41, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor based on LIF ATom 1, 1 2017, 02, 21, 2017, 12, 07 0 Start_UTC, seconds, seconds since takeoff's midnight UTC 5 1, 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since takeoff's midnight UTC Mid_UTC, seconds, seconds since takeoff's midnight UTC OH_pptv, pptv, OH mixing ratio in pptv HO2_pptv, pptv, HO2 mixing ratio in pptv OHR_Hz, Hz, OH reactivity in Hz 0 22 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom II: Science Flight #11 -- ANC - PMD ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 with Laser Induced Fluorescence; OH reactivity with discharge flow DATA_INFO: Units are pptv for OH and HO2; Hz for OHR. UNCERTAINTY: Normaly HOx absolute accuracy is estimated to be +/- 32% at two sigma confidence. Please see comments below. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Semi-Final Data. Calibrating ATHOS with the new OH scavenging inlet is proving to be difficult. Until we complete more tests, OH uncertainty above 6 km estimated to be a factor of 2, 2 sigma confidence HO2 uncertainty for all altitudes estimated to be a factor of 1.6, 2 sigma confidence. OHR uncertainty estimated to be 15%, 2 sigma confidence, with 0.3 s^-1 zero uncertainty. OHR correction for NO appears to work for conditions with ambient NO<=~5 ppbv; OHR data are not reported for higher NO conditions. REVISION: R0 R0: Final Data Start_UTC, Stop_UTC, Mid_UTC, OH_pptv, HO2_pptv, OHR_Hz 64897, 64916, 64906, 0.028, 1.682, 3.258 64917, 64936, 64926, 0.028, 1.004, -9999.000 64937, 64956, 64946, -0.005, 1.017, 1.018 64957, 64976, 64966, -0.005, 1.030, -9999.000 64977, 64996, 64986, 0.013, 1.051, 0.762 64997, 65016, 65006, 0.013, 0.477, 1.072 65017, 65036, 65026, 0.041, 0.769, 2.999 65037, 65056, 65046, 0.041, 1.061, 2.340 65057, 65076, 65066, 0.005, 0.946, 1.630 65077, 65096, 65086, 0.005, 1.276, 1.122 65097, 65116, 65106, -0.015, 1.069, 1.838 65117, 65137, 65126, -0.015, 0.863, 0.296 65138, 65157, 65147, -0.020, 0.437, -9999.000 65158, 65177, 65167, -0.020, 0.264, -9999.000 65178, 65197, 65187, -0.002, 0.275, -9999.000 65198, 65217, 65207, -0.002, 0.287, 0.616 65218, 65237, 65227, 0.015, 0.323, -0.170 65238, 65257, 65247, 0.015, 0.360, 1.707 65258, 65277, 65267, -0.022, 0.396, 0.420 65278, 65297, 65287, -0.022, 0.432, 0.365 65298, 65317, 65307, 0.013, 0.469, 0.338 65318, 65337, 65327, 0.013, 0.505, -0.166 65338, 65357, 65347, 0.017, 0.542, 0.367 65358, 65377, 65367, 0.017, 0.578, 0.756 65378, 65397, 65387, 0.011, 0.615, -0.297 65398, 65417, 65407, 0.011, 0.799, -0.388 65418, 65437, 65427, 0.005, 1.118, -0.561 65438, 65457, 65447, 0.005, 1.437, 0.781 65458, 65477, 65467, 0.016, 0.848, 