40, 1001 Wennberg, P.O. California Institute of Technology Gas phase Methyl Hydrogen Peroxide (CH3OOH) from DC8 ATom 1 1, 1 2016, 08, 23, 2018, 03, 09 0 UTCstart, seconds of day 3 1, 1, 1 -9999, -9999, -9999 UTCstop, seconds of day UTCmid, seconds of day MHP_CIT, pptv, volume_mixing_ratio_of_methyl_hydrogen_peroxide_in_air 0 23 PI_CONTACT_INFO: Address: California Institute of Technology. MC 131-24. 1200 E. California Blvd, Pasadena, CA, 91125. Email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 aircraft LOCATION: DC-8 location data available at https://espoarchive.nasa.gov/archive/browse/atom/DC8/MMS-1HZ ASSOCIATED_DATA: See http://espoarchive.nasa.gov/archive/browse/atom INSTRUMENT_INFO: CIT-Triple-CIMS: Chemical Ionization Triple Quadrupole Mass Spectrometer. Direct measurements of methyl hydrogen peroxide (MHP) vapor in air. DATA_INFO: Measurements are reported as 1 second averages every 10-15 seconds and in units of parts per trillion (pptv). CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Mixing ratio are calculated by fraction of standard addition of an isotopic label. Absolute calibration based on FT-IR cross section of 3.20e-19 cm^2 molecule-1 at 2963.8 cm-1 (Niki et al.,1983) UNCERTAINTY: 25 pptv [+-30% of measurement]. Accuracy is humidity dependent. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: Michelle J. Kim, California Institute of Technology M/C 131-24. 1200 E. California Blvd. Pasadena, CA 91125. Email: mjk@caltech.edu PROJECT_INFO: ATOM I study; July-Aug 2016 STIPULATIONS_ON_USE: Data is publicly available. Adherence to the ATom data protocol is required. OTHER_COMMENTS: Final Data. REVISION: R2 R2: Revision 2 data computed as fraction of labeled standard addition.. R1: Revision 1 data computed based on laboratory calibrations. UTCstart, UTCstop, UTCmid, MHP_CIT 54317.6, 54318.7, 54318.1, -9999 54331.2, 54332.4, 54331.8, -9999 54342.3, 54343.4, 54342.8, -9999 54355.4, 54356.5, 54356.0, -9999 54369.1, 54370.2, 54369.6, -9999 54380.1, 54381.2, 54380.6, -9999 54393.2, 54394.4, 54393.8, -9999 54406.9, 54408.1, 54407.5, -9999 54417.9, 54419.1, 54418.5, -9999 54431.1, 54432.2, 54431.7, -9999 54444.8, 54446.0, 54445.4, -9999 54455.8, 54456.9, 54456.3, -9999 54468.9, 54470.0, 54469.5, -9999 54482.7, 54483.8, 54483.2, -9999 54493.6, 54494.8, 54494.2, 1860 54506.8, 54507.9, 54507.3, 2055 54520.5, 54521.6, 54521.0, 1937 54531.5, 54532.6, 54532.0, 2071 54544.7, 54545.8, 54545.2, 1533 54558.3, 54559.5, 54558.9, 1326 54569.3, 54570.4, 54569.8, 1561 54582.4, 54583.5, 54582.9, 1680 54596.0, 54597.1, 54596.5, 1447 54606.9, 54608.1, 54607.5, 1356 54620.1, 54621.2, 54620.7, 1373 54633.8, 54635.0, 54634.4, 1407 54644.8, 54646.0, 54645.4, 1378 54658.0, 54659.2, 54658.6, 1373 54671.7, 54672.8, 