47, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2017, 02, 13, 2018, 10, 25 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 29 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom II: Science Flight #7 -- PUQ - ASI ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 32% (actually a multiplicative factor of 1/1.32 to 1.32), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R3 R3: Final Data (see OTHER_COMMENTS) R2: Final Data (see OTHER_COMMENTS) R1: Final Data R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 39668, 39687, 39678, -9999.000, -9999.000 39688, 39707, 39698, -9999.000, -9999.000 39708, 39727, 39718, -9999.000, -9999.000 39728, 39747, 39738, -9999.000, -9999.000 39748, 39767, 39758, -9999.000, -9999.000 39768, 39787, 39778, -9999.000, -9999.000 39788, 39807, 39798, -0.005, 3.123 39808, 39827, 39818, 0.013, 3.279 39828, 39847, 39838, 0.013, 2.335 39848, 39867, 39858, -0.003, 3.562 39868, 39887, 39878, -0.003, 2.893 39888, 39907, 39898, -0.003, 2.225 39909, 39928, 39919, -0.017, 2.422 39929, 39948, 39939, -0.012, 2.720 39949, 39968, 39959, -0.012, 2.510 39969, 39988, 39979, 0.035, 2.300 39989, 40008, 39999, 0.035, 2.374 40009, 40028, 40019, 0.035, 2.240 40029, 40048, 40039, 0.004, 2.278 40049, 40068, 40059, 0.010, 2.315 40069, 40088, 40079, 0.010, 1.539 40089, 40108, 40099, 0.009, 2.095 40109, 40128, 40119, 0.009, 2.063 40129, 40148, 40139, -0.015, 2.032 40149, 40168, 40159, -0.015, 2.361 40169, 40188, 40179, 0.031, 2.116 40189, 40208, 40199, 0.031, 1.871 40209, 40228, 40219, 0.031, 1.626 40229, 40248, 40239, 0.018, 1.380 40249, 40268, 40259, -0.017, 1.133 40269, 40288, 40279, -0.017, 0.888 40289, 40308, 40299, -0.017, 0.643 40309, 40328, 40319, 0.014, 0.866 40329, 40348, 40339, 0.034, 0.333 40349, 40368, 40359, 0.034, 1.414 40369, 40388, 40379, 0.016, 2.507 40389, 40408, 40399, 0.016, 3.475 40409, 40428, 40419, 0.024, 3.590 40429, 40448, 40439, 0.024, 3.712 40449, 40468, 40459, 0.024, 3.835 40469, 40488, 40479, 0.005, 3.509 40490, 40509, 40500, 0.005, 4.422 40510, 40529, 40520, 0.026, 4.759 40530, 40549, 40540, 0.025, 5.095 40550, 40569, 40560, 0.025, 3.908 40570, 40589, 40580, 0.025, 4.753 40590, 40609, 40600, 0.058, 4.225 40610, 40629, 40620, 0.058, 3.695 40630, 40649, 40640, 0.031, 3.956 40650, 40669, 40660, 0.074, 4.345 40670, 40689, 40680, 0.074, 4.704 40690, 40709, 40700, 0.076, 5.062 40710, 40729, 40720, 0.076, 4.116 40730, 40749, 40740, 0.060, -9999.000 40750, 40769, 40760, 0.060, -9999.000 40770, 40789, 40780, 0.049, 3.989 40790, 40809, 40800, 0.049, 4.892 40810, 40829, 40820, 0.049, 4.937 40830, 40849, 40840, 0.045, 4.737 40850, 40869, 40860, 0.011, 4.538 40870, 40889, 40880, 0.011, 3.992 40890, 40909, 40900, 0.011, 4.428 40910, 40929, 40920, 0.003, 4.295 40930, 40949, 40940, 0.054, 4.162 40950, 