84, 1001 Montzka, S., Sweeney, C. Global Monitoring Division/ESRL/NOAA PFP; Flask measurements of trace gases from PFP flasks ATom 1,1 2017, 10, 04, 2019, 02, 27 0 Start_UTC, seconds 51 1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1 -999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 Stop_UTC, seconds, elapsed time since midnight (GMT) of the day of takeoff CO2_PFP, ppm, carbon dioxide, dry-air mole fraction, micro mole per mole (as part per million) CH4_PFP, ppb, methane, dry-air mole fraction, nano mole per mole (as part per billion) CO_PFP, ppb, carbon monoxide, dry-air mole fraction, nano mole per mole (as part per billion) N2O_PFP, ppb, nitrous oxide, dry-air mole fraction, nano mole per mole (as part per billion) SF6_CCGG_PFP, ppt, sulfur hexafluoride dry-air mole fraction, pico mole per mole (as part per trillion, or ppt), measured by electron capture detection in carbon cycle group H2_PFP, ppb, hydrogen, dry-air mole fraction, nano mole per mole (as part per billion) d13CH4_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CH4 relative to Vienna Pee Dee Belemnite d13CO2_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CO2 relative to Vienna Pee Dee Belemnite HFC134a_PFP, ppt, 1,1,1,2-tetrafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC22_PFP, ppt, chlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC12_PFP, ppt, dichlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3Cl_PFP, ppt, methyl chloride, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC142b_PFP, ppt, 1-chloro-1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H1211_PFP, ppt, bromodichlorofluoromethane (halon-1211), dry-air mole fraction, pico mole per mole (as part per trillion) CH3Br_PFP, ppt, methyl bromide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC11_PFP, ppt, trichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC141b_PFP, ppt, 1,1-chloro-1-fluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3I_PFP, ppt, methyl iodide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC113_PFP, ppt, 1,1,2-trichloro-1,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Cl2_PFP, ppt, dichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHCl3_PFP, ppt, trichloromethane (chloroform), dry-air mole fraction, pico mole per mole (as part per trillion) CH3CCl3_PFP, ppt, 1,1,1-trichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CCl4_PFP, ppt, tetrachloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Br2_PFP, ppt, dibromomethane, dry-air mole fraction, pico mole per mole (as part per trillion) C2Cl4_PFP, ppt, tetrachloroethylene, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr3_PFP, ppt, tribromomethane (bromorform), dry-air mole fraction, pico mole per mole (as part per trillion) Benzene_PFP, ppt, C6H6, dry-air mole fraction, pico mole per mole (as part per trillion) OCS_PFP, ppt, carbonyl sulfide, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC21_PFP, ppt, dichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC152a_PFP, ppt, 1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H2402_PFP, ppt, 1,2-dibromo-1,1,2,2-tetrafluoroethane (halon-2402, dry-air mole fraction, pico mole per mole (as part per trillion) HFC365mfc_PFP, ppt, 1,1,1,3,3-pentafluorobutane, dry-air mole fraction, pico mole per mole (as part per trillion) Propyne_PFP, ppt, C3H4, dry-air mole fraction, pico mole per mole (as part per