80,1001 Karl Froyd and Daniel Murphy NOAA Chemical Sciences Division PALMS ATom-1 1,1 2016,08,06, 2019,11,14 0 PALMSstartTime, UTC seconds, from 00:00:00 of flight day 18 1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1 -9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999 PALMSstopTime, UTC seconds, from 00:00:00 of flight day PALMSmidTime, UTC seconds, from 00:00:00 of flight day SulfOrgNitFrac_PALMS, number fraction, mixed sulfate-organic-nitrate particles BioBurnFrac_PALMS, number fraction, biomass burning particles SootFrac_PALMS, number fraction, elemental carbon particles MineralFrac_PALMS, number fraction, mineral/metallic particles MeteoricFrac_PALMS, number fraction, particles with meteoric material AlkaliSaltFrac_PALMS, number fraction, alkali salt particles SeaSaltFrac_PALMS, number fraction, sea salt particles OilCombFrac_PALMS, number fraction, particles from heavy oil combustion UnclassFrac_PALMS, number fraction, unclassified particles OrgSulfMF_PALMS, mass fraction, organic-to-sulfate mass fraction IEPOXmf_PALMS, mass fraction, fraction of submicron aerosol mass attributed to IEPOX sulfate GASmf_PALMS, mass fraction, fraction of submicron aerosol mass attributed to glycolic acid sulfate SulfNeut_PALMS, molar ratio, degree of sulfate neutralization Npos_PALMS, counts, positive ion particles NNeg_PALMS, counts, negative ion products NAcid_PALMS, counts, SulfNeut product 26 PALMS aerosol composition for diam ~150 to >3000 nm. PALMS samples from the Clarke/Langely common aerosol inlet. Particles are sent through a virtual impactor to improve sampling statistics for large particles. Typically the PALMS size range spans the peak of the aerosol mass mode. Single particles are classified into the particle types shown below. Number fractions of these particle types are calculated over each time segment, and these averages are presented as the primary data products. Some additional chemical data products are also given. PALMS alternates between positive and negative ion detection mode, which yields different data products. If there were at least 5 suitable particles in a time interval, average values are calculated. The number of particles used to calculate the averages is also reported. Other data products, including size-resolved composition, are available - contact the PI. ***Positive ion mode data products: SulfOrgNitFrac, BioBurnFrac, SootFrac, MineralFrac, MeteoricFrac, AlkaliSaltFrac, SeaSaltFrac, OilCombFrac, UnclassFrac, OrgSulfMF The Sulfate/Organic/Nitrate fraction (0 to 1) is the number fraction of particles that are identified as sulfate/organic/nitrate internal mixtures. Likewise for particles identified as biomass burning, soot, mineral dust/metallic, meteoric, alkali salts, sea salt, heavy oil combustion (vanadium tracer), and unclassified (other) particles. OrgSulfMF is the mass fraction of organic material relative to sulfate: Org mass/(org+sulf mass) = 0-1. This parameter is a calibrated quantity and is only calculated for particles that are sulfate-organic-nitrate internal mixtures (which is often the predominant particle type). ***Negative ion mode data products: IEPOXmf_PALMS, GASmf_PALMS IEPOXmf_PALMS is the fraction of submicron aerosol mass attributed to IEPOX sulfate ester, an organosulfate derived from isoprene oxidation products. GASmf_PALMS is the fraction of submicron aerosol mass attributed to glycolic acid sulfate, an organosulfate derived from isoprene and other precursors. ***Acidity data product: SulfNeut This is the average degree of sulfuric acid neutralization calculated only for particles that are sulfate-organic-nitrate internal mixtures. It is reported as the ammonium-to-sulfate ratio, NH4:SO4. This calibrated product becomes insensitive to the degreee of neutralization for highly neutralized sulfate. Values >=2 are therefore not quantitative but nevertheless indicate complete neutralization. 