41, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor based on LIF ATom 1, 1 2016, 08, 17, 2017, 06, 06 0 Start_UTC, seconds, seconds since takeoff's midnight UTC 5 1, 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since takeoff's midnight UTC Mid_UTC, seconds, seconds since takeoff's midnight UTC OH_pptv, pptv, OH mixing ratio in pptv HO2_pptv, pptv, HO2 mixing ratio in pptv OHR_Hz, Hz, OH reactivity in Hz 0 22 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom I: Science Flight #8 -- ASI - TER ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 with Laser Induced Fluorescence; OH reactivity with discharge flow DATA_INFO: Units are pptv for OH and HO2; Hz for OHR. UNCERTAINTY: Normaly HOx absolute accuracy is estimated to be +/- 32% at two sigma confidence. Please see comments below. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Semi-Final Data. Calibrating ATHOS with the new OH scavenging inlet is proving to be difficult. Until we complete more tests, OH uncertainty above 6 km estimated to be a factor of 2, 2 sigma confidence HO2 uncertainty for all altitudes estimated to be a factor of 1.6, 2 sigma confidence. OHR uncertainty estimated to be 15%, 2 sigma confidence, with 0.3 s^-1 zero uncertainty. OHR correction for NO appears to work for conditions with ambient NO<=~5 ppbv; OHR data are not reported for higher NO conditions. REVISION: R1 R1: Final Data Start_UTC, Stop_UTC, Mid_UTC, OH_pptv, HO2_pptv, OHR_Hz 29334, 29363, 29348, -9999.000, -9999.000, 2.499 29364, 29393, 29378, -9999.000, -9999.000, 3.164 29394, 29423, 29408, -9999.000, 16.140, 3.803 29424, 29453, 29438, -9999.000, 15.332, 2.329 29454, 29483, 29468, 0.041, 14.697, 1.962 29484, 29513, 29498, 0.055, 14.235, 1.519 29514, 29543, 29528, 0.055, 11.230, 2.445 29544, 29573, 29558, 0.119, 8.225, 1.022 29574, 29603, 29588, 0.119, 7.205, 0.700 29604, 29633, 29618, 0.030, 6.181, 0.903 29634, 29663, 29648, 0.030, 5.157, 0.964 29664, 29693, 29678, 0.050, 4.136, 1.982 29694, 29723, 29708, 0.050, 3.709, 1.593 29724, 29753, 29738, 0.063, 3.322, 1.918 29754, 29783, 29768, 0.063, 3.409, 1.232 29784, 29813, 29798, 0.070, 3.495, 1.104 29814, 29843, 29828, 0.070, 4.521, 0.817 29844, 29873, 29858, 0.030, 3.871, 1.279 29875, 29904, 29889, 0.030, 4.613, 1.615 29905, 29934, 29919, 0.059, 5.353, 0.561 29935, 29964, 29949, 0.059, 5.341, 1.268 29965, 29994, 29979, 0.105, 6.300, 0.635 29995, 30024, 30009, 0.105, 6.064, 1.429 30025, 30054, 30039, 0.110, 5.828, 1.834 30055, 30084, 30069, 0.110, 6.097, 1.211 30085, 30114, 30099, 0.114, 5.820, 1.445 30115, 30144, 30129, 0.114, 5.597, 0.796 30145, 30174, 30159, 0.144, 5.375, 1.025 30175, 30204, 30189, 0.144, 6.330, 0.743 30205, 30234, 30219, 0.150, 5.582, 1.253 30235, 30264, 30249, 0.150, 5.377, 1.080 30265, 30294, 30279, 0.175, 5.172, 0.976 30295, 30324, 30309, 0.175, 5.598, 1.521 30325, 30354, 30339, 0.177, 6.635, 0.728 30355, 30384, 30369, 0.177, 6.257, 0.793 30385, 30414, 30399, 0.185, 5.879, 1.362 30416, 30445, 30430, 0.185, 6.392, 1.462 30446, 30475, 30460, 0.185, 6.229, 0.719 30476, 30505, 30490, 0.185, 6.465, 