41, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor based on LIF ATom 1, 1 2016, 08, 08, 2017, 06, 06 0 Start_UTC, seconds, seconds since takeoff's midnight UTC 5 1, 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since takeoff's midnight UTC Mid_UTC, seconds, seconds since takeoff's midnight UTC OH_pptv, pptv, OH mixing ratio in pptv HO2_pptv, pptv, HO2 mixing ratio in pptv OHR_Hz, Hz, OH reactivity in Hz 0 22 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom I: Science Flight #5 -- PPG - CHC ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 with Laser Induced Fluorescence; OH reactivity with discharge flow DATA_INFO: Units are pptv for OH and HO2; Hz for OHR. UNCERTAINTY: Normaly HOx absolute accuracy is estimated to be +/- 32% at two sigma confidence. Please see comments below. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Semi-Final Data. Calibrating ATHOS with the new OH scavenging inlet is proving to be difficult. Until we complete more tests, OH uncertainty above 6 km estimated to be a factor of 2, 2 sigma confidence HO2 uncertainty for all altitudes estimated to be a factor of 1.6, 2 sigma confidence. OHR uncertainty estimated to be 15%, 2 sigma confidence, with 0.3 s^-1 zero uncertainty. OHR correction for NO appears to work for conditions with ambient NO<=~5 ppbv; OHR data are not reported for higher NO conditions. REVISION: R1 R1: Final Data Start_UTC, Stop_UTC, Mid_UTC, OH_pptv, HO2_pptv, OHR_Hz 70509, 70538, 70523, -9999.000, 10.707, -0.744 70539, 70568, 70553, -9999.000, 11.266, 3.049 70569, 70598, 70583, -9999.000, 17.976, 0.810 70599, 70628, 70613, 0.100, 17.546, 0.641 70629, 70658, 70643, 0.100, 17.115, 3.340 70659, 70688, 70673, 0.104, 16.366, 1.808 70689, 70718, 70703, 0.104, 16.210, 4.151 70719, 70748, 70733, 0.095, 14.328, 1.319 70749, 70778, 70763, 0.095, 12.434, 0.753 70779, 70808, 70793, 0.062, 10.541, 0.357 70809, 70838, 70823, 0.062, 10.014, 1.218 70839, 70868, 70853, 0.066, 9.185, 1.800 70869, 70898, 70883, 0.066, 8.355, 1.341 70899, 70928, 70913, 0.090, 7.528, 1.078 70929, 70958, 70943, 0.090, 6.702, 2.595 70959, 70988, 70973, 0.076, 5.875, 3.943 70989, 71018, 71003, 0.076, 5.043, 1.737 71019, 71048, 71033, 0.101, 5.638, 1.476 71049, 71078, 71063, 0.101, 8.159, 1.564 71079, 71108, 71093, 0.128, 8.536, 1.287 71109, 71138, 71123, 0.128, 8.918, 2.631 71139, 71168, 71153, 0.123, 9.354, 1.900 71169, 71198, 71183, 0.123, 8.538, 0.386 71200, 71229, 71214, 0.127, 8.036, 1.118 71230, 71259, 71244, 0.127, 7.536, 1.178 71260, 71289, 71274, 0.132, 8.381, 1.474 71290, 71319, 71304, 0.132, 8.546, 1.644 71320, 71349, 71334, 0.144, 8.759, 1.305 71350, 71379, 71364, 0.144, 8.971, 0.848 71380, 