97, 1001 Montzka, S., Sweeney, C. Global Monitoring Division/ESRL/NOAA PFP; Flask measurements of trace gases from PFP flasks ATom 1,1 2016, 08, 22, 2019, 02, 27 0 Start_UTC, seconds 62 1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1 -999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 Stop_UTC, seconds CO2_PFP, ppm, carbon dioxide, dry-air mole fraction, micro mole per mole (as part per million) CH4_PFP, ppb, methane, dry-air mole fraction, nano mole per mole (as part per billion) CO_PFP, ppb, carbon monoxide, dry-air mole fraction, nano mole per mole (as part per billion) N2O_PFP, ppb, nitrous oxide, dry-air mole fraction, nano mole per mole (as part per billion) SF6_CCGG_PFP, ppt, sulfur hexafluoride dry-air mole fraction, pico mole per mole (as part per trillion, or ppt), measured by electron capture detection in carbon cycle group SF6_HATS_PFP, ppt, sulfur hexafluoride dry-air mole fraction, pico mole per mole (as part per trillion, or ppt), measured by mass spectrometry in HATS group H2_PFP, ppb, hydrogen, dry-air mole fraction, nano mole per mole (as part per billion) d13C_CH4_PFP, per mil, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CH4 relative to Vienna Pee Dee Belemnite d13C_CO2_PFP, per mil, per mil, deviation in the 13C/12C Stable Carbon Isotope Ratio in CO2 relative to Vienna Pee Dee Belemnite CFC11_PFP, ppt, trichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC12_PFP, ppt, dichlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC13_PFP, ppt, chlorotrifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC113_PFP, ppt, 1,1,2-trichloro-1,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC115_PFP, ppt, chloropentafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CFC112_PFP, ppt, 1,1,2,2-tetrachloro-1,2-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC22_PFP, ppt, chlorodifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC142b_PFP, ppt, 1-chloro-1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC141b_PFP, ppt, 1,1-chloro-1-fluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC21_PFP, ppt, dichlorofluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC133a_PFP, ppt, 1-chloro-2,2,2-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HCFC124_PFP, ppt, 1-chloro-1,2,2,2-tetrafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC23_PFP, ppt, trifluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC32_PFP, ppt, difluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC134a_PFP, ppt, 1,1,1,2-tetrafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC152a_PFP, ppt, 1,1-difluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC125_PFP, ppt, pentafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC143a_PFP, ppt, 1,1,1-trifluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC227ea_PFP, ppt, 1,1,1,2,3,3,3-heptafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC365mfc_PFP, ppt, 1,1,1,3,3-pentafluorobutane, dry-air mole fraction, pico mole per mole (as part per trillion) H1211_PFP, ppt, bromodichlorofluoromethane (halon-1211), dry-air mole fraction, pico mole per mole (as part per trillion) H1301_PFP, ppt, bromotrifluoromethane (halon-1301), dry-air