41, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor based on LIF ATom 1, 1 2016, 08, 20, 2017, 06, 06 0 Start_UTC, seconds, seconds since takeoff's midnight UTC 5 1, 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since takeoff's midnight UTC Mid_UTC, seconds, seconds since takeoff's midnight UTC OH_pptv, pptv, OH mixing ratio in pptv HO2_pptv, pptv, HO2 mixing ratio in pptv OHR_Hz, Hz, OH reactivity in Hz 0 22 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom I: Science Flight #9 -- TER - SFJ ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 with Laser Induced Fluorescence; OH reactivity with discharge flow DATA_INFO: Units are pptv for OH and HO2; Hz for OHR. UNCERTAINTY: Normaly HOx absolute accuracy is estimated to be +/- 32% at two sigma confidence. Please see comments below. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Semi-Final Data. Calibrating ATHOS with the new OH scavenging inlet is proving to be difficult. Until we complete more tests, OH uncertainty above 6 km estimated to be a factor of 2, 2 sigma confidence HO2 uncertainty for all altitudes estimated to be a factor of 1.6, 2 sigma confidence. OHR uncertainty estimated to be 15%, 2 sigma confidence, with 0.3 s^-1 zero uncertainty. OHR correction for NO appears to work for conditions with ambient NO<=~5 ppbv; OHR data are not reported for higher NO conditions. REVISION: R1 R1: Final Data Start_UTC, Stop_UTC, Mid_UTC, OH_pptv, HO2_pptv, OHR_Hz 32930, 32959, 32944, -9999.000, -9999.000, 2.290 32960, 32989, 32974, -9999.000, -9999.000, 1.253 32990, 33019, 33004, -9999.000, -9999.000, 0.844 33020, 33049, 33034, -9999.000, 16.105, 0.791 33050, 33079, 33064, 0.274, 15.131, 0.692 33081, 33110, 33095, 0.274, 16.045, 1.903 33111, 33140, 33125, 0.146, 16.568, 1.637 33141, 33170, 33155, 0.146, 17.090, 1.760 33171, 33200, 33185, 0.344, 15.415, 2.319 33201, 33230, 33215, 0.344, 13.740, 4.103 33231, 33260, 33245, 0.233, 12.071, 2.831 33261, 33290, 33275, 0.233, 10.379, 2.527 33291, 33320, 33305, 0.284, 11.228, 2.193 33321, 33350, 33335, 0.284, 10.329, 1.618 33351, 33380, 33365, 0.279, 11.003, 1.442 33381, 33410, 33395, 0.279, 11.671, 2.885 33411, 33440, 33425, 0.353, 12.097, 1.085 33441, 33470, 33455, 0.353, 11.227, 1.624 33471, 33500, 33485, 0.344, 10.533, 1.895 33502, 33531, 33516, 0.344, 9.835, 1.872 33532, 33561, 33546, 0.284, 12.167, 2.326 33562, 33591, 33576, 0.284, 11.993, 1.643 33592, 33621, 33606, 0.441, 11.912, 2.534 33622, 33651, 33636, 0.441, 11.832, 1.085 33652, 33681, 33666, 0.566, 11.645, 1.804 33682, 33711, 33696, 0.566, 10.610, 1.096 33712, 33741, 33726, 0.363, 9.680, 1.047 33742, 33771, 33756, 0.363, 8.743, 1.767 33772, 33801, 33786, 0.375, 8.774, 1.737 33802, 33831, 33816, 0.375, 8.237, 1.379 33832, 33861, 33846, 0.322, 8.260, 1.675 33862, 33891, 33876, 0.322, 8.283, 1.361 33893, 33922, 33907, 0.221, 9.845, 1.103 33923, 33952, 33937, 