84, 1001 Montzka, S., Sweeney, C. Global Monitoring Division/ESRL/NOAA PFP; Flask measurements of trace gases from PFP flasks ATom 1,1 2017, 10, 01, 2019, 02, 27 0 Start_UTC, seconds 51 1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1 -999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 Stop_UTC, seconds, elapsed time since midnight (GMT) of the day of takeoff CO2_PFP, ppm, carbon dioxide, dry-air mole fraction, micro mole per mole (as part per million) CH4_PFP, ppb, methane, dry-air mole fraction, nano mole per mole (as part per billion) CO_PFP, ppb, carbon monoxide, dry-air mole fraction, nano mole per mole (as part per billion) N2O_PFP, ppb, nitrous oxide, dry-air mole fraction, nano mole per mole (as part per billion) SF6_CCGG_PFP, ppt, sulfur hexafluoride dry-air mole fraction, pico mole per mole (as part per trillion, or ppt), measured by electron capture detection in carbon cycle group H2_PFP, ppb, hydrogen, dry-air mole fraction, nano mole per mole (as part per billion) d13CH4_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CH4 relative to Vienna Pee Dee Belemnite d13CO2_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CO2 relative to Vienna Pee Dee Belemnite HFC134a_PFP, ppt, 1,1,1,2-tetrafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC22_PFP, ppt, chlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC12_PFP, ppt, dichlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3Cl_PFP, ppt, methyl chloride, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC142b_PFP, ppt, 1-chloro-1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H1211_PFP, ppt, bromodichlorofluoromethane (halon-1211), dry-air mole fraction, pico mole per mole (as part per trillion) CH3Br_PFP, ppt, methyl bromide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC11_PFP, ppt, trichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC141b_PFP, ppt, 1,1-chloro-1-fluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3I_PFP, ppt, methyl iodide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC113_PFP, ppt, 1,1,2-trichloro-1,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Cl2_PFP, ppt, dichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHCl3_PFP, ppt, trichloromethane (chloroform), dry-air mole fraction, pico mole per mole (as part per trillion) CH3CCl3_PFP, ppt, 1,1,1-trichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CCl4_PFP, ppt, tetrachloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Br2_PFP, ppt, dibromomethane, dry-air mole fraction, pico mole per mole (as part per trillion) C2Cl4_PFP, ppt, tetrachloroethylene, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr3_PFP, ppt, tribromomethane (bromorform), dry-air mole fraction, pico mole per mole (as part per trillion) Benzene_PFP, ppt, C6H6, dry-air mole fraction, pico mole per mole (as part per trillion) OCS_PFP, ppt, carbonyl sulfide, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC21_PFP, ppt, dichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC152a_PFP, ppt, 1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H2402_PFP, ppt, 1,2-dibromo-1,1,2,2-tetrafluoroethane (halon-2402, dry-air mole fraction, pico mole per mole (as part per trillion) HFC365mfc_PFP, ppt, 1,1,1,3,3-pentafluorobutane, dry-air mole fraction, pico mole per mole (as part per trillion) Propyne_PFP, ppt, C3H4, dry-air mole fraction, pico mole per mole (as part