43, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor based on LIF ATom 1, 1 2016, 08, 12, 2018, 02, 16 0 Start_UTC, seconds, seconds since takeoff's midnight UTC 5 1, 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since takeoff's midnight UTC Mid_UTC, seconds, seconds since takeoff's midnight UTC OH_pptv, pptv, OH mixing ratio in pptv HO2_pptv, pptv, HO2 mixing ratio in pptv OHR_Hz, Hz, OH reactivity in Hz 0 24 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom I: Science Flight #6 -- CHC - PUQ ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 with Laser Induced Fluorescence; OH reactivity with discharge flow DATA_INFO: Units are pptv for OH and HO2; Hz for OHR. UNCERTAINTY: Normaly HOx absolute accuracy is estimated to be +/- 32% at two sigma confidence. Please see comments below. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. ATHOS is calibrated with the new OH scavenging inlet. Differences with previous version due to improved calibration methods. OH & HO2 uncertainty ~1.32, 2 sigma confidence. Data in dense clouds is noisy, and is removed. OHR uncertainty estimated to be 15%, 2 sigma confidence, with 0.3 s^-1 zero uncertainty. OHR correction for NO works for conditions up to ambient NO ~20 ppbv; data are not recoverd for some low altitudes. REVISION: R2 R2: Final Data (see OTHER_COMMENTS) R1: Final Data R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_pptv, HO2_pptv, OHR_Hz 80144, 80173, 80158, -9999.000, -9999.000, 0.845 80204, 80233, 80218, -9999.000, -9999.000, 2.842 80235, 80264, 80249, -9999.000, -9999.000, 1.541 80265, 80294, 80279, -9999.000, -9999.000, 2.782 80295, 80324, 80309, -9999.000, -9999.000, 2.669 80325, 80354, 80339, -9999.000, -9999.000, 4.186 80355, 80384, 80369, -9999.000, -9999.000, 1.890 80385, 80414, 80399, -9999.000, -9999.000, 1.739 80415, 80444, 80429, -9999.000, -9999.000, 1.618 80445, 80474, 80459, -9999.000, -9999.000, 1.972 80505, 80534, 80519, -9999.000, -9999.000, 0.102 80535, 80564, 80549, 0.043, -9999.000, 2.399 80565, 80594, 80579, 0.043, -9999.000, 1.730 80595, 80624, 80609, 0.063, 2.430, 1.106 80625, 80654, 80639, 0.063, 4.059, 0.859 80656, 80685, 80670, 0.090, 3.382, 2.288 80685, 80714, 80699, 0.090, 3.139, 1.011 80715, 80744, 80729, 0.095, 2.896, 1.099 80746, 80775, 80760, 0.095, 2.869, 2.433 80776, 80805, 80790, 0.038, 2.168, 1.991 80806, 80835, 80820, 0.038, 2.019, 1.201 80836, 80865, 80850, 0.030, 1.870, 0.847 80866, 80895, 80880, 0.030, 2.086, 1.386 80896, 80925, 80910, 0.051, 1.572, 0.521 80926, 80955, 80940, 0.051, 1.808, 1.719 80956, 80985, 80970, 0.037, 2.043, 0.849 80986, 81015, 81000, 0.037, 1.711, 1.460 81016, 81045, 81030, 0.028, 2.368, 1.273 