mole fraction, pico mole per mole (as part per trillion) H2402_PFP, ppt, 1,2-dibromo-1,1,2,2-tetrafluoroethane (halon-2402, dry-air mole fraction, pico mole per mole (as part per trillion) CCl4_PFP, ppt, tetrachloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CH3CCl3_PFP, ppt, 1,1,1-trichloroethane, dry-air mole fraction, pico mole per mole (as part per trillion) CF4_PFP, ppt, tetrafluoromethane, dry-air mole fraction, pico mole per mole (as part per trillion) C2F6_PFP, ppt, hexafluoroethane, dry-air mole fraction, pico mole per mole (as part per trillion) NF3_PFP, ppt, nitrogen trifluoride, dry-air mole fraction, pico mole per mole (as part per trillion) SO2F2_PFP, ppt, sulfuryl fluoride, dry-air mole fraction, pico mole per mole (as part per trillion) CH3Cl_PFP, ppt, methyl chloride, dry-air mole fraction, pico mole per mole (as part per trillion) CH3Br_PFP, ppt, methyl bromide, dry-air mole fraction, pico mole per mole (as part per trillion) CH3I_PFP, ppt, methyl iodide, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Br2_PFP, ppt, dibromomethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHBr3_PFP, ppt, tribromomethane (bromorform), dry-air mole fraction, pico mole per mole (as part per trillion) OCS_PFP, ppt, carbonyl sulfide, dry-air mole fraction, pico mole per mole (as part per trillion) CH2Cl2_PFP, ppt, dichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) CHCl3_PFP, ppt, trichloromethane (chloroform), dry-air mole fraction, pico mole per mole (as part per trillion) C2Cl4_PFP, ppt, tetrachloroethylene, dry-air mole fraction, pico mole per mole (as part per trillion) Ethyne_PFP, ppt, C2H4 (or acetylene), dry-air mole fraction, pico mole per mole (as part per trillion) Ethane_PFP, ppt, C2H6, dry-air mole fraction, pico mole per mole (as part per trillion) Propane_PFP, ppt, C3H8, dry-air mole fraction, pico mole per mole (as part per trillion) nButane_PFP, ppt, normal butane (C4H10), dry-air mole fraction, pico mole per mole (as part per trillion) iButane_PFP, ppt, isobutane (C4H10, or 2-methyl propane), dry-air mole fraction, pico mole per mole (as part per trillion) nPentane_PFP, ppt, normal pentane (C5H12), dry-air mole fraction, pico mole per mole (as part per trillion) iPentane_PFP, ppt, isopentane (C5H12, or 2-methyl butane), dry-air mole fraction, pico mole per mole (as part per trillion) Benzene_PFP, ppt, C6H6, dry-air mole fraction, pico mole per mole (as part per trillion) Toluene_PFP, ppt, C7H8, dry-air mole fraction, pico mole per mole (as part per trillion) CH2BrCl_PFP, ppt, bromodichloromethane, dry-air mole fraction, pico mole per mole (as part per trillion) HFC236fa_PFP, ppt, 1,1,1,3,3,3-hexafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) C2HCl3_PFP, ppt, trichloroethylene, dry-air mole fraction, pico mole per mole (as part per trillion) C3F8_PFP, ppt, octafluoropropane, dry-air mole fraction, pico mole per mole (as part per trillion) CS2_PFP, ppt, carbon disulfide, dry-air mole fraction, pico mole per mole (as part per trillion) 0 21 PI_CONTACT_INFO: 303-497-6657 325 Broadway, Boulder CO 80305 email stephen.a.montzka@noaa.gov colm.sweeney@noaa.gov PLATFORM: