46, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2018, 05, 06, 2018, 11, 28 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 28 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom IV: Science Flight #6 -- CHC - PUQ ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 32% (actually a multiplicative factor of 1/1.32 to 1.32), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R2 R2: Final Data (see OTHER_COMMENTS) R1: Final Data (see OTHER_COMMENTS) R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 73255, 73284, 73270, -9999.000, -9999.000 73285, 73314, 73300, -9999.000, -9999.000 73315, 73344, 73330, -9999.000, -9999.000 73345, 73374, 73360, -9999.000, -9999.000 73375, 73404, 73390, 0.001, 1.677 73405, 73434, 73420, 0.001, 2.498 73435, 73464, 73450, 0.003, 2.717 73465, 73494, 73480, 0.017, 2.393 73495, 73524, 73510, 0.017, 2.069 73526, 73555, 73541, 0.016, 2.178 73556, 73585, 73571, 0.016, 2.028 73586, 73615, 73601, 0.021, 2.413 73616, 73645, 73631, 0.021, 2.798 73646, 73675, 73661, 0.021, 2.598 73676, 73705, 73691, 0.017, 2.398 73706, 73735, 73721, 0.012, 2.197 73736, 73765, 73751, 0.012, 1.997 73766, 73795, 73781, 0.012, 2.038 73796, 73825, 73811, 0.042, 2.113 73826, 73855, 73841, 0.042, 1.978 73856, 73885, 73871, 0.032, 1.843 73886, 73915, 73901, 0.010, 2.266 73916, 73945, 73931, 0.010, 2.194 73946, 73975, 73961, 0.001, 2.152 73976, 74005, 73991, 0.001, 2.109 74006, 74035, 74021, 0.001, 2.116 74036, 74065, 74051, 0.011, 2.073 74066, 74095, 74081, 0.011, 1.581 74096, 74125, 74111, 0.014, 1.089 74126, 74155, 74141, 0.014, 1.383 74156, 74185, 74171, 0.024, 1.659 74186, 74215, 74201, 0.004, 1.449 74216, 74245, 74231, 0.004, 1.240 74246, 74275, 74261, 0.004, 1.519 74276, 74305, 74291, 0.019, 1.409 74307, 74336, 74322, 0.019, 1.357 74337, 74366, 74352, 0.006, 1.306 74367, 74396, 74382, 0.006, 1.376 74397, 74426, 74412, 0.003, 1.080 74427, 74456, 74442, 0.003, 1.278 74457, 74486, 74472, 0.012, 1.477 74487, 74516, 74502, 0.022, 1.035 74517, 74546, 74532, 0.022, 1.934 74547, 74576, 74562, 0.038, 1.902 74577, 74606, 74592, 0.038, 1.871 74607, 74636, 74622, 0.038, 1.682 74637, 74666, 74652, 0.020, 1.630 74667, 74696, 74682, 0.020, 1.529 74697, 74726, 74712, 0.041, 1.428 74727, 74756, 74742, 0.041, 1.732 74757, 74786, 74772, 0.027, 1.761 74787, 74816, 74802, 0.027, 1.439 74817, 74846, 74832, 0.012, 1.115 74847, 74876, 74862, 0.021, 1.978 74877, 74906, 74892, 0.021, 1.712 74907, 74936, 74922, 0.029, 1.552 74937, 74966, 74952, 0.029, 1.392 74967, 74996, 74982, 0.026, 1.649 74997, 75026, 75012, 0.026, 1.275 75027, 75056, 75042, 0.026, 1.407 75057, 75086, 75072, 0.029, 1.540 75186, 75215, 75201, 0.036, 2.348 75216, 75245, 75231, 0.036, 2.294 75246, 75275, 75261, 0.036, 2.374 75276, 75305, 75291, 0.060, 2.454 75306, 75335, 75321, 0.094, 2.760 75336, 75365, 75351, 0.094, 2.355 75366, 75395, 75381, -9999.000, 2.198 75396, 75425, 75411, -9999.000, 2.042 75426, 75455, 75441, -9999.000, 2.823 75456, 75485, 75471, -9999.000, 1.984 75486, 75515, 75501, -9999.000, 2.213 75516, 75545, 75531, -9999.000, 2.443 75546, 75575, 75561, -9999.000, 2.640 75577, 75606, 75592, -9999.000, 