22 PI_CONTACT_INFO: Karl.Froyd@noaa.gov PLATFORM: NASA DC-8 LOCATION: ATom-1, Palmdale, CA ASSOCIATED_DATA: N/A INSTRUMENT_INFO: The Particle Analysis by Laser Mass Spectrometry instrument measures single particle composition DATA_INFO: Units: Frac products: number fractions from 0-1. Org MF from 0-1. Sulfate Neut product: NH4:SO4 ratio from 0-2.5. UNCERTAINTY: See Froyd et al., AMT 2019 ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: Karl.Froyd@noaa.gov PROJECT_INFO: NASA Atmospheric Tomography campaign, deployment 1, July-Aug 2016 STIPULATIONS_ON_USE: Contact the PIs prior to using this data. OTHER_COMMENTS: N/A REVISION: R3 R0: Preliminary data. R1: Final data. Time bins are 3 mins. Cloudy sampling periods, zero checks, and diagnostic periods were excluded at 1 sec resolution. Data times adjusted to account for inlet tubing residence time. See other PALMS archive files for Mass Concentration products. Size-dependent and other chemical data available - contact PI. R2: Minor revisions to particle classification R3: Minor revisions to particle classification PALMSstartTime,PALMSstopTime,PALMSmidTime,SulfOrgNitFrac_PALMS,BioBurnFrac_PALMS,SootFrac_PALMS,MineralFrac_PALMS,MeteoricFrac_PALMS,AlkaliSaltFrac_PALMS,SeaSaltFrac_PALMS,OilCombFrac_PALMS,UnclassFrac_PALMS,OrgSulfMF_PALMS,IEPOXmf_PALMS,GASmf_PALMS,SulfNeut_PALMS,Npos_PALMS,NNeg_PALMS,NAcid_PALMS 64620, 64800, 64710, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 64800, 64980, 64890, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 64980, 65160, 65070, 0.80851, 0.15957, 0.00000, 0.010638, 0.010638, 0.00000, 0.00000, 0.00000, 0.010638, 0.19671, -9999.0, -9999.0, -9999.0, 94, 0, 0 65160, 65340, 65250, 0.90000, 0.033333, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.066667, 0.10629, 0.0076088, 0.0033753, 0.41320, 30, 71, 71 65340, 65520, 65430, 0.84127, 0.063492, 0.00000, 0.015873, 0.00000, 0.00000, 0.00000, 0.00000, 0.079365, 0.24491, -9999.0, -9999.0, -9999.0, 63, 0, 0 65520, 65700, 65610, 0.77778, 0.074074, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.14815, 0.43504, 0.00000, 0.0087415, 0.24161, 27, 24, 23 65700, 65880, 65790, 0.86538, 0.076923, 0.00000, 0.00000, 0.00000, 0.00000, 0.019231, 0.00000, 0.038462, 0.40465, 0.00000, 0.011193, 0.50794, 52, 31, 31 65880, 66060, 65970, 0.80392, 0.068627, 0.00000, 0.00000, 0.019608, 0.00000, 0.00000, 0.00000, 0.10784, 0.45823, 0.00000, 0.012681, 0.52684, 102, 48, 48 66060, 66240, 66150, 0.86154, 0.030769, 0.00000, 0.00000, 0.030769, 0.00000, 0.015385, 0.00000, 0.061538, 0.37135, 0.00000, 0.013932, 0.55362, 65, 89, 89 66240, 66420, 66330, 0.81818, 0.12121, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.030303, 0.030303, 0.42541, 0.00000, 0.014609, 0.53112, 33, 125, 125 66420, 66600, 66510, 0.78261, 0.10145, 0.00000, 0.00000, 0.014493, 0.00000, 0.00000, 0.014493, 0.086957, 0.42295, 0.00000, 0.014313, 0.59331, 69, 23, 23 66600, 66780, 66690, 0.78125, 0.062500, 0.031250, 0.00000, 0.031250, 0.00000, 0.031250, 0.00000, 0.062500, 0.39967, 0.00000, 0.012306, 0.37121, 32, 