NASA DC8 LOCATION: Aircraft location here with appropriate date indicated: http://espoarchive.nasa.gov/archive/fileinfo/MMS-FlightPath_DC8_YYYYMMDD.ict ASSOCIATED_DATA: See http://espoarchive.nasa.gov/archive/browse/atom INSTRUMENT_INFO: Programmable Flask Package results from multiple analysis instruments at NOAA and CU/INSTAAR DATA_INFO: N/A UNCERTAINTY: tbd ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: Steve Montzka, 303-497-6657, 325 Broadway, Boulder, CO 80305 PROJECT_INFO: ATom-1; 10-Jul-2016 to 26-Aug-2016; https://espo.nasa.gov/home/atom/content/ATom STIPULATIONS_ON_USE: Until made public, only the ATom science team is allowed to use this data, per the ATom data protocol. Notificaiton of S. Montzka or C. Sweeney is also requested. OTHER_COMMENTS: all measurement results are given in dry-air mole fractions REVISION: R4 R1: Preliminary Field Data, all times should be accurate, updated results from R0 R2: Preliminary Field Data, all times should be accurate, updated results from R1 including full isotope results R3: revised data, for public release R4: revised data to increase consistency across all ATom deployments, for public release Start_UTC,Stop_UTC,CO2_PFP,CH4_PFP,CO_PFP,N2O_PFP,SF6_CCGG_PFP,SF6_HATS_PFP,H2_PFP,d13C_CH4_PFP,d13C_CO2_PFP,CFC11_PFP,CFC12_PFP,CFC13_PFP,CFC113_PFP,CFC115_PFP,CFC112_PFP,HCFC22_PFP,HCFC142b_PFP,HCFC141b_PFP,HCFC21_PFP,HCFC133a_PFP,HCFC124_PFP,HFC23_PFP,HFC32_PFP,HFC134a_PFP,HFC152a_PFP,HFC125_PFP,HFC143a_PFP,HFC227ea_PFP,HFC365mfc_PFP,H1211_PFP,H1301_PFP,H2402_PFP,CCl4_PFP,CH3CCl3_PFP,CF4_PFP,C2F6_PFP,NF3_PFP,SO2F2_PFP,CH3Cl_PFP,CH3Br_PFP,CH3I_PFP,CH2Br2_PFP,CHBr3_PFP,OCS_PFP,CH2Cl2_PFP,CHCl3_PFP,C2Cl4_PFP,Ethyne_PFP,Ethane_PFP,Propane_PFP,nButane_PFP,iButane_PFP,nPentane_PFP,iPentane_PFP,Benzene_PFP,Toluene_PFP,CH2BrCl_PFP,HFC236fa_PFP,C2HCl3_PFP,C3F8_PFP,CS2_PFP 47790,47810,-999.99,1895.65,92.14,329.32,9.17,9.125,516.37,-47.687,-8.308,231.012,512.548,3.328,71.512,8.619,-999.99,249.762,22.893,26.004,-999.99,0.513,-999.99,-999.99,13.379,96.298,8.386,21.822,19.878,1.387,0.991,3.57,3.384,0.422,82.432,2.65,83.301,4.628,-999.99,2.393,538.731,7.456,0.087,0.555,-999.99,494.306,53.72,12.242,-999.99,-999.99,695.663,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 48467,48475,-999.99,1904.92,102.93,329.17,9.16,9.146,494.46,-47.7,-8.156,230.546,511.415,3.394,71.181,8.588,-999.99,248.871,22.877,26.002,-999.99,0.526,-999.99,-999.99,13.256,96.186,8.52,21.795,20.072,1.286,0.97,3.524,3.355,0.412,81.889,2.615,83.226,4.699,-999.99,2.367,508.994,7.106,0.099,0.652,-999.99,453.877,52.218,12.884,-999.99,-999.99,705.674,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 48808,48816,-999.99,1910.98,95.34,328.99,9.2,9.142,475.02,-47.676,-8.033,230.174,511.724,3.366,71.181,8.564,-999.99,248.202,22.849,25.834,-999.99,0.521,-999.99,-999.99,13.243,96.936,9.098,21.818,20.109,1.257,1.007,3.458,3.337,0.42,82.032,2.622,83.434,4.626,-999.99,2.36,486.418,6.886,0.408,1.068,-999.99,439.629,51.426,14.53,-999.99,-999.99,665.629,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 