0.198 65478, 65497, 65487, 0.016, 0.765, 0.175 65498, 65517, 65507, 0.026, 0.841, 0.038 65518, 65537, 65527, 0.026, 0.915, 1.515 65538, 65557, 65547, 0.010, 0.990, -0.564 65558, 65577, 65567, 0.010, 1.105, 0.145 65578, 65597, 65587, 0.027, 1.022, 0.541 65598, 65617, 65607, 0.027, 0.939, -0.329 65618, 65637, 65627, 0.009, 0.881, 0.349 65638, 65657, 65647, 0.009, 0.910, -0.350 65658, 65677, 65667, -0.005, 0.850, 0.121 65678, 65697, 65687, -0.005, 0.790, 0.895 65698, 65717, 65707, 0.017, 0.731, -0.140 65718, 65737, 65727, 0.017, 0.914, -9999.000 65738, 65757, 65747, -0.008, 0.867, 0.761 65758, 65777, 65767, -0.008, 0.821, -0.484 65778, 65797, 65787, 0.016, 0.683, -0.171 65798, 65817, 65807, 0.016, 0.576, 1.344 65818, 65837, 65827, 0.026, 0.641, 0.962 65838, 65857, 65847, 0.026, 0.707, -0.226 65858, 65877, 65867, -0.008, 0.772, 0.306 65878, 65898, 65887, -0.008, 0.326, 1.868 65899, 65918, 65908, 0.014, 0.538, -0.180 65919, 65938, 65928, 0.014, 0.749, 0.845 65939, 65958, 65948, 0.027, 0.910, 0.792 65959, 65978, 65968, 0.027, 0.928, -0.012 65979, 65998, 65988, -0.018, 0.982, -0.116 65999, 66018, 66008, -0.018, 1.035, 0.211 66019, 66038, 66028, 0.015, 1.089, -9999.000 66039, 66058, 66048, 0.015, 1.718, -9999.000 66059, 66078, 66068, 0.014, 1.512, 0.153 66079, 66098, 66088, 0.014, 1.306, -9999.000 66099, 66118, 66108, 0.021, 1.108, 0.554 66119, 66138, 66128, 0.021, 1.544, 0.905 66139, 66158, 66148, 0.045, 1.170, -9999.000 66159, 66178, 66168, 0.045, 0.793, -9999.000 66179, 66198, 66188, 0.058, 0.419, 1.039 66199, 66218, 66208, 0.058, 0.484, 0.098 66219, 66238, 66228, 0.051, 0.589, 0.849 66239, 66258, 66248, 0.051, 0.693, 0.952 66259, 66278, 66268, 0.013, 0.482, 0.219 66279, 66298, 66288, 0.013, 0.685, -9999.000 66299, 66318, 66308, 0.075, 0.701, -9999.000 66319, 66338, 66328, 0.075, 0.717, -9999.000 66339, 66358, 66348, 0.037, 0.733, -9999.000 66359, 66378, 66368, 0.037, 0.771, -9999.000 66379, 66398, 66388, 0.058, 0.857, -9999.000 66399, 66423, 66408, 0.058, 0.942, -9999.000 66489, 66513, 66503, 0.058, 0.983, -9999.000 66514, 66533, 66523, 0.058, 1.154, 0.129 66534, 66553, 66543, 0.039, 1.008, 0.546 66554, 66573, 66563, 0.039, 0.862, -9999.000 66574, 66593, 66583, 0.047, 0.716, 0.265 66594, 66613, 66603, 0.047, 1.240, -9999.000 66614, 66633, 66623, 0.032, 1.044, -0.071 66634, 66653, 66643, 0.032, 0.847, -9999.000 66654, 66673, 66663, -0.005, 1.211, 1.113 66674, 66693, 66683, -0.005, 1.290, -9999.000 66694, 66713, 66703, 0.035, 1.209, -9999.000 66714, 66733, 66723, 0.035, 1.128, -9999.000 66734, 66753, 66743, 0.046, 1.047, -9999.000 66754, 66773, 66763, 0.046, 1.017, 0.352 66774, 66793, 66783, 0.034, 1.217, -9999.000 66794, 66813, 66803, 