84, 1001 Montzka, S., Sweeney, C. Global Monitoring Division/ESRL/NOAA PFP; Flask measurements of trace gases from PFP flasks ATom 1,1 2017, 10, 06, 2019, 02, 27 0 Start_UTC, seconds 51 1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1 -999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 Stop_UTC, seconds, elapsed time since midnight (GMT) of the day of takeoff CO2_PFP, ppm, carbon dioxide, dry-air mole fraction, micro mole per mole (as part per million) CH4_PFP, ppb, methane, dry-air mole fraction, nano mole per mole (as part per billion) CO_PFP, ppb, carbon monoxide, dry-air mole fraction, nano mole per mole (as part per billion) N2O_PFP, ppb, nitrous oxide, dry-air mole fraction, nano mole per mole (as part per billion) SF6_CCGG_PFP, ppt, sulfur hexafluoride dry-air mole fraction, pico mole per mole (as part per trillion, or ppt), measured by electron capture detection in carbon cycle group H2_PFP, ppb, hydrogen, dry-air mole fraction, nano mole per mole (as part per billion) d13CH4_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CH4 relative to Vienna Pee Dee Belemnite d13CO2_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CO2 relative to Vienna Pee Dee Belemnite HFC134a_PFP, ppt, 1,1,1,2-tetrafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC22_PFP, ppt, chlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC12_PFP, ppt, dichlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3Cl_PFP, ppt, methyl chloride, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC142b_PFP, ppt, 1-chloro-1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H1211_PFP, ppt, bromodichlorofluoromethane (halon-1211), dry-air mole fraction, pico mole per mole (as part per trillion) CH3Br_PFP, ppt, methyl bromide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC11_PFP, ppt, trichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC141b_PFP, ppt, 1,1-chloro-1-fluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3I_PFP, ppt, methyl iodide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC113_PFP, ppt, 1,1,2-trichloro-1,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Cl2_PFP, ppt, dichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHCl3_PFP, ppt, trichloromethane (chloroform), dry-air mole fraction, pico mole per mole (as part per trillion) CH3CCl3_PFP, ppt, 1,1,1-trichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CCl4_PFP, ppt, tetrachloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Br2_PFP, ppt, dibromomethane, dry-air mole fraction, pico mole per mole (as part per trillion) C2Cl4_PFP, ppt, tetrachloroethylene, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr3_PFP, ppt, tribromomethane (bromorform), dry-air mole fraction, pico mole per mole (as part per trillion) Benzene_PFP, ppt, C6H6, dry-air mole fraction, pico mole per mole (as part per trillion) OCS_PFP, ppt, carbonyl sulfide, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC21_PFP, ppt, dichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC152a_PFP, ppt, 1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H2402_PFP, ppt, 1,2-dibromo-1,1,2,2-tetrafluoroethane (halon-2402, dry-air mole fraction, pico mole per mole (as part per trillion) HFC365mfc_PFP, ppt, 1,1,1,3,3-pentafluorobutane, dry-air mole fraction, pico mole per mole (as part per trillion) Propyne_PFP, ppt, C3H4, dry-air mole fraction, pico mole