47, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2017, 02, 21, 2018, 11, 28 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 29 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom II: Science Flight #11 -- ANC - PMD ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 32% (actually a multiplicative factor of 1/1.32 to 1.32), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R3 R3: Final Data (see OTHER_COMMENTS) R2: Final Data (see OTHER_COMMENTS) R1: Final Data R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 64856, 64875, 64866, -9999.000, -9999.000 64876, 64895, 64886, -9999.000, -9999.000 64896, 64915, 64906, -9999.000, -9999.000 64916, 64935, 64926, -9999.000, -9999.000 64936, 64955, 64946, -9999.000, -9999.000 64956, 64975, 64966, -9999.000, -9999.000 64976, 64995, 64986, 0.020, 0.780 64996, 65015, 65006, 0.020, 0.293 65016, 65035, 65026, 0.027, 0.614 65036, 65055, 65046, 0.013, 0.936 65056, 65075, 65066, 0.013, 0.818 65076, 65095, 65086, -0.009, 1.254 65096, 65115, 65106, -0.009, 1.095 65116, 65135, 65126, -0.009, 0.936 65137, 65156, 65147, -0.030, 0.450 65157, 65176, 65167, -0.006, 0.203 65177, 65196, 65187, -0.006, 0.224 65197, 65216, 65207, -0.006, 0.244 65217, 65236, 65227, 0.013, 0.304 65237, 65256, 65247, 0.013, 0.365 65257, 65276, 65267, 0.020, 0.425 65277, 65296, 65287, 0.020, 0.485 65297, 65316, 65307, 0.038, 0.546 65317, 65336, 65327, 0.038, 0.607 65337, 65356, 65347, 0.004, 0.667 65357, 65376, 65367, 0.004, 0.728 65377, 65396, 65387, 0.005, 0.788 65397, 65416, 65407, 0.012, 1.087 65417, 65436, 65427, 0.012, 1.566 65437, 65456, 65447, 0.011, 2.044 65457, 65476, 65467, 0.011, 1.145 65477, 65496, 65487, 0.011, 1.033 65497, 65516, 65507, 0.023, 1.163 65517, 65536, 65527, 0.000, 1.291 65537, 65556, 65547, 0.000, 1.419 65557, 65576, 65567, 0.000, 1.610 65577, 65596, 65587, 0.028, 1.463 65597, 65616, 65607, 0.006, 1.315 65617, 65636, 65627, 0.006, 1.243 65637, 65656, 65647, 0.006, 1.266 65657, 65676, 65667, -0.008, 1.170 65677, 65696, 65687, 0.013, 1.075 65697, 65716, 65707, 0.013, 0.980 65717, 65736, 65727, -0.005, 1.250 65737, 65756, 65747, -0.005, 1.166 65757, 65776, 65767, 0.014, 1.082 65777, 65796, 65787, 0.014, 0.865 65797, 65816, 65807, 0.014, 0.706 65817, 65836, 65827, 0.016, 0.799 65837, 65856, 65847, 0.016, 0.891 65857, 65876, 65867, -0.002, 0.983 65877, 65896, 65887, -0.002, 0.338 65898, 65917, 65908, 0.024, 0.636 65918, 65937, 65928, 0.024, 0.931 65938, 65957, 65948, 0.004, 1.157 65958, 65977, 65968, -0.007, 1.179 65978, 65997, 65988, -0.007, 1.249 65998, 66017, 66008, -0.007, 1.321 66018, 66037, 66028, 0.008, 1.392 66038, 66057, 66048, 0.008, 2.218 66058, 66077, 66068, 0.007, 1.916 66078, 66097, 66088, 0.010, 1.615 66098, 66117, 66108, 0.010, 1.352 66118, 66137, 66128, 0.010, 1.925 66138, 66157, 66148, 0.039, 1.417 66158, 66177, 66168, 0.036, 0.905 66178, 66197, 