per trillion) C2H5Cl_PFP, prelim, chloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC227ea_PFP, ppt, 1,1,1,2,3,3,3-heptafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) nPentane_PFP, ppt, normal pentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) nHexane_PFP, ppt, normal hexane (C6H14), dry-air mole fraction, pico mole per mole (as part per trillion) HCFC133a_PFP, ppt, 1-chloro-2,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClI_PFP, ppt, chloroiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2I2_PFP, ppt, diiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrCl_PFP, ppt, bromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClCH2Cl_PFP, ppt, 1,2-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) Propane_PFP, ppt, C3H8, dry-air mole fraction, pico mole per mole (as part per trillion) iPentane_PFP, ppt, isopentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) iButane_PFP, ppt, isobutane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) nButane_PFP, ppt, normal butane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) CHBrCl2_PFP, ppt, bromodichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrI_PFP, ppt, bromoiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3CHCl2_PFP, prelim, 1,1-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr2Cl_PFP, ppt, dibromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) 0 19 PI_CONTACT_INFO: 303-497-6657 325 Broadway, Boulder CO 80305 email stephen.a.montzka@noaa.gov colm.sweeney@noaa.gov PLATFORM: NASA DC8 LOCATION: Aircraft location here with appropriate date indicated: http://espoarchive.nasa.gov/archive/fileinfo/MMS-FlightPath_DC8_YYYYMMDD.ict ASSOCIATED_DATA: See http://espoarchive.nasa.gov/archive/browse/atom INSTRUMENT_INFO: Programmable Flask Package results from multiple analysis instruments at NOAA and CU/INSTAAR DATA_INFO: N/A UNCERTAINTY: tbd ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: Steve Montzka, 303-497-6657, 325 Broadway, Boulder, CO 80305 PROJECT_INFO: ATom-2; 04-Dec-2016 to 22-Feb-2017; https://espo.nasa.gov/home/atom/content/ATom STIPULATIONS_ON_USE: Notification of S. Montzka or C. Sweeney is requested with use of data. OTHER_COMMENTS: all measurement results are given in dry-air mole fractions; results for two gases are on preliminary scales (not mole fractions) REVISION: R1 R0: preliminary data R1: final data, for public release Start_UTC,Stop_UTC,CO2_PFP,CH4_PFP,CO_PFP,N2O_PFP,SF6_CCGG_PFP,H2_PFP,d13CH4_PFP,d13CO2_PFP,HFC134a_PFP,HCFC22_PFP,CFC12_PFP,CH3Cl_PFP,HCFC142b_PFP,H1211_PFP,CH3Br_PFP,CFC11_PFP,HCFC141b_PFP,CH3I_PFP,CFC113_PFP,CH2Cl2_PFP,CHCl3_PFP,CH3CCl3_PFP,CCl4_PFP,CH2Br2_PFP,C2Cl4_PFP,CHBr3_PFP,Benzene_PFP,OCS_PFP,HCFC21_PFP,HFC152a_PFP,H2402_PFP,HFC365mfc_PFP,Propyne_PFP,C2H5Cl_PFP,HFC227ea_PFP,nPentane_PFP,nHexane_PFP,HCFC133a_PFP,CH2ClI_PFP,CH2I2_PFP,CH2BrCl_PFP,CH2ClCH2Cl_PFP,Propane_PFP,iPentane_PFP,iButane_PFP,nButane_PFP,CHBrCl2_PFP,CH2BrI_PFP,CH3CHCl2_PFP,CHBr2Cl_PFP 61170,61190,403.06,1879.2,75.9,330.45,9.45,526.21,-47.503,-8.355,100.87,250.26,507.64,537.81,22.46,3.433,6.96,229.78,-999.99,0.113,70.55,66.51,12.9,2.085,80.14,0.685,-999.99,0.31,5.75,499.8,0.384,6.84,0.406,0.992,0.2,0.32,-999.99,0.58,1.27,0.499,0.005,0,0.103,12.57,20.24,0.33,0.87,1.31,0.153,-0.008,0.43,0.095 