48, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2016, 08, 06, 2018, 11, 28 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 30 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom I: Science Flight #4 -- KOA - PPG ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 32% (actually a multiplicative factor of 1/1.32 to 1.32), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R4 R4: Final Data (see OTHER_COMMENTS) R3: Final Data (see OTHER_COMMENTS) R2: Final Data (see OTHER_COMMENTS) R1: Final Data R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 65514, 65543, 65529, -9999.000, -9999.000 65544, 65573, 65559, -9999.000, -9999.000 65574, 65603, 65589, -9999.000, -9999.000 65604, 65633, 65619, -9999.000, 12.442 65634, 65663, 65649, -9999.000, 8.882 65664, 65693, 65679, -9999.000, 9.400 65694, 65723, 65709, -9999.000, 8.747 65724, 65753, 65739, 0.152, 8.898 65754, 65783, 65769, 0.152, 9.050 65785, 65814, 65800, 0.197, 8.391 65815, 65844, 65830, 0.197, 9.089 65845, 65874, 65860, 0.141, 9.234 65875, 65904, 65890, 0.133, 9.378 65905, 65934, 65920, 0.133, 10.053 65935, 65964, 65950, 0.143, 9.648 65965, 65994, 65980, 0.143, 9.066 65995, 66024, 66010, 0.143, 8.485 66025, 66054, 66040, 0.125, 7.899 66055, 66084, 66070, 0.125, 7.318 66085, 66114, 66100, 0.186, 6.735 66116, 66145, 66131, 0.171, 6.151 66146, 66175, 66161, 0.171, 7.309 66176, 66205, 66191, 0.141, 6.869 66206, 66235, 66221, 0.141, 7.575 66236, 66265, 66251, 0.141, 8.280 66266, 66295, 66281, 0.185, 8.246 66296, 66325, 66311, 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