49581,49598,-999.99,1894.52,95.73,329.37,9.17,9.168,521.08,-47.633,-8.365,231.408,511.724,3.383,70.907,8.568,-999.99,250.975,22.978,26.128,-999.99,0.505,-999.99,-999.99,13.982,99.081,10.411,22.261,20.338,1.261,0.992,3.579,3.328,0.395,81.948,2.421,83.059,4.618,-999.99,2.433,541.432,7.356,0.147,0.612,-999.99,491.205,53.773,12.391,-999.99,-999.99,890.029,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 50447,50467,-999.99,1905.77,106.79,329.8,9.15,9.179,517.86,-47.088,-8.362,231.501,511.621,3.406,71.116,8.549,-999.99,255.754,23.127,26.61,-999.99,0.496,-999.99,-999.99,15.726,104.261,13.853,23.634,20.946,1.26,1.024,3.524,3.372,0.42,81.764,2.42,83.092,4.641,-999.99,2.59,544.373,7.539,0.199,0.614,-999.99,478.114,53.963,13.082,-999.99,-999.99,1198.426,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 53601,53611,-999.99,1913.69,101.83,328.56,9.13,9.171,506.32,-47.511,-8.179,229.917,511.158,3.345,71.245,8.558,-999.99,247.881,22.774,25.663,-999.99,0.51,-999.99,-999.99,13.104,96.579,8.291,21.893,20.005,1.224,0.991,3.538,3.326,0.417,82.14,2.48,82.709,4.641,-999.99,2.35,520.634,7.239,0.104,0.587,-999.99,455.928,51.42,12.306,-999.99,-999.99,723.011,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 53926,53936,-999.99,1918.93,104.42,328.83,9.1,9.144,489.24,-47.73,-8.112,230.384,511.158,3.373,70.878,8.554,-999.99,248.054,22.751,25.575,-999.99,0.534,-999.99,-999.99,12.9,96.035,8.338,21.799,19.999,1.297,1.005,3.609,3.318,0.454,81.705,2.463,82.926,4.665,-999.99,2.325,503.318,7.199,0.419,0.686,-999.99,437.212,51.058,13.795,-999.99,-999.99,705.43,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 54737,54754,-999.99,1900.74,96.28,328.09,9.14,9.146,515.38,-47.746,-8.239,229.336,509.768,3.383,70.779,8.596,-999.99,247.46,22.753,25.678,-999.99,0.49,-999.99,-999.99,13.403,97.216,8.762,21.96,20.179,1.246,0.999,3.461,3.294,0.412,81.864,2.469,82.784,4.602,-999.99,2.351,532.999,7.363,0.05,0.535,-999.99,473.752,50.809,11.346,-999.99,-999.99,797.73,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 55677,55751,-999.99,1746.79,32.32,309.24,8.54,8.532,543.45,-47.523,-8.439,194.261,478.046,3.295,54.229,8.416,-999.99,222.355,20.349,16.455,-999.99,0.337,-999.99,-999.99,9.382,80.644,4.674,17.587,17.232,1.058,0.159,2.901,2.998,0.27,53.546,0.685,81.725,4.452,-999.99,2.089,445.545,3.837,0.066,0.046,-999.99,349.99,3.842,0.407,-999.99,-999.99,96.45,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 57985,57992,-999.99,1980.58,101.85,328.64,9.15,9.171,461.08,-47.583,-999.99,230.546,511.261,3.3,71.181,8.539,-999.99,247.137,22.776,25.653,-999.99,0.528,-999.99,-999.99,12.978,96.176,8.889,21.922,19.991,1.278,1.009,3.526,3.28,0.429,82.382,2.41,82.984,4.647,-999.99,2.297,476.642,6.623,0.511,0.83,-999.99,393.207,50.779,18.484,-999.99,-999.99,713.977,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 58940,58960,-999.99,1900.62,98.41,328.49,9.09,9.134,514.13,-48.206,-8.371,230.127,510.437,3.33,70.965,8.581,-999.99,249.02,22.705,25.546,-999.99,0.514,-999.99,-999.99,13.566,97.713,8.725,22.153,20.314,1.276,0.992,3.512,3.319,0.435,81.531,2.435,83.117,4.645,-999.99,2.311,537.477,7.391,0.245,0.568,-999.99,478.169,53.761,12.303,-999.99,-999.99,790.404,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 