81046, 81075, 81060, -9999.000, -9999.000, 1.349 81076, 81105, 81090, 0.037, 2.304, 0.467 81106, 81135, 81120, 0.037, 2.794, 1.067 81136, 81165, 81150, 0.045, 1.925, 1.774 81166, 81195, 81180, 0.045, 1.963, 0.923 81196, 81225, 81210, 0.057, 2.002, 0.698 81227, 81256, 81241, 0.057, 2.715, 0.805 81257, 81286, 81271, -0.032, 2.253, 0.851 81287, 81316, 81301, -9999.000, -9999.000, 1.851 81317, 81346, 81331, -9999.000, -9999.000, 1.998 81377, 81406, 81391, 0.024, 2.557, 1.302 81407, 81436, 81421, 0.024, 2.724, 0.801 81437, 81466, 81451, 0.045, 2.890, 1.935 81467, 81496, 81481, 0.045, 2.732, 1.167 81497, 81526, 81511, 0.105, 2.950, 0.607 81527, 81556, 81541, 0.105, 2.762, 1.028 81558, 81587, 81572, 0.053, 2.573, -9999.000 81588, 81617, 81602, 0.053, 2.432, 0.925 81618, 81647, 81632, 0.081, 2.556, 0.648 81648, 81677, 81662, 0.081, 2.481, 0.687 81678, 81707, 81692, 0.069, 2.407, 1.337 81708, 81737, 81722, 0.069, 2.578, 0.867 81738, 81767, 81752, 0.091, 1.837, -9999.000 81768, 81797, 81782, 0.091, 1.684, 1.105 81798, 81827, 81812, 0.080, 1.530, 0.426 81828, 81857, 81842, 0.080, 2.284, 1.306 81858, 81887, 81872, 0.082, 2.444, 0.885 81888, 81917, 81902, 0.082, 2.150, 0.584 81919, 81948, 81933, 0.059, 1.856, 0.800 81949, 81978, 81963, 0.059, 2.378, 0.838 81979, 82008, 81993, 0.104, 2.134, -9999.000 82009, 82038, 82023, 0.104, 2.139, -9999.000 82039, 82068, 82053, 0.075, 2.144, 0.735 82069, 82098, 82083, 0.075, 1.893, 0.556 82099, 82128, 82113, 0.078, 2.000, 0.886 82129, 82158, 82143, 0.078, 2.072, 1.353 82159, 82188, 82173, 0.090, 2.144, -9999.000 82189, 82218, 82203, 0.090, 2.332, 1.130 82219, 82248, 82233, 0.054, 2.292, 1.187 82249, 82278, 82263, 0.054, 2.524, 0.430 82279, 82308, 82293, 0.102, 2.758, -9999.000 82309, 82338, 82323, 0.102, 2.254, -9999.000 82339, 82368, 82353, 0.016, 2.698, -9999.000 82370, 82399, 82384, 0.016, 2.547, 1.231 82400, 82429, 82414, 0.058, 2.397, 0.380 82430, 82459, 82444, 0.058, 2.787, 0.418 82460, 82489, 82474, 0.058, 2.617, 0.845 82490, 82519, 82504, 0.058, 2.350, 0.879 82520, 82549, 82534, 0.039, 2.082, -9999.000 82550, 82579, 82564, 0.039, 2.436, -0.327 82580, 82609, 82594, 0.052, 2.641, 1.037 82610, 82639, 82624, 0.052, 2.855, -9999.000 82640, 82669, 82654, 0.028, 3.068, 0.774 82670, 82699, 82684, 0.028, 3.161, 0.329 82700, 82729, 82714, 0.004, 3.470, 0.750 82730, 82759, 82744, 0.004, 2.804, -9999.000 82761, 82790, 82775, 0.056, 2.131, 0.756 82790, 82819, 82804, 0.056, 3.231, 0.301 82820, 82849, 82834, 0.041, 2.760, 1.099 82851, 82880, 82865, 0.041, 2.884, 0.657 82881, 82910, 82895, -0.003, 3.007, -9999.000 82911, 82940, 82925, -0.003, 4.614, 0.743 82941, 82970, 82955, 0.009, 3.703, 0.683 82971, 83000, 82985, 0.009, 