39, 39 66780, 66960, 66870, 0.86486, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.13514, 0.39114, 0.00000, 0.013614, 0.47992, 37, 65, 65 66960, 67140, 67050, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0.00000, 0.0098513, 0.63413, 0, 11, 11 67140, 67320, 67230, 0.92857, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.071429, 0.00000, 0.40908, -9999.0, -9999.0, -9999.0, 14, 0, 0 67320, 67500, 67410, 0.87850, 0.028037, 0.00000, 0.0093458, 0.00000, 0.00000, 0.00000, 0.00000, 0.084112, 0.45830, 0.00000, 0.010441, 0.73695, 107, 26, 26 67500, 67680, 67590, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0.00000, 0.010762, 0.84598, 0, 172, 172 67680, 67860, 67770, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0.00000, 0.013174, 0.63701, 0, 123, 123 67860, 68040, 67950, 0.92000, 0.060000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.020000, 0.36325, -9999.0, -9999.0, -9999.0, 50, 0, 0 68040, 68220, 68130, 0.83505, 0.041237, 0.010309, 0.00000, 0.020619, 0.00000, 0.010309, 0.00000, 0.082474, 0.29427, -9999.0, -9999.0, -9999.0, 97, 0, 0 68220, 68400, 68310, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0.00000, 0.0040643, 0.29765, 0, 80, 80 68400, 68580, 68490, 0.66667, 0.28571, 0.00000, 0.00000, 0.00000, 0.00000, 0.023810, 0.00000, 0.023810, 0.25829, -9999.0, -9999.0, -9999.0, 84, 0, 0 68580, 68760, 68670, 0.80000, 0.10667, 0.00000, 0.020000, 0.00000, 0.00000, 0.026667, 0.020000, 0.026667, 0.14210, 0.00000, 0.00049615, 0.093840, 150, 211, 211 68760, 68940, 68850, 0.75786, 0.022013, 0.00000, 0.012579, 0.0062893, 0.00000, 0.18239, 0.00000, 0.018868, 0.13414, 0.00000, 0.00000, 0.20571, 318, 25, 25 68940, 69120, 69030, 0.71084, 0.00000, 0.00000, 0.00000, 0.012048, 0.00000, 0.26506, 0.00000, 0.012048, 0.16332, 0.00000, 0.00000, 0.11450, 83, 164, 164 69120, 69300, 69210, 0.67433, 0.022989, 0.00000, 0.049808, 0.0038314, 0.00000, 0.24138, 0.00000, 0.0076628, 0.15903, 0.00000, 0.00000, 0.060993, 261, 54, 53 69300, 69480, 69390, 0.52174, 0.31884, 0.00000, 0.12319, 0.00000, 0.00000, 0.021739, 0.0072464, 0.0072464, 0.29915, 0.00000, 0.00041091, 0.11962, 138, 163, 154 69480, 69660, 69570, 0.41304, 0.043478, 0.00000, 0.50000, 0.00000, 0.00000, 0.021739, 0.00000, 0.021739, 0.087786, 0.00000, 0.0029324, 0.040267, 46, 23, 16 69660, 69840, 69750, 0.66000, 0.020000, 0.00000, 0.30000, 0.00000, 0.00000, 0.00000, 0.00000, 0.020000, 0.21394, 0.00000, 0.0084936, 0.069475, 50, 8, 8 69840, 70020, 69930, 0.68750, 0.062500, 0.00000, 0.12500, 0.062500, 0.00000, 0.00000, 0.00000, 0.062500, 0.21596, 0.0054046, 0.0091311, 0.15414, 16, 40, 39 70020, 70200, 70110, 0.90000, 0.062500, 0.00000, 0.012500, 0.00000, 0.00000, 0.00000, 0.00000, 0.025000, 0.23943, 0.00000, 0.013412, 0.16358, 80, 7, 7 70200, 70380, 70290, 0.93182, 0.022727, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.022727, 0.022727, 0.33662, 0.00000, 0.012291, 0.29968, 44, 45, 43 70380, 70560, 70470, 0.83784, 0.081081, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.081081, 0.39720, 0.00030689, 0.0084679, 0.86533, 74, 72, 72 70560, 70740, 70650, 0.90000, 0.053846, 0.00000, 0.015385, 0.00000, 0.00000, 0.00000, 0.00000, 0.030769, 0.43623, 0.00000, 0.011072, 0.85885, 130, 45, 45 70740, 70920, 70830, 0.86364, 0.090909, 0.00000, 0.00000, 0.022727, 0.00000, 0.00000, 0.00000, 0.022727, 0.43080, 0.00000, 0.0069559, 0.91159, 44, 126, 126 70920, 71100, 71010, 0.88112, 0.076923, 0.00000, 0.0069930, 0.0069930, 0.00000, 0.00000, 0.00000, 0.027972, 0.45035, 0.00000, 