63193,63204,403.48,1890.54,80.56,330.44,9.51,530.35,-47.49,-8.352,100.49,250.91,507.03,570.58,22.38,3.463,7.46,229.27,-999.99,0.067,70.82,91.61,13.98,2.037,80.08,0.684,-999.99,0.27,10.23,507.2,0.391,6.3,0.407,0.957,0.07,0.53,-999.99,1.85,1,0.528,0,0,0.123,20.35,38.46,0.71,2.25,3.17,0.181,-0.008,0.456,0.096 63482,63491,403.3,1863.02,63.73,330.5,9.56,529.16,-47.554,-8.348,100.03,247.73,507.33,529.75,22.23,3.433,6.81,229.55,-999.99,0.077,70.63,57.03,10.41,2.063,79.99,0.625,-999.99,0.19,2.97,502.9,0.351,6.39,0.421,0.96,0.01,0.3,-999.99,5.7,1.15,0.509,0.006,0.001,0.101,9.76,9.12,1.21,2.48,0.62,0.146,0.004,0.276,0.083 63862,63868,402.17,1914.02,105.23,330.48,9.55,498.57,-47.452,-8.321,104.65,253.37,507.27,504.45,22.99,3.424,6.91,230.42,-999.99,0.85,70.67,59.3,16.18,2.141,79.81,0.854,-999.99,0.85,20.44,461.2,0.447,8.82,0.415,1.084,0.3,0.41,1.45,8.08,1.38,0.514,0.093,0.005,0.114,10.7,76.34,2.7,7.9,6.87,0.211,-0.003,0.509,0.145 66109,66129,403.58,1862.54,69.03,330.59,9.45,529.42,-47.706,-8.384,99.36,246.29,509.67,552.02,22.34,3.447,6.91,229.48,-999.99,0.061,70.82,57.5,10.28,2.055,80.22,0.75,-999.99,0.31,4.77,503,0.357,6.35,0.401,0.936,0.09,0.31,-999.99,2.9,1.14,0.495,0.002,0,0.1,10.92,20.38,0.75,1.58,1.96,0.186,-0.005,0.28,0.105 66949,66960,403.15,1874.74,66.82,330.76,9.48,530.28,-47.525,-8.361,99.82,248.34,507.22,550.57,22.26,3.448,7.04,229.81,-999.99,0.051,70.8,64.34,11.01,2.056,80.26,0.672,-999.99,0.21,4.27,504.7,0.359,6.4,0.418,0.956,0.1,0.3,-999.99,2.48,0.4,0.509,0.002,-0.001,0.107,11.54,15.36,0.4,1.08,1.15,0.168,0.009,0.345,0.084 67587,67595,402.22,1913.25,103.03,329.96,9.5,498.61,-47.492,-8.307,104.46,253.55,507.56,507.9,23.01,3.439,6.96,230.44,-999.99,0.961,70.57,59.69,16.15,2.129,79.64,0.865,-999.99,0.83,19.11,466.2,0.45,8.88,0.413,1.072,0.28,0.38,1.45,7.34,1.55,0.507,0.018,0.006,0.133,10.69,72.68,2.51,6.86,6.49,0.207,-0.005,0.484,0.153 68094,68103,402.88,1868.41,65.56,330.32,9.51,526.86,-47.654,-8.347,99.9,246.98,506.33,531.14,22.49,3.417,6.92,228.9,-999.99,0.084,70.61,56.91,10.88,2.054,79.86,0.623,-999.99,0.21,4.17,504.3,0.344,6.45,0.417,0.954,0.22,0.34,-999.99,7.75,0.87,0.499,0.003,0.006,0.108,9.57,8.89,2.38,3.05,1.14,0.158,0.002,0.318,0.075 69969,69994,403.52,1866.53,70.47,330.55,9.5,529.4,-47.638,-8.379,99.63,247.12,506.5,552.21,22.21,3.428,6.93,229.41,-999.99,0.055,70.76,60.89,10.65,2.039,79.79,0.716,-999.99,0.27,4.09,499.5,0.355,6.39,0.422,0.958,-0.09,0.29,-999.99,3.2,1.48,0.477,-0.002,-0.004,0.113,11.27,22.45,0.53,1.43,1.81,0.182,-0.02,0.312,0.094 71261,71268,402.29,1932.53,108.98,330.03,9.49,469.65,-47.485,-8.361,104.91,253.58,508.85,478.48,23.09,3.42,6.47,230.12,-999.99,0.632,70.71,56.37,17.06,2.151,79.16,0.987,-999.99,1.16,25.57,418.2,0.433,9.08,0.415,1.09,0.57,0.35,1.42,8.55,3.14,0.514,0.01,0.007,0.136,9.77,117.21,4.7,11.47,15.99,0.234,-0.003,0.472,0.171 73588,73613,403.14,1876.64,75.91,330.28,9.52,526.52,-47.686,-8.355,100.62,249.76,508.48,548.77,22.44,3.443,7.05,229.66,-999.99,0.098,70.68,66.94,12.21,2.052,79.99,0.708,-999.99,0.29,6.41,497.2,0.373,6.64,0.419,0.974,0.02,0.4,-999.99,2.42,1.94,0.503,0.006,-0.001,0.119,13.02,26.63,0.75,2,2.31,0.163,-0.02,0.4,0.11 74093,74105,402.79,1884.23,79.92,330.12,9.5,522.68,-47.828,-8.373,102.16,251.4,508.39,535.56,22.55,3.443,7,229.96,-999.99,0.217,70.74,65.57,12.86,2.066,79.68,0.682,-999.99,0.33,9.65,495.3,0.394,7.17,0.422,1.011,1.04,0.34,-999.99,4.37,2.37,0.507,-0.003,0.003,0.107,12.36,39.04,1.51,3.24,4.67,0.168,0,0.411,0.106 