0.546 30506, 30535, 30520, 0.174, 6.703, 0.664 30536, 30565, 30550, 0.174, 6.759, 0.851 30566, 30595, 30580, 0.173, 6.633, 0.779 30596, 30625, 30610, 0.173, 6.597, 0.949 30626, 30655, 30640, 0.234, 6.560, 0.789 30656, 30685, 30670, 0.234, 7.107, 1.645 30686, 30715, 30700, 0.219, 7.479, 0.858 30716, 30745, 30730, 0.219, 6.902, 1.087 30746, 30775, 30760, 0.300, 6.325, 0.495 30776, 30805, 30790, 0.300, 6.496, 0.372 30806, 30835, 30820, 0.357, 7.787, 0.645 30836, 30865, 30850, 0.357, 8.171, 0.854 30866, 30895, 30880, 0.393, 8.554, 0.826 30896, 30925, 30910, 0.393, 9.600, 0.855 30927, 30956, 30941, 0.416, 9.117, 1.121 30957, 30986, 30971, 0.416, 8.762, 1.105 31080, 31109, 31094, 0.364, 7.304, -9999.000 31110, 31139, 31124, 0.364, 7.348, -0.031 31140, 31169, 31154, 0.308, 7.360, 0.766 31170, 31199, 31184, 0.308, 6.814, 0.623 31200, 31229, 31214, 0.280, 6.267, 0.183 31230, 31259, 31244, 0.280, 6.650, -0.190 31260, 31289, 31274, 0.295, 6.532, -0.381 31290, 31319, 31304, 0.295, 6.160, 0.736 31320, 31349, 31334, 0.317, 5.787, 0.590 31350, 31379, 31364, 0.317, 6.009, 0.292 31380, 31409, 31394, 0.259, 6.914, 0.059 31410, 31439, 31424, 0.259, 6.539, 0.742 31440, 31469, 31454, 0.203, 6.163, 0.174 31470, 31499, 31484, 0.203, 7.100, 0.474 31500, 31529, 31514, 0.277, 7.305, 0.224 31530, 31559, 31544, 0.277, 7.064, 0.754 31560, 31589, 31574, 0.286, 6.823, -0.129 31591, 31620, 31605, 0.286, 7.146, 0.046 31620, 31649, 31634, 0.209, 7.196, 1.170 31651, 31680, 31665, 0.209, 6.744, -0.359 31680, 31709, 31694, 0.201, 6.293, 0.107 31711, 31740, 31725, 0.201, 6.495, -0.232 31741, 31770, 31755, 0.240, 8.202, -9999.000 31771, 31800, 31785, 0.240, 7.838, 0.483 31801, 31830, 31815, 0.297, 7.473, 0.535 31831, 31860, 31845, 0.297, 9.182, -0.303 31861, 31890, 31875, 0.235, 8.883, -0.330 31891, 31920, 31905, 0.235, 7.536, -0.125 31921, 31950, 31935, 0.173, 6.180, -0.201 31951, 31980, 31965, 0.173, 7.610, 0.452 31981, 32010, 31995, 0.099, 7.499, 0.379 32011, 32040, 32025, 0.099, 7.986, 0.505 32041, 32070, 32055, 0.116, 8.475, -0.269 32071, 32100, 32085, 0.116, 7.366, -0.180 32101, 32130, 32115, 0.090, 10.134, 0.735 32131, 32160, 32145, 0.090, 11.277, 0.812 32161, 32190, 32175, 0.092, 12.428, 1.364 32191, 32220, 32205, 0.092, 12.421, 1.628 32221, 32250, 32235, 0.034, 16.106, 1.772 32252, 32281, 32266, 0.034, 17.936, 3.891 32282, 32311, 32296, 0.080, 19.753, 2.778 32312, 32341, 32326, 0.080, 21.162, 2.871 32342, 32371, 32356, 0.112, 19.645, 1.930 32372, 32401, 32386, 0.112, 19.380, 3.182 32402, 32431, 32416, 0.044, 19.116, 2.843 32432, 32461, 32446, 0.044, 7.618, 3.738 32462, 32491, 32476, 0.011, 10.438, 3.047 32492, 32521, 32506, 0.011, 11.315, 1.464 32522, 32551, 32536, -0.006, 12.196, -0.769 32552, 32581, 32566, -0.006, 13.381, 0.635 32582, 32611, 32596, 0.015, 12.930, -0.144 32612, 32641, 32626, 0.015, 12.063, 1.085 32642, 32671, 32656, 0.039, 11.202, 0.448 32672, 32701, 32686, 0.039, 13.506, 0.253 32703, 32732, 32717, 0.074, 14.307, -0.124 32733, 32762, 32747, 0.074, 14.031, -0.375 32763, 32792, 32777, 0.035, 13.757, -0.061 32793, 32822, 32807, 0.035, 