per mole (as part per trillion) C2H5Cl_PFP, prelim, chloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC227ea_PFP, ppt, 1,1,1,2,3,3,3-heptafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) nPentane_PFP, ppt, normal pentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) nHexane_PFP, ppt, normal hexane (C6H14), dry-air mole fraction, pico mole per mole (as part per trillion) HCFC133a_PFP, ppt, 1-chloro-2,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClI_PFP, ppt, chloroiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2I2_PFP, ppt, diiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrCl_PFP, ppt, bromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClCH2Cl_PFP, ppt, 1,2-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) Propane_PFP, ppt, C3H8, dry-air mole fraction, pico mole per mole (as part per trillion) iPentane_PFP, ppt, isopentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) iButane_PFP, ppt, isobutane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) nButane_PFP, ppt, normal butane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) CHBrCl2_PFP, ppt, bromodichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrI_PFP, ppt, bromoiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3CHCl2_PFP, prelim, 1,1-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr2Cl_PFP, ppt, dibromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) 0 19 PI_CONTACT_INFO: 303-497-6657 325 Broadway, Boulder CO 80305 email stephen.a.montzka@noaa.gov colm.sweeney@noaa.gov PLATFORM: NASA DC8 LOCATION: Aircraft location here with appropriate date indicated: http://espoarchive.nasa.gov/archive/fileinfo/MMS-FlightPath_DC8_YYYYMMDD.ict ASSOCIATED_DATA: See http://espoarchive.nasa.gov/archive/browse/atom INSTRUMENT_INFO: Programmable Flask Package results from multiple analysis instruments at NOAA and CU/INSTAAR DATA_INFO: N/A UNCERTAINTY: tbd ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: Steve Montzka, 303-497-6657, 325 Broadway, Boulder, CO 80305 PROJECT_INFO: ATom-2; 04-Dec-2016 to 22-Feb-2017; https://espo.nasa.gov/home/atom/content/ATom STIPULATIONS_ON_USE: Notification of S. Montzka or C. Sweeney is requested with use of data. OTHER_COMMENTS: all measurement results are given in dry-air mole fractions; results for two gases are on preliminary scales (not mole fractions) REVISION: R1 R0: preliminary data R1: final data, for public release Start_UTC,Stop_UTC,CO2_PFP,CH4_PFP,CO_PFP,N2O_PFP,SF6_CCGG_PFP,H2_PFP,d13CH4_PFP,d13CO2_PFP,HFC134a_PFP,HCFC22_PFP,CFC12_PFP,CH3Cl_PFP,HCFC142b_PFP,H1211_PFP,CH3Br_PFP,CFC11_PFP,HCFC141b_PFP,CH3I_PFP,CFC113_PFP,CH2Cl2_PFP,CHCl3_PFP,CH3CCl3_PFP,CCl4_PFP,CH2Br2_PFP,C2Cl4_PFP,CHBr3_PFP,Benzene_PFP,OCS_PFP,HCFC21_PFP,HFC152a_PFP,H2402_PFP,HFC365mfc_PFP,Propyne_PFP,C2H5Cl_PFP,HFC227ea_PFP,nPentane_PFP,nHexane_PFP,HCFC133a_PFP,CH2ClI_PFP,CH2I2_PFP,CH2BrCl_PFP,CH2ClCH2Cl_PFP,Propane_PFP,iPentane_PFP,iButane_PFP,nButane_PFP,CHBrCl2_PFP,CH2BrI_PFP,CH3CHCl2_PFP,CHBr2Cl_PFP 71026,71046,403.38,1850.72,64.51,331.01,9.48,530.22,-47.377,-8.362,98.2,243.78,505.85,534.89,22.15,3.419,6.61,228.97,24.61,0.055,70.7,42.65,8.64,2.051,80.21,0.749,-999.99,0.26,2.43,492.8,0.322,6.19,0.421,0.951,0.33,0.16,-999.99,4.11,1.98,0.457,0.001,0.001,0.101,6.34,12.78,0.46,0.5,0.8,0.168,0.013,0.206,0.09 