24.03,6.2,2.071,78.85,0.769,-999.99,0.53,15.52,489.7,0.269,5.07,0.392,0.883,1.25,0.19,-999.99,2.7,0.6,0.424,0.001,0.002,0.104,2.55,33.95,0.59,1.7,3.03,0.162,0.007,0.046,0.102 78112,78121,403.85,1815.02,73.89,328.95,9.19,530.26,-47.245,-8.452,93.59,235.04,509,563.82,21.63,3.395,6.38,228.71,24.25,0.582,70.71,21.29,6.85,2.077,79.27,0.874,-999.99,0.48,6.82,497.3,0.257,4.94,0.414,0.872,0.49,0.15,-999.99,6.48,0.74,0.419,0.008,0.006,0.12,2.06,8.65,2.08,4.21,1.08,0.171,-0.002,0.076,0.134 78531,78537,403.47,1814.28,69.22,328.58,9.12,527.93,-47.332,-8.415,92.3,233.43,508.11,559.18,21.62,3.353,6.37,226.96,23.76,0.591,70.45,20.72,7.08,2.081,78.92,0.911,-999.99,0.58,6.35,493.4,0.257,4.87,0.403,0.863,0.3,0.16,1.37,6.31,0.87,0.415,0.038,0.008,0.126,2.02,9.14,2.06,4.05,0.83,0.176,0.004,0.054,0.146 80306,80326,405.38,1826.72,104.59,328.49,9.22,537.81,-47.277,-8.496,93.34,234.87,505.96,587.52,21.53,3.404,6.89,226.42,23.84,0.057,70.13,22.99,6.21,2.076,78.64,0.778,-999.99,0.46,11.66,492,0.267,4.97,0.399,0.879,0.42,0.23,-999.99,3.79,0.78,0.426,0.008,0,0.11,2.29,27.32,0.78,1.76,2.49,0.158,0.017,0.064,0.104 82672,82682,404.35,1816.6,79.18,329.07,9.13,529.79,-47.282,-8.449,92.97,234.04,506.29,568.39,21.66,3.402,6.72,227.32,24.27,0.311,70.65,21.03,6.64,2.064,79.14,0.899,-999.99,0.58,7.7,495.3,0.258,4.88,0.412,0.865,0.33,0.2,-999.99,6.66,0.75,0.418,0.005,-0.001,0.098,2.05,12.45,1.29,2.66,1.46,0.186,0.003,0.043,0.146 82969,82977,404.46,1823.94,86.9,329.43,9.18,532.63,-47.301,-8.45,93.29,235.28,509.5,571.95,21.67,3.401,6.58,227.55,24,0.068,70.79,21.93,6.44,2.105,79.02,0.813,-999.99,0.43,10.26,494.2,0.259,5.04,0.406,0.858,0.48,0.17,1.35,2.52,0.75,0.419,0.002,0.002,0.114,2.13,18.78,0.75,1.9,1.75,0.174,0.001,0.05,0.119 83291,83297,402.99,1821.31,68,329.72,9.12,526.19,-47.372,-8.409,93.26,234.24,508.41,577.79,21.67,3.404,6.47,227.99,24.38,0.42,70.75,21.23,7.07,2.106,78.89,0.956,-999.99,0.7,7.28,491.1,0.256,5.21,0.412,0.867,5.18,0.17,1.4,4.78,1.03,0.404,0.042,0.003,0.1,1.94,16.16,1.83,3.81,4.42,0.189,-0.012,0.06,0.138 85271,85296,406.45,1840.9,139.18,329.51,9.25,546.86,-47.339,-8.508,95.47,237.66,508.91,617.65,21.7,3.403,7.04,228.36,24.36,0.049,70.81,24.71,6.11,2.028,79.16,0.721,-999.99,0.3,12.52,492.5,0.269,5.14,0.408,0.875,0.61,0.23,-999.99,5.53,0.95,0.432,0.003,0.002,0.101,2.42,52.03,0.84,2.02,3.96,0.153,-0.019,0.063,0.076 86888,86895,403.36,1817.97,60.96,328.77,9.18,521.67,-47.169,-8.446,92.14,231.79,506.57,547.66,21.74,3.36,6.02,227.21,23.83,0.187,70.49,20.79,7.24,2.16,79,1.044,-999.99,1.11,7.14,489.7,0.258,4.81,0.405,0.859,0.22,0.22,1.27,6.34,1.08,0.404,0.007,0.002,0.121,2.07,18.92,1.4,2.96,3.44,0.208,0,0.128,0.199 87358,87366,404.44,1822.32,82.16,330.15,9.3,532.86,-47.255,-8.445,93.7,234.42,505.95,565.46,21.84,3.374,6.57,226.9,23.89,0.041,70.24,22.42,5.89,2.07,79.34,0.783,-999.99,0.24,9.51,491.3,0.251,4.96,0.427,0.872,0.16,0.21,-999.99,5.53,2.61,0.417,0.001,0.003,0.108,2.29,15.49,0.76,1.38,1.26,0.145,0,0.087,0.087 