66188, 0.036, 0.397 66198, 66217, 66208, 0.041, 0.485 66218, 66237, 66228, 0.041, 0.612 66238, 66257, 66248, 0.026, 0.739 66258, 66277, 66268, 0.026, 0.450 66278, 66297, 66288, 0.026, 0.681 66298, 66317, 66308, 0.039, 0.676 66318, 66337, 66328, 0.039, 0.671 66338, 66357, 66348, 0.034, 0.667 66358, 66377, 66368, 0.035, 0.745 66378, 66397, 66388, 0.035, 0.836 66398, 66417, 66408, 0.035, 0.928 66493, 66512, 66503, 0.045, 0.948 66513, 66532, 66523, 0.025, 1.163 66533, 66552, 66543, 0.025, 0.984 66553, 66572, 66563, 0.025, 0.804 66573, 66592, 66583, 0.028, 0.624 66593, 66612, 66603, 0.033, 1.258 66613, 66632, 66623, 0.033, 1.041 66633, 66652, 66643, 0.033, 0.823 66653, 66672, 66663, 0.012, 1.223 66673, 66692, 66683, 0.012, 1.355 66693, 66712, 66703, 0.018, 1.258 66713, 66732, 66723, 0.018, 1.161 66733, 66752, 66743, 0.029, 1.064 66753, 66772, 66763, 0.029, 1.013 66773, 66792, 66783, 0.016, 1.242 66793, 66812, 66803, 0.025, 1.470 66813, 66832, 66823, 0.025, 1.065 66833, 66852, 66843, 0.025, 1.135 66853, 66872, 66863, 0.052, 1.070 66873, 66892, 66883, 0.030, 1.005 66893, 66912, 66903, 0.030, 0.939 66914, 66933, 66924, 0.042, 1.321 66934, 66953, 66944, 0.042, 1.331 66954, 66973, 66964, 0.054, 1.340 66974, 66993, 66984, 0.054, 1.190 66994, 67013, 67004, 0.054, 1.229 67014, 67033, 67024, 0.039, 1.335 67034, 67053, 67044, 0.039, 1.441 67054, 67073, 67064, 0.017, 1.548 67074, 67093, 67084, 0.017, 3.267 67094, 67113, 67104, 0.037, 3.043 67114, 67133, 67124, 0.039, 2.819 67134, 67153, 67144, 0.039, 3.123 67154, 67173, 67164, 0.039, 3.980 67174, 67193, 67184, 0.008, 3.584 67194, 67213, 67204, 0.009, 3.188 67214, 67233, 67224, 0.009, 2.793 67234, 67253, 67244, 0.009, 3.118 67254, 67273, 67264, 0.011, 2.900 67274, 67293, 67284, 0.051, 2.683 67294, 67313, 67304, 0.051, 2.436 67314, 67333, 67324, 0.051, 3.170 67334, 67353, 67344, 0.011, 2.965 67354, 67373, 67364, 0.031, 2.761 67374, 67393, 67384, 0.031, 2.557 67394, 67413, 67404, 0.031, 2.768 67414, 67433, 67424, 0.011, 2.381 67434, 67453, 67444, 0.011, 1.994 67455, 67474, 67465, 0.005, 1.903 67475, 67494, 67485, 0.007, 2.175 67495, 67514, 67505, 0.007, 1.871 67515, 67534, 67525, 0.007, 1.567 67535, 67554, 67545, 0.021, 1.263 67555, 67574, 67565, -0.016, 1.597 67575, 67594, 67585, -0.016, 1.388 67595, 67614, 67605, -0.016, 1.178 67615, 67634, 67625, 0.017, 1.415 67635, 67654, 67645, 0.017, 1.887 67655, 67674, 67665, -0.015, 1.646 67675, 67694, 67685, -0.015, 1.405 67695, 67714, 67705, 0.003, 1.164 67715, 67734, 67725, 0.003, 1.456 67735, 67754, 67745, 0.018, 2.004 67755, 67774, 67765, -0.006, 2.552 67775, 67794, 67785, -0.006, 2.027 67795, 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68441, 0.059, -9999.000 68451, 68470, 68461, 0.059, 1.960 68471, 68490, 68481, -0.003, 1.498 68491, 68510, 68501, -0.003, 1.037 68511, 68530, 68521, 0.079, 1.042 68531, 68550, 68541, 0.063, 