12.648, 0.314 32823, 32852, 32837, 0.076, 10.567, -0.608 32853, 32882, 32867, 0.076, 9.367, 3.400 32883, 32912, 32897, 0.044, 8.170, 0.063 32913, 32942, 32927, 0.044, 10.389, -0.300 32943, 32972, 32957, -0.015, 11.278, -9999.000 32973, 33002, 32987, -0.015, 9.955, -0.759 33003, 33032, 33017, 0.058, 8.623, -0.203 33033, 33062, 33047, 0.058, 12.127, 1.468 33063, 33092, 33077, 0.035, 11.162, 1.125 33093, 33122, 33107, 0.035, 15.326, 1.289 33123, 33152, 33137, 0.086, 19.490, 4.898 33154, 33183, 33168, 0.086, 20.265, 2.637 33183, 33212, 33197, 0.126, 19.294, 1.780 33214, 33243, 33228, 0.126, 18.658, 1.363 33244, 33273, 33258, 0.119, 18.026, 1.535 33274, 33303, 33288, 0.119, 19.684, 0.802 33304, 33333, 33318, 0.100, 20.255, 0.991 33334, 33363, 33348, 0.100, 19.193, 2.171 33364, 33393, 33378, 0.123, 18.135, -0.270 33394, 33423, 33408, 0.123, 15.615, 1.106 33424, 33453, 33438, 0.119, 14.547, 1.511 33454, 33483, 33468, 0.119, 13.376, 0.597 33484, 33513, 33498, 0.145, 12.208, 0.388 33514, 33543, 33528, 0.145, 11.608, 0.690 33544, 33573, 33558, 0.120, 9.948, -0.002 33574, 33603, 33588, 0.120, 10.309, -0.151 33604, 33633, 33618, 0.165, 10.672, 0.276 33634, 33663, 33648, 0.165, 12.022, 0.085 33664, 33693, 33678, 0.147, 9.317, 0.870 33694, 33723, 33708, 0.147, 8.801, -0.096 33724, 33753, 33738, 0.205, 8.283, 0.178 33754, 33783, 33768, 0.205, 8.907, 0.222 33784, 33813, 33798, 0.175, 8.959, 0.333 33815, 33844, 33829, 0.175, 8.820, 0.782 33845, 33874, 33859, 0.202, 8.683, 0.523 33875, 33904, 33889, 0.202, 7.957, 0.740 33905, 33934, 33919, 0.217, 8.912, -0.114 33935, 33964, 33949, 0.217, 8.942, 0.277 33965, 33994, 33979, 0.218, 8.971, -0.128 33995, 34024, 34009, 0.218, 9.922, 0.403 34025, 34054, 34039, 0.234, 12.986, 0.666 34055, 34084, 34069, 0.234, 12.792, 0.201 34085, 34114, 34099, 0.190, 12.597, -0.243 34115, 34144, 34129, 0.190, 12.871, -0.121 34145, 34174, 34159, 0.183, 13.293, -0.324 34175, 34204, 34189, 0.183, 11.581, 0.326 34205, 34234, 34219, 0.245, 9.880, 0.055 34235, 34264, 34249, 0.245, 10.680, 0.091 34265, 34294, 34279, 0.372, 10.412, 1.252 34296, 34325, 34310, 0.372, 10.321, 0.751 34326, 34355, 34340, 0.340, 10.230, 0.455 34356, 34385, 34370, 0.340, 9.931, 0.590 34386, 34415, 34400, 0.363, 11.571, -0.104 34416, 34445, 34430, 0.363, 9.888, 0.128 34446, 34475, 34460, 0.337, 8.211, -0.428 34476, 34505, 34490, 0.337, 8.967, -0.352 34506, 34535, 34520, 0.326, 9.816, 0.307 34536, 34565, 34550, 0.326, 8.979, 0.860 34566, 34595, 34580, 0.360, 8.142, 0.157 34596, 34625, 34610, 0.360, 9.200, -0.171 34626, 34655, 34640, 0.354, 9.100, 0.486 34656, 34685, 34670, 0.354, 8.721, -0.071 34686, 34715, 34700, 0.354, 8.340, 0.187 34819, 34848, 34833, 0.597, 11.611, -9999.000 34849, 34878, 34863, 0.597, 11.395, 0.260 34879, 34908, 34893, 0.597, 10.860, 0.744 34909, 34938, 34923, 0.562, 10.323, -0.360 34939, 34968, 34953, 0.562, 10.798, 0.217 34969, 34998, 34983, 0.542, 9.486, 0.693 34999, 35028, 35013, 0.542, 10.549, 0.573 35029, 35058, 35043, 0.574, 11.612, 0.482 35059, 35088, 35073, 0.574, 10.916, 0.042 35089, 35118, 35103, 0.619, 12.002, -0.070 