93, 1001 Jimenez, Jose Luis CIRES and Department of Chemistry, University of Colorado Boulder Chemically speciated submicron non-refractory particulate mass, 60 s resolution ATom 1, 1 2017, 10, 06, 2018, 12, 07 0 Starttime_AMS_60s, seconds_past_midnight, UTC_start_time_in_seconds_from_midnight 59 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1 -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999 Stoptime_AMS_60s, seconds_past_midnight, UTC_end_time_in_seconds_from_midnight MidPointTime_AMS_60s, seconds_past_midnight, UTC_midpoint_time_in_seconds_from_midnight LAT_AMS_60s, deg, Aircraft_latitude_at_time_of_sampling LON_AMS_60s, deg, Aircraft_longitude_at_time_of_sampling ALT_AMS_60s, m, Aircraft_GPS_altitude_at_time_of_sampling OA_PM1_AMS_60s, ugsm-3, Mass_concentration_of_PM1_organic_aerosol_in_air_than_1um_measured_by_HRAMS OA_prec_PM1_AMS_60s, ugsm-3, 1s_precision_error_of_the_mass_concentration_of_PM1_organic_aerosol_in_air OA_DL_PM1_AMS_60s, ugsm-3, Detection_limit_for_the_mass_concentration_of_PM1_organic_aerosol_in_air Sulfate_PM1_AMS_60s, ugsm-3, Mass_concentration_of_PM1_sulfate_aerosol_in_air Sulfate_prec_PM1_AMS_60s, ugsm-3, 1s_precision_error_of_mass_concentration_of_PM1_sulfate_aerosol_in_air Sulfate_DL_PM1_AMS_60s, ugsm-3, Detection_limit_for_the_mass_concentration_of_PM1_sulfate_aerosol_in_air Nitrate_PM1_AMS_60s, ugsm-3, Mass_concentration_of_PM1_nitrate_aerosol_in_air Nitrate_prec_PM1_AMS_60s, ugsm-3, 1s_precision_error_of_mass_concentration_of_PM1_nitrate_aerosol_in_air Nitrate_DL_PM1_AMS_60s, ugsm-3, Detection_limit_for_the_mass_concentration_of_PM1_nitrate_aerosol_in_air Ammonium_PM1_AMS_60s, ugsm-3, Mass_concentration_of_PM1_ammonium_aerosol_in_air Ammonium_prec_PM1_AMS_60s, ugsm-3, 1s_precision_error_of_mass_concentration_of_PM1_ammonium_aerosol_in_air Ammonium_DL_PM1_AMS_60s, ugsm-3, Detection_limit_for_the_mass_concentration_of_PM1_ammonium_aerosol_in_air Chloride_PM1_AMS_60s, ugsm-3, Mass_concentration_of_PM1_chloride_aerosol_in_air Chloride_prec_PM1_AMS_60s, ugsm-3, 1s_precision_error_of_mass_concentration_of_PM1_chloride_aerosol_in_air Chloride_DL_PM1_AMS_60s, ugsm-3, Detection_limit_for_the_mass_concentration_of_PM1_chloride_aerosol_in_air Seasalt_PM1_AMS_60s, ugsm-3, Mass_concentration_of_PM1_seasalt_aerosol_in_air Seasalt_prec_PM1_AMS_60s, ugsm-3, 1s_precision_error_of_mass_concentration_of_PM1_seasalt_aerosol_in_air Seasalt_DL_PM1_AMS_60s, ugsm-3, Detection_limit_for_the_mass_concentration_of_PM1_seasalt_aerosol_in_air MSA_PM1_AMS_60s, ugsm-3, Mass_concentration_of_PM1_MSA_aerosol_in_air MSA_prec_PM1_AMS_60s, ugsm-3, 1s_precision_error_of_mass_concentration_of_PM1_MSA_aerosol_in_air MSA_DL_PM1_AMS_60s, ugsm-3, Detection_limit_for_the_mass_concentration_of_PM1_MSA_aerosol_in_air ClO4_PM1_AMS_60s, ugsm-3, Mass_concentration_of_PM1_perchlorate_aerosol_in_air ClO4_prec_PM1_AMS_60s, ugsm-3, 1s_precision_error_of_mass_concentration_of_PM1_perchlorate_aerosol_in_air ClO4_DL_PM1_AMS_60s, ugsm-3, Detection_limit_for_the_mass_concentration_of_PM1_perchlorate_aerosol_in_air Bromine_PM1_AMS_60s, ugsm-3, Mass_concentration_of_PM1_bromine_aerosol_in_air Bromine_prec_PM1_AMS_60s, ugsm-3, 1s_precision_error_of_mass_concentration_of_PM1_bromine_aerosol_in_air Bromine_DL_PM1_AMS_60s, ugsm-3, Detection_limit_for_the_mass_concentration_of_PM1_bromine_aerosol_in_air Iodine_PM1_AMS_60s, ugsm-3, Mass_concentration_of_PM1_iodine_aerosol_in_air Iodine_prec_PM1_AMS_60s, ugsm-3, 