71409, 71394, 0.223, 9.758, 1.484 71410, 71439, 71424, 0.223, 10.776, 1.546 71440, 71469, 71454, 0.106, 9.315, 1.493 71470, 71499, 71484, 0.106, 7.860, 1.092 71500, 71529, 71514, 0.251, 11.525, 1.276 71530, 71559, 71544, 0.251, 11.989, 0.589 71560, 71589, 71574, 0.202, 10.931, 1.304 71590, 71619, 71604, 0.202, 9.881, 1.024 71620, 71649, 71634, 0.204, 7.031, 1.161 71650, 71679, 71664, 0.204, 7.171, 1.490 71680, 71709, 71694, 0.224, 7.905, 1.285 71710, 71739, 71724, 0.224, 8.639, 1.051 71740, 71769, 71754, 0.174, 10.723, 1.150 71771, 71800, 71785, 0.174, 9.850, 1.110 71801, 71830, 71815, 0.280, 10.039, 1.033 71831, 71860, 71845, 0.280, 10.228, 1.118 71861, 71890, 71875, 0.232, 12.446, 0.903 71891, 71920, 71905, 0.232, 11.938, 1.169 71921, 71950, 71935, 0.193, 12.542, 1.141 71951, 71980, 71965, 0.193, 13.146, 1.394 71981, 72010, 71995, 0.208, 13.574, 1.383 72011, 72040, 72025, 0.208, 13.556, 1.072 72124, 72153, 72138, 0.251, 8.431, -9999.000 72154, 72183, 72168, 0.251, 7.052, 0.234 72184, 72213, 72198, 0.238, 10.508, 0.459 72214, 72243, 72228, 0.238, 11.238, 1.007 72244, 72273, 72258, 0.230, 10.869, 0.925 72274, 72303, 72288, 0.230, 10.499, 0.843 72304, 72333, 72318, 0.314, 10.814, 1.522 72334, 72363, 72348, 0.314, 10.545, 0.864 72364, 72393, 72378, 0.290, 10.859, 0.699 72394, 72423, 72408, 0.290, 11.172, 0.285 72424, 72453, 72438, 0.318, 11.471, 0.505 72454, 72483, 72468, 0.318, 11.522, 0.779 72484, 72513, 72498, 0.356, 12.555, 0.882 72514, 72543, 72528, 0.356, 13.589, 0.148 72545, 72574, 72559, 0.288, 12.636, 0.676 72575, 72604, 72589, 0.288, 13.425, 2.062 72605, 72634, 72619, 0.289, 13.826, 0.917 72635, 72664, 72649, 0.289, 14.221, 0.806 72665, 72694, 72679, 0.230, 15.115, 0.119 72695, 72724, 72709, 0.230, 17.593, 0.637 72725, 72754, 72739, 0.268, 14.820, 0.351 72755, 72784, 72769, 0.268, 12.056, 0.626 72785, 72814, 72799, 0.218, 11.966, 0.261 72815, 72844, 72829, 0.218, 11.612, -0.067 72845, 72874, 72859, 0.184, 10.770, 0.339 72875, 72904, 72889, 0.184, 9.931, 0.196 72906, 72935, 72920, 0.211, 11.024, -9999.000 72936, 72965, 72950, 0.211, 10.155, 0.044 72966, 72995, 72980, 0.155, 10.481, -0.669 72996, 73025, 73010, 0.155, 10.807, 0.329 73026, 73055, 73040, 0.179, 9.300, 0.301 73056, 73085, 73070, 0.179, 10.696, 0.961 73086, 73115, 73100, 0.154, 10.722, 0.659 73116, 73145, 73130, 0.154, 10.748, 0.790 73146, 73175, 73160, 0.153, 9.625, 0.813 73176, 73205, 73190, 0.153, 10.989, 0.810 73206, 73235, 73220, 0.121, 11.622, 0.205 73236, 73265, 73250, 0.121, 12.255, 1.418 73266, 73295, 73280, 0.099, 12.270, 0.229 73296, 73325, 73310, 0.099, 13.374, 0.941 73326, 73355, 73340, 0.124, 11.883, 0.639 73356, 73385, 73370, 0.124, 10.398, 1.067 