0.221, 8.533, 1.623 33953, 33982, 33967, 0.250, 7.611, 1.145 33983, 34012, 33997, 0.250, 6.684, -9999.000 34113, 34142, 34127, 0.195, 9.345, -9999.000 34143, 34172, 34157, 0.195, 9.615, 0.885 34173, 34202, 34187, 0.267, 8.850, 0.823 34203, 34232, 34217, 0.267, 8.081, 1.395 34234, 34263, 34248, 0.395, 9.142, 1.399 34264, 34293, 34278, 0.395, 10.282, 1.587 34294, 34323, 34308, 0.272, 9.878, 0.422 34324, 34353, 34338, 0.272, 9.475, 0.733 34354, 34383, 34368, 0.304, 9.333, 0.873 34384, 34413, 34398, 0.304, 9.622, 1.267 34414, 34443, 34428, 0.252, 9.688, 0.504 34444, 34473, 34458, 0.252, 9.754, 0.695 34474, 34503, 34488, 0.317, 8.826, 1.476 34504, 34533, 34518, 0.317, 9.843, 0.441 34534, 34563, 34548, 0.339, 9.624, 0.445 34564, 34593, 34578, 0.339, 9.405, 1.036 34594, 34623, 34608, 0.331, 9.785, 0.773 34625, 34654, 34639, 0.331, 10.018, 0.790 34655, 34684, 34669, 0.253, 9.043, 0.143 34685, 34714, 34699, 0.253, 8.068, 1.065 34715, 34744, 34729, 0.254, 8.867, 1.221 34745, 34774, 34759, 0.254, 9.793, 0.518 34775, 34804, 34789, 0.296, 9.612, 1.069 34805, 34834, 34819, 0.296, 9.429, 0.928 34835, 34864, 34849, 0.270, 9.439, -0.033 34865, 34894, 34879, 0.270, 8.685, 1.056 34895, 34924, 34909, 0.236, 8.283, 0.817 34925, 34954, 34939, 0.236, 7.882, 0.752 34955, 34984, 34969, 0.287, 9.212, 1.084 34985, 35014, 34999, 0.287, 9.157, 0.447 35015, 35044, 35029, 0.250, 8.605, 0.915 35046, 35075, 35060, 0.250, 8.049, 0.563 35076, 35105, 35090, 0.177, 8.326, 0.300 35106, 35135, 35120, 0.177, 10.350, -0.000 35136, 35165, 35150, 0.284, 11.212, 0.792 35166, 35195, 35180, 0.284, 12.071, 0.755 35196, 35225, 35210, 0.268, 14.202, 0.855 35226, 35255, 35240, 0.268, 13.773, 1.143 35256, 35285, 35270, 0.318, 12.050, 0.634 35286, 35315, 35300, 0.318, 10.314, 0.635 35316, 35345, 35330, 0.228, 10.307, 0.859 35346, 35375, 35360, 0.228, 10.782, 0.565 35376, 35405, 35390, 0.280, 10.537, 0.243 35406, 35435, 35420, 0.280, 10.293, 0.467 35436, 35465, 35450, 0.226, 12.039, 0.738 35467, 35496, 35481, 0.226, 13.156, 1.669 35497, 35526, 35511, 0.299, 12.858, 1.958 35527, 35556, 35541, 0.299, 12.559, 1.499 35557, 35586, 35571, 0.329, 12.992, 0.664 35587, 35616, 35601, 0.329, 15.228, 0.938 35617, 35646, 35631, 0.285, 14.070, 1.412 35647, 35676, 35661, 0.285, 12.913, 0.994 35677, 35706, 35691, 0.195, 13.478, 0.736 35707, 35736, 35721, 0.195, 12.888, 3.577 35737, 35766, 35751, 0.302, 15.308, 2.600 35767, 35796, 35781, 0.302, 17.744, 2.640 35797, 35826, 35811, 0.019, 14.004, 2.155 35827, 35856, 35841, 0.019, 18.201, 1.050 35857, 35886, 35871, 0.041, 15.472, -0.654 35887, 35916, 35901, 0.041, 12.752, 1.672 35918, 35947, 35932, 0.041, 13.012, -9999.000 36055, 36084, 36069, -0.032, 13.383, -9999.000 36141, 36170, 36155, 0.071, 17.219, -9999.000 36171, 36200, 36185, 0.071, 18.564, 1.576 36201, 36230, 36215, 0.100, 23.236, 2.107 36231, 36260, 36245, 0.100, 24.099, 1.514 36262, 36291, 