85, 1001 Montzka, S., Sweeney, C. Global Monitoring Division/ESRL/NOAA PFP; Flask measurements of trace gases from PFP flasks ATom 1,1 2017, 02, 15, 2019, 02, 27 0 Start_UTC, seconds 51 1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1 -999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 Stop_UTC, seconds, elapsed time since midnight (GMT) of the day of takeoff CO2_PFP, ppm, carbon dioxide, dry-air mole fraction, micro mole per mole (as part per million) CH4_PFP, ppb, methane, dry-air mole fraction, nano mole per mole (as part per billion) CO_PFP, ppb, carbon monoxide, dry-air mole fraction, nano mole per mole (as part per billion) N2O_PFP, ppb, nitrous oxide, dry-air mole fraction, nano mole per mole (as part per billion) SF6_CCGG_PFP, ppt, sulfur hexafluoride dry-air mole fraction, pico mole per mole (as part per trillion, or ppt), measured by electron capture detection in carbon cycle group H2_PFP, ppb, hydrogen, dry-air mole fraction, nano mole per mole (as part per billion) d13C_CH4_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CH4 relative to Vienna Pee Dee Belemnite d13C_CO2_PFP, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CO2 relative to Vienna Pee Dee Belemnite HFC134a_PFP, ppt, 1,1,1,2-tetrafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC22_PFP, ppt, chlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC12_PFP, ppt, dichlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3Cl_PFP, ppt, methyl chloride, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC142b_PFP, ppt, 1-chloro-1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H1211_PFP, ppt, bromodichlorofluoromethane (halon-1211), dry-air mole fraction, pico mole per mole (as part per trillion) CH3Br_PFP, ppt, methyl bromide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC11_PFP, ppt, trichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC141b_PFP, ppt, 1,1-chloro-1-fluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3I_PFP, ppt, methyl iodide, dry-air mole fraction, pico mole per mole (as part per trillion) CFC113_PFP, ppt, 1,1,2-trichloro-1,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Cl2_PFP, ppt, dichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHCl3_PFP, ppt, trichloromethane (chloroform), dry-air mole fraction, pico mole per mole (as part per trillion) CH3CCl3_PFP, ppt, 1,1,1-trichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CCl4_PFP, ppt, tetrachloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Br2_PFP, ppt, dibromomethane, dry-air mole fraction, pico mole per mole (as part per trillion) C2Cl4_PFP, ppt, tetrachloroethylene, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr3_PFP, ppt, tribromomethane (bromorform), dry-air mole fraction, pico mole per mole (as part per trillion) Benzene_PFP, ppt, C6H6, dry-air mole fraction, pico mole per mole (as part per trillion) OCS_PFP, ppt, carbonyl sulfide, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC21_PFP, ppt, dichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC152a_PFP, ppt, 1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) H2402_PFP, ppt, 1,2-dibromo-1,1,2,2-tetrafluoroethane (halon-2402, dry-air mole fraction, pico mole per mole (as part per trillion) HFC365mfc_PFP, ppt, 1,1,1,3,3-pentafluorobutane, dry-air mole fraction, pico mole per mole (as part per