1s_precision_error_of_mass_concentration_of_PM1_iodine_aerosol_in_air Iodine_DL_PM1_AMS_60s, ugsm-3, Detection_limit_for_the_mass_concentration_of_PM1_iodine_aerosol_in_air StdtoVol_AMS_60s, m3sm-3, Conversion_factor_from_std_to_ambient_volume_and_pressure CloudFlag_AMS_60s, unitless, Datapoints_suspected_to_be_impacted_by_artifacts_due_to_ice_impaction_on_the_inlet InletRH_AMS_60s, %, Relative_humidity_in_the_AMS_inlet_before_entering_the_aerodynamic_lens Flowrate_AMS_60s, scm-3, AMS_Sampling_flow AmmBalance_PM1_AMS_60s, unitless, Ammonium_Molar_Balance_for_non_refractory_PM1_inorganic_species_less_than_1um_measured_by_HRAMS Density_PM1_AMS_60s, gcm-3, Estimated_PM1_aerosol_density_assuming_internally_mixed_aerosol OADensity_PM1_AMS_60s, gcm-3, Estimated_density_of_the_PM1_organic_aerosol_fraction_assuming_internally_mixed_aerosol OtoC_Ratio_PM1_AMS_60s, unitless, O/C_atomic_ratio_of_the_organic_mass_fraction_of_the_PM1_aerosol HtoC_Ratio_PM1_AMS_60s, unitless, H/C_atomic_ratio_of_the_organic_mass_fraction_of_the_PM1_aerosol OAtoOC_PM1_AMS_60s, unitless, Organic_aerosol_to_organic_carbon_ratio_of_the_organic_mass_fraction_of_the_PM1_aerosol OSc_PM1_AMS_60s, unitless, Estimated_average_oxidation_state_of_carbon_of_the_organic_mass_fraction_of_the_PM1_aerosol OrgNitr_Fraction_PM1_AMS_60s, unitless, Estimated_organic_nitrate_fractional_contribution_to_total_PM1_aerosol_nitrate_mass_by_HRAMS f43_PM1_AMS_60s, unitless, Fractional_contribution_of_m/z_43_to_total_organic_mass f44_PM1_AMS_60s, unitless, Fractional_contribution_of_m/z_44_to_total_organic_mass f57_PM1_AMS_60s, unitless, Fractional_contribution_of_m/z_57_to_total_organic_mass f60_PM1_AMS_60s, unitless, Fractional_contribution_of_m/z_60_to_total_organic_mass f82_PM1_AMS_60s, unitless, Fractional_contribution_of_m/z_82_to_total_organic_mass f91_PM1_AMS_60s, unitless, Fractional_contribution_of_m/z_91_to_total_organic_mass fC2H3O_PM1_AMS_60s, unitless, Fractional_contribution_of_C2H3O+_to_total_organic_mass fCO2_PM1_AMS_60s, unitless, Fractional_contribution_of_CO2+_to_total_organic_mass fC4H9_PM1_AMS_60s, unitless, Fractional_contribution_of_C4H9+_to_total_organic_mass fC2H4O2_PM1_AMS_60s, unitless, Fractional_contribution_of_C2H4O2+_to_total_organic_mass fC5H6O_PM1_AMS_60s, unitless, Fractional_contribution_of_C5H6O+_to_total_organic_mass fC7H7_PM1_AMS_60s, unitless, Fractional_contribution_of_C7H7+_to_total_organic_mass 1 N/A 19 PI_CONTACT_INFO: Jose-Luis Jimenez, jose.jimenez@colorado.edu, Address: University of Colorado UCB 216; CIRES Bldg., Boulder, CO 80309-0216, phone +1-303-492-3557, fax +1-303-492-1149 PLATFORM: NASA DC-8 Aircraft LOCATION: Airports serving as home base on this deployment: PMD, ANC, KOA, PPG, CHC, PUQ, ASI, SID, TER, THU, ANC, PMD ASSOCIATED_DATA: N/A INSTRUMENT_INFO: AMS_Type=V; Ionization_type=EI; AMS_SamplingTime: 1 s; AMS_SamplingCycle: Fast Mode, 6 s closed and 46 s open (+5 s PToF, reported under a different DataID), 1 min synchronization clock; for flux measurements, sampling time 0.3 s, 8 s closed and ~ 500 s open, no synchronization. AMS_LensType=standard; AMS_LensPressure=1.50 Torr (actively controlled);AMS_FlowRate=Flowrate_AMS; AMS_PrsTempFlowCal: 273K, 1 bar; AMS_STPConversionFactor=StdtoVol_AMS; AMS_DAQType = ADQ_1600; AMS_CE: Calculated using the algorithm from Middlebrook et al 2012, AS&T 46, 258–271 [https://doi.org/10.1080/02786826.2011.620041] using 1 min data when total inorganic aerosol is below 5 ug sm-3 and 1 s data above 5 ug