72390,72398,402.56,1886.74,79.21,329.7,9.56,517.96,-45.783,-8.327,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-1000,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 72992,73000,402.96,1866.77,71.84,330.43,9.43,522.57,-47.479,-8.342,100.97,247.95,507.78,527.2,22.44,3.434,6.79,230.5,25.23,0.196,70.82,48.55,10.78,2.116,80.92,0.715,-999.99,0.36,4.47,491.1,0.366,7.44,0.414,0.991,0.11,0.28,-999.99,9.78,1.34,0.466,0.001,0.003,0.107,7.94,10.38,1.77,2.8,0.71,0.168,0.001,0.264,0.113 73332,73342,403.37,1853.08,68.03,330.35,9.36,527.98,-46.063,-8.364,99.03,244.34,508.3,538.25,22.39,3.45,6.73,230.17,25.17,0.059,70.85,41.1,8.97,2.111,80.55,0.821,-999.99,0.41,3.64,495.7,0.326,6.44,0.406,0.936,-0.08,0.21,-999.99,5.94,2.02,0.459,0.004,0,0.12,6.19,13.22,0.81,0.96,0.73,0.185,0.033,0.196,0.112 75853,75859,402.52,1889.89,83.88,330.58,9.58,515.56,-999.99,-8.336,103.27,252.18,507.62,524.95,22.88,3.441,6.83,230.7,26.44,1.077,70.85,59.44,14.23,2.138,80.81,0.708,-999.99,0.5,10.21,486.2,0.408,8.11,0.42,1.031,0.38,0.35,1.42,7.59,1.69,0.499,0.031,0.004,0.13,10.23,22.46,1.42,2.72,1.26,0.197,0.025,0.411,0.134 78097,78118,403.42,1854.25,65,330.11,9.41,530.93,-47.407,-8.372,98.96,245.08,508.68,545.76,22.2,3.427,6.77,230.01,24.82,0.053,70.69,47.26,9.26,2.046,80.71,0.724,-999.99,0.35,3.36,503.3,0.328,6.29,0.426,0.94,1.19,0.27,-999.99,1.82,2.33,0.458,0.003,0.001,0.095,7.79,13.42,0.45,0.84,1.44,0.167,-0.019,0.218,0.096 78922,78933,403.5,1849.28,64.79,330.44,9.48,529.48,-47.471,-8.373,98.37,243.74,507.87,535.4,22.35,3.428,6.67,229.46,24.7,0.077,70.85,42.02,9.01,2.052,80.4,0.773,-999.99,0.46,3.78,502,0.324,6.2,0.403,0.925,0.11,0.24,-999.99,9.2,1.41,0.47,0.002,0,0.123,6.68,10.56,1.63,2.88,0.66,0.194,-0.003,0.187,0.125 79214,79221,403.06,1870.59,70.9,330.27,9.47,525.25,-47.529,-8.351,100.47,248.54,508.93,535.57,22.66,3.43,6.85,230.02,25.3,0.213,70.71,59.18,11.21,2.059,80.92,0.667,-999.99,0.29,5.34,506.1,0.359,6.7,0.418,0.968,0.46,0.34,1.41,8.05,0.67,0.501,0.003,0.002,0.092,10.58,10.28,1.27,1.59,0.92,0.175,-0.013,0.308,0.085 79570,79578,402.71,1868.24,70.94,329.2,9.47,522.24,-47.458,-8.331,101.26,249.12,507.64,524.69,22.66,3.467,6.69,230.26,25.5,0.613,70.67,54.22,11.39,2.143,80.61,0.686,-999.99,0.38,6.95,502.3,0.382,7.28,0.42,1.006,1.01,0.4,1.44,8.69,5.21,0.491,0.008,0.007,0.12,8.72,11.12,1.44,0.83,1.37,0.166,-0.002,0.326,0.096 82127,82154,404.07,1833.26,61.91,329.45,9.31,531.2,-47.355,-8.393,96.41,240.18,508.04,541.6,22.08,3.42,6.51,229.57,24.2,0.068,70.85,33.85,7.32,2.045,80.26,0.882,-999.99,0.5,3.36,505.6,0.29,5.59,0.398,0.909,0.88,0.2,-999.99,4.81,0.26,0.446,0.01,0.002,0.116,4.76,7.91,0.62,1.34,1.06,0.192,-0.012,0.128,0.14 84123,84134,403.84,1840.88,61.5,330.04,9.3,530.68,-46.445,-8.398,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-1000,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 84715,84723,404.39,1816.52,61.56,330.95,9.25,531.55,-47.274,-8.387,95.11,236.44,508.32,539.92,21.73,3.362,6.25,228.44,23.97,0.343,70.59,23.2,6.51,2.105,79.97,1.065,-999.99,1.12,3.73,514.7,0.27,5.3,0.411,0.89,0.71,0.21,1.34,9.39,1.71,0.412,0.019,0.003,0.13,2.53,2.28,1.42,1.83,0.62,0.246,0.006,0.092,0.261 85287,85296,403.95,1828.28,63.13,329.63,9.28,531.91,-47.409,-8.383,96.01,238.7,508.81,541.26,21.89,3.391,6.55,228.93,24.34,0.172,70.7,27.81,7.04,2.068,80.19,0.918,-999.99,0.58,17.63,507.8,0.273,5.57,0.41,0.916,0.08,0.18,-999.99,7,0.65,0.43,0.001,0.009,0.126,3.53,7.64,2.88,8.33,0.76,0.197,0.004,0.158,0.156 