36276, 0.074, 26.664, -0.762 36292, 36321, 36306, 0.074, 29.221, 1.587 36322, 36351, 36336, 0.149, 21.849, 0.065 36352, 36381, 36366, 0.149, 25.869, -0.045 36382, 36411, 36396, 0.029, 21.039, 2.434 36412, 36441, 36426, 0.029, -9999.000, 2.344 36442, 36471, 36456, -9999.000, -9999.000, 2.673 36472, 36501, 36486, -9999.000, 15.518, 1.844 36502, 36531, 36516, 0.223, 15.266, 1.205 36532, 36561, 36546, 0.223, -9999.000, 2.038 36562, 36591, 36576, -9999.000, -9999.000, 2.590 36592, 36621, 36606, -9999.000, -9999.000, 3.004 36622, 36651, 36636, 0.573, 24.297, 0.644 36652, 36681, 36666, 0.573, 16.423, 1.993 36682, 36711, 36696, 0.694, 17.402, 0.659 36712, 36741, 36726, 0.694, 20.189, 1.339 36743, 36772, 36757, 0.677, 18.421, 0.464 36773, 36802, 36787, 0.677, 16.659, 1.187 36803, 36832, 36817, 0.554, 18.094, 1.381 36833, 36862, 36847, 0.554, 15.836, 1.437 36863, 36892, 36877, 0.716, 15.675, 1.086 36893, 36922, 36907, 0.716, 15.514, 0.143 36923, 36952, 36937, 0.774, 14.676, 0.290 36953, 36982, 36967, 0.774, 16.122, 0.671 36983, 37012, 36997, 0.609, 15.697, 1.399 37013, 37042, 37027, 0.609, 15.270, 0.692 37043, 37072, 37057, 0.655, 16.557, 1.299 37073, 37102, 37087, 0.655, 14.230, 0.876 37103, 37132, 37117, 0.590, 13.199, 0.838 37133, 37162, 37147, 0.590, 12.163, 0.717 37164, 37193, 37178, 0.537, 14.635, 0.392 37194, 37223, 37208, 0.537, 14.134, 1.417 37224, 37253, 37238, 0.645, 14.866, 0.431 37254, 37283, 37268, 0.645, 15.598, 1.051 37284, 37313, 37298, 0.627, 14.413, 0.662 37314, 37343, 37328, 0.627, 15.040, -0.038 37344, 37373, 37358, 0.579, 14.271, 1.020 37374, 37403, 37388, 0.579, 13.503, 1.381 37404, 37433, 37418, 0.679, 13.652, 1.269 37434, 37463, 37448, 0.679, 14.791, 0.288 37464, 37493, 37478, 0.871, 14.230, 0.922 37494, 37523, 37508, 0.871, 13.672, 0.605 37524, 37553, 37538, 0.778, 13.672, 1.095 37554, 37583, 37568, 0.778, 12.877, 1.155 37585, 37614, 37599, 0.853, 13.789, -0.338 37615, 37644, 37629, 0.853, 14.696, 0.325 37645, 37674, 37659, 0.971, 14.010, 0.447 37675, 37704, 37689, 0.971, 14.147, 0.368 37705, 37734, 37719, 0.866, 13.448, 0.278 37735, 37764, 37749, 0.866, 12.740, -0.434 37765, 37794, 37779, 0.726, 14.976, 0.239 37795, 37824, 37809, 0.726, 15.251, 0.413 37825, 37854, 37839, 0.726, 15.899, 0.159 37944, 37973, 37958, 0.698, 18.454, -9999.000 37974, 38003, 37988, 0.698, 18.610, 0.091 38004, 38033, 38018, 0.698, 21.427, -0.072 38034, 38063, 38048, 0.561, 17.867, 0.839 38065, 38094, 38079, 0.561, 14.306, 0.344 38095, 38124, 38109, 0.715, 19.412, 0.890 38125, 38154, 38139, 0.715, 18.465, 0.704 38155, 38184, 38169, 0.623, 17.109, 0.575 38185, 38214, 38199, 0.623, 15.754, 0.174 38215, 38244, 38229, -9999.000, -9999.000, 0.755 38245, 38274, 38259, 0.420, 15.822, 0.813 38275, 38304, 38289, 0.564, 15.594, -0.341 38305, 38334, 38319, 0.564, 15.366, 1.542 38335, 38364, 38349, 0.489, 17.109, 0.971 38365, 38394, 38379, 0.489, 17.895, 