trillion) C2H5Cl_PFP, prelim, chloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC227ea_PFP, ppt, 1,1,1,2,3,3,3-heptafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) nPentane_PFP, ppt, normal pentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) nHexane_PFP, ppt, normal hexane (C6H14), dry-air mole fraction, pico mole per mole (as part per trillion) HCFC133a_PFP, ppt, 1-chloro-2,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClI_PFP, ppt, chloroiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2I2_PFP, ppt, diiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrCl_PFP, ppt, bromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClCH2Cl_PFP, ppt, 1,2-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) Propane_PFP, ppt, C3H8, dry-air mole fraction, pico mole per mole (as part per trillion) iPentane_PFP, ppt, isopentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) iButane_PFP, ppt, isobutane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) nButane_PFP, ppt, normal butane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) CHBrCl2_PFP, ppt, bromodichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrI_PFP, ppt, bromoiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3CHCl2_PFP, prelim, 1,1-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr2Cl_PFP, ppt, dibromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) 0 19 PI_CONTACT_INFO: 303-497-6657 325 Broadway, Boulder CO 80305 email stephen.a.montzka@noaa.gov colm.sweeney@noaa.gov PLATFORM: NASA DC8 LOCATION: Aircraft location here with appropriate date indicated: http://espoarchive.nasa.gov/archive/fileinfo/MMS-FlightPath_DC8_YYYYMMDD.ict ASSOCIATED_DATA: See http://espoarchive.nasa.gov/archive/browse/atom INSTRUMENT_INFO: Programmable Flask Package results from multiple analysis instruments at NOAA and CU/INSTAAR DATA_INFO: N/A UNCERTAINTY: tbd ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: Steve Montzka, 303-497-6657, 325 Broadway, Boulder, CO 80305 PROJECT_INFO: ATom-2; 04-Dec-2016 to 22-Feb-2017; https://espo.nasa.gov/home/atom/content/ATom STIPULATIONS_ON_USE: Notification of S. Montzka or C. Sweeney is requested with use of data. OTHER_COMMENTS: all measurement results are given in dry-air mole fractions; results for two gases are on preliminary scales (not mole fractions) REVISION: R1 R0: preliminary data R1: final data, for public release Start_UTC,Stop_UTC,CO2_PFP,CH4_PFP,CO_PFP,N2O_PFP,SF6_CCGG_PFP,H2_PFP,d13CH4_PFP,d13CO2_PFP,HFC134a_PFP,HCFC22_PFP,CFC12_PFP,CH3Cl_PFP,HCFC142b_PFP,H1211_PFP,CH3Br_PFP,CFC11_PFP,HCFC141b_PFP,CH3I_PFP,CFC113_PFP,CH2Cl2_PFP,CHCl3_PFP,CH3CCl3_PFP,CCl4_PFP,CH2Br2_PFP,C2Cl4_PFP,CHBr3_PFP,Benzene_PFP,OCS_PFP,HCFC21_PFP,HFC152a_PFP,H2402_PFP,HFC365mfc_PFP,Propyne_PFP,C2H5Cl_PFP,HFC227ea_PFP,nPentane_PFP,nHexane_PFP,HCFC133a_PFP,CH2ClI_PFP,CH2I2_PFP,CH2BrCl_PFP,CH2ClCH2Cl_PFP,Propane_PFP,iPentane_PFP,iButane_PFP,nButane_PFP,CHBrCl2_PFP,CH2BrI_PFP,CH3CHCl2_PFP,CHBr2Cl_PFP 67401,67425,403.86,1894.56,76.49,330.43,9.43,527.62,-47.463,-8.404,103.47,249.68,507.35,566.2,22.53,3.453,7.25,229.54,25.69,0.072,70.37,51.9,10.05,2.021,80.08,0.618,-999.99,0.18,4.66,477.1,0.357,8.46,0.411,0.969,0.52,0.24,-999.99,4.99,1.52,0.494,0.007,0.004,0.117,7.55,319.52,2.45,15.16,43.57,0.16,-0.009,0.267,0.079 69382,69394,403.86,1895.81,94.45,330.81,9.61,522.07,-47.543,-8.392,103.39,254.91,509.45,550.23,22.89,3.528,7.27,231.56,26.37,0.287,70.85,83.41,16.4,2.103,81.31,0.735,-999.99,0.52,19.34,507.5,0.43,7.72,0.416,1.025,0.58,0.53,-999.99,4.48,1.04,0.526,0.005,0,0.114,19.45,77.39,1.61,5.95,7.88,0.203,0.001,0.646,0.117 