47, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2018, 05, 06, 2019, 05, 24 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 29 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom IV: Science Flight #6 -- CHC - PUQ ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 35% (actually a multiplicative factor of 1/1.35 to 1.35), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R3 R3: Final Data (see OTHER_COMMENTS) R2: Final Data (see OTHER_COMMENTS) R1: Final Data (see OTHER_COMMENTS) R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 73255, 73284, 73270, -9999.000, -9999.000 73285, 73314, 73300, -9999.000, -9999.000 73315, 73344, 73330, -9999.000, -9999.000 73345, 73374, 73360, -9999.000, -9999.000 73375, 73404, 73390, 0.001, 1.471 73405, 73434, 73420, 0.001, 2.211 73435, 73464, 73450, 0.003, 2.396 73465, 73494, 73480, 0.017, 2.119 73495, 73524, 73510, 0.017, 1.843 73526, 73555, 73541, 0.016, 1.981 73556, 73585, 73571, 0.016, 1.869 73586, 73615, 73601, 0.021, 2.265 73616, 73645, 73631, 0.021, 2.661 73646, 73675, 73661, 0.021, 2.478 73676, 73705, 73691, 0.017, 2.295 73706, 73735, 73721, 0.012, 2.112 73736, 73765, 73751, 0.012, 1.930 73766, 73795, 73781, 0.012, 1.982 73796, 73825, 73811, 0.042, 2.087 73826, 73855, 73841, 0.042, 1.968 73856, 73885, 73871, 0.032, 1.849 73886, 73915, 73901, 0.010, 2.307 73916, 73945, 73931, 0.010, 2.243 73946, 73975, 73961, 0.001, 2.219 73976, 74005, 73991, 0.001, 2.195 74006, 74035, 74021, 0.001, 2.217 74036, 74065, 74051, 0.011, 2.180 74066, 74095, 74081, 0.011, 1.674 74096, 74125, 74111, 0.014, 1.169 74126, 74155, 74141, 0.014, 1.489 74156, 74185, 74171, 0.024, 1.790 74186, 74215, 74201, 0.004, 1.570 74216, 74245, 74231, 0.004, 1.352 74246, 74275, 74261, 0.004, 1.661 74276, 74305, 74291, 0.019, 1.559 74307, 74336, 74322, 0.019, 1.505 74337, 74366, 74352, 0.006, 1.451 74367, 74396, 74382, 0.006, 1.530 74397, 74426, 74412, 0.003, 1.204 74427, 74456, 74442, 0.003, 1.429 74457, 74486, 74472, 0.012, 1.654 74487, 74516, 74502, 0.022, 1.167 74517, 74546, 74532, 0.022, 2.169 74547, 74576, 74562, 0.038, 2.138 74577, 74606, 74592, 0.038, 2.106 74607, 74636, 74622, 0.038, 1.896 74637, 74666, 74652, 0.020, 1.840 74667, 74696, 74682, 0.020, 1.731 74697, 74726, 74712, 0.041, 1.621 74727, 74756, 74742, 0.041, 1.964 74757, 74786, 74772, 0.027, 1.995 74787, 74816, 74802, 0.027, 1.634 74817, 74846, 74832, 0.012, 1.271 74847, 74876, 74862, 0.021, 2.240 74877, 74906, 74892, 0.021, 1.941 74907, 74936, 74922, 0.029, 1.762 74937, 74966, 74952, 0.029, 1.582 74967, 74996, 74982, 0.026, 1.874 74997, 75026, 75012, 0.026, 1.453 75027, 75056, 75042, 0.026, 1.602 75057, 75086, 75072, 0.029, 1.751 75186, 75215, 75201, 0.036, 2.662 75216, 75245, 75231, 0.036, 2.599 75246, 75275, 75261, 0.036, 2.689 75276, 75305, 75291, 0.060, 2.778 75306, 75335, 75321, 0.094, 3.124 75336, 75365, 75351, 0.094, 2.666 75366, 75395, 75381, -9999.000, 2.489 75396, 75425, 75411, -9999.000, 2.311 75426, 75455, 75441, -9999.000, 3.197 75456, 75485, 75471, -9999.000, 2.248 75486, 75515, 75501, -9999.000, 2.507 75516, 75545, 75531, -9999.000, 2.766 75546, 75575, 75561, -9999.000, 2.991 