59901,59985,-999.99,1740.98,31.06,307.73,8.5,8.482,545.38,-46.693,-8.435,191.65,476.089,3.308,52.366,8.362,-999.99,222.404,20.089,15.239,-999.99,0.326,-999.99,-999.99,9.72,80.231,4.575,17.535,17.119,1.02,0.109,2.872,2.939,0.256,50.635,0.478,81.704,4.497,-999.99,2.038,417.03,3.088,0.083,0.021,-999.99,261.725,2.576,0.303,-999.99,-999.99,72.277,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 60774,60785,-999.99,1911.46,97.78,328.85,9.11,9.129,495.1,-47.154,-8.15,230.38,511.261,3.385,71.339,8.568,-999.99,247.732,22.731,25.755,-999.99,0.514,-999.99,-999.99,13.127,96.392,8.468,21.908,20.205,1.263,1.016,3.503,3.315,0.412,81.428,2.61,83.221,4.648,-999.99,2.345,513.04,7.324,0.397,0.658,-999.99,459.426,50.311,12.423,-999.99,-999.99,840.461,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 61277,61286,-999.99,1957.71,108.15,329.06,9.17,9.109,465,-47.711,-7.916,230.45,510.694,3.376,71.44,8.62,-999.99,247.806,22.921,25.657,-999.99,0.526,-999.99,-999.99,13.076,97.188,9.093,22.118,20.213,1.281,1.008,3.519,3.311,0.431,82.305,2.562,83.004,4.661,-999.99,2.347,488.29,7.019,0.463,0.762,-999.99,382.26,50.967,15.08,-999.99,-999.99,780.393,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 62150,62300,-999.99,1877.66,80.71,329.14,9.18,9.174,530.47,-48.003,-8.322,231.614,511.93,3.39,71.138,8.559,-999.99,251.545,22.765,25.851,-999.99,0.512,-999.99,-999.99,13.238,95.202,7.305,21.683,19.762,1.262,0.955,3.508,3.31,0.414,82.055,2.503,83.163,4.679,-999.99,2.376,560.897,7.303,0.289,0.617,-999.99,531.758,63.535,12.981,-999.99,-999.99,499.832,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 63136,63214,-999.99,1876.39,82.12,329.16,9.16,9.155,537.96,-47.397,-8.372,230.427,511.158,3.371,68.75,8.574,-999.99,253.253,22.712,25.601,-999.99,0.511,-999.99,-999.99,13.34,94.191,6.879,21.488,19.368,1.246,0.796,3.528,3.281,0.41,78.081,2.21,83.28,4.657,-999.99,2.342,590.051,7.422,0.104,0.22,-999.99,536.227,65.117,10.065,-999.99,-999.99,471.508,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 64262,64274,-999.99,1865.98,76.88,329.35,9.16,9.154,522.65,-47.401,-8.306,230.45,511.673,3.373,71.023,8.54,-999.99,246.617,22.515,25.215,-999.99,0.505,-999.99,-999.99,12.847,94.771,7.414,21.576,19.748,1.22,0.93,3.467,3.28,0.415,81.345,2.438,83.171,4.628,-999.99,2.345,523.317,7.079,0.268,0.508,-999.99,508.314,48.633,9.936,-999.99,-999.99,469.798,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 64785,64795,-999.99,1966.56,107.92,329.7,9.15,9.156,468.78,-47.448,-7.863,230.078,511.055,3.298,70.886,8.55,-999.99,249.045,23.109,25.866,-999.99,0.516,-999.99,-999.99,13.538,98.369,10.599,22.315,20.428,1.25,1.007,3.583,3.308,0.424,81.745,2.631,83.155,4.628,-999.99,2.29,483.839,7.301,0.47,0.748,-999.99,389.094,50.012,14.392,-999.99,-999.99,987.212,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99 66120,66146,-999.99,1838.94,57.16,329.33,8.99,9.037,532.69,-47.855,-8.408,229.798,511.724,3.291,71.447,8.534,-999.99,240.676,22.067,24.726,-999.99,0.476,-999.99,-999.99,12.017,92.12,6.531,20.853,19.466,1.226,0.863,3.513,3.296,0.415,81.42,2.493,82.888,4.609,-999.99,2.341,555.775,6.969,0.261,0.681,-999.99,516.831,38.628,7.419,-999.99,-999.99,277.142,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99,-999.99