0.010485, 0.81022, 143, 15, 15 71100, 71280, 71190, 0.86567, 0.059701, 0.00000, 0.014925, 0.00000, 0.00000, 0.00000, 0.014925, 0.044776, 0.40389, 0.00000, 0.0095040, 0.97004, 67, 86, 86 71280, 71460, 71370, 0.90090, 0.063063, 0.00000, 0.00000, 0.0090090, 0.00000, 0.00000, 0.00000, 0.027027, 0.43305, 0.0075497, 0.0081511, 0.86767, 111, 63, 63 71460, 71640, 71550, 0.83607, 0.13115, 0.00000, 0.016393, 0.00000, 0.00000, 0.00000, 0.00000, 0.016393, 0.26187, 0.00000, 0.011302, 0.72424, 61, 14, 14 71640, 71820, 71730, 0.58824, 0.058824, 0.058824, 0.11765, 0.00000, 0.00000, 0.058824, 0.00000, 0.11765, 0.21053, 0.00000, 0.00000, 0.11976, 17, 45, 43 71820, 72000, 71910, 0.41007, 0.41007, 0.00000, 0.13669, 0.00000, 0.00000, 0.028777, 0.0071942, 0.0071942, 0.41316, -9999.0, -9999.0, -9999.0, 139, 3, 3 72000, 72180, 72090, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0.00000, 0.0032172, 0.15655, 0, 47, 37 72180, 72360, 72270, 0.46753, 0.038961, 0.00000, 0.025974, 0.00000, 0.00000, 0.44156, 0.00000, 0.025974, 0.27308, -9999.0, -9999.0, -9999.0, 77, 0, 0 72360, 72540, 72450, 0.31765, 0.038235, 0.00000, 0.0058824, 0.00000, 0.00000, 0.62941, 0.00000, 0.0088235, 0.27703, 0.00000, 0.00000, 1.0408, 340, 37, 35 72540, 72720, 72630, 0.56140, 0.074561, 0.00000, 0.017544, 0.0043860, 0.00000, 0.34211, 0.00000, 0.00000, 0.33443, 0.00000, 0.00000, 0.97804, 228, 129, 125 72720, 72900, 72810, 0.62500, 0.10938, 0.00000, 0.046875, 0.00000, 0.00000, 0.18750, 0.031250, 0.00000, 0.33977, 0.00000, 0.0014568, 0.23745, 64, 92, 85 72900, 73080, 72990, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0.00000, 0.00000, 0.0094331, 0, 8, 7 73080, 73260, 73170, 0.83636, 0.090909, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.054545, 0.018182, 0.22182, -9999.0, -9999.0, -9999.0, 55, 0, 0 73260, 73440, 73350, 0.87500, 0.062500, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.062500, 0.24381, 0.034203, 0.013308, 0.21418, 32, 30, 30 73440, 73620, 73530, 0.84783, 0.13043, 0.00000, 0.021739, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.25480, 0.00000, 0.015479, 0.29641, 46, 22, 20 73620, 73800, 73710, 0.79012, 0.13580, 0.012346, 0.012346, 0.00000, 0.00000, 0.00000, 0.00000, 0.049383, 0.42106, 0.00000, 0.011712, 0.30797, 81, 23, 23 73800, 73980, 73890, 0.84615, 0.038462, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.11538, 0.37528, 0.00000, 0.0094852, 1.0250, 26, 130, 128 73980, 74160, 74070, 0.95000, 0.028571, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.021429, 0.43484, 0.00000, 0.011533, 2.0638, 140, 6, 6 74160, 74340, 74250, 0.84615, 0.076923, 0.038462, 0.038462, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.47714, 0.00000, 0.0079933, 2.3552, 26, 22, 22 74340, 74520, 74430, 0.89474, 0.052632, 0.00000, 0.00000, 0.017544, 0.00000, 0.00000, 0.017544, 0.017544, 0.44214, 0.00000, 0.020331, 0.85887, 57, 15, 15 74520, 74700, 74610, 0.84483, 0.10345, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.051724, 0.49239, 0.00000, 0.0096314, 0.65388, 58, 41, 41 74700, 74880, 74790, 0.84375, 0.093750, 0.00000, 0.00000, 0.031250, 0.00000, 0.031250, 0.00000, 0.00000, 0.42995, 0.00000, 0.0093152, 0.69109, 32, 38, 38 74880, 75060, 74970, 0.91228, 0.052632, 0.00000, 0.017544, 0.00000, 0.00000, 0.00000, 0.00000, 0.017544, 0.43905, 0.00000, 0.010487, 0.51504, 57, 5, 5 75060, 75240, 75150, 0.68182, 0.00000, 0.00000, 0.31818, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.32622, 0.00000, 0.0097297, 0.036620, 22, 35, 34 75240, 75420, 