sm-3; AMS_PMCut= ~1 um vacuum aerodynamic, based on in-field calibrations; AMS_Calibrations: AN mass Calibration (400 nm particles) after every flight; Chloride, MSA, perchlorate and sulfate RIE, as well a PSL size calibration (75-900 nm), at regular intervals, bromine, iodine and seasalt calibrations post-deployments; AMS_FilEmmCurr = 1.4 mA (actively controlled); AMS_InletRH=not actively controlled, reported as InletRH_AMS based on data from the MMS and DLH instruments and confirmed with an inline sensor (Vaisala HMP-70); AMS_SquirrelVersion=1.61F; AMS_IEOverAB=7.78E-13; AMS_RIENH4=3.60; AMS_RIESO4=1.62; AMS_RIEChl=1.94; AMS_RIEClO4=0.76; (based on in-field calibrations) AMS_RIEBr=0.68, AMSRIEI=0.73, AMS_CFMSA=0.133, AMS_CFSeasalt=1/88 (based on post-deployment calibrations), AMS_PieberCorr=1.95% (as discussed in Pieber et al 2016, ES&T 50 (19), 10494–10503 [https://doi.org/10.1021/acs.est.6b01035]; AMS_HuCorr=1.64% (as discussed in Hu et al 2017, AS&T 51 [https://doi.org/DOI:10.1080/02786826.2017.1296104] DATA_INFO: Only brief explanations are provided here. Please refer to http://tinyurl.com/FAQ-AMS-Data for additional topics and more detailed explanations, and contact the PIs if in doubt. Both that web page and this header are updated regularly in response to questions from data users and/or new information about the instrument and data interpretation. All concentration data is reported under STP (273 K & 1013 mb); use the provided conversion factor to calculate under ambient temperature and pressure. Note that several other definitions of standard conditions are in use by others in the community, and some groups and models report under ambient and not standard conditions--check carefully before comparing!! IMPORTANT: All reported data in this file is derived by analyzing the averaged raw spectra at 60 s resolution, it is NOT an arithmetic average of the data reported under the AMS Id for 1 s resolution. Hence it has higher S/N than the simple average and should be preferentially used for longer timescales.Data was taken on a 1 min clock with 6 s background and 46 s ambient measurements, reported in 1 s increments. The remaining time was either instrument overhead or was spent taking particle size segregated data (reported in a separate data id). Time base is corrected for inlet lag (about 0.4 s in the BL, 0.8 s in the stratosphere). Latitude, Longitude and GPS Altitude are provided (inlet lag adjusted) from the instruments' own GPS datafeed. All reported data (including the individual f_x marker fractions) are derived from fitting individual HR ions using PIKA, and NOT by using the unit mass resolution (UMR) signal (“Squirrel” in AMS parlance). Unlike the aerosol species concentrations (extensive properties), all the variables (intensive properties) detailing the chemical composition of the organic fraction were thresholded for the organic detection limit to avoid averaging artifacts; the thresholded data should be averaged to slower time resolutions with OA mass weighting. Reported aerosol density is estimated for non-refractory material assuming an internally mixed aerosol, following the method of Salcedo et al 2006, ACP 6, 925–946 [https://doi.org/doi:10.5194/acp-6-925-2006]; please note that this calculation does not include seasalt, which is typically externally mixed with the non-refractory aerosol. The density of the organic fraction is estimated with the expression provided in Kuwata et al 2012, ES&T 46, 