0.034, 1.417, 0.127 66814, 66833, 66823, 0.024, 1.061, -9999.000 66834, 66853, 66843, 0.024, 1.119, 1.758 66854, 66873, 66863, 0.071, 1.062, 0.582 66874, 66893, 66883, 0.071, 1.004, -1.783 66894, 66913, 66903, 0.050, 0.946, 0.733 66914, 66934, 66924, 0.050, 1.295, -9999.000 66935, 66954, 66944, 0.040, 1.277, 0.586 66955, 66974, 66964, 0.040, 1.260, -9999.000 66975, 66994, 66984, 0.067, 1.177, -9999.000 66995, 67014, 67004, 0.067, 1.218, 0.490 67015, 67034, 67024, 0.060, 1.303, 0.741 67035, 67054, 67044, 0.060, 1.389, -9999.000 67055, 67074, 67064, -0.005, 1.475, -0.001 67075, 67094, 67084, -0.005, 2.900, -0.333 67095, 67114, 67104, 0.071, 2.664, -9999.000 67115, 67134, 67124, 0.071, 2.428, -9999.000 67135, 67154, 67144, 0.043, 2.613, -9999.000 67155, 67174, 67164, 0.043, 3.194, 0.353 67175, 67194, 67184, 0.014, 2.853, -9999.000 67195, 67214, 67204, 0.014, 2.513, -9999.000 67215, 67234, 67224, 0.004, 2.173, -9999.000 67235, 67254, 67244, 0.004, 2.398, 1.113 67255, 67274, 67264, 0.033, 2.206, -9999.000 67275, 67294, 67284, 0.033, 2.015, -9999.000 67295, 67314, 67304, 0.039, 1.810, -9999.000 67315, 67334, 67324, 0.039, 2.281, -0.824 67335, 67354, 67344, 0.027, 2.116, -0.089 67355, 67374, 67364, 0.027, 1.951, -0.418 67375, 67394, 67384, 0.034, 1.787, 1.095 67395, 67414, 67404, 0.034, 1.914, -0.511 67415, 67434, 67424, 0.014, 1.661, -0.454 67435, 67454, 67444, 0.014, 1.407, -0.278 67455, 67475, 67465, 0.011, 1.351, 0.519 67476, 67495, 67485, 0.011, 1.526, -0.922 67496, 67515, 67505, -0.003, 1.339, 0.355 67516, 67535, 67525, -0.003, 1.152, 0.606 67536, 67555, 67545, 0.014, 0.964, 0.448 67556, 67575, 67565, 0.014, 1.191, -0.523 67576, 67595, 67585, -0.013, 1.079, -0.553 67596, 67615, 67605, -0.013, 0.966, 2.080 67616, 67635, 67625, 0.019, 1.140, 0.241 67636, 67655, 67645, 0.019, 1.485, 0.459 67656, 67675, 67665, -0.024, 1.339, -0.425 67676, 67695, 67685, -0.024, 1.193, -9999.000 67696, 67715, 67705, 0.008, 1.048, 0.982 67716, 67735, 67725, 0.008, 1.334, -9999.000 67736, 67755, 67745, 0.013, 1.893, 1.220 67756, 67775, 67765, 0.013, 2.452, 2.228 67776, 67795, 67785, -0.009, 2.076, -9999.000 67796, 67815, 67805, -0.009, -9999.000, 5.095 67816, 67835, 67825, -9999.000, -9999.000, 0.854 67836, 67855, 67845, -9999.000, -9999.000, 3.923 67856, 67875, 67865, -9999.000, -9999.000, 7.536 67876, 67895, 67885, -9999.000, 4.507, -9999.000 67896, 67915, 67905, -0.028, 4.014, 1.243 67916, 67935, 67925, -0.028, 3.527, -9999.000 67936, 67955, 67945, 0.066, 3.119, -9999.000 67956, 67975, 67965, 0.066, 4.525, 14.877 67976, 67995, 67985, 0.067, 3.875, -9999.000 67996, 68015, 68005, 0.067, 3.231, 3.655 68016, 68035, 68025, -0.007, 2.584, -9999.000 68036, 68060, 