trillion) Propyne_PFP, ppt, C3H4, dry-air mole fraction, pico mole per mole (as part per trillion) C2H5Cl_PFP, prelim, chloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC227ea_PFP, ppt, 1,1,1,2,3,3,3-heptafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) nPentane_PFP, ppt, normal pentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) nHexane_PFP, ppt, normal hexane (C6H14), dry-air mole fraction, pico mole per mole (as part per trillion) HCFC133a_PFP, ppt, 1-chloro-2,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClI_PFP, ppt, chloroiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2I2_PFP, ppt, diiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrCl_PFP, ppt, bromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2ClCH2Cl_PFP, ppt, 1,2-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) Propane_PFP, ppt, C3H8, dry-air mole fraction, pico mole per mole (as part per trillion) iPentane_PFP, ppt, isopentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) iButane_PFP, ppt, isobutane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) nButane_PFP, ppt, normal butane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) CHBrCl2_PFP, ppt, bromodichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrI_PFP, ppt, bromoiodomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3CHCl2_PFP, prelim, 1,1-dichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr2Cl_PFP, ppt, dibromochloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) 0 20 PI_CONTACT_INFO: 303-497-6657 325 Broadway, Boulder CO 80305 email stephen.a.montzka@noaa.gov colm.sweeney@noaa.gov PLATFORM: NASA DC8 LOCATION: Aircraft location here with appropriate date indicated: http://espoarchive.nasa.gov/archive/fileinfo/MMS-FlightPath_DC8_YYYYMMDD.ict ASSOCIATED_DATA: See http://espoarchive.nasa.gov/archive/browse/atom INSTRUMENT_INFO: Programmable Flask Package results from multiple analysis instruments at NOAA and CU/INSTAAR DATA_INFO: Units on fields: seconds,ppm,ppb,ppb,ppb,ppt,ppb,per mil,per mil,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,prelim,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,ppt,prelim,ppt, UNCERTAINTY: tbd ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: Steve Montzka, 303-497-6657, 325 Broadway, Boulder, CO 80305 PROJECT_INFO: ATom-2; 04-Dec-2016 to 22-Feb-2017; https://espo.nasa.gov/home/atom/content/ATom STIPULATIONS_ON_USE: Notification of S. Montzka or C. Sweeney is requested with use of data. OTHER_COMMENTS: all measurement results are given in dry-air mole fractions; results for two gases are on preliminary scales (not mole fractions) REVISION: R2 R0: preliminary data R1: data for public release R2: final data, for public release Start_UTC,Stop_UTC,CO2_PFP,CH4_PFP,CO_PFP,N2O_PFP,SF6_CCGG_PFP,H2_PFP,d13C_CH4_PFP,d13C_CO2_PFP,HFC134a_PFP,HCFC22_PFP,CFC12_PFP,CH3Cl_PFP,HCFC142b_PFP,H1211_PFP,CH3Br_PFP,CFC11_PFP,HCFC141b_PFP,CH3I_PFP,CFC113_PFP,CH2Cl2_PFP,CHCl3_PFP,CH3CCl3_PFP,CCl4_PFP,CH2Br2_PFP,C2Cl4_PFP,CHBr3_PFP,Benzene_PFP,OCS_PFP,HCFC21_PFP,HFC152a_PFP,H2402_PFP,HFC365mfc_PFP,Propyne_PFP,C2H5Cl_PFP,HFC227ea_PFP,nPentane_PFP,nHexane_PFP,HCFC133a_PFP,CH2ClI_PFP,CH2I2_PFP,CH2BrCl_PFP,CH2ClCH2Cl_PFP,Propane_PFP,iPentane_PFP,iButane_PFP,nButane_PFP,CHBrCl2_PFP,CH2BrI_PFP,CH3CHCl2_PFP,CHBr2Cl_PFP 