90173,90195,404.31,1816.78,57.8,328.63,9.16,532,-47.361,-8.393,94.42,236.26,508.75,548.79,21.93,3.398,6.38,228.61,24.39,0.033,70.76,23.41,5.81,2.036,79.76,0.833,-999.99,0.39,1.26,504.4,0.266,5.15,0.403,0.878,0.65,0.13,-999.99,2.17,0.48,0.435,0.001,0.003,0.099,2.31,5.81,0.32,0.69,0.99,0.208,0.007,0.051,0.151 91183,91190,404.07,1819.47,55.66,329.3,9.29,531.18,-47.347,-8.395,95.89,238.07,506.64,533.01,22.04,3.452,6.31,229.22,24.84,0.051,70.57,25.52,6.04,2.057,80.04,0.798,-999.99,0.34,1.98,500.4,0.278,5.26,0.412,0.887,0.53,0.15,1.36,1.5,0.59,0.439,0.003,0.009,0.114,2.89,2.13,0.42,0.15,0.55,0.165,0.015,0.071,0.118 91507,91513,404.6,1815.09,59.66,329.71,9.24,531.02,-47.371,-8.392,95.21,236.88,509.49,538.09,21.79,3.387,6.3,229.21,24.06,0.279,70.78,22.85,6.72,2.058,80.22,1.13,-999.99,1.49,3.39,517.4,0.272,5.44,0.409,0.896,0.29,0.18,1.27,5.68,0.39,0.433,0.006,0.002,0.129,2.54,2.36,3.2,7.61,1.03,0.337,0.031,0.077,0.377 92654,92669,404.35,1818.43,58.71,330.31,9.3,531.79,-47.314,-8.39,95.09,237.39,509.88,547.81,21.84,3.43,6.38,229.56,24.55,0.067,70.94,24.11,6.39,2.092,80.62,0.937,-999.99,0.7,2.92,509,0.262,5.24,0.422,0.886,0.42,0.16,-999.99,5.74,0.89,0.426,-0.002,0.002,0.126,2.73,6.29,1.96,5.09,0.93,0.21,-0.009,0.091,0.189 93401,93431,404.25,1819.42,62.41,330.2,9.33,532.29,-47.327,-8.403,94.42,236.44,507.19,557.13,21.92,3.434,6.48,228.62,24.6,0.04,70.7,24.38,6.02,2.026,79.87,0.801,-999.99,0.44,2.6,495.4,0.266,5.11,0.416,0.876,0.83,0.16,-999.99,2.76,0.9,0.426,0,0.003,0.121,2.48,10.99,0.61,0.5,0.98,0.172,0.004,0.104,0.105 94568,94576,404.23,1816.41,58.09,328.58,9.26,531.51,-47.421,-8.404,94.62,236.95,508.52,541.33,21.88,3.377,6.4,228.68,24.1,0.127,70.62,23.36,6.26,2.051,80.02,0.831,-999.99,0.51,2.54,509.9,0.265,5.33,0.408,0.892,0.11,0.21,-999.99,6.83,0.85,0.43,0.003,0.001,0.118,2.65,4.32,2.52,6.48,0.62,0.178,0.008,0.083,0.149 94960,94968,404.15,1811.28,69.7,328.78,9.21,530.96,-47.355,-8.413,92.87,233.8,506.01,555.45,21.73,3.376,6.38,227.42,23.96,0.408,70.44,21,6.68,2.102,79.45,0.903,-999.99,0.7,6.37,514,0.252,4.92,0.411,0.863,0.35,0.2,1.28,8.98,0.81,0.416,0.011,0.007,0.125,2.14,8.18,2.06,5.58,0.93,0.171,-0.005,0.112,0.153 96004,96020,404.23,1815.51,61.11,329.48,9.23,531.07,-47.367,-8.418,94.16,235.75,507.52,553.14,21.96,3.425,6.37,228.4,24.05,0.154,70.64,22.87,5.84,2.042,79.64,0.875,-999.99,0.51,3.93,509.9,0.268,5,0.406,0.883,0.8,0.14,-999.99,1.91,0.56,0.425,-0.001,0.001,0.13,2.37,6.36,0.45,0.42,0.64,0.173,-0.013,0.05,0.125 96932,96978,403.9,1843.3,78.04,330.41,9.23,532.93,-47.42,-8.416,96.12,239.82,509.25,585.49,21.98,3.434,7.03,228.79,24.83,0.063,70.42,29.61,7.12,2.026,80.11,0.602,-999.99,0.19,2.08,491.3,0.276,5.33,0.417,0.903,0.24,0.26,-999.99,8.41,0.71,0.438,0.004,0.004,0.09,2.88,35.87,4.45,12.24,2.98,0.142,0,0.112,0.069 98658,98669,404.16,1832.11,72.76,329.98,9.27,536.94,-47.355,-8.407,95.34,237.85,507.25,571.74,21.76,3.394,6.72,228.61,24.29,0.029,70.73,25.71,6.06,2.026,79.96,0.772,-999.99,0.3,4.62,490.7,0.265,5.37,0.408,0.9,0.73,0.13,-999.99,2.17,0.65,0.433,0.003,-0.001,0.106,2.94,13.09,0.4,1.04,0.91,0.172,-0.004,0.109,0.101 98955,98963,404.2,1815.5,73.11,329.67,9.3,534.12,-47.287,-8.409,93.64,235.01,507.34,562.91,21.72,3.412,6.81,228.14,23.78,0.231,70.46,21.91,6.13,2.067,79.73,0.821,-999.99,0.45,6.18,503.7,0.254,5,0.402,0.886,0.85,0.2,-999.99,5.16,0.53,0.41,0.004,0.003,0.129,2.3,8.1,1.99,4.32,1.13,0.171,-0.005,0.058,0.123