49, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2016, 08, 12, 2019, 05, 24 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 31 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom I: Science Flight #6 -- CHC - PUQ ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 35% (actually a multiplicative factor of 1/1.35 to 1.35), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R5 R5: Final Data (see OTHER_COMMENTS) R4: Final Data (see OTHER_COMMENTS) R3: Final Data (see OTHER_COMMENTS) R2: Final Data (see OTHER_COMMENTS) R1: Final Data R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 80113, 80142, 80128, -9999.000, -9999.000 80143, 80172, 80158, -9999.000, -9999.000 80173, 80202, 80188, -9999.000, -9999.000 80203, 80232, 80218, -9999.000, -9999.000 80234, 80263, 80249, -9999.000, 1.965 80264, 80293, 80279, -9999.000, 1.835 80294, 80323, 80309, -9999.000, -0.034 80324, 80353, 80339, -9999.000, 2.538 80354, 80383, 80369, -9999.000, 5.076 80384, 80413, 80399, -9999.000, 4.555 80414, 80443, 80429, -9999.000, -9999.000 80444, 80473, 80459, -9999.000, -9999.000 80474, 80503, 80489, -9999.000, 1.118 80504, 80533, 80519, -9999.000, 1.486 80534, 80563, 80549, -9999.000, 1.853 80564, 80593, 80579, 0.051, 2.222 80594, 80623, 80609, 0.051, 2.590 80624, 80653, 80639, 0.051, 4.476 80655, 80684, 80670, -0.000, 4.359 80684, 80713, 80699, 0.061, 3.771 80714, 80743, 80729, 0.061, 3.185 80745, 80774, 80760, 0.044, 2.959 80775, 80804, 80790, 0.044, 2.372 80805, 80834, 80820, 0.040, 2.207 80835, 80864, 80850, 0.040, 2.041 80865, 80894, 80880, 0.040, 2.311 80895, 80924, 80910, 0.032, 1.699 80925, 80954, 80940, 0.033, 1.991 80955, 80984, 80970, 0.033, 2.283 80985, 81014, 81000, 0.031, 1.881 81015, 81044, 81030, 0.031, 2.068 81045, 81074, 81060, 0.031, 2.291 81075, 81104, 81090, 0.018, 2.515 81105, 81134, 81120, 0.018, 2.207 81135, 81164, 81150, -0.002, 2.163 81165, 81194, 81180, -0.002, 2.204 81195, 81224, 81210, 0.050, 2.245 81226, 81255, 81241, 0.043, 3.091 81256, 81285, 81271, 0.043, 2.879 81286, 81315, 81301, 0.043, 2.325 81316, 81345, 81331, 0.077, 1.767 81346, 81375, 81361, 0.077, 4.402 81376, 81405, 81391, 0.068, 2.756 81406, 81435, 81421, 0.033, 3.016 81436, 81465, 81451, 0.033, 3.273 81466, 81495, 81481, 0.067, 3.132 81496, 81525, 81511, 0.067, 3.400 81526, 81555, 81541, 0.067, 3.183 81557, 81586, 81572, 0.043, 2.965 81587, 81616, 81602, 0.043, 2.798 81617, 81646, 81632, 0.064, 2.937 81647, 81676, 81662, 0.056, 2.839 81677, 81706, 81692, 0.056, 2.743 81707, 81736, 81722, 0.064, 3.004 81737, 81766, 81752, 0.064, 2.069 81767, 81796, 81782, 0.064, 1.890 81797, 81826, 81812, 0.070, 1.711 81827, 81856, 81842, 0.070, 2.610 81857, 81886, 81872, 0.071, 2.817 81887, 81916, 81902, 0.071, 2.465 81918, 81947, 81933, 0.046, 2.113 81948, 81977, 81963, 0.065, 2.745 81978, 82007, 81993, 0.065, 2.444 82008, 82037, 82023, 0.065, 2.448 82038, 82067, 82053, 0.070, 2.452 82068, 82097, 82083, 0.070, 2.138 82098, 82127, 82113, 0.054, 2.257 82128, 82157, 82143, 0.078, 2.358 82158, 82187, 82173, 0.078, 2.458 82188, 82217, 82203, 0.048, 2.701 82218, 82247, 82233, 0.048, 2.641 82248, 82277, 82263, 0.048, 2.901 