75330, 0.60976, 0.00000, 0.00000, 0.36585, 0.00000, 0.00000, 0.00000, 0.00000, 0.024390, 0.19256, 0.00000, 0.0030995, 0.029103, 82, 24, 9 75420, 75600, 75510, 0.39535, 0.046512, 0.023256, 0.53488, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.22018, 0.00055317, 0.0037674, 0.093365, 43, 30, 14 75600, 75780, 75690, 0.40541, 0.054054, 0.00000, 0.48649, 0.00000, 0.00000, 0.054054, 0.00000, 0.00000, 0.25045, 0.00000, 0.0012613, 0.077085, 37, 65, 57 75780, 75960, 75870, 0.27881, 0.037175, 0.00000, 0.0037175, 0.00000, 0.00000, 0.68030, 0.00000, 0.00000, 0.26791, 0.00000, 0.0013460, 0.40372, 269, 20, 20 75960, 76140, 76050, 0.058824, 0.058824, 0.00000, 0.058824, 0.00000, 0.00000, 0.82353, 0.00000, 0.00000, 0.33736, 0.00000, 0.0016216, 0.096144, 17, 40, 38 76140, 76320, 76230, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 76320, 76500, 76410, 0.71429, 0.13690, 0.00000, 0.00000, 0.0059524, 0.00000, 0.10119, 0.0059524, 0.035714, 0.35071, -9999.0, -9999.0, -9999.0, 168, 0, 0 76500, 76680, 76590, 0.82353, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.11765, 0.00000, 0.058824, 0.24485, 0.023831, 0.011486, 0.029894, 17, 22, 22 76680, 76860, 76770, 0.93333, 0.044444, 0.00000, 0.00000, 0.022222, 0.00000, 0.00000, 0.00000, 0.00000, 0.24649, 0.020185, 0.010905, 0.030372, 45, 21, 21 76860, 77040, 76950, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0.082008, 0.013343, 0.11129, 0, 17, 17 77040, 77220, 77130, 0.82456, 0.070175, 0.017544, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.087719, 0.28745, -9999.0, -9999.0, -9999.0, 57, 0, 0 77220, 77400, 77310, 0.77778, 0.11111, 0.00000, 0.00000, 0.11111, 0.00000, 0.00000, 0.00000, 0.00000, 0.23087, 0.00000, 0.0089872, 0.19762, 9, 28, 28 77400, 77580, 77490, 0.90909, 0.030303, 0.00000, 0.00000, 0.030303, 0.00000, 0.00000, 0.00000, 0.030303, 0.33861, -9999.0, -9999.0, -9999.0, 33, 2, 2 77580, 77760, 77670, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0.00000, 0.011531, 0.20217, 2, 11, 11 77760, 77940, 77850, 0.80000, 0.10000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.10000, 0.27498, -9999.0, -9999.0, -9999.0, 10, 3, 3 77940, 78120, 78030, 0.90000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.10000, 0.29213, -9999.0, -9999.0, -9999.0, 10, 2, 2 78120, 78300, 78210, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 2, 2, 2 78300, 78480, 78390, 0.87500, 0.062500, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.062500, 0.31984, -9999.0, -9999.0, -9999.0, 16, 1, 1 78480, 78660, 78570, 0.89655, 0.034483, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.068966, 0.23737, 0.00000, 0.011526, 0.10882, 29, 32, 32 78660, 78840, 78750, 0.87500, 0.031250, 0.031250, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.062500, 0.16822, 0.059755, 0.010129, 0.031623, 32, 28, 28 78840, 79020, 78930, 0.85106, 0.085106, 0.021277, 0.021277, 0.021277, 0.00000, 0.00000, 0.00000, 0.00000, 0.13896, 0.026925, 0.0095434, 0.035745, 47, 24, 24 79020, 79200, 79110, 0.77273, 0.13636, 0.00000, 0.00000, 0.00000, 0.00000, 0.045455, 0.00000, 0.045455, 0.17781, 0.0024779, 0.0010961, 0.17663, 22, 84, 84 79200, 79380, 79290, 0.42400, 0.088000, 0.00000, 0.0026667, 0.00000, 0.00000, 0.46933, 0.0053333, 0.010667, 0.17459, 0.00000, 0.00000, 1.0847, 375, 5, 5 79380, 79560, 79470, 0.60109, 0.10929, 0.0054645, 0.00000, 0.00000, 0.00000, 0.23497, 0.00000, 0.049180, 0.14625, 0.00000, 0.00041792, 0.94875, 183, 207, 205 79560, 79740, 79650, 0.33745, 0.061728, 0.00000, 0.00000, 0.00000, 