48, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2016, 08, 23, 2018, 11, 28 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 30 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom I: Science Flight #11 -- MSP - PMD ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 32% (actually a multiplicative factor of 1/1.32 to 1.32), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R4 R4: Final Data (see OTHER_COMMENTS) R3: Final Data (see OTHER_COMMENTS) R2: Final Data (see OTHER_COMMENTS) R1: Final Data R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 54315, 54344, 54330, -9999.000, -9999.000 54345, 54374, 54360, -9999.000, -9999.000 54375, 54404, 54390, -9999.000, -9999.000 54405, 54434, 54420, -9999.000, -9999.000 54435, 54464, 54450, 0.190, 37.442 54465, 54494, 54480, 0.190, 33.906 54495, 54524, 54510, 0.196, 34.029 54525, 54554, 54540, 0.196, 33.309 54555, 54584, 54570, 0.196, 32.589 54585, 54614, 54600, 0.262, 35.005 54616, 54645, 54631, 0.236, 33.852 54646, 54675, 54661, 0.236, 29.855 54676, 54705, 54691, 0.236, 25.858 54706, 54735, 54721, 0.273, 21.847 54736, 54765, 54751, 0.293, 17.837 54766, 54795, 54781, 0.293, 13.840 54796, 54825, 54811, 0.293, 9.829 54826, 54855, 54841, 0.267, 14.751 54856, 54885, 54871, 0.215, 14.377 54886, 54915, 54901, 0.215, 13.086 54916, 54945, 54931, 0.215, 11.795 54946, 54975, 54961, 0.242, 14.000 54976, 55005, 54991, 0.242, 13.016 55006, 55035, 55021, 0.273, 12.627 55036, 55065, 55051, 0.273, 12.243 55066, 55095, 55081, 0.255, 14.982 55096, 55125, 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