1.264 68551, 68570, 68561, 0.063, 1.223 68571, 68590, 68581, 0.063, 1.181 68591, 68610, 68601, -9999.000, 1.140 68611, 68630, 68621, -9999.000, 1.399 68631, 68650, 68641, -9999.000, 1.162 68651, 68670, 68661, -0.009, 0.922 68671, 68690, 68681, -0.009, 1.580 68691, 68710, 68701, 0.019, 0.838 68711, 68730, 68721, 0.019, 1.110 68731, 68750, 68741, 0.019, 1.382 68751, 68770, 68761, -0.013, 1.655 68771, 68790, 68781, 0.023, 2.611 68791, 68810, 68801, 0.023, 2.353 68811, 68830, 68821, 0.023, 2.097 68831, 68850, 68841, 0.025, 2.336 68851, 68870, 68861, 0.017, 1.804 68871, 68890, 68881, 0.017, 1.796 68891, 68910, 68901, 0.017, 1.787 68911, 68930, 68921, 0.025, 1.778 68932, 68951, 68942, 0.013, 1.610 68952, 68971, 68962, 0.013, 2.131 68972, 68991, 68982, 0.013, 2.651 68992, 69011, 69002, 0.006, 2.573 69012, 69031, 69022, -0.003, 2.453 69032, 69051, 69042, -0.003, 2.565 69052, 69071, 69062, 0.009, 2.677 69072, 69091, 69082, 0.009, 2.790 69092, 69111, 69102, 0.037, 3.404 69112, 69131, 69122, 0.037, 4.170 69132, 69151, 69142, 0.037, 4.937 69152, 69171, 69162, 0.006, 4.071 69172, 69191, 69182, 0.006, 3.583 69192, 69211, 69202, 0.018, 3.586 69212, 69231, 69222, 0.015, 3.590 69232, 69251, 69242, 0.015, 3.593 69252, 69271, 69262, 0.015, 3.855 69272, 69291, 69282, 0.026, 3.832 69292, 69311, 69302, 0.026, 3.808 69312, 69331, 69322, 0.022, 4.029 69332, 69351, 69342, 0.047, 3.764 69352, 69371, 69362, 0.047, 3.705 69372, 69391, 69382, 0.003, 3.647 69392, 69411, 69402, 0.003, 3.588 69412, 69431, 69422, 0.003, 3.681 69432, 69451, 69442, 0.037, 3.920 69452, 69471, 69462, 0.022, 4.160 69472, 69491, 69482, 0.022, 3.463 69492, 69511, 69502, 0.039, 4.455 69512, 69531, 69522, 0.039, 4.397 69532, 69551, 69542, 0.039, 4.339 69552, 69571, 69562, 0.058, 4.280 69572, 69591, 69582, 0.058, 3.871 69592, 69611, 69602, 0.039, 3.996 69612, 69631, 69622, 0.050, 4.121 69632, 69651, 69642, 0.050, 4.003 69652, 69671, 69662, 0.050, 3.687 69672, 69691, 69682, 0.132, 3.533 69692, 69711, 69702, 0.136, 3.379 69712, 69731, 69722, 0.136, 3.225 69732, 69751, 69742, 0.165, 3.240 69752, 69771, 69762, 0.165, 2.698 69772, 69791, 69782, 0.165, 2.155 69792, 69811, 69802, 0.136, 1.940 69812, 69831, 69822, 0.136, 2.158 69833, 69852, 69843, 0.121, 2.104 69853, 69872, 69863, 0.121, 2.050 69873, 69892, 69883, 0.117, 1.997 69893, 69912, 69903, 0.130, 1.795 69913, 69932, 69923, 0.130, 2.313 69933, 69952, 69943, 0.130, 2.831 69953, 69972, 69963, 0.135, 2.625 69973, 69992, 69983, 0.094, 2.066 69993, 70012, 70003, 0.094, 1.776 70013, 70032, 70023, 0.100, 1.487 70033, 70052, 70043, 0.100, 1.197 70135, 70154, 70145, 0.085, 1.809 70155, 70174, 70165, 0.085, 1.614 70175, 70194, 70185, 0.094, 1.421 70195, 70214, 70205, 0.094, 1.118 70215, 70234, 70225, 0.094, 1.037 70235, 70254, 70245, 0.090, 1.189 70255, 70274, 70265, 0.090, 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