3.960, 1.292 83001, 83030, 83015, 0.052, 4.219, 1.239 83031, 83060, 83045, 0.052, 3.761, 3.524 83061, 83090, 83075, 0.049, 4.354, -9999.000 83091, 83120, 83105, 0.049, 4.802, 0.242 83121, 83150, 83135, 0.067, 5.246, 1.946 83151, 83180, 83165, 0.067, 6.023, 1.069 83182, 83211, 83196, 0.021, 5.102, 1.338 83212, 83241, 83226, -9999.000, 4.551, 3.382 83242, 83271, 83256, -9999.000, 4.001, 3.055 83272, 83301, 83286, -9999.000, 4.204, 2.168 83302, 83331, 83316, -9999.000, 5.122, 2.487 83332, 83361, 83346, -9999.000, 4.075, 1.848 83362, 83391, 83376, -9999.000, -9999.000, 0.809 83502, 83531, 83516, -9999.000, 4.484, -9999.000 83532, 83561, 83546, -9999.000, 3.641, 1.612 83562, 83591, 83576, -9999.000, 3.518, 1.995 83592, 83621, 83606, -9999.000, 3.396, 0.611 83622, 83651, 83636, -9999.000, 3.682, 2.262 83652, 83681, 83666, -9999.000, -9999.000, 2.136 83682, 83711, 83696, -9999.000, -9999.000, 1.891 83742, 83771, 83756, -9999.000, -9999.000, 2.078 83773, 83802, 83787, -9999.000, -9999.000, 1.271 83803, 83832, 83817, -9999.000, -9999.000, 0.646 83833, 83862, 83847, -9999.000, -9999.000, 0.576 83863, 83892, 83877, -9999.000, -9999.000, 2.723 83893, 83922, 83907, -9999.000, -9999.000, 1.568 83923, 83952, 83937, -9999.000, -9999.000, 2.030 83953, 83982, 83967, -9999.000, -9999.000, 0.909 83983, 84012, 83997, -9999.000, -9999.000, 0.902 84013, 84042, 84027, -9999.000, -9999.000, 1.221 84043, 84072, 84057, -9999.000, -9999.000, 0.498 84073, 84102, 84087, -9999.000, -9999.000, 1.115 84103, 84132, 84117, -9999.000, -9999.000, 0.227 84133, 84162, 84147, -9999.000, -9999.000, 0.385 84164, 84193, 84178, -9999.000, -9999.000, 0.736 84194, 84223, 84208, -9999.000, -9999.000, 1.102 84224, 84253, 84238, -9999.000, -9999.000, 0.426 84254, 84283, 84268, -9999.000, -9999.000, 0.958 84284, 84313, 84298, -9999.000, -9999.000, 1.691 84314, 84343, 84328, -9999.000, -9999.000, 0.797 84344, 84373, 84358, -9999.000, -9999.000, 0.279 84374, 84403, 84388, -9999.000, -9999.000, -0.052 84434, 84463, 84448, -9999.000, -9999.000, 1.495 84464, 84493, 84478, -9999.000, -9999.000, 1.267 84494, 84523, 84508, -9999.000, -9999.000, 0.616 84524, 84553, 84538, -9999.000, -9999.000, 1.705 84554, 84583, 84568, -9999.000, -9999.000, 1.385 84584, 84613, 84598, -9999.000, -9999.000, 0.267 84614, 84643, 84628, -9999.000, -9999.000, 1.059 84645, 84674, 84659, -9999.000, -9999.000, 0.745 84675, 84704, 84689, -9999.000, -9999.000, 0.393 84705, 84734, 84719, -9999.000, -9999.000, 0.396 84735, 84764, 84749, -9999.000, -9999.000, 0.805 84765, 84794, 84779, -9999.000, -9999.000, 0.370 84795, 84824, 84809, -9999.000, -9999.000, 0.663 84855, 84884, 84869, -9999.000, -9999.000, 0.024 84885, 84914, 