35119, 35148, 35133, 0.619, 11.492, 0.225 35149, 35178, 35163, 0.629, 10.980, -0.021 35179, 35208, 35193, 0.629, 10.634, -0.029 35209, 35238, 35223, 0.611, 11.207, -0.088 35239, 35268, 35253, 0.611, 10.937, 0.448 35269, 35298, 35283, 0.682, 10.667, -0.262 35300, 35329, 35314, 0.682, 13.843, -0.029 35330, 35359, 35344, 0.720, 11.896, 0.167 35360, 35389, 35374, 0.720, 13.054, 0.446 35390, 35419, 35404, 0.692, 14.220, -0.020 35420, 35449, 35434, 0.692, 17.054, -0.251 35450, 35479, 35464, 0.283, 18.197, -0.285 35480, 35509, 35494, 0.283, 17.314, -0.377 35510, 35539, 35524, 0.422, 16.431, -0.294 35540, 35569, 35554, 0.422, 16.738, -0.169 35570, 35599, 35584, 0.330, 15.981, -0.353 35600, 35629, 35614, 0.330, 14.179, 0.287 35630, 35659, 35644, 0.191, 12.401, -0.899 35660, 35689, 35674, 0.191, 10.044, 0.345 35690, 35719, 35704, 0.280, 16.008, -0.490 35720, 35749, 35734, 0.280, 15.712, 0.646 35750, 35779, 35764, 0.198, 15.417, 1.254 35780, 35809, 35794, 0.198, 17.986, 0.350 35810, 35839, 35824, 0.250, 22.814, 0.290 35840, 35869, 35854, 0.250, 21.465, 0.852 35870, 35899, 35884, 0.202, 20.116, 1.427 35901, 35930, 35915, 0.202, 17.988, 1.258 35931, 35960, 35945, 0.111, 19.512, 0.809 35961, 35990, 35975, 0.111, 23.765, 1.489 35991, 36020, 36005, 0.195, 28.019, 0.870 36021, 36050, 36035, 0.195, 26.849, 2.868 36051, 36080, 36065, 0.138, 26.496, 1.186 36081, 36110, 36095, 0.138, 29.905, 2.317 36111, 36140, 36125, 0.183, 33.336, 3.526 36141, 36170, 36155, 0.183, 35.818, 2.689 36171, 36200, 36185, 0.148, 30.963, 1.264 36201, 36230, 36215, 0.148, 26.368, 2.722 36231, 36260, 36245, 0.090, 21.804, 0.824 36261, 36290, 36275, 0.090, 26.818, 0.789 36291, 36320, 36305, 0.087, 27.633, -1.066 36321, 36350, 36335, 0.087, 29.841, -0.090 36449, 36478, 36463, 0.145, 39.215, -9999.000 36479, 36508, 36493, 0.145, 39.437, 2.267 36509, 36538, 36523, 0.133, 37.005, 1.058 36540, 36569, 36554, 0.133, 31.467, 0.205 36570, 36599, 36584, 0.094, 25.928, -9999.000 36600, 36629, 36614, 0.094, 26.301, -0.121 36630, 36659, 36644, 0.121, 28.597, 1.049 36660, 36689, 36674, 0.121, 24.935, 1.088 36690, 36719, 36704, 0.125, 21.261, 1.173 36720, 36749, 36734, 0.125, 25.001, 1.032 36750, 36779, 36764, 0.123, 23.840, 0.319 36780, 36809, 36794, 0.123, 29.918, 3.596 36810, 36839, 36824, 0.201, 36.038, 3.206 36840, 36869, 36854, 0.201, 30.801, 1.108 36870, 36899, 36884, 0.213, 29.545, 2.516 36900, 36929, 36914, 0.213, 29.064, 2.154 36930, 36959, 36944, 0.272, 28.584, 1.111 36960, 36989, 36974, 0.272, 33.102, 1.715 36990, 37019, 37004, 0.238, 27.117, 0.995 37020, 37049, 37034, 0.238, 22.301, 1.476 37050, 37079, 37064, 0.214, 17.485, 0.409 37080, 37109, 37094, 0.214, 18.902, 1.027 37110, 37139, 37124, 0.212, 18.707, 0.390 37141, 37170, 37155, 0.212, 19.740, 1.005 37171, 37200, 37185, 0.244, 20.773, 1.230 37201, 37230, 37215, 0.244, 17.840, 0.735 37231, 37260, 37245, 0.169, 16.849, 0.781 37261, 37290, 37275, 0.169, 14.716, 1.980 37291, 37320, 37305, 0.075, 12.569, 0.913 37321, 37350, 37335, 0.075, 13.765, 0.374 37351, 37380, 37365, 0.209, 18.428, 0.097 37381, 37410, 37395, 0.209, 