54672.3, 1174 54682.7, 54683.8, 54683.3, 1091 54695.9, 54697.0, 54696.5, 1205 54709.8, 54710.9, 54710.3, 1432 54720.7, 54721.9, 54721.3, 1238 54733.9, 54735.0, 54734.5, 1526 54771.1, 54772.2, 54771.6, -9999 54782.1, 54783.2, 54782.6, -9999 54795.2, 54796.3, 54795.7, -9999 54808.9, 54810.0, 54809.5, -9999 54819.9, 54821.1, 54820.5, -9999 54833.1, 54834.2, 54833.7, -9999 54846.8, 54847.9, 54847.3, -9999 54857.8, 54858.9, 54858.3, -9999 54870.9, 54872.0, 54871.5, -9999 54884.6, 54885.7, 54885.2, -9999 54895.6, 54896.7, 54896.2, -9999 54908.7, 54909.9, 54909.3, -9999 54957.7, 54958.8, 54958.3, 322 54968.7, 54969.8, 54969.3, 293 54981.9, 54983.0, 54982.4, 318 54995.6, 54996.7, 54996.1, 361 55006.6, 55007.7, 55007.1, 252 55019.7, 55020.8, 55020.3, 356 55033.4, 55034.5, 55034.0, 218 55044.4, 55045.5, 55044.9, 226 55057.5, 55058.6, 55058.1, 258 55071.3, 55072.4, 55071.9, 198 55082.3, 55083.4, 55082.9, 132 55095.4, 55096.6, 55096.0, 354 55109.1, 55110.2, 55109.6, 611 55120.1, 55121.2, 55120.7, 729 55133.2, 55134.4, 55133.8, 366 55146.9, 55148.0, 55147.5, 500 55157.9, 55159.0, 55158.5, 342 55171.1, 55172.2, 55171.6, 567 55184.7, 55185.9, 55185.3, 429 55195.7, 55196.8, 55196.3, 589 55208.8, 55210.0, 55209.4, 484 55222.4, 55223.5, 55223.0, 193 55233.4, 55234.5, 55234.0, 269 55246.5, 55247.6, 55247.1, 263 55260.1, 55261.2, 55260.6, 180 55271.2, 55272.3, 55271.7, 165 55284.3, 55285.5, 55284.9, 134 55297.9, 55299.0, 55298.5, 165 55308.9, 55310.0, 55309.5, 235 55322.1, 55323.2, 55322.6, 183 55335.8, 55336.9, 55336.3, 200 55346.7, 55347.9, 55347.3, 204 55359.8, 55361.0, 55360.4, 118 55373.4, 55374.6, 55374.0, 95 55384.4, 55385.5, 55385.0, 52 55397.5, 55398.7, 55398.1, 130 55411.3, 55412.4, 55411.8, 46 55422.3, 55423.4, 55422.8, 115 55435.4, 55436.5, 55436.0, 157 55449.1, 55450.2, 55449.7, 134 55460.1, 55461.2, 55460.7, 165 55473.2, 55474.4, 55473.8, 199 55486.8, 55487.9, 55487.4, 264 55497.8, 55498.9, 55498.3, 229 55510.9, 55512.0, 55511.4, 333 55524.4, 55525.6, 55525.0, 333 55535.4, 55536.6, 55536.0, 232 55548.6, 55549.7, 55549.2, 316 55562.3, 55563.4, 55562.9, 341 55573.2, 55574.4, 55573.8, 208 55586.4, 55586.7, 55586.6, 309 55589.3, 55590.2, 55589.8, 227 55602.9, 55604.0, 55603.4, 256 55613.9, 55615.0, 55614.4, 203 55627.0, 55628.1, 55627.6, 235 55640.7, 55641.9, 55641.3, 187 55651.7, 55652.9, 55652.3, 174 55664.9, 55666.0, 55665.4, 216 55678.6, 55679.7, 55679.1, 206 55689.5, 55690.6, 55690.1, 227 55702.7, 55703.8, 55703.2, 204 55716.2, 55717.4, 55716.8, 215 55727.2, 55728.3, 55727.8, 177 55740.4, 55741.5, 55740.9, 251 55754.1, 55755.2, 55754.7, 269 55765.1, 55766.2, 55765.7, 185 55778.2, 55779.4, 55778.8, 236 55814.0, 55815.1, 55814.5, -9999 55825.0, 55826.1, 55825.5, -9999 55838.1, 55839.2, 55838.7, -9999 55851.8, 55853.0, 