0.333 38395, 38424, 38409, 0.374, 15.123, 0.536 38425, 38454, 38439, 0.374, 12.351, 0.556 38455, 38484, 38469, -9999.000, -9999.000, 0.537 38515, 38544, 38529, -9999.000, -9999.000, 1.918 38546, 38575, 38560, -9999.000, -9999.000, 1.369 38576, 38605, 38590, -9999.000, -9999.000, -0.026 38606, 38635, 38620, -9999.000, -9999.000, 1.320 38636, 38665, 38650, 0.189, -9999.000, 1.111 38666, 38695, 38680, 0.189, -9999.000, 0.268 38696, 38725, 38710, -9999.000, -9999.000, 3.061 38726, 38755, 38740, -9999.000, -9999.000, 2.386 38756, 38785, 38770, -9999.000, -9999.000, 1.985 38786, 38815, 38800, -9999.000, 18.590, 1.577 38816, 38845, 38830, 0.195, 19.969, 2.495 38847, 38876, 38861, 0.195, 20.250, 1.841 38877, 38906, 38891, 0.164, 19.171, 2.565 38907, 38936, 38921, 0.164, 18.092, 0.828 38937, 38966, 38951, 0.226, 19.007, 2.275 38967, 38996, 38981, 0.226, 19.266, 2.396 38997, 39026, 39011, 0.238, 21.069, 1.631 39027, 39056, 39041, 0.238, 22.871, 0.493 39057, 39086, 39071, 0.310, 19.946, 1.437 39087, 39116, 39101, 0.310, 19.187, 2.226 39117, 39146, 39131, 0.262, 18.625, 0.858 39147, 39176, 39161, 0.262, 18.061, 0.953 39177, 39206, 39191, 0.152, 16.404, 0.514 39207, 39236, 39221, 0.152, 15.293, 1.149 39238, 39267, 39252, 0.249, 14.481, 1.238 39268, 39297, 39282, 0.249, 13.675, 1.325 39298, 39327, 39312, 0.386, 14.164, 0.867 39328, 39357, 39342, 0.386, 14.644, 0.732 39358, 39387, 39372, 0.333, 12.619, 0.096 39388, 39417, 39402, 0.333, 10.588, 0.503 39418, 39447, 39432, 0.248, 12.615, 0.248 39448, 39477, 39462, 0.248, 12.988, 0.671 39478, 39507, 39492, 0.290, 12.916, 0.797 39508, 39537, 39522, 0.290, 12.844, 0.425 39538, 39567, 39552, 0.285, 11.189, 0.577 39568, 39597, 39582, 0.285, 12.051, -0.098 39598, 39627, 39612, 0.434, 11.368, 0.197 39628, 39657, 39642, 0.434, 10.682, 0.153 39658, 39687, 39672, 0.452, 11.803, 0.425 39688, 39717, 39702, 0.452, 9.590, 0.316 39718, 39747, 39732, 0.697, 9.792, 0.516 39749, 39778, 39763, 0.697, 9.994, -0.010 39779, 39808, 39793, 0.615, 11.711, 0.476 39809, 39838, 39823, 0.615, 11.888, 0.402 39839, 39868, 39853, 0.781, 12.455, 0.140 39869, 39898, 39883, 0.781, 13.021, 0.083 39899, 39928, 39913, 0.829, 13.360, 0.586 39929, 39958, 39943, 0.829, 11.917, 0.292 39959, 39988, 39973, 0.566, 12.202, 0.757 39989, 40018, 40003, 0.566, 12.489, 0.351 40019, 40048, 40033, 0.578, 15.038, 1.125 40049, 40078, 40063, 0.578, 16.455, 1.402 40080, 40109, 40094, 0.554, 15.138, 0.840 40110, 40139, 40124, 0.554, 13.839, 0.249 40140, 40169, 40154, 0.588, 15.586, 0.215 40170, 40199, 40184, 0.588, 15.640, 0.200 40200, 40229, 40214, 0.745, 15.734, 0.389 40230, 40259, 40244, 0.745, 15.828, 0.183 40260, 40289, 40274, 0.739, 16.188, -0.140 40290, 40319, 40304, 0.739, 14.388, 0.067 40320, 40349, 40334, 0.467, 13.280, 0.698 40350, 40379, 40364, 0.467, 12.179, 0.636 40380, 40409, 40394, 0.480, 13.004, -0.304 40410, 40439, 40424, 0.480, 14.052, 