0.00000, 0.56790, 0.0041152, 0.028807, 0.15775, -9999.0, -9999.0, -9999.0, 243, 0, 0 79740, 79920, 79830, 0.70854, 0.14070, 0.0050251, 0.0050251, 0.00000, 0.00000, 0.11558, 0.00000, 0.025126, 0.23969, -9999.0, -9999.0, -9999.0, 199, 0, 0 79920, 80100, 80010, 0.76471, 0.17647, 0.00000, 0.058824, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.19125, 0.018339, 0.0048539, 0.073190, 17, 30, 30 80100, 80280, 80190, 0.87838, 0.027027, 0.00000, 0.013514, 0.027027, 0.00000, 0.00000, 0.00000, 0.054054, 0.16317, -9999.0, -9999.0, -9999.0, 74, 0, 0 80280, 80460, 80370, 0.85714, 0.00000, 0.00000, 0.00000, 0.047619, 0.00000, 0.00000, 0.00000, 0.095238, 0.30066, 0.046309, 0.0021543, 0.076495, 21, 28, 28 80460, 80640, 80550, 0.80000, 0.14286, 0.00000, 0.00000, 0.00000, 0.00000, 0.028571, 0.00000, 0.028571, 0.25854, 0.00000, 0.0085838, 0.0094331, 35, 5, 5 80640, 80820, 80730, 0.90909, 0.00000, 0.018182, 0.00000, 0.00000, 0.00000, 0.00000, 0.018182, 0.054545, 0.43504, 0.00000, 0.019689, 0.43251, 55, 24, 24 80820, 81000, 80910, 0.90000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.10000, 0.34453, 0.00000, 0.010476, 0.18417, 20, 12, 12 81000, 81180, 81090, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 81180, 81360, 81270, 1.0000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.43047, -9999.0, -9999.0, -9999.0, 12, 0, 0 81360, 81540, 81450, 1.0000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.38776, 0.00000, 0.012357, 0.54212, 13, 14, 14 81540, 81720, 81630, 0.85000, 0.10000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.050000, 0.40499, 0.00000, 0.021836, 1.0637, 20, 5, 5 81720, 81900, 81810, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0.00000, 0.0093593, 0.13861, 2, 10, 10 81900, 82080, 81990, 0.75000, 0.12500, 0.00000, 0.00000, 0.12500, 0.00000, 0.00000, 0.00000, 0.00000, 0.57372, 0.00000, 0.0092800, -9999.0, 8, 8, 0 82080, 82260, 82170, 0.90476, 0.047619, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.047619, 0.27229, 0.00000, 0.0079309, 0.011986, 21, 9, 9 82260, 82440, 82350, 0.78788, 0.060606, 0.030303, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.12121, 0.23551, 0.00000, 0.013712, 0.025942, 33, 8, 8 82440, 82620, 82530, 0.91667, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.083333, 0.00000, 0.18459, 0.0053568, 0.010188, 0.047325, 12, 37, 37 82620, 82800, 82710, 0.84058, 0.086957, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.014493, 0.057971, 0.16642, -9999.0, -9999.0, -9999.0, 69, 0, 0 82800, 82980, 82890, 0.82353, 0.044118, 0.014706, 0.00000, 0.00000, 0.00000, 0.00000, 0.014706, 0.10294, 0.098504, -9999.0, -9999.0, -9999.0, 68, 0, 0 82980, 83160, 83070, 0.52439, 0.25610, 0.012195, 0.012195, 0.00000, 0.00000, 0.15854, 0.012195, 0.024390, 0.27555, 0.00000, 0.0016447, 1.0141, 82, 123, 123 83160, 83340, 83250, 0.29526, 0.11699, 0.0055710, 0.00000, 0.00000, 0.00000, 0.55989, 0.0027855, 0.019499, 0.21483, 0.00000, 0.00000, 1.0856, 359, 9, 9 83340, 83520, 83430, 0.071429, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.92857, 0.00000, 0.00000, 0.28806, 0.0027192, 0.0020883, 1.2182, 14, 129, 129 83520, 83700, 83610, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 83700, 83880, 83790, 0.71429, 0.14286, 0.00000, 0.14286, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.31493, -9999.0, -9999.0, -9999.0, 7, 0, 0 83880, 84060, 83970, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 84060, 84240, 84150, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 