82278, 82307, 82293, 0.070, 3.162 82308, 82337, 82323, 0.070, 2.579 82338, 82367, 82353, 0.040, 3.098 82369, 82398, 82384, 0.034, 2.906 82399, 82428, 82414, 0.034, 2.716 82429, 82458, 82444, 0.034, 3.178 82459, 82488, 82474, 0.055, 2.954 82489, 82518, 82504, 0.055, 2.624 82519, 82548, 82534, 0.032, 2.292 82549, 82578, 82564, 0.036, 2.727 82579, 82608, 82594, 0.036, 2.931 82609, 82638, 82624, 0.027, 3.185 82639, 82668, 82654, 0.027, 3.437 82669, 82698, 82684, 0.012, 3.493 82699, 82728, 82714, 0.012, 3.846 82729, 82758, 82744, 0.012, 3.057 82760, 82789, 82775, 0.038, 2.260 82789, 82818, 82804, 0.038, 3.501 82819, 82848, 82834, 0.035, 2.961 82850, 82879, 82865, 0.009, 3.081 82880, 82909, 82895, 0.009, 3.200 82910, 82939, 82925, 0.009, 4.968 82940, 82969, 82955, -0.002, 3.912 82970, 82999, 82985, -0.002, 4.200 83000, 83029, 83015, 0.048, 4.489 83030, 83059, 83045, 0.041, 3.943 83060, 83089, 83075, 0.041, 4.595 83090, 83119, 83105, 0.058, 5.050 83120, 83149, 83135, 0.058, 5.502 83150, 83179, 83165, 0.058, 6.324 83181, 83210, 83196, 0.024, 5.311 83211, 83240, 83226, 0.024, 4.718 83241, 83270, 83256, 0.024, 4.125 83271, 83300, 83286, 0.036, 4.336 83301, 83330, 83316, 0.036, 5.288 83331, 83360, 83346, 0.036, 4.160 83361, 83390, 83376, 0.045, 3.032 83501, 83530, 83516, 0.009, 4.662 83531, 83560, 83546, 0.009, 3.742 83561, 83590, 83576, 0.009, 3.604 83591, 83620, 83606, 0.048, 3.467 83621, 83650, 83636, 0.013, 3.805 83651, 83680, 83666, 0.013, 4.678 83681, 83710, 83696, -9999.000, -9999.000 83711, 83740, 83726, -9999.000, -9999.000 83741, 83770, 83756, -9999.000, -9999.000 83772, 83801, 83787, -9999.000, -9999.000 83802, 83831, 83817, -9999.000, -9999.000 83832, 83861, 83847, -9999.000, -9999.000 83862, 83891, 83877, -9999.000, -9999.000 83892, 83921, 83907, -9999.000, -9999.000 83922, 83951, 83937, -9999.000, -9999.000 83952, 83981, 83967, -9999.000, -9999.000 83982, 84011, 83997, -9999.000, -9999.000 84012, 84041, 84027, -9999.000, -9999.000 84042, 84071, 84057, -9999.000, -9999.000 84072, 84101, 84087, -9999.000, -9999.000 84102, 84131, 84117, -9999.000, -9999.000 84132, 84161, 84147, -9999.000, -9999.000 84163, 84192, 84178, -9999.000, -9999.000 84193, 84222, 84208, -9999.000, -9999.000 84223, 84252, 84238, -9999.000, -9999.000 84253, 84282, 84268, -9999.000, -9999.000 84283, 84312, 84298, -9999.000, -9999.000 84313, 84342, 84328, -9999.000, -9999.000 84343, 84372, 84358, -9999.000, -9999.000 84373, 84402, 84388, -9999.000, -9999.000 84403, 84432, 84418, -9999.000, -9999.000 84433, 84462, 84448, -9999.000, -9999.000 84463, 84492, 84478, -9999.000, -9999.000 84493, 84522, 84508, -9999.000, -9999.000 84523, 84552, 84538, -9999.000, -9999.000 84553, 84582, 84568, -9999.000, -9999.000 84583, 84612, 84598, -9999.000, -9999.000 84613, 84642, 84628, -9999.000, -9999.000 84644, 84673, 84659, -9999.000, -9999.000 84674, 84703, 84689, -9999.000, -9999.000 84704, 84733, 84719, -9999.000, -9999.000 84734, 84763, 84749, -9999.000, -9999.000 84764, 84793, 84779, -9999.000, -9999.000 84794, 84823, 84809, -9999.000, -9999.000 84824, 84853, 84839, -9999.000, -9999.000 84854, 84883, 84869, -9999.000, -9999.000 