2.487 75607, 75636, 75622, 0.017, 2.368 75637, 75666, 75652, 0.017, 2.249 75667, 75696, 75682, 0.017, 2.461 75697, 75726, 75712, 0.033, 2.553 75727, 75756, 75742, 0.033, 2.374 75757, 75786, 75772, 0.052, 2.196 75787, 75816, 75802, 0.052, 1.982 75817, 75846, 75832, 0.051, 2.736 75847, 75876, 75862, 0.051, 2.113 75877, 75906, 75892, 0.060, 1.491 75907, 75936, 75922, 0.060, 2.011 75937, 75966, 75952, 0.080, 1.469 75967, 75996, 75982, 0.080, 1.625 75997, 76026, 76012, 0.074, 1.781 76027, 76056, 76042, 0.074, 1.798 76057, 76086, 76072, 0.092, 1.710 76087, 76116, 76102, 0.092, 1.723 76117, 76146, 76132, 0.064, 1.736 76147, 76176, 76162, 0.069, 1.820 76177, 76206, 76192, 0.069, 1.944 76207, 76236, 76222, 0.052, 1.681 76237, 76266, 76252, 0.052, 1.418 76267, 76296, 76282, 0.052, 1.352 76297, 76326, 76312, 0.059, 1.488 76328, 76357, 76343, 0.071, 1.349 76358, 76387, 76373, 0.071, 1.210 76388, 76417, 76403, 0.071, 1.635 76418, 76447, 76433, 0.046, 1.511 76448, 76477, 76463, 0.051, 1.527 76478, 76507, 76493, 0.051, 1.544 76508, 76537, 76523, 0.073, 1.852 76538, 76567, 76553, 0.073, 1.825 76568, 76597, 76583, 0.073, 1.592 76598, 76627, 76613, 0.076, 1.357 76628, 76657, 76643, 0.090, 1.768 76658, 76687, 76673, 0.090, 1.663 76688, 76717, 76703, 0.090, 1.595 76718, 76747, 76733, 0.097, 1.528 76748, 76777, 76763, 0.097, 1.692 76778, 76807, 76793, 0.092, 1.845 76808, 76837, 76823, 0.092, 1.558 76838, 76867, 76853, 0.066, 1.271 76868, 76897, 76883, 0.094, 1.600 76898, 76927, 76913, 0.094, 1.231 76928, 76957, 76943, 0.094, 1.290 76958, 76987, 76973, 0.076, 1.349 76988, 77017, 77003, 0.076, 1.737 77018, 77047, 77033, 0.044, 1.943 77048, 77077, 77063, 0.044, 1.783 77079, 77108, 77094, 0.076, 1.622 77109, 77138, 77124, 0.076, 1.793 77139, 77168, 77154, 0.049, 1.657 77169, 77198, 77184, 0.049, 1.310 77199, 77228, 77214, 0.057, 0.963 77229, 77258, 77244, 0.058, 1.507 77259, 77288, 77274, 0.058, 1.825 77289, 77318, 77304, 0.054, 1.842 77319, 77348, 77334, 0.054, 1.859 77349, 77378, 77364, 0.054, 2.274 77379, 77408, 77394, 0.031, 1.965 77409, 77438, 77424, 0.045, 1.786 77439, 77468, 77454, 0.045, 1.606 77469, 77498, 77484, 0.045, 1.674 77499, 77528, 77514, 0.018, 1.940 77529, 77558, 77544, 0.053, 1.771 77559, 77588, 77574, 0.053, 1.602 77589, 77618, 77604, 0.053, 2.085 77619, 77648, 77634, 0.039, 1.908 77649, 77678, 77664, 0.039, 1.626 77679, 77708, 77694, -0.001, 1.343 77709, 77738, 77724, 0.003, 2.060 77739, 77768, 77754, 0.003, 1.711 77769, 77798, 77784, 0.003, 1.628 77799, 77828, 77814, 0.016, 1.544 77830, 77859, 77845, -0.002, 2.154 77860, 77889, 77875, -0.002, 2.243 77890, 77919, 77905, -0.002, 1.980 77920, 77949, 77935, -9999.000, 1.718 77950, 77979, 77965, -9999.000, 1.107 77980, 78009, 77995, -9999.000, 2.708 78010, 78039, 78025, -9999.000, 1.870 78040, 78069, 78055, -9999.000, 1.035 78070, 78099, 78085, -9999.000, 2.822 78100, 78129, 78115, -9999.000, 1.801 78130, 78159, 78145, -9999.000, 1.181 78160, 78189, 78175, -9999.000, 0.564 78190, 78219, 78205, -9999.000, 1.594 78220, 78249, 78235, -9999.000, 1.374 78250, 78279, 78265, -9999.000, 1.642 78280, 78309, 78295, -9999.000, 1.910 