84899, -9999.000, -9999.000, 1.174 84915, 84944, 84929, -9999.000, -9999.000, 0.770 84945, 84974, 84959, -9999.000, -9999.000, -0.087 84975, 85004, 84989, -9999.000, -9999.000, 0.177 85005, 85034, 85019, -9999.000, -9999.000, 1.329 85035, 85064, 85049, -9999.000, -9999.000, 0.362 85066, 85095, 85080, -9999.000, 3.964, 0.558 85096, 85125, 85110, 0.034, 3.529, 0.172 85126, 85155, 85140, 0.034, 3.361, 0.896 85156, 85185, 85170, 0.079, 3.192, 0.241 85186, 85215, 85200, 0.079, 3.367, 0.416 85216, 85245, 85230, 0.047, 3.472, 0.747 85246, 85275, 85260, 0.047, 3.257, 0.602 85276, 85305, 85290, 0.044, 3.042, -9999.000 85306, 85335, 85320, 0.044, 3.625, 0.688 85336, 85365, 85350, 0.062, 3.588, 0.421 85366, 85395, 85380, 0.062, 3.610, 0.235 85396, 85425, 85410, 0.028, 3.633, 1.268 85426, 85455, 85440, 0.028, 4.034, 0.392 85457, 85486, 85471, 0.070, 3.622, 0.138 85487, 85516, 85501, 0.070, 3.537, 0.175 85517, 85546, 85531, 0.042, 3.453, 0.699 85547, 85576, 85561, 0.042, 3.307, 0.650 85577, 85606, 85591, 0.058, 3.019, 0.309 85607, 85636, 85621, 0.058, 3.112, 0.450 85637, 85666, 85651, 0.073, 3.204, 0.455 85667, 85696, 85681, 0.073, 3.240, 0.248 85697, 85726, 85711, 0.035, 3.377, 0.188 85727, 85756, 85741, 0.035, 3.150, 0.194 85757, 85786, 85771, 0.065, 2.924, 0.215 85788, 85817, 85802, 0.065, 2.749, 0.934 85818, 85847, 85832, 0.024, 3.186, 0.713 85847, 85876, 85861, 0.024, 3.304, 0.501 85878, 85907, 85892, 0.050, 3.423, 0.486 85908, 85937, 85922, 0.050, 3.484, 0.954 85938, 85967, 85952, 0.045, 4.135, 0.518 85968, 85997, 85982, 0.045, 3.654, 0.367 85998, 86027, 86012, 0.018, 3.177, -9999.000 86028, 86057, 86042, 0.018, 2.123, 0.832 86058, 86087, 86072, -0.029, 2.117, -9999.000 86088, 86117, 86102, -0.029, 2.045, -9999.000 86118, 86147, 86132, 0.055, 1.974, 0.602 86148, 86177, 86162, 0.055, 2.695, -9999.000 86178, 86207, 86192, 0.055, 2.348, 1.119 86208, 86237, 86222, 0.055, 2.856, 1.610 86239, 86268, 86253, 0.050, 3.364, 2.883 86269, 86298, 86283, 0.050, 4.554, -9999.000 86299, 86328, 86313, -9999.000, 5.078, -9999.000 86329, 86358, 86343, -9999.000, 3.924, -9999.000 86359, 86388, 86373, -0.020, 2.769, 1.244 86389, 86418, 86403, -0.020, 2.907, 1.611 86419, 86448, 86433, 0.047, 2.340, -9999.000 86449, 86478, 86463, 0.047, 2.309, 1.218 86479, 86508, 86493, 0.046, 2.277, 1.062 86509, 86538, 86523, 0.046, 1.644, -0.059 86539, 86568, 86553, -0.018, 2.590, 0.360 86569, 86598, 86583, -0.018, 2.101, 1.856 86599, 86628, 86613, 0.018, 1.612, 1.048 86629, 86658, 86643, 0.018, 1.815, 0.427 86660, 86689, 86674, -0.007, 2.523, 0.379 86690, 86719, 86704, -0.007, 2.515, 0.383 86720, 86749, 86734, 0.028, 2.507, 1.152 86750, 86779, 86764, 0.028, 1.985, 2.229 86810, 