84884, 84913, 84899, -9999.000, -9999.000 84914, 84943, 84929, -9999.000, -9999.000 84944, 84973, 84959, -9999.000, -9999.000 84974, 85003, 84989, -9999.000, -9999.000 85004, 85033, 85019, -9999.000, -9999.000 85034, 85063, 85049, -9999.000, -9999.000 85065, 85094, 85080, 0.029, 4.706 85095, 85124, 85110, 0.029, 4.128 85125, 85154, 85140, 0.029, 3.935 85155, 85184, 85170, 0.046, 3.741 85185, 85214, 85200, 0.046, 3.969 85215, 85244, 85230, 0.052, 4.109 85245, 85274, 85260, 0.026, 3.841 85275, 85304, 85290, 0.026, 3.574 85305, 85334, 85320, 0.052, 4.295 85335, 85364, 85350, 0.052, 4.244 85365, 85394, 85380, 0.052, 4.255 85395, 85424, 85410, 0.032, 4.265 85425, 85454, 85440, 0.032, 4.780 85456, 85485, 85471, 0.047, 4.251 85486, 85515, 85501, 0.042, 4.166 85516, 85545, 85531, 0.042, 4.082 85546, 85575, 85561, 0.042, 3.858 85576, 85605, 85591, 0.035, 3.523 85606, 85635, 85621, 0.035, 3.623 85636, 85665, 85651, 0.061, 3.723 85666, 85695, 85681, 0.038, 3.763 85696, 85725, 85711, 0.038, 3.918 85726, 85755, 85741, 0.048, 3.617 85756, 85785, 85771, 0.048, 3.318 85787, 85816, 85802, 0.033, 3.150 85817, 85846, 85832, 0.033, 3.632 85846, 85875, 85861, 0.033, 3.767 85877, 85906, 85892, 0.019, 3.903 85907, 85936, 85922, 0.042, 3.928 85937, 85966, 85952, 0.042, 4.698 85967, 85996, 85982, 0.023, 4.105 85997, 86026, 86012, 0.023, 3.516 86027, 86056, 86042, 0.023, 2.296 86057, 86086, 86072, 0.001, 2.252 86087, 86116, 86102, 0.001, 2.168 86117, 86146, 86132, 0.029, 2.085 86147, 86176, 86162, 0.048, 2.931 86177, 86206, 86192, 0.048, 2.524 86207, 86236, 86222, 0.045, 3.083 86238, 86267, 86253, 0.045, 3.642 86268, 86297, 86283, 0.045, 4.886 86298, 86327, 86313, -0.005, 3.954 86328, 86357, 86343, -0.005, 3.426 86358, 86387, 86373, -0.022, 2.897 86388, 86417, 86403, 0.020, 3.033 86418, 86447, 86433, 0.020, 2.407 86448, 86477, 86463, 0.047, 2.342 86478, 86507, 86493, 0.047, 2.278 86508, 86537, 86523, 0.047, 1.635 86538, 86567, 86553, -0.008, 2.667 86568, 86597, 86583, 0.016, 2.135 86598, 86627, 86613, 0.016, 1.604 86628, 86657, 86643, 0.016, 1.826 86659, 86688, 86674, -0.001, 2.631 86689, 86718, 86704, -0.001, 2.598 86719, 86748, 86734, 0.020, 2.565 86749, 86778, 86764, 0.020, 2.003 86779, 86808, 86794, 0.011, 1.729 86809, 86838, 86824, -9999.000, -9999.000 86839, 86868, 86854, -9999.000, -9999.000 86869, 86898, 86884, -9999.000, -9999.000 86899, 86928, 86914, -9999.000, 3.990 86929, 86958, 86944, -9999.000, 3.301 86959, 86988, 86974, 0.048, 2.605 86989, 87018, 87004, 0.028, 2.546 87019, 87048, 87034, 0.028, 2.662 87049, 87078, 87064, 0.050, 2.524 87079, 87108, 87094, 0.050, 2.387 87109, 87138, 87124, 0.050, 3.537 87140, 87169, 87155, 0.050, 4.987 87170, 87199, 87185, 0.050, 5.258 87200, 87229, 87215, 0.059, 5.532 87230, 87259, 87245, 0.038, 4.447 87260, 87289, 87275, 0.038, 4.404 87290, 87319, 87305, 0.031, 4.184 87320, 87349, 87335, 0.031, 3.965 87350, 87379, 87365, 0.012, 3.342 87380, 87409, 87395, 0.012, 3.010 87410, 87439, 87425, 0.012, 3.046 87441, 87470, 87456, 0.023, 3.082 87471, 87500, 87486, 0.023, 4.208 87501, 87530, 87516, 0.030, 4.267 87531, 87560, 87546, 0.005, 4.129 87561, 87590, 87576, 0.005, 3.992 