45, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2018, 05, 03, 2018, 10, 25 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 27 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom IV: Science Flight #5 -- NAN - CHC ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 32% (actually a multiplicative factor of 1/1.32 to 1.32), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R1 R1: Final Data (see OTHER_COMMENTS) R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 75476, 75505, 75491, -9999.000, -9999.000 75506, 75535, 75521, -9999.000, -9999.000 75536, 75565, 75551, -9999.000, -9999.000 75566, 75595, 75581, -9999.000, -9999.000 75596, 75625, 75611, 0.155, 20.823 75626, 75655, 75641, 0.155, 19.552 75656, 75685, 75671, 0.192, 18.277 75686, 75715, 75701, 0.082, 20.170 75716, 75745, 75731, 0.082, 17.782 75746, 75775, 75761, 0.102, 15.499 75776, 75805, 75791, 0.102, 13.216 75806, 75835, 75821, 0.102, 8.038 75836, 75865, 75851, 0.036, 7.382 75866, 75895, 75881, 0.068, 6.716 75896, 75925, 75911, 0.068, 6.053 75926, 75955, 75941, 0.095, 5.387 75956, 75985, 75971, 0.095, 4.722 75986, 76015, 76001, 0.095, 4.058 76016, 76045, 76031, 0.057, 3.395 76046, 76075, 76061, 0.057, 4.389 76077, 76106, 76092, 0.098, 4.158 76107, 76136, 76122, 0.069, 3.573 76137, 76166, 76152, 0.069, 2.988 76167, 76196, 76182, 0.006, 2.571 76197, 76226, 76212, 0.006, 2.706 76227, 76256, 76242, 0.045, 2.890 76257, 76286, 76272, 0.045, 3.074 76287, 76316, 76302, 0.045, 2.807 76317, 76346, 76332, 0.012, 2.914 76347, 76376, 76362, 0.034, 2.523 76377, 76406, 76392, 0.034, 2.134 76407, 76436, 76422, 0.034, 3.227 76437, 76466, 76452, 0.058, 2.769 76467, 76496, 76482, 0.046, 3.038 76497, 76526, 76512, 0.046, 3.307 76527, 76556, 76542, 0.051, 3.066 76557, 76586, 76572, 0.051, 2.523 76587, 76616, 76602, 0.086, 2.959 76617, 76646, 76632, 0.086, 3.393 76647, 76676, 76662, 0.090, 3.744 76677, 76706, 76692, 0.090, 4.042 76707, 76736, 76722, 0.116, 3.998 76738, 76767, 76753, 0.116, 3.954 76873, 76902, 76888, -9999.000, 7.752 76903, 76932, 76918, 0.145, 7.543 76933, 76962, 76948, 0.142, 6.696 76963, 76992, 76978, 0.142, 5.852 76993, 77022, 77008, 0.142, 7.082 77023, 77052, 77038, 0.191, 6.236 77053, 77082, 77068, 0.191, 6.326 77084, 77113, 77099, 0.146, 6.416 77114, 77143, 77129, 0.125, 7.881 77144, 77173, 77159, 0.125, 6.954 77174, 77203, 77189, 0.144, 6.703 77204, 77233, 77219, 0.144, 6.451 77234, 77263, 77249, 0.144, 6.134 77264, 77293, 77279, 0.111, 6.252 77294, 77323, 77309, 0.111, 5.875 77324, 77353, 77339, 0.128, 5.499 77354, 77383, 77369, 0.128, 7.100 77384, 77413, 77399, 0.154, 5.468 77414, 77443, 77429, 0.154, 5.360 77444, 77473, 77459, 0.078, 5.252 77474, 77503, 77489, 0.067, 5.053 77504, 77533, 77519, 0.067, 5.997 77534, 77563, 77549, 0.067, 5.119 77564, 77593, 77579, 0.084, 4.239 77594, 77623, 77609, 0.130, 6.973 77624, 77653, 77639, 0.130, 6.368 77654, 77683, 77669, 0.099, 5.195 77684, 77713, 