787-794 [https://doi.org/10.1021/es202525q]. Only species above DL are included in the density calculation. Atomic O/C, H/C and OA/OC ratios are reported using the updated calibration proposed by Canagaratna, Jimenez et al. 2015, ACP 15, 253-272 [https://doi.org/10.5194/acp-15-253-2015], which results in, on average, 28% higher O/C and 7% higher H/C ratios than using the Aiken et al 2008, ES&T 42, 4478–4485 [https://doi.org/10.1021/es703009q] method. Oxidation State of organic carbon is provided according to the approximate formula of Kroll et al 2011, Nat. Chem. 3, 133-139, 2011 [https://doi.org/10.1038/nchem.948] using the new calibration described in Canagaratna, Jimenez et al. 2015. The molar ion ratio of ammonium to the the inorganic anions (“Ammonium Balance”) is provided as a rough proxy for aerosol acidity; we also provide a modeled pH product (reported in a separate DataID) that is in general more meaningful. An IceFlag (based on AMS measurements of particulate water and Zinc) is included to identify periods when artifacts due to ice impaction on the inlet (not shared with the other aerosol instruments on the plane) were observed; in general, AMS data seems to be impacted to a much lesser extent by these artifacts than other instruments, but extra caution should be exercised when using data from these periods. An organic nitrate fraction is included as an experimental product (1 min resolution due to the lower signal-to-noise of this product), see Fry et al 2013, ACP 13, 8585-8605 [https://doi.org/10.5194/acp-13-8585-2013] for details; organic nitrate fraction data is not reported during elevated dust (identified by the PALMS instrument) or sea salt episodes that lead to significant interferences. Note that the AMS measures total and not inorganic sulfate. The organic sulfate fraction is thought to be small, but it may be as high as 20% in some areas (excluding MSA, discussed below). In some cases the measured nitrate might also include nitrite, although the presence of nitrite in submicron aerosols is very unusual in our experience (see Guo et al. 2016, JGR 121, 10355-10376 [https://doi.org/10.1002/2016JD025311]). Five new aerosol species are being reported as part of this dataset, particulate MSA, seasalt, perchlorate, bromine and iodine (all submicron). All of these data products have been calibrated with laboratory standards, and some of them further validated by comparison with the PALMS instrument. The calibration factor (CF=1/(f(Marker)*RIE)) was determined from chamber data with both wet and dry seasalt. MSA was quantified based on the CH3SO2+ AMS ion, which is specific to MSA and both f(CH3SO2+) and RIE_MSA were calibrated using laboratory standards and further confirmed by PMF analysis, see Hodshire et al, ACPD 18, [https://doi.org/10.5194/acp-2018-1022]. In this header we report the calibration factor CF=1/(f(Marker)*RIE)). Please note that while MSA is often detected as part of OA and sulfate in AMS measurements, in this dataset both OA and sulfate have been corrected for the MSA interference. For models that included MSA in OA, the reported MSA should be added to OA. Submicron seasalt is reported following the method from Ovadnevaite et al, JGR 2012, 117 (D16), 1–11 [https://doi.org/10.1029/2011JD017379] based on detection of the Na_35Cl+ marker ion. For this species, cloud artifacts are observed (unlike all other species), and the data has hence been filtered by the AMS cloudflag variable. The