73386, 73415, 73400, 0.135, 11.328, 2.525 73416, 73445, 73430, 0.135, 11.520, 1.397 73446, 73475, 73460, 0.250, 12.172, 1.296 73476, 73505, 73490, 0.250, 12.823, 3.355 73506, 73535, 73520, 0.513, 12.368, 1.101 73536, 73565, 73550, -9999.000, -9999.000, 2.716 73566, 73595, 73580, -9999.000, -9999.000, 3.300 73596, 73625, 73610, -9999.000, -9999.000, 3.408 73627, 73656, 73641, -9999.000, -9999.000, 3.955 73657, 73686, 73671, -9999.000, -9999.000, 2.196 73687, 73716, 73701, -9999.000, -9999.000, 2.171 73717, 73746, 73731, -9999.000, -9999.000, 1.924 73747, 73776, 73761, -9999.000, -9999.000, 4.398 73777, 73806, 73791, -9999.000, -9999.000, 1.804 73807, 73836, 73821, -9999.000, -9999.000, 2.755 73837, 73866, 73851, -9999.000, -9999.000, 0.205 73867, 73896, 73881, -9999.000, -9999.000, 3.093 73897, 73926, 73911, -9999.000, -9999.000, 1.709 73927, 73956, 73941, -9999.000, -9999.000, 2.843 73957, 73986, 73971, -9999.000, -9999.000, 1.547 73987, 74016, 74001, -9999.000, -9999.000, 1.508 74017, 74046, 74031, -9999.000, -9999.000, -0.377 74047, 74076, 74061, -9999.000, -9999.000, 0.868 74077, 74106, 74091, -9999.000, -9999.000, 0.951 74107, 74136, 74121, -9999.000, -9999.000, 1.841 74137, 74166, 74151, -9999.000, -9999.000, 0.689 74167, 74196, 74181, -9999.000, -9999.000, 1.478 74198, 74227, 74212, -9999.000, -9999.000, 1.149 74228, 74257, 74242, -9999.000, -9999.000, 0.356 74258, 74287, 74272, -9999.000, -9999.000, 0.045 74288, 74317, 74302, -9999.000, -9999.000, 0.516 74318, 74347, 74332, 0.055, 12.070, 2.925 74348, 74377, 74362, 0.064, 14.952, -0.362 74378, 74407, 74392, 0.064, 17.337, -9999.000 74408, 74437, 74422, 0.084, 19.517, 2.336 74438, 74467, 74452, 0.084, -9999.000, 1.457 74468, 74497, 74482, 0.078, -9999.000, -0.308 74498, 74527, 74512, 0.078, -9999.000, 0.144 74528, 74557, 74542, 0.065, -9999.000, 0.086 74558, 74587, 74572, 0.065, -9999.000, -0.613 74588, 74617, 74602, 0.047, -9999.000, 1.143 74618, 74647, 74632, 0.047, -9999.000, -0.333 74648, 74677, 74662, 0.098, 19.245, -0.662 74678, 74707, 74692, 0.098, 17.500, 0.436 74708, 74737, 74722, 0.070, -9999.000, -0.793 74738, 74767, 74752, 0.070, -9999.000, -0.009 74768, 74797, 74782, 0.120, -9999.000, 0.136 74798, 74827, 74812, 0.120, -9999.000, 0.353 74829, 74858, 74843, 0.120, -9999.000, 1.535 74859, 74888, 74873, 0.120, -9999.000, 0.319 74889, 74918, 74903, -9999.000, -9999.000, 1.915 74919, 74948, 74933, -9999.000, -9999.000, 1.798 74949, 74978, 74963, -9999.000, -9999.000, 2.590 74979, 75008, 74993, -9999.000, -9999.000, 1.683 75009, 75038, 75023, -9999.000, -9999.000, 1.260 75039, 75068, 75053, -9999.000, -9999.000, 1.805 75069, 75098, 75083, -9999.000, -9999.000, 0.496 75099, 