87591, 87620, 87606, 0.020, 3.925 87621, 87650, 87636, 0.020, 3.991 87651, 87680, 87666, 0.020, 3.862 87681, 87710, 87696, 0.027, 3.733 87711, 87740, 87726, 0.019, 4.442 87741, 87770, 87756, 0.019, 3.768 87771, 87800, 87786, 0.030, 3.832 87801, 87830, 87816, 0.030, 3.897 87831, 87860, 87846, 0.030, 4.235 87862, 87891, 87877, 0.043, 4.207 87892, 87921, 87907, 0.043, 4.211 87922, 87951, 87937, 0.056, 4.215 87952, 87981, 87967, 0.067, 4.419 87982, 88011, 87997, 0.067, 3.443 88012, 88041, 88027, 0.049, 3.686 88042, 88071, 88057, 0.049, 3.929 88072, 88101, 88087, 0.049, 4.055 88102, 88131, 88117, 0.039, 3.579 88132, 88161, 88147, 0.039, 3.663 88162, 88191, 88177, 0.030, 3.746 88192, 88221, 88207, 0.043, 4.259 88222, 88251, 88237, 0.043, 4.170 88252, 88281, 88267, 0.061, 3.914 88283, 88312, 88298, 0.061, 3.658 88313, 88342, 88328, 0.061, 3.568 88343, 88372, 88358, 0.055, 4.855 88373, 88402, 88388, 0.025, 4.422 88403, 88432, 88418, 0.025, 3.990 88433, 88462, 88448, 0.029, 3.596 88463, 88492, 88478, 0.029, 4.479 88493, 88522, 88508, 0.029, 4.159 88523, 88552, 88538, 0.046, 3.839 88553, 88582, 88568, 0.046, 3.683 88583, 88612, 88598, 0.043, 3.907 88613, 88642, 88628, 0.041, 3.941 88643, 88672, 88658, 0.041, 3.976 88673, 88702, 88688, 0.041, 3.962 88704, 88733, 88719, 0.037, 4.405 88734, 88763, 88749, 0.037, 4.140 88764, 88793, 88779, 0.056, 3.874 88794, 88823, 88809, 0.056, 4.659 88824, 88853, 88839, 0.039, 3.861 88854, 88883, 88869, 0.039, 3.514 88884, 88913, 88899, 0.039, 3.170 88914, 88943, 88929, 0.051, 3.658 88944, 88973, 88959, 0.051, 3.681 88974, 89003, 88989, 0.051, 3.508 89004, 89033, 89019, 0.036, 3.335 89034, 89063, 89049, 0.036, 4.027 89064, 89093, 89079, 0.037, 3.528 89095, 89124, 89110, 0.075, 3.276 89125, 89154, 89140, 0.075, 3.024 89155, 89184, 89170, 0.055, 3.531 89185, 89214, 89200, 0.055, 3.774 89215, 89244, 89230, 0.055, 3.493 89245, 89274, 89260, 0.065, 3.212 89275, 89304, 89290, 0.065, 3.336 89305, 89334, 89320, 0.063, 3.521 89335, 89364, 89350, 0.063, 3.147 89365, 89394, 89380, 0.036, 2.773 89395, 89424, 89410, 0.046, 2.793 89425, 89454, 89440, 0.046, 2.778 89455, 89484, 89470, 0.046, 2.711 89486, 89515, 89501, 0.056, 2.643 89516, 89545, 89531, 0.056, 3.513 89546, 89575, 89561, 0.052, 2.827 89576, 89605, 89591, 0.028, 2.589 89606, 89635, 89621, 0.028, 2.352 89636, 89665, 89651, 0.028, 2.857 89666, 89695, 89681, 0.014, 3.409 89696, 89725, 89711, 0.014, 2.847 89726, 89755, 89741, 0.016, 2.280 89756, 89785, 89771, 0.016, 3.050 89786, 89815, 89801, 0.026, 2.557 89816, 89845, 89831, 0.026, 2.356 89846, 89875, 89861, 0.026, 2.156 89876, 89905, 89891, 0.019, 2.142 89907, 89936, 89922, 0.019, 2.472 89937, 89966, 89952, 0.019, 2.265 89967, 89996, 89982, 0.006, 2.057 89997, 90026, 90012, 0.020, 1.917 90027, 90056, 90042, 0.020, 2.576 90057, 90086, 90072, 0.022, 2.300 90087, 90116, 90102, 0.022, 2.026 90117, 90146, 90132, 0.022, 2.373 90147, 90176, 90162, -0.005, 2.107 90177, 90206, 90192, -0.005, 1.874 90207, 90236, 90222, 0.014, 1.640 90237, 90266, 90252, 0.014, 2.237 90267, 90296, 90282, 0.021, 1.418 90298, 90327, 90313, -0.018, 1.325 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