46, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2018, 05, 19, 2018, 11, 28 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 28 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom IV: Science Flight #11 -- BGR - ANC ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 32% (actually a multiplicative factor of 1/1.32 to 1.32), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R2 R2: Final Data (see OTHER_COMMENTS) R1: Final Data (see OTHER_COMMENTS) R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 50514, 50543, 50529, -9999.000, -9999.000 50544, 50573, 50559, -9999.000, -9999.000 50574, 50603, 50589, -9999.000, -9999.000 50604, 50633, 50619, -9999.000, -9999.000 50634, 50663, 50649, 0.079, 24.087 50664, 50693, 50679, 0.036, 20.021 50694, 50723, 50709, 0.027, 21.293 50724, 50753, 50739, 0.027, 21.871 50754, 50783, 50769, 0.095, 22.449 50784, 50813, 50799, 0.095, 23.028 50814, 50843, 50829, 0.095, 23.606 50844, 50873, 50859, 0.133, 24.188 50874, 50903, 50889, 0.199, 24.766 50904, 50933, 50919, 0.199, 25.345 50934, 50963, 50949, 0.142, 25.925 50964, 50993, 50979, 0.142, 21.130 50994, 51023, 51009, 0.113, 16.335 51024, 51053, 51039, 0.113, 15.585 51054, 51083, 51069, 0.113, 16.753 51084, 51113, 51099, 0.131, 15.220 51114, 51143, 51129, 0.144, 13.686 51144, 51173, 51159, 0.144, 13.681 51174, 51203, 51189, 0.144, 15.394 51205, 51234, 51220, 0.141, 14.173 51235, 51264, 51250, 0.142, 12.953 51265, 51294, 51280, 0.142, 12.648 51295, 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52166, 52195, 52181, 0.360, 14.509 52196, 52225, 52211, 0.360, 14.510 52226, 52255, 52241, 0.283, 15.085 52256, 52285, 52271, 0.283, 14.097 52286, 52315, 52301, 0.335, 13.774 52317, 52346, 52332, 0.335, 13.448 52466, 52495, 52481, 0.300, 13.968 52497, 52526, 52512, 0.300, 12.933 52527, 52556, 52542, 0.290, 12.956 52557, 52586, 52572, 0.314, 12.979 52587, 52616, 52602, 0.314, 13.505 52617, 52646, 52632, 0.314, 13.800 52647, 52676, 52662, 0.242, 10.891 52677, 52706, 52692, 0.242, -9999.000 52707, 52736, 52722, 0.256, 14.978 52737, 52766, 52752, 0.355, 15.270 52767, 52796, 52782, 0.355, 14.864 52797, 52826, 52812, 0.355, 14.459 52827, 52856, 52842, 0.291, 17.156 52857, 52886, 52872, -9999.000, 17.317 52887, 52916, 52902, -9999.000, 16.038 52917, 52946, 52932, -9999.000, 14.760 52948, 52977, 52963, 0.186, 16.487 52978, 53007, 52993, 0.186, 17.170 53008, 53037, 53023, 0.215, 16.451 53038, 53067, 53053, 0.196, 15.729 53068, 53097, 53083, 0.196, 16.121 53098, 53127, 53113, 0.196, 15.508 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