75577, 75606, 75592, -9999.000, 2.816 75607, 75636, 75622, 0.017, 2.683 75637, 75666, 75652, 0.017, 2.550 75667, 75696, 75682, 0.017, 2.790 75697, 75726, 75712, 0.033, 2.890 75727, 75756, 75742, 0.033, 2.690 75757, 75786, 75772, 0.052, 2.489 75787, 75816, 75802, 0.052, 2.251 75817, 75846, 75832, 0.051, 3.097 75847, 75876, 75862, 0.051, 2.397 75877, 75906, 75892, 0.060, 1.697 75907, 75936, 75922, 0.060, 2.286 75937, 75966, 75952, 0.080, 1.672 75967, 75996, 75982, 0.080, 1.847 75997, 76026, 76012, 0.074, 2.023 76027, 76056, 76042, 0.074, 2.045 76057, 76086, 76072, 0.092, 1.942 76087, 76116, 76102, 0.092, 1.957 76117, 76146, 76132, 0.064, 1.972 76147, 76176, 76162, 0.069, 2.070 76177, 76206, 76192, 0.069, 2.206 76207, 76236, 76222, 0.052, 1.910 76237, 76266, 76252, 0.052, 1.615 76267, 76296, 76282, 0.052, 1.544 76297, 76326, 76312, 0.059, 1.694 76328, 76357, 76343, 0.071, 1.536 76358, 76387, 76373, 0.071, 1.379 76388, 76417, 76403, 0.071, 1.863 76418, 76447, 76433, 0.046, 1.721 76448, 76477, 76463, 0.051, 1.739 76478, 76507, 76493, 0.051, 1.756 76508, 76537, 76523, 0.073, 2.105 76538, 76567, 76553, 0.073, 2.072 76568, 76597, 76583, 0.073, 1.809 76598, 76627, 76613, 0.076, 1.545 76628, 76657, 76643, 0.090, 2.011 76658, 76687, 76673, 0.090, 1.889 76688, 76717, 76703, 0.090, 1.814 76718, 76747, 76733, 0.097, 1.738 76748, 76777, 76763, 0.097, 1.928 76778, 76807, 76793, 0.092, 2.095 76808, 76837, 76823, 0.092, 1.772 76838, 76867, 76853, 0.066, 1.449 76868, 76897, 76883, 0.094, 1.823 76898, 76927, 76913, 0.094, 1.404 76928, 76957, 76943, 0.094, 1.470 76958, 76987, 76973, 0.076, 1.536 76988, 77017, 77003, 0.076, 1.977 77018, 77047, 77033, 0.044, 2.207 77048, 77077, 77063, 0.044, 2.025 77079, 77108, 77094, 0.076, 1.842 77109, 77138, 77124, 0.076, 2.040 77139, 77168, 77154, 0.049, 1.883 77169, 77198, 77184, 0.049, 1.492 77199, 77228, 77214, 0.057, 1.101 77229, 77258, 77244, 0.058, 1.717 77259, 77288, 77274, 0.058, 2.071 77289, 77318, 77304, 0.054, 2.089 77319, 77348, 77334, 0.054, 2.107 77349, 77378, 77364, 0.054, 2.571 77379, 77408, 77394, 0.031, 2.216 77409, 77438, 77424, 0.045, 2.009 77439, 77468, 77454, 0.045, 1.803 77469, 77498, 77484, 0.045, 1.877 77499, 77528, 77514, 0.018, 2.164 77529, 77558, 77544, 0.053, 1.968 77559, 77588, 77574, 0.053, 1.772 77589, 77618, 77604, 0.053, 2.295 77619, 77648, 77634, 0.039, 2.083 77649, 77678, 77664, 0.039, 1.765 77679, 77708, 77694, -0.001, 1.445 77709, 77738, 77724, 0.003, 2.194 77739, 77768, 77754, 0.003, 1.807 77769, 77798, 77784, 0.003, 1.703 77799, 77828, 77814, 0.016, 1.600 77830, 77859, 77845, -0.002, 2.210 77860, 77889, 77875, -0.002, 2.278 77890, 77919, 77905, -0.002, 1.988 77920, 77949, 77935, -9999.000, 1.698 77950, 77979, 77965, -9999.000, 1.073 77980, 78009, 77995, -9999.000, 2.749 78010, 78039, 78025, -9999.000, 1.855 78040, 78069, 78055, -9999.000, 0.964 78070, 78099, 78085, -9999.000, 2.590 78100, 78129, 78115, -9999.000, 1.642 78130, 78159, 78145, -9999.000, 1.067 78160, 78189, 78175, -9999.000, 0.493 78190, 78219, 78205, -9999.000, 1.376 78220, 78249, 78235, -9999.000, 1.185 78250, 78279, 78265, -9999.000, 1.383 78280, 78309, 