75128, 75113, -9999.000, 13.453, 1.643 75129, 75158, 75143, 0.144, 12.329, 1.089 75159, 75188, 75173, 0.144, 11.205, 1.120 75189, 75218, 75203, 0.229, 12.458, 1.658 75219, 75248, 75233, 0.229, 11.935, 0.655 75249, 75278, 75263, 0.123, 11.355, 1.721 75279, 75308, 75293, 0.123, 10.773, 1.602 75309, 75338, 75323, 0.145, 11.021, 0.597 75339, 75368, 75353, 0.145, 9.323, 1.201 75369, 75398, 75383, -9999.000, -9999.000, 0.222 75399, 75428, 75413, -9999.000, -9999.000, 0.608 75429, 75458, 75443, -9999.000, -9999.000, 0.967 75460, 75489, 75474, -9999.000, 10.463, 0.302 75490, 75519, 75504, -9999.000, 8.893, 0.114 75520, 75549, 75534, -9999.000, -9999.000, 0.991 75550, 75579, 75564, 0.390, 6.776, 0.771 75580, 75609, 75594, -9999.000, -9999.000, 0.522 75610, 75639, 75624, -9999.000, -9999.000, 0.454 75640, 75669, 75654, -9999.000, 11.034, 0.392 75670, 75699, 75684, 0.238, 15.304, 0.853 75700, 75729, 75714, 0.238, 17.603, 0.362 75730, 75759, 75744, 0.178, 17.096, 0.622 75760, 75789, 75774, 0.178, 16.591, 1.376 75790, 75819, 75804, 0.249, 16.574, 0.950 75820, 75849, 75834, 0.249, 19.832, 0.760 75850, 75879, 75864, 0.488, 17.586, 0.652 75880, 75909, 75894, 0.488, 15.354, 0.628 75910, 75939, 75924, 0.568, 15.983, 0.751 75940, 75969, 75954, 0.568, 17.325, 0.304 75970, 75999, 75984, 0.509, 17.434, 1.284 76000, 76029, 76014, 0.509, 17.542, 0.681 76030, 76059, 76044, 0.566, 18.009, 0.864 76060, 76089, 76074, 0.566, 17.788, 0.612 76091, 76120, 76105, 0.350, 16.924, 0.236 76121, 76150, 76135, 0.350, 16.066, 1.289 76151, 76180, 76165, 0.433, 17.060, 0.035 76181, 76210, 76195, 0.433, 17.547, 0.822 76211, 76240, 76225, 0.630, 14.086, 0.398 76241, 76270, 76255, 0.630, 10.625, 0.722 76271, 76300, 76285, 0.482, 9.956, 1.066 76301, 76330, 76315, 0.482, 10.941, 0.547 76331, 76360, 76345, 0.613, 10.250, 0.704 76361, 76390, 76375, 0.613, 9.554, 0.014 76391, 76420, 76405, 0.729, 9.630, 1.279 76421, 76450, 76435, 0.729, 11.154, 0.682 76451, 76480, 76465, 0.549, 10.741, 0.382 76481, 76510, 76495, 0.549, 10.327, 0.786 76511, 76540, 76525, 0.519, 11.408, 0.954 76541, 76570, 76555, 0.519, 9.087, 0.629 76571, 76600, 76585, 0.737, 11.108, 0.740 76601, 76630, 76615, 0.737, 13.143, 1.126 76631, 76660, 76645, 0.412, 19.282, 0.762 76661, 76690, 76675, 0.412, -9999.000, 0.608 76691, 76720, 76705, 0.297, 19.775, 1.303 76722, 76751, 76736, 0.297, 19.484, 0.741 76752, 76781, 76766, -9999.000, -9999.000, 0.740 76782, 76811, 76796, 0.305, -9999.000, 0.301 76812, 76841, 76826, -9999.000, -9999.000, 0.833 76842, 76871, 76856, -9999.000, -9999.000, 0.942 76872, 76901, 76886, 0.184, -9999.000, 0.310 76902, 76931, 76916, 0.184, -9999.000, 0.601 76932, 76961, 76946, 0.207, -9999.000, 