78310, 78339, 78325, -9999.000, 1.064 78340, 78369, 78355, -9999.000, 1.647 78370, 78399, 78385, -9999.000, 1.272 78400, 78429, 78415, -9999.000, 0.896 78430, 78459, 78445, -9999.000, 2.380 78460, 78489, 78475, -9999.000, -9999.000 78490, 78519, 78505, -9999.000, 0.514 78520, 78549, 78535, -9999.000, 2.080 78550, 78579, 78565, -9999.000, 1.783 78581, 78610, 78596, -9999.000, 0.939 78611, 78640, 78626, -9999.000, 0.904 78641, 78670, 78656, -9999.000, 0.870 78671, 78700, 78686, -9999.000, 3.132 78701, 78730, 78716, -9999.000, 2.350 78731, 78760, 78746, -9999.000, 1.981 78761, 78790, 78776, -9999.000, 1.614 78791, 78820, 78806, -9999.000, -9999.000 78821, 78850, 78836, -9999.000, 1.252 78851, 78880, 78866, -9999.000, -0.316 78881, 78910, 78896, -9999.000, -9999.000 78911, 78940, 78926, 0.089, -0.235 78941, 78970, 78956, 0.089, 0.781 78971, 79000, 78986, 0.089, 1.283 79001, 79030, 79016, 0.043, 1.784 79031, 79060, 79046, 0.043, 1.905 79061, 79090, 79076, 0.051, 1.392 79091, 79120, 79106, 0.050, 1.331 79121, 79150, 79136, 0.050, 1.270 79151, 79180, 79166, 0.050, 1.565 79181, 79210, 79196, 0.091, 0.483 79211, 79240, 79226, 0.085, 0.504 79241, 79270, 79256, 0.085, 0.525 79271, 79300, 79286, 0.085, 0.755 79301, 79330, 79316, 0.102, 0.426 79331, 79360, 79346, 0.102, 0.547 79362, 79391, 79377, 0.102, 0.669 79392, 79421, 79407, 0.149, 0.821 79422, 79451, 79437, 0.149, 0.908 79452, 79481, 79467, 0.108, 0.965 79482, 79511, 79497, 0.108, 1.022 79512, 79541, 79527, 0.082, 1.489 79542, 79571, 79557, 0.082, 1.521 79572, 79601, 79587, 0.082, 1.307 79602, 79631, 79617, 0.089, 1.092 79632, 79661, 79647, 0.089, 1.482 79662, 79691, 79677, 0.083, 1.363 79692, 79721, 79707, 0.079, 1.361 79722, 79751, 79737, 0.079, 1.359 79752, 79781, 79767, 0.064, 1.831 79782, 79811, 79797, 0.064, 1.760 79812, 79841, 79827, 0.064, 1.338 79842, 79871, 79857, 0.104, 0.913 79872, 79901, 79887, 0.104, 1.639 79902, 79931, 79917, 0.071, 1.459 79932, 79961, 79947, 0.071, 1.694 79962, 79991, 79977, 0.038, 1.928 79992, 80021, 80007, 0.079, 1.972 80022, 80051, 80037, 0.079, 1.442 80052, 80081, 80067, 0.085, 1.298 80082, 80111, 80097, 0.085, 1.154 80113, 80142, 80128, 0.081, 1.376 80143, 80172, 80158, 0.081, 1.590 80173, 80202, 80188, -9999.000, -9999.000 80203, 80232, 80218, -9999.000, -9999.000 80233, 80262, 80248, -9999.000, -9999.000 80263, 80292, 80278, -9999.000, -9999.000 80293, 80322, 80308, -9999.000, -9999.000 80323, 80352, 80338, -9999.000, -9999.000 80353, 80382, 80368, -9999.000, -9999.000 80383, 80412, 80398, -9999.000, -9999.000 80413, 80442, 80428, -9999.000, -9999.000 80563, 80592, 80578, -9999.000, -9999.000 80594, 80623, 80609, -9999.000, -9999.000 80623, 80652, 80638, 0.089, 2.203 80654, 80683, 80669, 0.078, 1.876 80684, 80713, 80699, 0.078, 1.552 80714, 80743, 80729, 0.078, 1.832 80744, 80773, 80759, 0.093, 1.973 80774, 80803, 80789, 0.093, 1.808 80804, 80833, 80819, 0.095, 1.642 80834, 80863, 80849, 0.095, 2.154 80864, 80893, 80879, 0.093, 1.686 80894, 80923, 80909, 0.100, 1.576 80924, 80953, 80939, 0.100, 1.467 80954, 80983, 80969, 0.123, 1.791 80984, 81013, 80999, 0.123, 2.040 81014, 81043, 81029, 