55852.4, -9999 55862.8, 55864.0, 55863.4, -9999 55876.0, 55877.2, 55876.6, -9999 55913.2, 55914.3, 55913.8, 315 55924.2, 55925.3, 55924.8, 308 55937.3, 55938.4, 55937.9, 322 55951.1, 55952.2, 55951.6, 303 55962.1, 55963.2, 55962.6, 288 55975.2, 55976.3, 55975.8, 288 55988.9, 55990.0, 55989.4, 267 55999.9, 56001.0, 56000.5, 347 56013.1, 56014.2, 56013.6, 309 56026.8, 56027.9, 56027.3, 266 56037.8, 56038.9, 56038.3, 258 56050.9, 56052.1, 56051.5, 245 56064.6, 56065.7, 56065.2, 279 56075.6, 56076.7, 56076.1, 163 56088.7, 56089.8, 56089.3, 108 56102.3, 56103.4, 56102.8, 152 56113.3, 56114.4, 56113.8, 122 56126.4, 56127.5, 56126.9, 138 56140.1, 56141.2, 56140.7, 87 56151.1, 56152.2, 56151.7, 125 56164.2, 56165.3, 56164.8, 111 56177.8, 56178.9, 56178.3, 42 56188.8, 56189.9, 56189.4, 103 56202.0, 56203.1, 56202.6, 77 56215.6, 56216.8, 56216.2, 65 56226.6, 56227.7, 56227.1, 44 56239.8, 56240.9, 56240.3, 87 56253.5, 56254.6, 56254.1, 116 56264.5, 56265.6, 56265.0, 158 56277.6, 56278.7, 56278.1, 142 56291.1, 56292.3, 56291.7, 103 56302.1, 56303.3, 56302.7, 153 56315.3, 56316.4, 56315.8, 219 56329.0, 56330.1, 56329.5, 144 56340.0, 56341.1, 56340.6, 234 56353.1, 56354.2, 56353.7, 280 56366.7, 56367.8, 56367.2, 247 56377.6, 56378.8, 56378.2, 293 56390.8, 56391.9, 56391.3, 193 56404.5, 56405.6, 56405.1, 279 56415.5, 56416.6, 56416.0, 436 56428.6, 56429.7, 56429.2, 797 56442.2, 56443.3, 56442.7, 746 56453.2, 56454.3, 56453.7, 680 56466.3, 56467.4, 56466.8, 609 56479.8, 56481.0, 56480.4, 693 56490.8, 56492.0, 56491.4, 861 56503.9, 56505.1, 56504.5, 1102 56517.5, 56518.6, 56518.1, 794 56528.5, 56529.6, 56529.0, 920 56541.6, 56542.7, 56542.1, 988 56555.2, 56556.3, 56555.7, 762 56566.1, 56567.3, 56566.7, 1058 56579.3, 56580.4, 56579.9, 975 56593.0, 56594.1, 56593.6, 1715 56604.0, 56605.1, 56604.6, 1338 56617.1, 56618.3, 56617.7, 532 56630.7, 56631.8, 56631.2, 612 56641.6, 56642.8, 56642.2, 491 56654.8, 56655.9, 56655.3, 436 56668.3, 56669.5, 56668.9, 537 56679.4, 56680.5, 56679.9, 518 56692.5, 56693.6, 56693.0, 634 56706.2, 56707.3, 56706.8, 552 56717.2, 56718.4, 56717.8, 604 56730.4, 56731.5, 56730.9, 554 56744.1, 56745.2, 56744.6, 447 56755.0, 56756.2, 56755.6, 412 56768.2, 56769.3, 56768.7, 623 56804.1, 56805.3, 56804.7, -9999 56815.1, 56816.2, 56815.7, -9999 56828.3, 56829.4, 56828.8, -9999 56842.0, 56843.1, 56842.6, -9999 56853.0, 56854.2, 56853.6, -9999 56866.2, 56867.3, 56866.7, -9999 56879.8, 56880.9, 56880.4, -9999 56890.8, 56891.9, 56891.4, -9999 56903.9, 56905.1, 56904.5, -9999 56917.7, 56918.8, 56918.2, -9999 56928.7, 56929.8, 56929.3, -9999 56941.9, 56943.0, 56942.4, -9999 56987.9, 56989.0, 56988.4, 2039 56998.9, 57000.0, 56999.4, 1780 57012.0, 57013.1, 57012.5, 2183 57025.7, 57026.9, 57026.3, 2489 57036.7, 57037.8, 