78295, -9999.000, 1.581 78310, 78339, 78325, -9999.000, 0.874 78340, 78369, 78355, -9999.000, 1.369 78370, 78399, 78385, -9999.000, 1.071 78400, 78429, 78415, -9999.000, 0.772 78430, 78459, 78445, -9999.000, 2.006 78460, 78489, 78475, -9999.000, -9999.000 78490, 78519, 78505, -9999.000, 0.427 78520, 78549, 78535, -9999.000, 1.738 78550, 78579, 78565, -9999.000, 1.486 78581, 78610, 78596, -9999.000, 0.770 78611, 78640, 78626, -9999.000, 0.744 78641, 78670, 78656, -9999.000, 0.718 78671, 78700, 78686, -9999.000, 2.743 78701, 78730, 78716, -9999.000, 2.120 78731, 78760, 78746, -9999.000, 1.819 78761, 78790, 78776, -9999.000, 1.519 78791, 78820, 78806, -9999.000, -9999.000 78821, 78850, 78836, -9999.000, 1.238 78851, 78880, 78866, -9999.000, -0.333 78881, 78910, 78896, -9999.000, -9999.000 78911, 78940, 78926, 0.089, -0.238 78941, 78970, 78956, 0.089, 0.803 78971, 79000, 78986, 0.089, 1.337 79001, 79030, 79016, 0.043, 1.871 79031, 79060, 79046, 0.043, 2.017 79061, 79090, 79076, 0.051, 1.491 79091, 79120, 79106, 0.050, 1.438 79121, 79150, 79136, 0.050, 1.386 79151, 79180, 79166, 0.050, 1.722 79181, 79210, 79196, 0.091, 0.542 79211, 79240, 79226, 0.085, 0.568 79241, 79270, 79256, 0.085, 0.594 79271, 79300, 79286, 0.085, 0.854 79301, 79330, 79316, 0.102, 0.486 79331, 79360, 79346, 0.102, 0.622 79362, 79391, 79377, 0.102, 0.758 79392, 79421, 79407, 0.149, 0.937 79422, 79451, 79437, 0.149, 1.026 79452, 79481, 79467, 0.108, 1.093 79482, 79511, 79497, 0.108, 1.160 79512, 79541, 79527, 0.082, 1.692 79542, 79571, 79557, 0.082, 1.726 79572, 79601, 79587, 0.082, 1.486 79602, 79631, 79617, 0.089, 1.246 79632, 79661, 79647, 0.089, 1.687 79662, 79691, 79677, 0.083, 1.551 79692, 79721, 79707, 0.079, 1.549 79722, 79751, 79737, 0.079, 1.547 79752, 79781, 79767, 0.064, 2.082 79782, 79811, 79797, 0.064, 1.999 79812, 79841, 79827, 0.064, 1.523 79842, 79871, 79857, 0.104, 1.044 79872, 79901, 79887, 0.104, 1.866 79902, 79931, 79917, 0.071, 1.661 79932, 79961, 79947, 0.071, 1.924 79962, 79991, 79977, 0.038, 2.188 79992, 80021, 80007, 0.079, 2.238 80022, 80051, 80037, 0.079, 1.639 80052, 80081, 80067, 0.085, 1.478 80082, 80111, 80097, 0.085, 1.316 80113, 80142, 80128, 0.081, 1.569 80143, 80172, 80158, 0.081, 1.805 80173, 80202, 80188, -9999.000, -9999.000 80203, 80232, 80218, -9999.000, -9999.000 80233, 80262, 80248, -9999.000, -9999.000 80263, 80292, 80278, -9999.000, -9999.000 80293, 80322, 80308, -9999.000, -9999.000 80323, 80352, 80338, -9999.000, -9999.000 80353, 80382, 80368, -9999.000, -9999.000 80383, 80412, 80398, -9999.000, -9999.000 80413, 80442, 80428, -9999.000, -9999.000 80563, 80592, 80578, -9999.000, -9999.000 80594, 80623, 80609, -9999.000, -9999.000 80623, 80652, 80638, 0.089, 2.491 80654, 80683, 80669, 0.078, 2.124 80684, 80713, 80699, 0.078, 1.760 80714, 80743, 80729, 0.078, 2.079 80744, 80773, 80759, 0.093, 2.234 80774, 80803, 80789, 0.093, 2.048 80804, 80833, 80819, 0.095, 1.861 80834, 80863, 80849, 0.095, 2.440 80864, 80893, 80879, 0.093, 1.910 80894, 80923, 80909, 0.100, 1.787 80924, 80953, 80939, 0.100, 1.663 80954, 80983, 80969, 0.123, 2.033 80984, 81013, 80999, 0.123, 2.308 81014, 81043, 