77699, 0.099, 4.022 77714, 77743, 77729, 0.103, 4.736 77745, 77774, 77760, 0.103, 5.087 77775, 77804, 77790, 0.121, 4.878 77805, 77834, 77820, 0.121, 4.668 77835, 77864, 77850, 0.123, 4.968 77865, 77894, 77880, 0.123, 4.737 77895, 77924, 77910, 0.123, 4.485 77925, 77954, 77940, 0.093, 4.232 77955, 77984, 77970, 0.093, 5.782 77985, 78014, 78000, 0.093, 4.524 78015, 78044, 78030, 0.094, 6.983 78045, 78074, 78060, 0.094, 9.435 78075, 78104, 78090, 0.094, 9.793 78105, 78134, 78120, -9999.000, 21.267 78135, 78164, 78150, 0.394, 14.168 78165, 78194, 78180, 0.394, 7.139 78195, 78224, 78210, 0.179, 12.504 78225, 78254, 78240, 0.179, 13.206 78255, 78284, 78270, 0.176, 12.947 78285, 78314, 78300, 0.176, 12.689 78315, 78344, 78330, 0.176, 15.313 78345, 78374, 78360, 0.170, 11.988 78375, 78404, 78390, 0.170, 12.964 78406, 78435, 78421, 0.166, 13.947 78436, 78465, 78451, 0.166, 14.704 78466, 78495, 78481, 0.164, 15.991 78496, 78525, 78511, 0.164, 13.936 78526, 78555, 78541, 0.122, 11.873 78556, 78585, 78571, 0.101, 15.458 78586, 78615, 78601, 0.101, 12.664 78616, 78645, 78631, 0.101, 12.797 78646, 78675, 78661, 0.117, 12.930 78676, 78705, 78691, 0.172, 17.414 78706, 78735, 78721, 0.172, 14.580 78736, 78765, 78751, 0.152, 14.182 78766, 78795, 78781, 0.152, 13.784 78796, 78825, 78811, 0.152, 15.411 78826, 78855, 78841, 0.125, 12.401 78856, 78885, 78871, 0.125, 11.698 78886, 78915, 78901, 0.115, 10.995 78916, 78945, 78931, 0.115, 13.406 78946, 78975, 78961, 0.146, 11.633 78976, 79005, 78991, 0.102, 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8.082 81674, 81703, 81689, 0.082, 8.200 81704, 81733, 81719, 0.089, 11.921 81734, 81763, 81749, 0.089, 15.643 81765, 81794, 81780, 0.163, 16.597 81795, 81824, 81810, 0.163, 16.734 81825, 81854, 81840, 0.163, 15.135 81855, 81884, 81870, 0.141, 13.529 81885, 81914, 81900, 0.106, 13.434 81915, 81944, 81930, 0.106, 13.338 81945, 81974, 81960, 0.169, 15.014 81975, 82004, 81990, 0.169, 16.691 82005, 82034, 82020, 0.204, 18.412 82035, 82064, 82050, 0.204, 18.950 82065, 82094, 82080, 0.204, 18.901 82095, 82124, 82110, 0.137, 18.851 82125, 82154, 82140, 0.167, 22.191 82155, 82184, 82170, 0.167, 22.162 82185, 82214, 82200, 0.167, 19.992 82215, 82244, 82230, 0.141, 17.821 82245, 82274, 82260, 0.141, 19.981 82275, 82304, 82290, 0.212, 18.691 82305, 82334, 82320, 0.180, 16.806 82335, 82364, 82350, 0.180, 14.927 82365, 82394, 82380, 0.229, 21.687 82395, 82424, 82410, 0.229, 19.749 82425, 82454, 82440, 0.229, 18.114 82456, 82485, 82471, 0.205, 16.474 82486, 82515, 82501, 0.071, 18.720 82516, 82545, 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5.680 83417, 83446, 83432, 0.122, 5.417 83447, 83476, 83462, 0.122, 6.363 83477, 83506, 83492, 0.142, 6.309 83507, 83536, 83522, 0.142, 6.064 83537, 83566, 83552, 0.140, 5.819 83567, 83596, 83582, 0.140, 5.707 83597, 83626, 83612, 0.153, 5.354 83627, 83656, 83642, 0.179, 4.636 83657, 83686, 83672, 0.179, 