45, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2018, 05, 18, 2018, 10, 25 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 27 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom IV: BONUS Flight #1 -- SFJ - BGR ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 32% (actually a multiplicative factor of 1/1.32 to 1.32), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R1 R1: Final Data (see OTHER_COMMENTS) R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 44564, 44593, 44579, -9999.000, -9999.000 44594, 44623, 44609, -9999.000, 3.816 44624, 44653, 44639, -9999.000, 4.496 44654, 44683, 44669, -9999.000, 11.741 44685, 44714, 44700, 0.042, 10.928 44715, 44744, 44730, 0.031, 10.115 44745, 44774, 44760, 0.031, 3.414 44775, 44804, 44790, 0.031, 11.251 44805, 44834, 44820, 0.070, 9.556 44835, 44864, 44850, 0.070, 7.861 44865, 44894, 44880, 0.062, 7.944 44895, 44924, 44910, 0.104, 8.676 44925, 44954, 44940, 0.104, 8.290 44955, 44984, 44970, 0.082, 7.904 44985, 45014, 45000, 0.082, 8.925 45015, 45044, 45030, 0.082, 10.337 45045, 45074, 45060, 0.027, 9.135 45075, 45104, 45090, 0.027, 7.942 45105, 45134, 45120, 0.079, 9.354 45135, 45164, 45150, 0.079, 10.350 45165, 45194, 45180, 0.087, 8.890 45195, 45224, 45210, 0.164, 7.420 45225, 45254, 45240, 0.164, 7.748 45255, 45284, 45270, 0.104, 7.791 45285, 45314, 45300, 0.104, 7.961 45315, 45344, 45330, 0.104, 8.133 45345, 45374, 45360, 0.103, 7.270 45375, 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47265, 47294, 47280, 0.075, 3.125 47295, 47324, 47310, 0.075, 3.168 47325, 47354, 47340, 0.118, 3.220 47355, 47384, 47370, 0.118, 3.271 47385, 47414, 47400, 0.092, 2.757 47415, 47444, 47430, 0.131, 3.637 47445, 47474, 47460, 0.131, 3.353 47475, 47504, 47490, 0.131, 3.069 47505, 47534, 47520, 0.122, 3.392 47535, 47564, 47550, 0.119, 3.897 47565, 47594, 47580, 0.119, 3.528 47595, 47624, 47610, 0.119, 3.159 47625, 47654, 47640, 0.134, 3.378 47655, 47684, 47670, 0.134, 3.553 47686, 47715, 47701, 0.111, 3.193 47716, 47745, 47731, 0.111, 2.835 47746, 47775, 47761, 0.090, 3.240 47776, 47805, 47791, 0.090, 3.752 47806, 47835, 47821, 0.114, 3.348 47836, 47865, 47851, 0.065, 2.944 47866, 47895, 47881, 0.065, 3.039 47896, 47925, 47911, 0.127, 3.283 47926, 47955, 47941, 0.127, 3.149 47956, 47985, 47971, 0.127, 3.014 47986, 48015, 48001, 0.121, 3.804 48016, 48045, 48031, 0.114, 3.683 48046, 48075, 48061, 0.114, 3.416 48076, 48105, 48091, 0.114, 3.149 48106, 48135, 48121, 0.095, 3.047 48136, 48165, 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