calibration factor CF=1/(f(Marker)*RIE) was determined by chamber calibrations with dry and wet NaCl, and does not include other seasalt components (seasalt sulfate, primary OA). Perchlorate is detected as the sum of ClOx ions, with a contribution from Cl that is determined from calibrations. Note that the main ions, ClO2+ and ClO3+, suffer from interferences of H_34SOx ions, so that we do not report perchlorate at high sulfate concentrations. Neither perchlorate nor seasalt are part of the AMS chloride species reported here, but this is often not the case for other AMS datasets. Bromine and iodine are reported for the first time based on RIE calibrations with Br-/I- and BrOn/IOn salts. Note that only the halogen is detected for the haloxides and the sensitivity is the same regardless of oxidation state. For some flights, the AMS is run at times in so-called fluxmode (3-5 Hz acquisition rate, less-frequent backgrounds, no size-segregated measurements, no clock synchronization) to be able to calculate aerosol fluxes (see Farmer et al AMT 2011 [https://doi.org/10.5194/amt-4-1275-2011] for details). Due to the larger intervals between backgrounds, the uncertainty on the quantification of low volatility compounds (highly oxidized OA, sulfate and sea salt) is larger than during regular acquisition. UNCERTAINTY: Accuracy estimate (2sdev): Inorganics +/-34%, Organics +/-38%, dominated by uncertainty in particle collection efficiency due to particle bounce, and absolute and relative ionization efficiency, as estimated in Bahreini et al. 2009, JGR 114, D00F16 (Supp. Info.)[https://doi.org/10.1029/2008JD011493]. Precision error (1sdev) for each species is provided as a separate variable. Continuous detection limits are estimated based on the method of Drewnick et al, AMT 2, 33-46, 2009 [https://doi.org/10.5194/amt-2-33-2009] and were corrected by comparison with frequent, periodic blanks (every 18 min for this mission) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: -9999, -9999, -9999, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888 DM_CONTACT_INFO: Pedro Campuzano Jost, Pedro.CampuzanoJost-1@colorado.edu, Address: University of Colorado UCB 216; CIRES Bldg., Boulder, CO 80309-0216, phone +1-303-492-9599, fax +1-303-492-1149 PROJECT_INFO: NASA ATom-3 Mission, September-October 2017 STIPULATIONS_ON_USE: Final Data. The users are strongly encouraged to consult with the PI for proper data use. OTHER_COMMENTS: N/A REVISION: R1 R1: Final Data; R0: Preliminary Data Starttime_AMS_60s, Stoptime_AMS_60s, MidPointTime_AMS_60s, LAT_AMS_60s, LON_AMS_60s, ALT_AMS_60s, OA_PM1_AMS_60s, OA_prec_PM1_AMS_60s, OA_DL_PM1_AMS_60s, Sulfate_PM1_AMS_60s, Sulfate_prec_PM1_AMS_60s, Sulfate_DL_PM1_AMS_60s, Nitrate_PM1_AMS_60s, Nitrate_prec_PM1_AMS_60s, Nitrate_DL_PM1_AMS_60s, Ammonium_PM1_AMS_60s, Ammonium_prec_PM1_AMS_60s, Ammonium_DL_PM1_AMS_60s, Chloride_PM1_AMS_60s, Chloride_prec_PM1_AMS_60s, Chloride_DL_PM1_AMS_60s, Seasalt_PM1_AMS_60s, Seasalt_prec_PM1_AMS_60s, Seasalt_DL_PM1_AMS_60s, MSA_PM1_AMS_60s, MSA_prec_PM1_AMS_60s, MSA_DL_PM1_AMS_60s, ClO4_PM1_AMS_60s, ClO4_prec_PM1_AMS_60s, ClO4_DL_PM1_AMS_60s, Bromine_PM1_AMS_60s, Bromine_prec_PM1_AMS_60s, Bromine_DL_PM1_AMS_60s, Iodine_PM1_AMS_60s, Iodine_prec_PM1_AMS_60s, Iodine_DL_PM1_AMS_60s, StdtoVol_AMS_60s, CloudFlag_AMS_60s, InletRH_AMS_60s, Flowrate_AMS_60s, AmmBalance_PM1_AMS_60s, Density_PM1_AMS_60s, OADensity_PM1_AMS_60s, 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