86839, 86824, -9999.000, -9999.000, 1.253 86840, 86869, 86854, -9999.000, -9999.000, 1.152 86870, 86899, 86884, -9999.000, -9999.000, 1.563 86900, 86929, 86914, 0.030, 3.683, 2.811 86930, 86959, 86944, 0.030, 3.084, 1.942 86960, 86989, 86974, 0.056, 2.480, 1.242 86990, 87019, 87004, 0.056, 2.388, 1.243 87020, 87049, 87034, 0.019, 2.494, 0.683 87050, 87079, 87064, 0.019, 2.370, 1.809 87080, 87109, 87094, 0.062, 2.247, 1.033 87110, 87139, 87124, 0.062, 3.237, 0.133 87141, 87170, 87155, 0.078, 4.505, 1.487 87171, 87200, 87185, 0.078, 4.717, 0.281 87201, 87230, 87215, 0.066, 4.931, -9999.000 87231, 87260, 87245, 0.066, 3.984, 0.806 87261, 87290, 87275, 0.038, 3.923, -0.008 87291, 87320, 87305, 0.038, 3.729, 0.032 87321, 87350, 87335, 0.012, 3.535, 0.403 87351, 87380, 87365, 0.012, 2.999, -9999.000 87381, 87410, 87395, 0.022, 2.697, 1.699 87411, 87440, 87425, 0.022, 2.717, 0.963 87442, 87471, 87456, 0.037, 2.736, -0.004 87472, 87501, 87486, 0.037, 3.654, 0.912 87502, 87531, 87516, 0.038, 3.676, -0.097 87532, 87561, 87546, 0.038, 3.554, 0.760 87562, 87591, 87576, -0.002, 3.433, 0.720 87592, 87621, 87606, -0.002, 3.404, 0.526 87622, 87651, 87636, 0.037, 3.461, -9999.000 87652, 87681, 87666, 0.037, 3.347, 0.830 87682, 87711, 87696, 0.027, 3.232, 0.724 87712, 87741, 87726, 0.027, 3.804, 0.394 87742, 87771, 87756, 0.038, 3.221, -0.038 87772, 87801, 87786, 0.038, 3.282, 0.504 87802, 87831, 87816, 0.031, 3.344, 0.411 87832, 87861, 87846, 0.031, 3.641, 0.156 87863, 87892, 87877, 0.060, 3.614, 0.460 87893, 87922, 87907, 0.060, 3.597, 0.179 87923, 87952, 87937, 0.085, 3.580, 0.824 87953, 87982, 87967, 0.085, 3.764, 0.867 87983, 88012, 87997, 0.074, 2.995, 0.713 88013, 88042, 88027, 0.074, 3.181, 0.215 88043, 88072, 88057, 0.046, 3.367, 0.391 88073, 88102, 88087, 0.046, 3.444, -9999.000 88103, 88132, 88117, 0.048, 3.054, 0.486 88133, 88162, 88147, 0.048, 3.109, 0.556 88163, 88192, 88177, 0.044, 3.164, -9999.000 88193, 88222, 88207, 0.044, 3.591, 0.292 88223, 88252, 88237, 0.054, 3.492, -9999.000 88253, 88282, 88267, 0.054, 3.305, -9999.000 88284, 88313, 88298, 0.080, 3.118, -9999.000 88314, 88343, 88328, 0.080, 3.032, 0.202 88344, 88373, 88358, 0.075, 4.113, -9999.000 88374, 88403, 88388, 0.075, 3.750, 1.656 88404, 88433, 88418, 0.009, 3.388, 0.364 88434, 88463, 88448, 0.009, 3.055, 0.018 88464, 88493, 88478, 0.035, 3.798, -9999.000 88494, 88523, 88508, 0.035, 3.534, 0.855 88524, 88553, 88538, 0.077, 3.271, 1.311 88554, 88583, 88568, 0.077, 3.136, 0.423 88584, 88613, 88598, 0.055, 3.303, 0.995 88614, 88643, 88628, 0.055, 3.328, 0.646 88644, 88673, 88658, 0.050, 3.354, 0.821 88674, 88703, 88688, 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