3.921 83688, 83717, 83703, 0.176, 4.283 83717, 83746, 83732, 0.176, 4.675 83747, 83776, 83762, 0.176, 4.196 83778, 83807, 83793, 0.188, 3.716 83808, 83837, 83823, 0.152, 5.271 83838, 83867, 83853, 0.152, 4.783 83868, 83897, 83883, 0.152, 4.518 83898, 83927, 83913, 0.238, 4.251 84018, 84047, 84033, 0.190, 5.651 84048, 84077, 84063, 0.190, 5.522 84078, 84107, 84093, 0.207, 5.478 84108, 84137, 84123, 0.207, 5.433 84138, 84167, 84153, 0.207, 5.870 84168, 84197, 84183, 0.242, 5.089 84198, 84227, 84213, 0.242, 5.001 84228, 84257, 84243, 0.210, 4.913 84258, 84287, 84273, 0.210, 5.690 84288, 84317, 84303, 0.189, 5.463 84318, 84347, 84333, 0.119, 5.906 84348, 84377, 84363, 0.119, 6.350 84379, 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99537, 99566, 99552, 0.142, 1.800 99567, 99596, 99582, 0.134, 1.792 99597, 99626, 99612, 0.138, 2.169 99627, 99656, 99642, 0.138, 1.593 99657, 99686, 99672, 0.138, 1.602 99687, 99716, 99702, 0.182, 1.611 99717, 99746, 99732, 0.182, 2.416 99747, 99776, 99762, 0.180, 1.990 99777, 99806, 99792, 0.180, 1.920 99807, 99836, 99822, 0.145, 1.851 99837, 99866, 99852, 0.145, 1.537 99867, 99896, 99882, 0.144, 1.693 99897, 99926, 99912, 0.144, 1.514 99927, 99956, 99942, 0.135, 1.335 99957, 99986, 99972, 0.146, 2.044 99987, 100016, 100002, 0.146, 2.287 100017, 100046, 100032, 0.146, 2.756 100048, 100077, 100063, 0.137, 3.226 100078, 100107, 100093, 0.091, 4.655 100108, 100137, 100123, 0.091, 4.516 100138, 100167, 100153, 0.091, 3.860 100168, 100197, 100183, 0.082, 3.200 100198, 100227, 100213, 0.082, 3.963 100228, 100257, 100243, 0.109, 4.119 100258, 100287, 100273, 0.109, 3.659 100288, 100317, 100303, 0.074, 3.196 100318, 100347, 100333, 0.074, 4.214 100348, 100377, 100363, 0.048, 4.525 100378, 100407, 100393, 0.048, 3.697 100408, 100437, 100423, 0.027, 2.868 100438, 100467, 100453, 0.027, 3.842 100468, 100497, 100483, 0.043, 3.865 100498, 100527, 100513, 0.029, 3.698 100528, 100557, 100543, 0.029, 3.531 100558, 100587, 100573, 0.029, 4.362 100588, 100617, 100603, 0.050, 4.248 100618, 100647, 100633, 0.028, 4.133 100648, 100677, 100663, 0.028, 4.018 100678, 100707, 100693, 0.028, 5.205 100708, 100737, 100723, 0.027, 4.506 100739, 100768, 100754, 0.051, 4.256 100769, 100798, 100784, 0.051, 4.008 100799, 100828, 100814, 0.051, 5.766 100829, 100858, 100844, 0.065, 5.749 100859, 100888, 100874, 0.065, 5.399 100889, 100918, 100904, 0.034, 5.048 100919, 100948, 100934, 0.034, 6.646 100949, 100978, 100964, 0.013, 6.310 100979, 101008, 100994, 0.013, 6.126 101009, 101038, 101024, 0.019, 5.942 101039, 101068, 101054, 0.035, 5.244 101069, 101098, 101084, 0.035, 7.789 101099, 101128, 101114, 0.066, 6.457 101129, 101158, 101144, 0.066, 5.125 101159, 101188, 101174, 0.043, 6.066 101189, 101218, 101204, 0.043, 6.545 101219, 101248, 101234, 0.028, 6.433 101249, 101278, 101264, 0.028, 6.320 101279, 101308, 101294, 0.028, 5.873 101309, 101338, 101324, 0.062, 5.792 