40969, 40960, 0.054, 4.047 40970, 40989, 40980, 0.054, 4.329 40990, 41009, 41000, 0.033, 4.747 41010, 41029, 41020, 0.033, 5.162 41030, 41049, 41040, 0.051, 5.682 41050, 41069, 41060, 0.051, 5.087 41070, 41089, 41080, 0.101, 5.317 41090, 41109, 41100, 0.103, 5.548 41110, 41129, 41120, 0.103, 4.527 41130, 41149, 41140, 0.027, 5.364 41150, 41169, 41160, 0.027, 4.310 41170, 41189, 41180, 0.038, 3.255 41190, 41209, 41200, 0.038, 3.643 41211, 41230, 41221, 0.038, 3.925 41231, 41250, 41241, -9999.000, 3.808 41251, 41270, 41261, -9999.000, 3.690 41271, 41290, 41281, 0.126, 4.068 41291, 41310, 41301, 0.234, 3.977 41311, 41330, 41321, 0.234, 3.640 41331, 41350, 41341, 0.234, 3.302 41351, 41370, 41361, 0.217, 4.110 41371, 41390, 41381, 0.758, 4.133 41391, 41410, 41401, 0.758, 4.248 41411, 41430, 41421, 0.331, 4.364 41431, 41450, 41441, 0.331, 4.864 41451, 41470, 41461, 0.055, 4.476 41471, 41490, 41481, 0.055, 4.665 41491, 41510, 41501, 0.723, 4.856 41511, 41530, 41521, 0.723, 3.126 41531, 41550, 41541, 0.723, 4.965 41551, 41570, 41561, -9999.000, 3.888 41571, 41590, 41581, -9999.000, 2.811 41591, 41610, 41601, 0.443, 5.045 41611, 41630, 41621, 0.443, 5.849 41631, 41650, 41641, 0.306, 4.370 41651, 41670, 41661, -9999.000, 2.892 41671, 41690, 41681, -9999.000, 6.737 41691, 41710, 41701, 0.082, 5.677 41711, 41730, 41721, 0.082, 5.301 41731, 41750, 41741, 0.050, 4.925 41751, 41770, 41761, 0.050, 6.108 41771, 41790, 41781, 0.230, 4.564 41791, 41810, 41801, 0.230, 5.774 41811, 41830, 41821, 0.230, 6.991 41964, 41983, 41974, 0.302, 7.401 41984, 42003, 41994, 0.100, 8.037 42004, 42023, 42014, 0.100, 7.391 42024, 42043, 42034, 0.100, 6.746 42044, 42063, 42054, 0.042, 8.550 42064, 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43936, 0.107, 7.534 43946, 43965, 43956, 0.117, 7.329 43966, 43985, 43976, 0.075, 7.123 43986, 44005, 43996, 0.075, 8.660 44006, 44025, 44016, 0.113, 7.993 44026, 44045, 44036, 0.113, 7.522 44046, 44065, 44056, 0.113, 7.050 44066, 44085, 44076, 0.078, 7.505 44086, 44105, 44096, 0.078, 8.656 44106, 44125, 44116, 0.089, 8.113 44126, 44145, 44136, 0.092, 7.570 44146, 44165, 44156, 0.092, 6.477 44166, 44185, 44176, 0.092, 7.540 44186, 44205, 44196, 0.077, 7.319 44206, 44225, 44216, 0.077, 7.098 44226, 44245, 44236, 0.068, 8.555 44246, 44265, 44256, 0.068, 8.638 44266, 44285, 44276, 0.116, 8.332 44286, 44305, 44296, 0.083, 8.026 44306, 44325, 44316, 0.083, 7.241 44326, 44345, 44336, 0.083, 8.037 44346, 44365, 44356, 0.079, 7.131 44366, 44385, 44376, 0.093, 6.225 44386, 44405, 44396, 0.093, 6.899 44406, 44425, 44416, 0.093, 7.995 44426, 44445, 44436, 0.089, 7.139 44446, 44465, 44456, 0.076, 6.282 44466, 44485, 44476, 0.076, 7.535 44486, 44505, 44496, 0.076, 6.971 44506, 44525, 44516, 0.109, 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