68045, -0.007, 2.207, 1.280 68146, 68170, 68160, 0.031, 2.775, -9999.000 68171, 68190, 68180, 0.031, 2.874, -0.174 68191, 68210, 68200, 0.114, -9999.000, -9999.000 68211, 68231, 68221, 0.114, -9999.000, -9999.000 68232, 68251, 68241, 0.024, -9999.000, 5.562 68252, 68271, 68261, 0.024, -9999.000, 1.269 68272, 68291, 68281, 0.047, -9999.000, -9999.000 68292, 68311, 68301, 0.047, -9999.000, 3.711 68312, 68331, 68321, -0.123, -9999.000, 1.319 68332, 68351, 68341, -0.123, -9999.000, 1.196 68352, 68371, 68361, 0.174, -9999.000, 18.774 68372, 68391, 68381, 0.174, -9999.000, -9999.000 68392, 68411, 68401, -0.069, -9999.000, -1.085 68412, 68431, 68421, -0.069, -9999.000, -0.264 68432, 68451, 68441, 0.109, 0.763, 2.216 68452, 68471, 68461, -9999.000, -9999.000, 0.573 68472, 68491, 68481, 0.075, 2.054, 1.214 68492, 68511, 68501, 0.075, 1.759, 1.023 68512, 68531, 68521, 0.058, 0.863, 0.990 68532, 68551, 68541, 0.058, 1.113, 1.806 68552, 68571, 68561, 0.155, 1.124, 0.747 68572, 68591, 68581, 0.155, 1.135, 0.080 68592, 68611, 68601, -0.200, 1.145, 3.903 68612, 68631, 68621, -0.200, 0.165, -9999.000 68632, 68651, 68641, -0.006, 1.574, 1.042 68652, 68671, 68661, -0.006, 2.999, 0.480 68672, 68691, 68681, -0.007, 1.856, -9999.000 68692, 68711, 68701, -0.007, 1.515, -9999.000 68712, 68731, 68721, 0.013, 1.486, 0.614 68732, 68751, 68741, 0.013, 1.457, 1.735 68752, 68771, 68761, -0.000, 1.428, 1.084 68772, 68791, 68781, -0.000, 2.078, 0.373 68792, 68811, 68801, 0.003, 1.837, -0.103 68812, 68831, 68821, 0.003, 1.598, -9999.000 68832, 68851, 68841, 0.042, 1.711, 0.199 68852, 68871, 68861, 0.042, 1.317, 0.008 68872, 68891, 68881, 0.018, 1.304, 0.278 68892, 68911, 68901, 0.018, 1.290, 0.967 68912, 68932, 68921, 0.029, 1.277, 1.137 68933, 68952, 68942, 0.029, 1.155, -9999.000 68953, 68972, 68962, 0.026, 1.484, -0.053 68973, 68992, 68982, 0.026, 1.813, -0.614 68993, 69012, 69002, -0.007, 1.757, -0.595 69013, 69032, 69022, -0.007, 1.658, -0.398 69033, 69052, 69042, -0.011, 1.728, -9999.000 69053, 69072, 69062, -0.011, 1.799, -9999.000 69073, 69092, 69082, 0.029, 1.870, -0.249 69093, 69112, 69102, 0.029, 2.216, 2.613 69113, 69132, 69122, 0.038, 2.724, -0.316 69133, 69152, 69142, 0.038, 3.231, 0.881 69153, 69172, 69162, -0.008, 2.619, -9999.000 69173, 69192, 69182, -0.008, 2.390, -9999.000 69193, 69212, 69202, 0.032, 2.389, -9999.000 69213, 69232, 69222, 0.032, 2.389, -9999.000 69233, 69252, 69242, 0.003, 2.389, -9999.000 69253, 69272, 69262, 0.003, 2.532, -9999.000 69273, 69292, 69282, 0.043, 2.592, -0.758 69293, 69312, 69302, 0.043, 2.651, -9999.000 69313, 69332, 69322, 0.029, 2.781, -0.558 69333, 69352, 69342, 0.029, 2.654, -9999.000 69353, 69372, 69362, 