69816,69824,403.46,1910.15,105.95,330.42,9.59,503.58,-47.601,-8.404,104.91,254.37,508.53,518.38,22.96,3.52,7,231.14,25.91,0.322,70.76,66.27,17.09,2.103,80.91,0.829,-999.99,0.76,25.56,473.9,0.425,8.96,0.422,1.078,0.25,0.51,1.49,11.54,1.1,0.507,0.005,0.004,0.123,13.57,127.17,4.55,13.27,16.5,0.217,0.003,0.638,0.142 70662,70669,404.55,1931.93,119.67,330.29,9.57,483.13,-47.739,-8.463,106.05,254.78,508.07,500.33,23.1,3.476,6.8,231.43,26.05,0.606,70.48,64.7,19.96,2.135,80.77,1.114,-999.99,2.4,38.62,437.1,0.451,9.15,0.42,1.099,0.69,0.43,1.46,14.41,2.6,0.503,0.668,0.158,0.139,12.72,183.31,9.82,25.87,30.95,0.244,0.001,0.656,0.253 73260,73283,403.8,1907.35,99.91,330.64,9.6,527.41,-47.539,-8.379,101.77,253.32,506.87,582.67,22.66,3.501,7.53,230.71,25.8,0.132,70.8,90.86,16.35,2.069,81.08,0.777,-999.99,0.5,25.2,505.8,0.422,6.99,0.414,0.997,0.57,0.61,-999.99,4.87,1,0.528,0.003,0.003,0.115,21.95,87.21,4.54,10.02,14.74,0.213,0.006,0.589,0.122 75058,75063,406.63,1941.85,117.61,330.33,9.58,452.29,-47.824,-8.578,105.47,253.36,506.84,470.76,23.02,3.503,6.42,230.84,26.04,0.632,70.64,59.58,19.17,2.154,80.57,0.99,-999.99,1.26,39.99,399.2,0.436,9.26,0.413,1.118,1.1,0.39,1.42,19.84,3.79,0.514,0.054,0.01,0.135,11.18,224.8,13.41,30.35,46.4,0.243,-0.021,0.554,0.181 75570,75579,402.92,1902.29,100.03,330.79,9.52,516.14,-47.519,-8.385,104.49,250.88,507.2,528.34,22.83,3.456,7.06,229.91,25.58,0.088,70.57,52.12,12.08,2.097,80.42,0.702,-999.99,0.48,22.94,488.6,0.383,8.68,0.414,1.039,0.39,0.36,-999.99,7.73,1.71,0.502,0.001,0.005,0.126,8.7,177.46,5.98,18.36,26.4,0.227,-0.019,0.704,0.136 75862,75873,403.6,1901.82,102.76,330.59,9.64,523.47,-47.4,-8.382,103.37,252.74,506.68,562.02,22.83,3.467,7.24,230.96,25.58,0.076,70.7,65.51,16.66,2.095,80.87,0.71,-999.99,0.4,43.71,522.7,0.395,7.86,0.421,1.006,0.83,0.55,-999.99,32.92,6.85,0.497,-0.004,0.005,0.127,15.8,585.22,27.45,62.93,135.79,0.235,-0.018,1.28,0.128 77019,77042,404.17,1900.54,100.13,330.46,9.65,520.19,-47.514,-8.42,103.12,255.09,507.06,546.4,22.97,3.519,7.3,230.28,26.15,0.116,70.9,89.48,17.54,2.089,80.97,0.771,-999.99,0.47,17.08,501.7,0.444,7.95,0.418,1.053,0.23,0.56,-999.99,3.75,0.81,0.533,0.001,0.003,0.104,21.57,81.77,1.49,5.31,8.33,0.205,-0.001,0.688,0.12 78542,78549,408.03,1938.21,114.47,330.09,9.54,443.25,-47.836,-8.65,105.06,252.06,505.96,464.76,23.12,3.456,6.21,229.73,25.97,0.604,69.91,57.03,18.17,2.132,80.26,0.991,-999.99,1.29,37.93,385.4,0.439,9.57,0.413,1.104,4.79,0.34,1.49,19.12,4.28,0.511,0.071,0.025,0.12,10.79,230.17,15.55,32.03,49.54,0.231,0.006,0.476,0.191 80086,80108,404.38,1908.4,107.11,330.58,9.67,515.39,-47.571,-8.426,104.18,256.16,506.84,546.42,23.13,3.516,7.42,231.33,26.21,0.087,70.43,91.38,18.2,2.095,80.95,0.805,-999.99,0.56,20.56,490.2,0.451,8.39,0.411,1.077,0.3,0.64,-999.99,3.91,0.87,0.542,0.004,0.006,0.129,22.1,116.86,2.77,9.38,13.52,0.21,0,0.706,0.147 81076,81087,403.09,1898.6,96.15,330.18,9.55,520.7,-47.519,-8.379,104.15,252.22,508.26,551.45,22.68,3.468,7.19,230.57,25.49,0.094,70.72,58.12,13.36,2.098,80.52,0.716,-999.99,0.42,30.74,500.7,0.384,8.2,0.411,1.04,0.6,0.4,-999.99,12.92,4.7,0.497,0.001,0.001,0.139,11.08,274.15,10.88,26.25,48.75,0.228,-0.009,0.653,0.137 81364,81372,403.53,1915.38,109.38,330.27,9.6,511.79,-47.478,-8.419,105.11,254.69,508.72,529.2,22.99,3.475,7.15,230.76,25.9,0.208,70.77,67.09,15.09,2.095,80.51,0.8,-999.99,0.69,32.04,493.3,0.44,9.1,0.414,1.145,0.56,0.44,-999.99,8.83,1.93,0.503,-0.001,0.008,0.138,12.32,239.57,9.48,23.99,38.32,0.235,0.008,0.767,0.166 