81029, 0.123, 1.879 81044, 81073, 81059, 0.123, 1.450 81074, 81103, 81089, 0.123, 2.090 81104, 81133, 81119, 0.157, 2.162 81134, 81163, 81149, 0.157, 2.143 81164, 81193, 81179, 0.128, 2.123 81194, 81223, 81209, 0.128, 2.790 81224, 81253, 81239, 0.091, 2.198 81254, 81283, 81269, 0.076, 2.110 81284, 81313, 81299, 0.076, 2.023 81314, 81343, 81329, 0.102, 1.855 81344, 81373, 81359, 0.102, 2.190 81374, 81403, 81389, 0.102, 1.777 81405, 81434, 81420, 0.066, 1.361 81435, 81464, 81450, 0.101, 2.056 81465, 81494, 81480, 0.101, 2.072 81495, 81524, 81510, 0.101, 1.705 81525, 81554, 81540, 0.121, 1.338 81555, 81584, 81570, 0.098, 1.511 81585, 81614, 81600, 0.098, 1.937 81615, 81644, 81630, 0.098, 1.743 81645, 81674, 81660, 0.096, 1.549 81675, 81704, 81690, 0.096, 2.102 81705, 81734, 81720, 0.092, 2.218 81735, 81764, 81750, 0.089, 1.984 81765, 81794, 81780, 0.089, 1.750 81795, 81824, 81810, 0.089, 2.138 81825, 81854, 81840, 0.086, 1.858 81855, 81884, 81870, 0.098, 1.867 81885, 81914, 81900, 0.098, 1.876 81915, 81944, 81930, 0.098, 1.728 81945, 81974, 81960, 0.070, 2.026 81975, 82004, 81990, 0.070, 2.081 82005, 82034, 82020, 0.084, 2.136 82035, 82064, 82050, 0.078, 2.067 82065, 82094, 82080, 0.078, 2.522 82095, 82124, 82110, 0.077, 2.353 82125, 82154, 82140, 0.077, 2.183 82156, 82185, 82171, 0.072, 2.831 82186, 82215, 82201, 0.072, 3.165 82216, 82245, 82231, 0.062, 2.926 82246, 82275, 82261, 0.062, 2.687 82276, 82305, 82291, 0.062, 3.403 82306, 82335, 82321, 0.051, 3.573 82336, 82365, 82351, 0.069, 2.864 82366, 82395, 82381, 0.069, 2.156 82396, 82425, 82411, 0.069, 2.323 82426, 82455, 82441, -9999.000, -9999.000 82456, 82485, 82471, 0.098, -9999.000 82486, 82515, 82501, 0.098, 3.397 82516, 82545, 82531, 0.153, 2.939 82546, 82575, 82561, 0.153, 3.414 82576, 82605, 82591, 0.153, 2.917 82606, 82635, 82621, 0.065, 2.417 82636, 82665, 82651, 0.065, 3.373 82666, 82695, 82681, 0.048, 3.543 82696, 82725, 82711, 0.048, 2.921 82726, 82755, 82741, 0.000, 2.298 82756, 82785, 82771, -0.026, 2.949 82786, 82815, 82801, -0.026, 3.690 82816, 82845, 82831, 0.004, 3.211 82846, 82875, 82861, 0.004, 2.731 82876, 82905, 82891, 0.004, 2.740 82907, 82936, 82922, 0.050, 3.647 82937, 82966, 82952, 0.050, 3.658 82967, 82996, 82982, 0.024, 3.668 82997, 83026, 83012, 0.024, 3.520 83027, 83056, 83042, -0.016, 3.614 83057, 83086, 83072, -9999.000, 3.234 83087, 83116, 83102, -9999.000, 2.858 83117, 83146, 83132, -9999.000, 1.830 83147, 83176, 83162, -0.008, 1.445 83177, 83206, 83192, 0.011, 1.600 83207, 83236, 83222, 0.011, 1.754 83237, 83266, 83252, 0.011, 0.958 83375, 83404, 83390, 0.003, 2.372 83405, 83434, 83420, -0.022, 1.986 83435, 83464, 83450, -0.022, 1.601 83465, 83494, 83480, 0.015, 1.783 83495, 83524, 83510, 0.015, 1.710 83525, 83554, 83540, 0.015, 0.877 83555, 83584, 83570, 0.239, 0.044 83585, 83614, 83600, 0.239, 4.267 83615, 83644, 83630, 0.011, 2.930 83645, 83674, 83660, 0.002, 3.247 83675, 83704, 83690, 0.002, 3.562 83705, 83734, 83720, 0.011, 3.871 83735, 83764, 83750, 0.011, 3.367 83765, 83794, 83780, 0.011, 3.098 83795, 83824, 83810, 0.053, 2.830 83825, 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