101339, 101368, 101354, 0.025, 5.554 101369, 101398, 101384, 0.025, 5.316 101399, 101428, 101414, 0.025, 6.319 101430, 101459, 101445, -0.032, 5.847 101460, 101489, 101475, -0.032, 5.540 101490, 101519, 101505, 0.018, 5.232 101520, 101549, 101535, 0.018, 4.925 101550, 101579, 101565, 0.043, 4.617 101580, 101609, 101595, 0.016, 4.309 101610, 101639, 101625, 0.016, 4.002 101640, 101669, 101655, 0.016, 4.353 101670, 101699, 101685, 0.045, 5.950 101700, 101729, 101715, 0.037, 5.393 101730, 101759, 101745, 0.037, 4.839 101760, 101789, 101775, 0.033, 7.615 101790, 101819, 101805, 0.033, 5.795 101820, 101849, 101835, 0.084, 4.555 101850, 101879, 101865, 0.084, 3.314 101880, 101909, 101895, 0.014, 5.183 101910, 101939, 101925, 0.014, 4.482 101940, 101969, 101955, 0.014, 3.713 101970, 101999, 101985, 0.002, 2.939 102000, 102029, 102015, 0.002, 3.235 102030, 102059, 102045, 0.008, 2.740 102060, 102089, 102075, 0.008, 3.586 102090, 102119, 102105, 0.002, 4.431 102121, 102150, 102136, 0.019, 4.457 102151, 102180, 102166, 0.019, 3.684 102181, 102210, 102196, 0.047, 3.279 102211, 102240, 102226, 0.047, 2.874 102241, 102270, 102256, 0.029, 4.811 102271, 102300, 102286, 0.029, 4.146 102301, 102330, 102316, 0.029, 3.336 102331, 102360, 102346, 0.045, 2.526 102361, 102390, 102376, 0.045, 3.261 102391, 102420, 102406, 0.029, 3.124 102421, 102450, 102436, 0.026, 3.309 102451, 102480, 102466, 0.026, 3.494 102481, 102510, 102496, 0.026, 3.431 102511, 102540, 102526, 0.032, 2.608 102541, 102570, 102556, 0.026, 2.444 102571, 102600, 102586, 0.026, 2.281 102601, 102630, 102616, 0.026, 3.716 102631, 102660, 102646, 0.123, 2.795 102661, 102690, 102676, 0.123, 2.645 102691, 102720, 102706, 0.128, 2.496 102721, 102750, 102736, 0.107, 2.187 102751, 102780, 102766, 0.107, 1.291 102781, 102810, 102796, 0.107, 1.798 102812, 102841, 102827, -9999.000, 2.308 102842, 102871, 102857, -9999.000, 2.304 102872, 102901, 102887, 0.022, 3.070 102902, 102931, 102917, 0.022, 2.665 102932, 102961, 102947, 0.017, 2.258 102962, 102991, 102977, 0.152, 2.560 102992, 103021, 103007, 0.152, 2.688 103022, 103051, 103037, 0.152, 2.284 103052, 103081, 103067, 0.071, 1.880 103082, 103111, 103097, -0.014, 2.902 103112, 103141, 103127, -0.014, 2.471 103142, 103171, 103157, -0.014, 2.994 103172, 103201, 103187, 0.004, 3.520 103202, 103231, 103217, -0.007, 4.108 103232, 103261, 103247, -0.007, 3.496 103262, 103291, 103277, -0.007, 3.357 103292, 103321, 103307, 0.007, 3.217 103322, 103351, 103337, -0.021, 3.655 103352, 103381, 103367, -0.021, 3.524 103382, 103411, 103397, 0.019, 3.192 103412, 103441, 103427, 0.019, 2.861 103443, 103472, 103458, 0.005, 1.931 103473, 103502, 103488, 0.005, 1.779 103503, 103532, 103518, 0.005, 2.130 103533, 103562, 103548, 0.028, 2.481 103563, 103592, 103578, -9999.000, 3.567 103593, 103622, 103608, -9999.000, 2.277 103623, 103652, 103638, -9999.000, -9999.000 103653, 103682, 103668, -9999.000, -9999.000