74381,74390,402.78,1877.4,72.88,330.5,9.53,525.87,-47.526,-8.349,101.61,251.72,510.92,526.98,22.66,3.441,6.89,231.09,25.61,0.125,70.63,62.08,12,2.054,81.33,0.605,-999.99,0.21,4.89,505.3,0.378,6.78,0.416,0.999,0.16,0.27,1.46,8.11,0.41,0.511,-0.001,0.002,0.096,11.07,15.44,1.4,2.94,1.39,0.151,0.001,0.418,0.083 74927,74934,402.45,1933.94,110.47,329.81,9.56,462.64,-47.773,-8.396,104.96,252.92,507.32,475.29,23.13,3.462,6.47,230.34,26.11,0.56,70.53,57.43,17.74,2.17,80.59,1.01,-999.99,1.44,30.32,412.4,0.419,9.25,0.414,1.106,0.82,0.36,1.44,12.66,1.44,0.507,0.012,0.007,0.138,10.46,138.11,6.56,13.82,21.93,0.246,-0.008,0.587,0.199 77522,77553,402.85,1883.88,80.53,330.51,9.55,522.51,-47.868,-8.366,101.44,249.92,508.33,540.45,22.73,3.442,7.03,230.49,25.45,0.067,70.58,65.76,12.83,2.068,80.76,0.699,-999.99,0.28,6.41,491.8,0.385,7.14,0.417,1.012,0.08,0.32,-999.99,2.71,0.48,0.512,0,0,0.111,12.36,35.63,0.72,2.54,3.56,0.163,0.008,0.453,0.102 82766,82797,402.97,1902.72,101.38,330.51,9.67,519.09,-47.573,-8.384,104.41,255.38,508.59,546.19,23.02,3.443,7.29,231.32,26.33,0.065,70.31,74.5,15.1,2.102,80.29,0.69,-999.99,0.32,14.49,478.2,0.441,8.29,0.407,1.092,0.35,0.46,-999.99,4.49,1.03,0.516,-0.001,0.002,0.1,13.64,126.04,4.17,11.24,19.85,0.186,0.004,0.607,0.103 84064,84077,402.72,1906.77,100.62,330.22,9.56,518.9,-47.55,-8.395,104.17,252.33,507.97,532.53,22.74,3.421,7.1,230.31,25.63,0.132,70.42,55.85,12.7,2.106,80.62,0.737,-999.99,0.58,24.54,483.9,0.39,8.67,0.412,1.034,0.54,0.3,-999.99,11.41,2.32,0.504,0.004,-0.001,0.108,9.67,223.02,10.14,24.27,41.44,0.228,-0.004,0.42,0.166 84399,84406,403,1924.5,114.18,330.3,9.56,486.22,-47.593,-8.404,104.79,253.85,507.58,499.08,23.13,3.442,6.83,230.7,26.6,0.478,70.34,60.5,17.41,2.155,80.65,0.921,-999.99,1.09,30.53,436,0.425,9.26,0.414,1.12,0.69,0.34,1.47,8.77,1.31,0.511,0.008,0.009,0.136,11.5,147.22,5.48,14.26,22.6,0.229,-0.002,0.622,0.184 85127,85134,399.53,1941.67,112.71,329.66,9.6,467.68,-47.798,-8.327,104.73,252.39,507.23,463.04,22.96,3.405,6.27,229.96,25.63,0.292,70.32,54.57,16,2.204,80.23,1.025,-999.99,1.46,31.83,402.2,0.432,9.04,0.41,1.078,1.33,0.24,1.4,16.41,2.2,0.518,0.071,0.004,0.137,9,160.88,9.14,19,33.66,0.225,-0.002,0.386,0.199 86046,86057,402.81,1906.79,109.22,330.01,9.55,513.16,-47.904,-8.38,104.69,253.9,508.72,525.64,22.95,3.436,7.13,230.53,25.9,0.123,70.68,60.82,15.1,2.105,80.48,0.717,-999.99,0.59,27.66,488.7,0.412,8.89,0.421,1.066,0.5,0.37,-999.99,5.93,0.99,0.506,0.001,0.005,0.118,11.53,144.25,4.39,12.91,20.71,0.194,0.007,0.764,0.144 87679,87686,403.43,1939.26,116.51,330.2,9.47,480.75,-47.66,-8.44,105.26,253.92,506.82,505.46,23.13,3.43,6.65,230.84,26.38,0.521,70.6,61.94,19.32,2.17,80.62,1.008,-999.99,1.29,32.36,424.3,0.445,9.4,0.412,1.123,1.42,0.43,1.48,12.27,1.58,0.513,0.39,0.015,0.134,11.63,159.53,7.44,16.67,25.68,0.254,0.018,0.589,0.21 87949,87956,402.7,1914.46,115.91,329.89,9.53,506.94,-47.856,-8.379,105.34,254.49,508.59,518.02,23.04,3.436,7.08,231.23,25.93,0.09,70.55,59.78,15.97,2.122,80.73,0.75,-999.99,0.59,28.55,469.2,0.432,9.15,0.416,1.084,0.29,0.35,-999.99,6.95,0.85,0.509,0.001,0,0.105,10.82,158.99,4.06,12.23,20.36,0.198,0.001,0.55,0.138 89318,89362,404.11,1861.18,59.49,327.61,9.36,530.49,-47.672,-8.443,98.74,246.41,502.64,552.53,22.36,3.422,7.11,225.71,24.99,0.059,69.68,54.15,9.3,2.042,78.73,0.547,-999.99,0.1,2.78,476.1,0.341,6.83,0.411,0.971,1.07,0.27,-999.99,1.73,0.84,0.488,-0.001,0.004,0.093,6.97,59.33,0.77,2.58,6.24,0.119,-0.014,0.291,0.046