0.075, 2.622, -0.087 69373, 69392, 69382, 0.075, 2.591, -0.430 69393, 69412, 69402, -0.007, 2.560, -9999.000 69413, 69432, 69422, -0.007, 2.616, -0.246 69433, 69452, 69442, 0.035, 2.822, -9999.000 69453, 69472, 69462, 0.035, 3.028, -0.570 69473, 69492, 69482, 0.035, 2.534, -9999.000 69493, 69512, 69502, 0.035, 3.244, -0.462 69513, 69532, 69522, 0.079, 3.247, -9999.000 69533, 69552, 69542, 0.079, 3.250, -9999.000 69553, 69572, 69562, 0.040, 3.254, -9999.000 69573, 69592, 69582, 0.040, 2.935, 0.397 69593, 69612, 69602, 0.059, 3.114, -9999.000 69613, 69632, 69622, 0.059, 3.291, -9999.000 69633, 69652, 69642, 0.113, 3.148, -9999.000 69653, 69672, 69662, 0.113, 2.913, 1.114 69673, 69692, 69682, 0.191, 2.816, -9999.000 69693, 69712, 69702, 0.191, 2.720, -9999.000 69713, 69732, 69722, 0.207, 2.623, -9999.000 69733, 69752, 69742, 0.207, 2.732, -9999.000 69753, 69772, 69762, 0.223, 2.305, -9999.000 69773, 69792, 69782, 0.223, 1.879, -9999.000 69793, 69812, 69802, 0.160, 1.742, -9999.000 69813, 69832, 69822, 0.160, 1.943, 1.549 69833, 69853, 69843, 0.170, 1.924, -9999.000 69854, 69873, 69863, 0.170, 1.905, -9999.000 69874, 69893, 69883, 0.172, 1.887, -9999.000 69894, 69913, 69903, 0.172, 1.780, -0.060 69914, 69933, 69923, 0.167, 2.367, 0.578 69934, 69953, 69943, 0.167, 2.954, -9999.000 69954, 69973, 69963, 0.203, 2.781, -0.249 69974, 69993, 69983, 0.203, 2.239, -9999.000 69994, 70013, 70003, 0.125, 1.952, -9999.000 70014, 70033, 70023, 0.125, 1.664, 0.530 70034, 70058, 70043, 0.125, 1.376, -9999.000 70131, 70155, 70145, 0.160, 2.073, -9999.000 70156, 70175, 70165, 0.160, 1.881, -9999.000 70176, 70195, 70185, 0.160, 1.691, -0.219 70196, 70215, 70205, 0.121, 1.346, 0.496 70216, 70235, 70225, 0.121, 1.292, -9999.000 70236, 70255, 70245, 0.150, 1.449, 0.441 70256, 70275, 70265, 0.150, 1.606, -9999.000 70276, 70296, 70285, 0.094, 1.763, 0.543 70297, 70316, 70306, 0.094, 1.457, -9999.000 70317, 70336, 70326, 0.106, 1.753, -9999.000 70337, 70356, 70346, 0.106, 2.050, 0.939 70357, 70376, 70366, 0.144, 1.790, 0.445 70377, 70396, 70386, 0.144, 1.615, -9999.000 70397, 70416, 70406, 0.224, 1.925, -9999.000 70417, 70436, 70426, 0.224, 2.236, -9999.000 70437, 70456, 70446, 0.182, 2.548, -9999.000 70457, 70476, 70466, 0.182, 1.993, -9999.000 70477, 70496, 70486, 0.215, 2.205, -9999.000 70497, 70516, 70506, 0.215, 2.417, 0.394 70517, 70536, 70526, 0.213, 2.011, -0.241 70537, 70556, 70546, 0.213, 2.235, -0.238 70557, 70576, 70566, 0.041, 2.558, -9999.000 70577, 70596, 70586, 0.041, 2.877, -9999.000 70597, 70616, 70606, 0.035, 3.196, -9999.000 70617, 70636, 70626, 0.035, 3.631, -9999.000 70637, 70656, 70646, 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