32288,32296,405.07,1866.51,136.23,330.26,9.13,534.48,-47.277,-8.489,93.4,239.69,510.32,646.43,22,3.471,8.02,230.26,24.7,0.16,71.21,41.98,8.36,2.273,80.74,0.732,-999.99,0.29,25.87,490.87,0.323,5.95,0.413,0.918,0.169,0.33,1.26,4.82,0.3,0.453,0.005,0.002,0.115,6.79,29.89,1.32,2.82,1.04,124.696,-0.019,0.249,0.111 32693,32705,406,1858.48,102.63,329.9,9.09,529.84,-47.25,-999.99,93.27,239.78,511.94,605.33,22.18,3.457,7.26,230.53,24.72,0.09,71.21,38.98,8.36,2.317,80.46,0.801,-999.99,0.29,17.83,488.58,0.316,6.17,0.42,0.923,0.342,0.27,1.227,2.9,0.5,0.468,0.005,0.007,0.109,6.23,37.99,0.53,2.06,2.555,117.693,0.01,0.229,0.09 33988,34006,402.91,1849.86,83.75,329.5,9.06,521.97,-47.241,-999.99,91.41,235.51,510.16,622.92,21.89,3.409,7.23,229.17,24.42,0.05,71.26,26.94,6.7,2.283,80.26,0.705,-999.99,0.39,6.33,467.89,0.281,5.24,0.414,0.878,0.393,0.22,1.245,2.04,0.8,0.41,0.007,0.004,0.106,3.43,36.32,0.98,3.17,4.697,83.42,0.008,0.128,0.083 35012,35020,406.88,1869.4,137.65,330.1,9.1,533.89,-47.177,-999.99,93.55,240.37,511.97,628.47,22.24,3.454,7.69,230.65,24.71,0.11,71.41,40.71,8.51,2.307,80.86,0.775,-999.99,0.3,31.95,485.54,0.327,6.12,0.424,0.926,0.652,0.35,1.245,2.78,0.48,0.454,0.003,0.002,0.105,6.64,51.82,0.76,2.83,3.418,113.213,-0.004,0.209,0.104 35329,35335,407.41,1857.24,195.48,329.25,9.07,557.5,-47.306,-999.99,92.99,238.79,508.87,631.95,22.18,3.462,7.49,229.74,24.5,0.92,70.98,37.85,7.71,2.3,80.12,0.754,-999.99,0.42,86.31,504.73,0.301,5.97,0.413,0.908,2.342,0.37,1.256,9.04,1.32,0.44,0.017,0.002,0.116,5.67,120.71,7.62,12.14,19.962,116.861,0.005,0.216,0.111 35499,35505,403.77,1812.82,85.6,328.64,8.99,533.35,-47.098,-999.99,90.27,233.13,509.71,566.09,21.78,3.425,6.95,229,24.06,0.94,71.22,22.94,5.71,2.281,80.28,0.634,-999.99,0.36,12.33,500.86,0.266,5.02,0.413,0.856,0.218,0.18,1.2,1.16,0.86,0.423,0.152,0.005,0.093,2.79,11.41,0.57,1.26,1.064,83.873,0.002,0.134,0.079 36055,36064,411.91,1911.68,302.17,329.83,9.25,567.65,-47.057,-999.99,97.08,245.08,510.66,672.65,22.54,3.499,8.21,230.68,25.47,0.3,71.37,54.28,10.59,2.424,80.54,0.94,-999.99,0.49,143.69,513.68,0.356,8.04,0.411,0.974,6.544,0.63,1.305,5.24,0.94,0.478,0.003,0.008,0.153,10.06,196.52,2.07,9.23,14.155,159.548,-0.003,0.365,0.145 36413,36426,405.86,1872.61,144.4,329.94,9.16,528.91,-47.167,-999.99,93.46,239.68,511.02,647.8,22.22,3.482,7.9,230.35,24.86,0.16,71.22,41.44,8.79,2.322,80.74,0.818,-999.99,0.43,40.95,479.4,0.313,6.14,0.422,0.912,1.007,0.36,1.251,4.84,1.43,0.453,0.004,0.008,0.109,6.9,124.14,2.82,9.78,17.685,124.621,0.006,0.269,0.117 37531,37551,405.73,1853.24,132.91,329.28,9.1,537.59,-47.198,-999.99,92.49,237.63,510.49,619.49,22.06,3.427,7.49,230.23,24.56,0.04,71.04,33.63,7.54,2.275,80.75,0.728,-999.99,0.31,20.4,486.01,0.301,5.88,0.424,0.9,0.498,0.27,1.227,1.86,0.63,0.439,0.005,0.005,0.108,4.91,60.74,1.43,3.86,6.735,103.172,0.015,0.163,0.091 38483,38492,406.34,1861.72,149.2,329.68,9.08,539.92,-47.204,-999.99,93.19,239.11,510.57,630.53,22.23,3.442,7.57,230.11,24.58,0.32,71.11,37.91,8.05,2.307,80.41,0.789,-999.99,0.39,41.37,491.1,0.311,6.11,0.412,0.91,0.819,0.39,1.25,3.5,1.12,0.45,0.003,0.001,0.094,5.85,68.11,1.51,4.32,6.778,117.283,0.021,0.197,0.099 38848,38855,408.89,1884.15,211.53,330.1,9.16,544.92,-47.151,-999.99,95.22,242.04,509.73,664.14,22.43,3.513,7.8,230.04,25.02,1.1,71.24,48.79,9.92,2.323,80.08,1.035,-999.99,1.08,93.73,497.05,0.336,7.09,0.417,0.959,4.64,0.45,1.27,5.62,1.41,0.464,0.015,0.005,0.123,8.03,142.96,4.43,9.83,16.886,161.498,-0.009,0.338,0.179 