87621,87632,404.53,1829.1,92.9,329.56,9.24,533.5,-47.311,-8.45,93.45,235.3,506.78,575.75,21.88,3.345,6.62,227.89,24.08,0.037,70.82,23.08,6.3,2.064,79.28,0.826,-999.99,0.3,11.41,492.3,0.257,5.01,0.401,0.883,0.32,0.19,-999.99,4.77,0.54,0.42,-0.002,0.003,0.123,2.28,31.96,0.9,2.56,3.78,0.159,0.013,0.098,0.095 89070,89100,407.04,1843.09,149.57,330.37,9.27,550.65,-47.093,-8.502,94.69,236.52,507.44,621.77,21.77,3.381,7.13,227.99,23.95,0.043,70.31,24.14,5.87,2.032,79.12,0.643,-999.99,0.14,10.22,481.4,0.267,5.15,0.402,0.889,0.47,0.19,-999.99,3.67,0.84,0.429,-0.001,0,0.105,2.2,47.23,0.54,2.07,3.7,0.131,-0.007,0.067,0.069 89806,89817,404.38,1827.35,87.74,329.93,9.19,532.05,-47.191,-8.444,93.21,234.97,506.49,570.4,21.74,3.398,6.55,227.7,24.03,0.027,70.61,22.61,6.09,2.114,79,0.824,-999.99,0.28,11.91,492.6,0.263,4.96,0.417,0.865,0.27,0.11,-999.99,3.21,2.05,0.421,0.001,0.006,0.111,2.2,40.29,1,3.33,6.48,0.164,-0.005,0.091,0.102 90190,90198,403.91,1817.44,72.4,329.24,9.22,528.29,-47.175,-8.428,92.73,233.77,505.84,554.7,21.65,3.344,6.32,227.64,23.85,0.073,70.35,21.14,6.3,2.106,79.03,0.847,-999.99,0.4,7.79,492.2,0.246,4.8,0.41,0.869,0.11,0.14,1.31,2.87,0.5,0.418,0.002,0.001,0.103,2,16.37,0.46,1.07,1.6,0.169,0.007,0.116,0.109 90437,90443,403.52,1816.58,64.08,329.61,9.22,523.14,-47.191,-8.438,92.09,232.63,506.83,546.49,21.65,3.389,6.15,227.29,23.81,0.276,70.76,20.94,6.9,2.14,78.85,0.985,-999.99,0.72,7.55,494,0.254,4.82,0.403,0.867,0.46,0.32,1.27,5.7,1.13,0.41,0.008,0.003,0.132,2.03,19.17,1.08,2.36,2.74,0.192,-0.001,0.122,0.16 94521,94550,404.74,1818.65,73.71,326.83,9.17,534.28,-47.181,-8.449,93.19,234.86,503.21,570.86,21.72,3.308,6.8,224.53,23.69,0.046,69.92,24.07,5.77,2.042,77.53,0.647,-999.99,0.21,3.79,480.2,0.264,5.03,0.399,0.867,0.25,0.17,-999.99,5.81,1.67,0.42,0.001,0.004,0.12,2.04,17.52,0.69,1.53,2.6,0.133,-0.004,0.136,0.087 95299,95311,404.47,1828.46,95.2,329.3,9.19,533.26,-47.237,-8.447,93.36,235.08,507.36,575.53,21.81,3.426,6.6,228.17,23.75,0.044,70.46,22.9,6.16,2.085,79.02,0.841,-999.99,0.37,15.78,490.2,0.263,4.95,0.412,0.887,0.29,0.16,-999.99,5.79,0.69,0.43,-0.001,0.002,0.124,2.15,40.21,1.02,3.01,5.42,0.164,-0.003,0.055,0.116 95599,95606,404.32,1821.69,73.32,328.73,9.16,531.23,-47.223,-8.419,93.7,235.11,507.59,563.31,21.91,3.387,6.53,228.04,23.95,0.029,70.73,22.33,5.75,2.071,79.71,0.744,-999.99,0.27,6.55,497.1,0.257,5.02,0.409,0.871,0.1,0.15,1.27,7.24,1.71,0.421,0.003,0,0.112,2.18,9.59,0.79,0.59,1.09,0.143,0.002,0.088,0.084 95942,95948,402.77,1820.34,64.96,329.26,9.11,518.89,-47.223,-8.393,92.24,232.64,506.12,551.01,21.95,3.396,6.03,227.24,23.87,0.213,70.56,21.38,7.81,2.129,78.88,0.979,-999.99,0.82,9.61,483.9,0.261,4.9,0.404,0.862,1.19,0.26,1.26,12.11,1.57,0.412,0.019,0.011,0.121,2.05,21.46,2.77,3.72,5.29,0.195,0.022,0.118,0.175 103134,103141,403.64,1820.44,75.02,328.88,9.14,525.31,-47.242,-8.419,93.62,234.47,508.52,578.8,22.08,3.372,6.82,227.96,23.84,0.188,70.89,21.94,7.57,2.085,79.24,0.906,-999.99,0.65,9.59,495.8,0.25,4.87,0.407,0.865,0.31,0.26,1.28,13.05,0.58,0.421,0.006,0.006,0.12,2.1,19.78,2.38,2.8,3.69,0.209,0.015,0.057,0.147