0.938 76962, 76991, 76976, -9999.000, -9999.000, 0.795 76992, 77021, 77006, -9999.000, -9999.000, 1.205 77022, 77051, 77036, -9999.000, 17.906, 0.935 77052, 77081, 77066, 0.285, 18.474, 0.336 77082, 77111, 77096, 0.285, 19.042, 0.452 77112, 77141, 77126, 0.201, 19.067, 0.520 77142, 77171, 77156, -9999.000, -9999.000, 1.016 77172, 77201, 77186, -9999.000, -9999.000, 1.813 77202, 77231, 77216, -9999.000, -9999.000, 1.020 77232, 77261, 77246, -9999.000, -9999.000, 0.697 77262, 77291, 77276, -9999.000, -9999.000, 0.344 77292, 77321, 77306, -9999.000, -9999.000, -0.005 77322, 77351, 77336, -9999.000, -9999.000, -0.084 77352, 77381, 77366, -9999.000, -9999.000, 0.674 77383, 77412, 77397, -9999.000, -9999.000, 1.292 77413, 77442, 77427, -9999.000, -9999.000, 1.388 77443, 77472, 77457, -9999.000, -9999.000, 0.882 77473, 77502, 77487, -9999.000, -9999.000, 0.578 77503, 77532, 77517, -9999.000, -9999.000, 0.921 77533, 77562, 77547, -9999.000, -9999.000, 0.299 77563, 77592, 77577, -9999.000, -9999.000, 0.553 77593, 77622, 77607, -9999.000, -9999.000, 1.342 77623, 77652, 77637, -9999.000, -9999.000, 0.959 77653, 77682, 77667, -9999.000, -9999.000, 0.461 77683, 77712, 77697, -9999.000, -9999.000, 0.173 77713, 77742, 77727, -9999.000, -9999.000, 0.280 77743, 77772, 77757, -9999.000, 18.885, 0.750 77773, 77802, 77787, 0.530, 16.811, 0.369 77803, 77832, 77817, 0.530, 14.750, 0.540 77833, 77862, 77847, 0.344, 13.706, 0.533 77863, 77892, 77877, 0.344, 16.665, 0.306 77893, 77922, 77907, 0.548, 16.462, 0.777 77923, 77952, 77937, 0.548, 16.258, -9999.000 77953, 77982, 77967, 0.461, 17.385, 1.054 77983, 78012, 77997, 0.461, 12.633, -0.004 78013, 78042, 78027, 0.517, 9.190, 0.692 78044, 78073, 78058, 0.517, 5.724, 0.069 78074, 78103, 78088, 0.395, 8.094, 1.444 78104, 78133, 78118, 0.395, 8.320, -0.121 78134, 78163, 78148, 0.365, 8.204, -0.055 78164, 78193, 78178, 0.365, 8.088, 0.374 78194, 78223, 78208, 0.421, 7.045, 0.578 78224, 78253, 78238, 0.421, 7.267, 0.588 78254, 78283, 78268, 0.362, 6.734, -0.294 78284, 78313, 78298, 0.362, 6.198, -9999.000 78314, 78343, 78328, 0.377, 7.027, 1.140 78344, 78373, 78358, 0.377, 6.357, 0.261 78374, 78403, 78388, 0.435, 6.437, 0.116 78404, 78433, 78418, 0.435, 6.516, -9999.000 78434, 78463, 78448, 0.336, 7.372, 0.343 78464, 78493, 78478, 0.336, 6.712, 1.328 78494, 78523, 78508, 0.285, 5.873, 0.730 78524, 78553, 78538, 0.285, 5.039, 0.289 78554, 78583, 78568, 0.264, 5.658, 0.905 78584, 78613, 78598, 0.264, 5.882, 0.779 78614, 78643, 78628, 0.312, 5.691, 0.386 78645, 78674, 78659, 0.312, 5.499, 0.172 78675, 78704, 78689, 0.354, 6.121, 1.017 78705, 78734, 78719, 0.354, 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