39051,39057,407.75,1885.55,126.74,329.86,9.18,521.58,-47.197,-999.99,96.74,245.55,511.84,609.39,22.51,3.499,7.2,231.05,25.45,0.99,71.23,53.62,11.88,2.402,80.35,1.428,-999.99,2.36,39.46,509.39,0.374,8.39,0.423,0.978,0.716,0.48,1.315,4.8,0.86,0.477,0.105,0.005,0.166,9.55,137.16,2.35,11.07,15.642,205.888,-0.012,0.416,0.287 39669,39678,410.37,1890.37,239.05,330.04,9.19,556.44,-47.156,-8.719,95.12,243.15,509.87,659.49,22.42,3.477,8.16,230.19,25.81,0.42,71.08,47.64,9.65,2.365,80.79,0.849,-999.99,0.44,98.12,509.17,0.338,7.21,0.417,0.943,3.17,0.49,1.234,5.06,0.38,0.468,0,0.006,0.147,8.33,134.71,1.67,6.2,10.035,143.198,-0.015,0.348,0.136 40128,40143,405.55,1850.61,119.56,329.92,9.06,534.97,-47.18,-8.502,92.43,237.46,511.17,609.59,22.07,3.445,7.3,230.12,24.85,0.18,71.64,33.8,7.64,2.331,80.79,0.79,-999.99,0.45,22.65,492.12,0.301,6.01,0.414,0.905,0.431,0.25,1.273,4.84,0.26,0.433,0.002,0.005,0.113,5.19,48.13,1.16,3.36,4.686,110.484,-0.01,0.204,0.119 40987,41007,405.87,1852.87,125.47,329.58,9.13,536.26,-47.179,-8.545,92.45,237.64,508.87,608.7,22.15,3.429,7.37,229.62,24.77,0.16,71.15,36.71,7.92,2.303,80.62,0.852,-999.99,0.66,21.89,495.59,0.303,6.14,0.415,0.918,0.409,0.27,1.28,4.01,0.18,0.438,0.005,0.005,0.116,5.68,49.11,0.83,3.29,4.021,122.092,0.001,0.238,0.135 42019,42028,409.28,1853.17,81.6,329.53,9.12,527.4,-47.146,-8.481,93.85,240.71,511.49,584.7,22.22,3.463,6.94,230.66,25.21,0.08,71.24,42.88,8.94,2.351,80.79,0.847,-999.99,0.35,7.71,501.4,0.328,6.48,0.408,0.932,0.134,0.26,1.259,2.28,0.27,0.458,-0.002,-0.001,0.107,7.14,29.92,0.4,1.16,1.367,124.692,-0.029,0.264,0.118 42329,42335,408.9,1874.91,198.26,330.02,9.15,551.94,-47.152,-8.651,94.72,241.38,509.88,643.37,22.32,3.48,7.61,230.62,-999.99,0.6,71.28,43.98,8.99,2.349,80.62,0.813,-999.99,0.41,59.53,500.52,0.323,6.99,0.408,0.947,1.042,0.41,1.222,4.16,0.27,0.448,0.002,0.006,0.124,6.87,76.6,1.71,5.12,5.246,130.034,0.005,0.276,0.1 42575,42582,407.37,1889.24,100.26,330.17,9.35,514.07,-47.18,-8.642,97.45,246.47,512.21,582.34,22.52,3.484,7.07,231.06,-999.99,0.65,71.44,58.04,12.67,2.431,81.05,1.237,-999.99,1.35,27.89,507.11,0.39,9.28,0.424,0.988,0.504,0.49,1.319,9.03,0.62,0.497,0.141,0.008,0.186,10.88,186.78,4.36,15.48,19.774,179.889,0.001,0.515,0.214 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44713,44737,404.87,1841.35,103.22,329.63,9.01,531.98,-47.22,-8.456,91.6,236.11,509.71,614.55,21.96,3.424,7.31,229.62,24.6,0.1,71.17,28.81,7.13,2.274,80.28,0.666,-999.99,0.41,10.43,479.08,0.293,5.55,0.424,0.883,0.633,0.31,1.211,4.11,0.43,0.432,0.001,0.002,0.102,4.61,30.77,1.41,2.62,3.158,100.205,-0.032,0.132,0.094 45495,45506,405.15,1847,72.33,329.49,9.1,526.03,-47.136,-8.461,93.09,239.77,512.45,581.35,22.2,3.473,6.86,230.41,24.91,0.04,71.48,39.32,8.27,2.306,80.75,0.803,-999.99,0.24,4.74,501.55,0.315,6.25,0.421,0.924,0.275,0.26,1.288,1.65,0.49,0.449,0.001,0.001,0.13,6.21,23.26,0.48,1.46,1.412,119.027,0.002,0.24,0.091 45812,45820,409.17,1883.17,188.98,329.51,9.2,545.37,-47.141,-8.661,95.78,243.5,512.56,614.78,22.52,3.492,7.56,231,25.64,0.22,71.36,47.79,9.93,2.331,80.85,0.887,-999.99,0.44,48.79,504.18,0.353,7.71,0.428,0.977,0.837,0.4,1.358,6.26,0.48,0.453,-0.001,0.006,0.172,7.71,69.05,1.72,4.73,3.759,136.563,-0.005,0.298,0.135 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