81787,81794,403.02,1921.89,111.93,330.5,9.6,492.6,-47.746,-8.409,105.05,254.51,508.06,506.6,23.2,3.484,6.91,231.5,25.85,0.604,71.12,62.36,17.37,2.189,80.8,0.894,-999.99,1.05,29.59,465.7,0.437,8.99,0.431,1.111,0.64,0.4,1.39,8.66,1.12,0.504,0.023,0.01,0.117,12.11,145.78,5.14,13.86,20.53,0.221,-0.02,0.7,0.169 82351,82357,403.01,1921.13,112.25,330.41,9.6,491.56,-47.683,-8.424,104.67,254.29,508.32,505.41,23.06,3.453,6.87,231.15,25.82,0.644,70.73,61.96,17.51,2.129,80.78,0.942,-999.99,1.1,30.28,457.8,0.457,8.93,0.419,1.115,0.64,0.37,1.37,10.67,1.24,0.504,0.039,0.009,0.124,11.99,148.36,5.67,14.62,21.15,0.234,-0.011,0.673,0.188 82871,82878,402.97,1921.51,111.6,330.02,9.6,493.01,-47.75,-8.456,105.62,253.76,508.73,506.44,23.24,3.536,6.89,231.22,25.94,0.614,70.9,62.13,17.37,2.143,80.47,0.93,-999.99,1.06,29.93,465.9,0.448,9.27,0.413,1.112,0.49,0.38,1.37,8.77,1.06,0.503,0.025,0.014,0.124,11.97,146,5.25,14.18,20.52,0.227,-0.02,0.647,0.167 83370,83378,403.81,1916.69,119.9,329.98,9.65,509.71,-999.99,-8.498,105.44,256.28,505.76,534.49,23.17,3.472,7.32,231.05,26.11,0.188,70.62,77.22,18.65,2.152,80.76,0.831,-999.99,0.77,40.35,489.7,0.474,9.34,0.413,1.2,0.79,0.65,-999.99,14.87,2.76,0.514,0.002,0.006,0.153,15.74,266.03,14.5,30.66,48.31,0.25,-0.01,0.956,0.16 83961,83977,404.26,1897.97,98.45,330.5,9.64,523.41,-47.34,-8.398,103.14,256.94,509.32,574.69,22.87,3.501,7.7,232.23,26.3,0.104,71.28,111.14,16.65,2.131,81.58,0.764,-999.99,0.42,26.29,526.3,0.442,7.58,0.424,1.019,0.35,0.58,-999.99,5.81,1.24,0.517,0.013,0.002,0.125,26.66,136.2,4.06,11.98,19.07,0.231,0.009,1.039,0.142 85183,85191,402.99,1887.88,80.14,330.44,9.62,526.56,-47.474,-8.368,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-1000,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 85733,85739,402.73,1899.37,92.41,330.37,9.62,507.34,-47.612,-8.369,104.93,253.27,508.39,517.51,23.08,3.429,6.91,231.34,25.79,0.9,70.91,60.53,15.03,2.108,80.82,0.754,-999.99,0.59,16.2,477.2,0.427,9.37,0.421,1.079,0.3,0.31,1.42,6.09,0.98,0.502,0.019,0.018,0.136,10.84,51.66,1.66,4.05,4.79,0.194,-0.015,0.546,0.127 86434,86446,402.98,1884.7,80.85,330.91,9.59,522.19,-47.427,-8.354,101.66,250.9,508.05,543.34,22.71,3.461,7.09,230.91,25.52,0.279,70.78,68.38,13.18,2.059,81.09,0.745,-999.99,0.39,9.74,501,0.402,7.27,0.425,1.035,0.01,0.39,-999.99,8.78,0.72,0.517,0.004,0.017,0.112,13.71,34.95,1.72,4.39,2.28,0.188,0,0.436,0.115 87391,87409,403.73,1890.86,74.79,330.13,9.51,531.31,-47.385,-8.413,101.01,251.01,508.11,573.47,22.43,3.486,7.48,229.45,25.61,0.079,70.92,79.34,12.82,2.088,80.49,0.694,-999.99,0.25,7.24,504.5,0.372,6.78,0.419,1.005,0.19,0.41,-999.99,2.44,0.81,0.513,0.008,0.012,0.097,16.68,61.86,0.75,3.03,4.94,0.189,-0.009,0.426,0.098 88734,88778,404.49,1932.29,96.39,331.4,9.68,538.74,-47.524,-8.421,101.9,256.04,508.61,622.84,22.56,3.6,8.3,231.21,26.34,0.131,71.13,133.17,16.41,2.069,81.31,0.695,-999.99,0.22,8.94,505.1,0.388,6.16,0.411,0.988,0.35,0.63,-999.99,2.45,0.91,0.577,0.074,0.006,0.105,30.21,82.17,0.82,4.28,6.86,0.201,0.014,0.595,0.091 90183,90195,402.84,1884.13,73.62,330.61,9.61,528.1,-47.433,-8.375,101.28,251.8,508.93,545.51,22.53,3.542,7.2,231.14,25.52,0.057,70.97,73.18,12.56,2.071,80.93,0.63,-999.99,0.19,5.71,501.1,0.377,6.62,0.409,0.997,0.02,0.27,-999.99,1.13,0.72,0.507,0.006,0.003,0.112,13.55,20.61,0.38,1.15,1.2,0.167,0.004,0.388,0.091