0.201 40440, 40469, 40454, 0.570, 12.963, -0.079 40471, 40500, 40485, 0.570, 11.867, 0.596 40501, 40530, 40515, 0.719, 12.283, 0.359 40531, 40560, 40545, 0.719, 12.690, 0.443 40561, 40590, 40575, 0.451, 11.747, 1.333 40591, 40620, 40605, 0.451, 10.811, 1.026 40621, 40650, 40635, 0.370, 11.644, 0.373 40651, 40680, 40665, 0.370, 12.019, 0.843 40681, 40710, 40695, 0.559, 10.907, 0.511 40711, 40740, 40725, 0.559, 9.788, 0.309 40741, 40770, 40755, 0.347, 10.002, 0.375 40771, 40800, 40785, 0.347, 9.387, 0.147 40801, 40830, 40815, 0.382, 10.123, 0.118 40831, 40860, 40845, 0.382, 10.855, 0.851 40861, 40890, 40875, 0.248, 12.253, 0.671 40892, 40921, 40906, 0.248, 12.323, 1.034 40922, 40951, 40936, 0.287, 12.189, 0.379 40952, 40981, 40966, 0.287, 12.053, 0.539 40982, 41011, 40996, 0.241, 12.811, -0.064 41012, 41041, 41026, 0.241, 13.455, 0.134 41042, 41071, 41056, 0.309, 13.168, 0.524 41072, 41101, 41086, 0.309, 12.882, 0.189 41102, 41131, 41116, 0.132, 11.883, -0.413 41132, 41161, 41146, 0.132, 11.918, 0.041 41162, 41191, 41176, 0.230, 10.998, 0.540 41192, 41221, 41206, 0.230, 10.075, 1.226 41222, 41251, 41236, 0.239, 13.246, 1.057 41252, 41281, 41266, 0.239, 12.608, 0.191 41282, 41311, 41296, 0.304, 11.974, 0.594 41312, 41341, 41326, 0.304, 11.344, 0.398 41342, 41371, 41356, 0.243, 12.149, 0.091 41373, 41402, 41387, 0.243, 14.482, 0.578 41403, 41432, 41417, 0.035, 13.028, 0.453 41433, 41462, 41447, 0.035, 11.568, -0.048 41463, 41492, 41477, 0.213, 12.171, 0.855 41493, 41522, 41507, 0.213, 10.649, 0.557 41523, 41552, 41537, -9999.000, -9999.000, 0.303 41553, 41582, 41567, -9999.000, -9999.000, 0.528 41583, 41612, 41597, 0.159, 11.618, 1.143 41613, 41642, 41627, 0.159, 10.905, 0.603 41643, 41672, 41657, 0.257, 9.624, 0.300 41673, 41702, 41687, 0.257, 8.347, 0.565 41703, 41732, 41717, 0.228, 7.544, -0.262 41733, 41762, 41747, 0.228, 6.570, 0.289 41763, 41792, 41777, 0.257, 6.200, 0.302 41793, 41822, 41807, 0.257, 5.830, 0.400 41823, 41852, 41837, 0.261, 6.316, -9999.000 41854, 41883, 41868, 0.261, 5.888, 0.723 41884, 41913, 41898, 0.251, 5.437, -0.094 41914, 41943, 41928, 0.251, 4.989, 1.033 41944, 41973, 41958, 0.236, 6.430, 0.668 41974, 42003, 41988, 0.236, 9.407, 0.512 42004, 42033, 42018, 0.194, 9.332, 0.640 42034, 42063, 42048, 0.194, 9.258, 0.686 42064, 42093, 42078, 0.128, 10.545, 0.494 42094, 42123, 42108, 0.128, 11.614, 0.716 42124, 42153, 42138, 0.148, 10.903, -0.219 42154, 42183, 42168, 0.148, 10.192, 0.240 42184, 42213, 42198, 0.075, 10.510, -0.050 42215, 42244, 42229, 0.075, 11.908, -0.301 42245, 42274, 42259, 0.064, 11.175, -9999.000 42275, 42304, 42289, 0.064, 10.442, -0.014 42305, 42334, 42319, 0.092, 9.727, 0.454 42335, 42364, 42349, 0.092, 11.301, 0.665 42365, 42394, 42379, 0.106, 10.852, 0.720 42395, 42424, 42409, 0.106, 10.402, -0.362 42425, 42454, 42439, 0.142, 9.495, 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