15.269, 0.487 37411, 37440, 37425, 0.227, 12.130, 0.179 37441, 37470, 37455, 0.227, 11.647, 0.014 37471, 37500, 37485, 0.254, 10.742, 0.247 37501, 37530, 37515, 0.254, 13.028, 1.071 37531, 37560, 37545, 0.268, 15.299, -0.251 37561, 37590, 37575, 0.268, 14.409, 0.588 37591, 37620, 37605, 0.322, 16.743, -0.463 37621, 37650, 37635, 0.322, 17.562, -0.780 37651, 37680, 37665, 0.439, 18.379, 1.014 37682, 37711, 37696, 0.439, 19.638, 0.817 37712, 37741, 37726, 0.453, 21.053, 0.515 37742, 37771, 37756, 0.453, 19.106, 0.483 37772, 37801, 37786, 0.621, 17.159, -0.043 37802, 37831, 37816, 0.621, 18.539, 0.056 37832, 37861, 37846, 0.513, 16.603, 0.480 37862, 37891, 37876, 0.513, 15.836, 0.389 37892, 37921, 37906, 0.513, 15.069, -9999.000 38001, 38030, 38015, 0.585, 22.752, -9999.000 38032, 38061, 38046, 0.585, 23.687, -0.565 38062, 38091, 38076, 0.585, 23.531, 0.309 38092, 38121, 38106, 0.323, 23.375, -0.099 38122, 38151, 38136, 0.323, 21.806, 0.027 38152, 38181, 38166, 0.556, 20.654, -0.536 38182, 38211, 38196, 0.556, 18.684, -0.052 38212, 38241, 38226, 0.669, 16.714, 0.278 38242, 38271, 38256, 0.669, 16.930, -0.250 38272, 38301, 38286, 0.857, 18.459, -0.013 38302, 38331, 38316, 0.857, 19.334, -0.013 38332, 38361, 38346, 0.872, 20.205, 0.297 38362, 38391, 38376, 0.872, 24.932, 0.673 38392, 38421, 38406, 0.678, 26.514, -0.095 38422, 38451, 38436, 0.678, 24.673, 0.459 38452, 38481, 38466, 0.776, 22.832, -0.412 38482, 38511, 38496, 0.776, 25.641, 0.285 38512, 38541, 38526, 0.412, 29.475, 0.104 38542, 38571, 38556, 0.412, 27.489, 0.039 38572, 38601, 38586, 0.392, 25.504, 1.888 38602, 38631, 38616, 0.392, 28.275, 2.566 38633, 38662, 38647, 0.405, 29.349, 3.086 38663, 38692, 38677, 0.405, 28.445, 2.351 38693, 38722, 38707, 0.822, 27.541, 2.060 38723, 38752, 38737, 0.822, 28.289, 1.990 38753, 38782, 38767, 0.647, 31.136, 1.652 38783, 38812, 38797, 0.647, 30.025, 1.235 38813, 38842, 38827, 0.555, 28.921, 0.969 38843, 38872, 38857, 0.555, 26.968, 1.096 38873, 38902, 38887, 0.566, 28.170, 1.100 38903, 38932, 38917, 0.566, 26.840, 0.832 38933, 38962, 38947, 0.751, 25.518, 1.066 38963, 38992, 38977, 0.751, 29.728, 0.187 38993, 39022, 39007, 0.314, 32.152, 0.461 39023, 39052, 39037, 0.314, 31.395, 0.595 39053, 39082, 39067, 0.400, 30.639, 0.565 39083, 39112, 39097, 0.400, 25.122, 0.827 39114, 39143, 39128, 0.881, 27.262, 0.754 39144, 39173, 39158, 0.881, 26.788, -0.020 39174, 39203, 39188, 0.533, 26.315, 0.405 39204, 39233, 39218, 0.533, 28.373, 0.598 39234, 39263, 39248, 0.429, 28.221, 0.187 39264, 39293, 39278, 0.429, 27.060, 0.055 39294, 39323, 39308, 0.498, 25.894, -0.200 39324, 39353, 39338, 0.498, 28.217, 0.623 39354, 39383, 39368, 0.553, 29.555, 0.817 39384, 39413, 39398, 0.553, 27.243, 0.283 39414, 39443, 39428, 0.365, 24.915, 1.061 39444, 39473, 39458, 0.365, 24.407, 1.070 39474, 39503, 39488, 0.511, 17.684, -0.323 39504, 39533, 39518, 0.511, 19.404, 0.533 39534, 39563, 39548, 0.333, 21.124, 0.765 39564, 39593, 39578, 0.333, 22.278, 0.326 39594, 39623, 39608, 0.310, 22.937, -0.028 39624, 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