84240, 84420, 84330, 1.0000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.57561, -9999.0, -9999.0, -9999.0, 11, 0, 0 84420, 84600, 84510, 0.90000, 0.066667, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.033333, 0.43366, -9999.0, -9999.0, -9999.0, 30, 0, 0 84600, 84780, 84690, 0.76190, 0.19048, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.047619, 0.56575, -9999.0, -9999.0, -9999.0, 21, 0, 0 84780, 84960, 84870, 0.89474, 0.10526, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.51144, -9999.0, -9999.0, -9999.0, 38, 0, 0 84960, 85140, 85050, 0.50000, 0.50000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.39790, -9999.0, -9999.0, -9999.0, 6, 0, 0 85140, 85320, 85230, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 1, 0, 0 85320, 85500, 85410, 0.82787, 0.14754, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.0081967, 0.016393, 0.26589, 0.00000, 0.0022723, 1.3176, 122, 102, 102 85500, 85680, 85590, 0.77483, 0.16556, 0.0066225, 0.00000, 0.00000, 0.00000, 0.033113, 0.013245, 0.0066225, 0.20531, 0.00000, 0.0052150, 1.4774, 151, 38, 38 85680, 85860, 85770, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0.00000, 0.00093874, 0.91426, 0, 164, 164 85860, 86040, 85950, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 86040, 86220, 86130, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 86220, 86400, 86310, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 86400, 86580, 86490, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 86580, 86760, 86670, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 86760, 86940, 86850, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 86940, 87120, 87030, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 87120, 87300, 87210, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 87300, 87480, 87390, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 1, 0, 0 87480, 87660, 87570, 1.0000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.53333, -9999.0, -9999.0, -9999.0, 9, 0, 0 87660, 87840, 87750, 0.89655, 0.068966, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.034483, 0.43097, -9999.0, -9999.0, -9999.0, 29, 0, 0 87840, 88020, 87930, 0.81818, 0.18182, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.43406, 0.00000, 0.010241, 0.38201, 11, 17, 17 88020, 88200, 88110, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0.00000, 0.0097685, 0.56706, 0, 21, 21 88200, 88380, 88290, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0.00000, 0.0096426, 0.31823, 1, 20, 20 88380, 88560, 88470, 0.96154, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.038462, 0.41497, -9999.0, -9999.0, -9999.0, 26, 0, 0 88560, 88740, 88650, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 4, 2, 2 88740, 88920, 88830, 0.91667, 0.083333, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.30324, 0.00000, 0.0087912, 0.035872, 12, 11, 11 88920, 89100, 89010, 0.92000, 0.080000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.24013, 0.00000, 0.0058223, 0.14435, 25, 9, 9 89100, 89280, 89190, 1.0000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.28213, 0.00000, 0.0082620, 0.046160, 10, 20, 20 89280, 89460, 89370, 0.83333, 0.16667, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.17700, -9999.0, -9999.0, -9999.0, 18, 0, 0 89460, 89640, 89550, 0.76923, 0.15385, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.076923, 0.31828, 0.00000, 0.0085346, 0.039277, 26, 29, 29 89640, 89820, 89730, 0.78462, 