0.123, 1.658 81044, 81073, 81059, 0.123, 1.275 81074, 81103, 81089, 0.123, 1.841 81104, 81133, 81119, 0.157, 1.911 81134, 81163, 81149, 0.157, 1.894 81164, 81193, 81179, 0.128, 1.877 81194, 81223, 81209, 0.128, 2.465 81224, 81253, 81239, 0.091, 1.941 81254, 81283, 81269, 0.076, 1.862 81284, 81313, 81299, 0.076, 1.784 81314, 81343, 81329, 0.102, 1.632 81344, 81373, 81359, 0.102, 1.934 81374, 81403, 81389, 0.102, 1.567 81405, 81434, 81420, 0.066, 1.197 81435, 81464, 81450, 0.101, 1.812 81465, 81494, 81480, 0.101, 1.829 81495, 81524, 81510, 0.101, 1.503 81525, 81554, 81540, 0.121, 1.176 81555, 81584, 81570, 0.098, 1.326 81585, 81614, 81600, 0.098, 1.710 81615, 81644, 81630, 0.098, 1.538 81645, 81674, 81660, 0.096, 1.367 81675, 81704, 81690, 0.096, 1.854 81705, 81734, 81720, 0.092, 1.961 81735, 81764, 81750, 0.089, 1.753 81765, 81794, 81780, 0.089, 1.545 81795, 81824, 81810, 0.089, 1.886 81825, 81854, 81840, 0.086, 1.640 81855, 81884, 81870, 0.098, 1.649 81885, 81914, 81900, 0.098, 1.658 81915, 81944, 81930, 0.098, 1.520 81945, 81974, 81960, 0.070, 1.788 81975, 82004, 81990, 0.070, 1.837 82005, 82034, 82020, 0.084, 1.887 82035, 82064, 82050, 0.078, 1.821 82065, 82094, 82080, 0.078, 2.228 82095, 82124, 82110, 0.077, 2.077 82125, 82154, 82140, 0.077, 1.925 82156, 82185, 82171, 0.072, 2.495 82186, 82215, 82201, 0.072, 2.797 82216, 82245, 82231, 0.062, 2.586 82246, 82275, 82261, 0.062, 2.375 82276, 82305, 82291, 0.062, 3.011 82306, 82335, 82321, 0.051, 3.170 82336, 82365, 82351, 0.069, 2.543 82366, 82395, 82381, 0.069, 1.916 82396, 82425, 82411, 0.069, 2.063 82426, 82455, 82441, -9999.000, -9999.000 82456, 82485, 82471, 0.098, -9999.000 82486, 82515, 82501, 0.098, 3.067 82516, 82545, 82531, 0.153, 2.658 82546, 82575, 82561, 0.153, 3.113 82576, 82605, 82591, 0.153, 2.671 82606, 82635, 82621, 0.065, 2.227 82636, 82665, 82651, 0.065, 3.130 82666, 82695, 82681, 0.048, 3.316 82696, 82725, 82711, 0.048, 2.751 82726, 82755, 82741, 0.000, 2.185 82756, 82785, 82771, -0.026, 2.832 82786, 82815, 82801, -0.026, 3.583 82816, 82845, 82831, 0.004, 3.150 82846, 82875, 82861, 0.004, 2.716 82876, 82905, 82891, 0.004, 2.760 82907, 82936, 82922, 0.050, 3.719 82937, 82966, 82952, 0.050, 3.782 82967, 82996, 82982, 0.024, 3.845 82997, 83026, 83012, 0.024, 3.749 83027, 83056, 83042, -0.016, 3.921 83057, 83086, 83072, -9999.000, 3.559 83087, 83116, 83102, -9999.000, 3.200 83117, 83146, 83132, -9999.000, 2.078 83147, 83176, 83162, -0.008, 1.679 83177, 83206, 83192, 0.011, 1.889 83207, 83236, 83222, 0.011, 2.098 83237, 83266, 83252, 0.011, 1.153 83375, 83404, 83390, 0.003, 2.809 83405, 83434, 83420, -0.022, 2.358 83435, 83464, 83450, -0.022, 1.908 83465, 83494, 83480, 0.015, 2.118 83495, 83524, 83510, 0.015, 2.041 83525, 83554, 83540, 0.015, 1.041 83555, 83584, 83570, 0.239, 0.040 83585, 83614, 83600, 0.239, 4.942 83615, 83644, 83630, 0.011, 3.294 83645, 83674, 83660, 0.002, 3.556 83675, 83704, 83690, 0.002, 3.816 83705, 83734, 83720, 0.011, 4.067 83735, 83764, 83750, 0.011, 3.459 83765, 83794, 83780, 0.011, 3.150 83795, 83824, 83810, 0.053, 2.842 83825, 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