57037.3, 2258 57049.8, 57050.9, 57050.4, 1928 57063.6, 57064.7, 57064.1, 2122 57074.6, 57075.7, 57075.1, 2203 57087.7, 57088.9, 57088.3, 2425 57101.4, 57102.5, 57101.9, 2224 57112.4, 57113.5, 57112.9, 2196 57125.5, 57126.6, 57126.1, 3199 57139.1, 57140.2, 57139.6, 1869 57150.1, 57151.2, 57150.6, 2181 57163.2, 57164.3, 57163.7, 2577 57176.9, 57178.0, 57177.5, 1587 57187.9, 57189.0, 57188.4, 2570 57201.0, 57202.1, 57201.6, 1946 57214.6, 57215.7, 57215.1, 2164 57225.5, 57226.6, 57226.1, 1903 57238.7, 57239.8, 57239.3, 1803 57252.4, 57253.6, 57253.0, 1361 57263.4, 57264.6, 57264.0, 1216 57276.6, 57277.7, 57277.1, 965 57290.3, 57291.4, 57290.8, 1419 57301.3, 57302.4, 57301.8, 1855 57314.4, 57315.5, 57314.9, 1501 57328.1, 57329.3, 57328.7, 2153 57339.2, 57340.3, 57339.8, 1852 57352.4, 57353.5, 57353.0, 2238 57366.2, 57367.3, 57366.7, 1839 57377.2, 57378.3, 57377.7, 1143 57390.3, 57391.5, 57390.9, 2114 57404.0, 57405.1, 57404.6, 1586 57415.0, 57416.1, 57415.6, 2182 57428.2, 57429.3, 57428.7, 2195 57441.8, 57443.0, 57442.4, 1447 57452.9, 57454.0, 57453.4, 1887 57466.1, 57467.2, 57466.6, 1928 57479.7, 57480.8, 57480.3, 2488 57490.7, 57491.9, 57491.3, 1999 57503.9, 57505.0, 57504.5, 1879 57517.6, 57518.7, 57518.1, 3244 57528.6, 57529.7, 57529.1, 2992 57541.7, 57542.8, 57542.3, 2806 57555.4, 57556.5, 57555.9, 1619 57566.3, 57567.5, 57566.9, 899 57579.5, 57580.6, 57580.1, 867 57593.2, 57594.4, 57593.8, 1285 57604.2, 57605.3, 57604.8, 1580 57617.3, 57618.4, 57617.9, 1582 57630.9, 57632.0, 57631.5, 1224 57641.9, 57643.0, 57642.4, 1279 57655.0, 57656.1, 57655.5, 1229 57668.6, 57669.7, 57669.1, 1441 57679.5, 57680.6, 57680.1, 1768 57692.6, 57693.7, 57693.1, 1257 57706.2, 57707.4, 57706.8, 1542 57717.2, 57718.3, 57717.7, 1483 57730.3, 57731.4, 57730.9, 1271 57743.9, 57745.0, 57744.5, 1324 57754.8, 57756.0, 57755.4, 1861 57768.0, 57769.1, 57768.5, 1517 57781.6, 57782.7, 57782.1, 1214 57792.6, 57793.7, 57793.1, 1109 57805.6, 57806.8, 57806.2, 796 57841.3, 57842.4, 57841.8, -9999 57852.2, 57853.3, 57852.8, -9999 57865.3, 57866.5, 57865.9, -9999 57879.0, 57880.1, 57879.5, -9999 57889.9, 57891.0, 57890.5, -9999 57903.0, 57904.1, 57903.6, -9999 57940.1, 57941.3, 57940.7, 854 57951.1, 57952.2, 57951.7, 592 57964.2, 57965.3, 57964.7, 700 57977.8, 57978.9, 57978.4, 492 57988.8, 57989.9, 57989.3, 644 58001.9, 58003.0, 58002.4, 606 58015.5, 58016.6, 58016.0, 668 58026.5, 58027.6, 58027.0, 566 58039.6, 58040.7, 58040.1, 537 58053.1, 58054.3, 58053.7, 579 58064.1, 58065.2, 58064.7, 598 58077.2, 58078.4, 58077.8, 582 58091.0, 58092.1, 58091.5, 554 58101.9, 58103.1, 58102.5, 574 58115.1, 58116.2, 58115.6, 527 58128.6, 58129.8, 58129.2, 681 58139.6, 58140.7, 58140.1, 515 58152.7, 58153.8, 58153.3, 167 58166.3, 58167.4, 58166.9, 205 58177.2, 58178.4, 