0.21538, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.35312, -9999.0, -9999.0, -9999.0, 65, 1, 1 89820, 90000, 89910, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 2, 2, 1 90000, 90180, 90090, 0.62857, 0.028571, 0.00000, 0.014286, 0.00000, 0.00000, 0.32857, 0.00000, 0.00000, 0.12597, 0.00000, 0.00000, 2.0598, 70, 46, 46 90180, 90360, 90270, 0.85057, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.14943, 0.00000, 0.00000, 0.12113, 0.00000, 0.00000, 1.0051, 87, 91, 91 90360, 90540, 90450, 0.84127, 0.037037, 0.00000, 0.00000, 0.00000, 0.00000, 0.11111, 0.00000, 0.010582, 0.12736, 0.00000, 0.00000, 1.3818, 189, 23, 23 90540, 90720, 90630, 0.66667, 0.047619, 0.00000, 0.00000, 0.00000, 0.00000, 0.28571, 0.00000, 0.00000, 0.17298, 0.00000, 0.00000, 1.4263, 21, 59, 59 90720, 90900, 90810, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 90900, 91080, 90990, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 91080, 91260, 91170, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 1, 0, 0 91260, 91440, 91350, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 3, 3 91440, 91620, 91530, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 91620, 91800, 91710, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 91800, 91980, 91890, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 91980, 92160, 92070, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 92160, 92340, 92250, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 92340, 92520, 92430, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 92520, 92700, 92610, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 92700, 92880, 92790, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 92880, 93060, 92970, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 1, 1 93060, 93240, 93150, 0.80000, 0.20000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.081486, -9999.0, -9999.0, -9999.0, 5, 3, 3 93240, 93420, 93330, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0.00000, 0.00000, 0.14513, 2, 8, 8 93420, 93600, 93510, 0.060086, 0.00000, 0.00000, 0.00000, 0.00000, 0.00000, 0.93991, 0.00000, 0.00000, 0.096589, -9999.0, -9999.0, -9999.0, 233, 0, 0 93600, 93780, 93690, 0.075949, 0.025316, 0.00000, 0.00000, 0.00000, 0.00000, 0.89873, 0.00000, 0.00000, 0.18187, 0.024747, 0.0057479, 0.11492, 79, 7, 6 93780, 93960, 93870, 0.010695, 0.0053476, 0.00000, 0.00000, 0.00000, 0.00000, 0.97326, 0.00000, 0.010695, 0.098300, -9999.0, -9999.0, -9999.0, 187, 3, 3 93960, 94140, 94050, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 94140, 94320, 94230, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 1, 0, 0 94320, 94500, 94410, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 94500, 94680, 94590, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 94680, 94860, 94770, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 94860, 95040, 94950, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, -9999.0, 0, 0, 0 95040, 95220, 95130, 0.60000, 0.10000, 0.00000, 0.00000, 0.00000, 0.00000, 0.20000, 0.00000, 0.10000, 0.11529, -9999.0, -9999.0, -9999.0, 10, 0, 0 95220, 95400, 95310, 0.025000, 0.00000, 0.00000, 0.17500, 0.00000, 0.00000, 0.80000, 0.00000, 0.00000, 0.094508, -9999.0, -9999.0, -9999.0, 40, 1, 1 95400, 95580, 95490, 0.045455, 0.011364, 0.00000, 0.028409, 0.00000, 0.00000, 0.65341, 0.00000, 0.26136, 0.48333, -9999.0, -9999.0, -9999.0, 176, 1, 1 95580, 95760, 95670, 0.033708, 0.011236, 0.00000, 0.022472, 0.00000, 0.00000, 0.73034, 0.00000, 0.20225, 0.81604, -9999.0, -9999.0, -9999.0, 89, 0, 0