58177.8, 202 58190.4, 58191.5, 58190.9, 216 58204.0, 58205.1, 58204.5, 183 58214.9, 58216.0, 58215.5, 201 58228.0, 58229.1, 58228.6, 211 58241.6, 58242.7, 58242.2, 153 58252.6, 58253.7, 58253.2, 169 58265.7, 58266.9, 58266.3, 127 58279.5, 58280.6, 58280.0, 134 58290.4, 58291.6, 58291.0, 313 58303.6, 58304.7, 58304.1, 215 58317.1, 58318.2, 58317.7, 263 58328.0, 58329.2, 58328.6, 144 58341.2, 58342.3, 58341.8, 116 58354.8, 58355.9, 58355.3, 54 58365.7, 58366.8, 58366.3, 112 58378.8, 58380.0, 58379.4, 133 58392.5, 58393.6, 58393.0, 113 58403.4, 58404.5, 58403.9, 156 58416.5, 58417.6, 58417.0, 164 58430.3, 58431.4, 58430.9, 171 58441.2, 58442.4, 58441.8, 274 58454.3, 58455.5, 58454.9, 272 58468.0, 58469.1, 58468.5, 294 58478.9, 58480.0, 58479.5, 292 58492.0, 58493.2, 58492.6, 322 58505.6, 58506.7, 58506.2, 341 58516.6, 58517.7, 58517.1, 299 58529.7, 58530.8, 58530.2, 284 58543.3, 58544.4, 58543.9, 193 58554.3, 58555.4, 58554.8, 108 58567.4, 58568.5, 58567.9, 87 58581.0, 58582.1, 58581.5, 88 58592.0, 58593.1, 58592.5, 69 58605.1, 58606.3, 58605.7, 38 58619.0, 58620.1, 58619.5, 68 58629.9, 58631.0, 58630.5, 79 58643.1, 58644.2, 58643.7, 176 58656.7, 58657.8, 58657.2, 193 58667.6, 58668.8, 58668.2, 147 58680.8, 58681.9, 58681.3, 119 58694.5, 58695.6, 58695.1, 99 58705.5, 58706.6, 58706.1, 88 58718.6, 58719.8, 58719.2, 56 58732.3, 58733.5, 58732.9, 82 58743.4, 58744.5, 58743.9, 56 58756.5, 58757.6, 58757.1, 49 58770.2, 58771.3, 58770.8, 46 58781.2, 58782.3, 58781.8, 45 58794.4, 58795.5, 58794.9, 25 58808.0, 58809.1, 58808.6, 57 58819.0, 58820.1, 58819.6, 62 58832.1, 58833.3, 58832.7, 56 58869.2, 58870.3, 58869.8, -9999 58880.2, 58881.3, 58880.8, -9999 58893.4, 58894.5, 58893.9, -9999 58907.1, 58908.2, 58907.6, -9999 58918.1, 58919.2, 58918.6, -9999 58931.2, 58932.3, 58931.7, -9999 58944.9, 58946.1, 58945.5, -9999 58955.9, 58957.0, 58956.5, -9999 58969.1, 58970.2, 58969.7, -9999 58982.8, 58983.9, 58983.3, -9999 58993.7, 58994.9, 58994.3, -9999 59006.9, 59008.0, 59007.5, -9999 59057.4, 59058.5, 59057.9, 44 59068.3, 59069.5, 59068.9, 42 59081.5, 59082.6, 59082.1, 29 59095.2, 59096.3, 59095.8, 22 59106.2, 59107.3, 59106.8, 27 59119.3, 59120.4, 59119.9, 39 59132.9, 59134.0, 59133.4, 50 59143.8, 59144.9, 59144.4, 33 59157.0, 59158.1, 59157.5, 36 59170.5, 59171.6, 59171.1, 54 59181.5, 59182.6, 59182.1, 52 59194.6, 59195.7, 59195.2, 52 59208.2, 59209.3, 59208.8, 58 59219.2, 59220.3, 59219.7, 66 59232.3, 59233.4, 59232.8, 83 59245.9, 59247.0, 59246.4, 93 59256.8, 59257.9, 59257.4, 94 59269.9, 59271.0, 59270.5, 125 59283.5, 59284.7, 59284.1, 113 59294.5, 59295.6, 59295.1, 104 59307.6, 59308.7, 59308.2, 192 59321.2, 59322.3, 59321.7, 133 59332.1, 59333.3, 59332.7, 151 59345.2, 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