75, 1001 Jimenez, Jose Luis CIRES and Department of Chemistry, University of Colorado Boulder Chemically speciated submicron non-refractory particulate mass, 60 s resolution ATom 1, 1 2017, 02, 18, 2017, 12, 04 0 AMS_Starttime_60s, seconds_past_midnight, UTC_start_time_in_seconds_from_midnight 42 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1, 1 -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999, -9999 AMS_Stoptime_60s, seconds_past_midnight, UTC_end_time_in_seconds_from_midnight AMS_MidPointTime_60s, seconds_past_midnight, UTC_midpoint_time_in_seconds_from_midnight AMS_LAT_60s, deg, Aircraft_latitude_at_time_of_sampling AMS_LON_60s, deg, Aircraft_longitude_at_time_of_sampling AMS_ALT_60s, m, Aircraft_GPS_altitude_at_time_of_sampling OA_lt_1um_AMS_60s, ug sm-3, Mass_concentration_of_organic_aerosol_in_air_for_particle_diameter_less_than_1um_measured_by_HRAMS OA_lt_1um_AMS_prec_60s, ug sm-3, 1s_precision_error_of_the_mass_concentration_of_organic_aerosol_in_air_for_particle_diameter_less_than_1um_measured_by_HRAMS OA_lt_1um_AMS_DL_60s, ug sm-3, Detection_limit_for_the_mass_concentration_of_organic_aerosol_in_air_for_particle_diameter_less_than_1um_measured_by_HRAMS Sulfate_lt_1um_AMS_60s, ug sm-3, Mass_concentration_of_sulfate_aerosol_in_air_for_particle_diameter_less_than_1um_measured_by_HRAMS Sulfate_lt_1um_AMS_prec_60s, ug sm-3, 1s_precision_error_of_mass_concentration_of_sulfate_aerosol_in_air_for_particle_diameter_less_than_1um_measured_by_HRAMS Sulfate_lt_1um_AMS_DL_60s, ug sm-3, Detection_limit_for_the_mass_concentration_of_sulfate_aerosol_in_air_for_particle_diameter_less_than_1um_measured_by_HRAMS Ammonium_lt_1um_AMS_60s, ug sm-3, Mass_concentration_of_nitrate_aerosol_in_air_for_particle_diameter_less_than_1um_measured_by_HRAMS Ammonium_lt_1um_AMS_prec_60s, ug sm-3, 1s_precision_error_of_mass_concentration_of_nitrate_aerosol_in_air_for_particle_diameter_less_than_1um_measured_by_HRAMS Ammonium_lt_1um_AMS_DL_60s, ug sm-3, Detection_limit_for_the_mass_concentration_of_nitrate_aerosol_in_air_for_particle_diameter_less_than_1um_measured_by_HRAMS Nitrate_lt_1um_AMS_60s, ug sm-3, Mass_concentration_of_ammonium_aerosol_in_air_for_particle_diameter_less_than_1um_measured_by_HRAMS Nitrate_lt_1um_AMS_prec_60s, ug sm-3, 1s_precision_error_of_mass_concentration_of_ammonium_aerosol_in_air_for_particle_diameter_less_than_1um_measured_by_HRAMS Nitrate_lt_1um_AMS_DL_60s, ug sm-3, Detection_limit_for_the_mass_concentration_of_ammonium_aerosol_in_air_for_particle_diameter_less_than_1um_measured_by_HRAMS Chloride_lt_1um_AMS_60s, ug sm-3, Mass_concentration_of_chloride_aerosol_in_air_for_particle_diameter_less_than_1um_measured_by_HRAMS Chloride_lt_1um_AMS_prec_60s, ug sm-3, 1s_precision_error_of_mass_concentration_of_chloride_aerosol_in_air_for_particle_diameter_less_than_1um_measured_by_HRAMS Chloride_lt_1um_AMS_DL_60s, ug sm-3, Detection_limit_for_the_mass_concentration_of_chloride_aerosol_in_air_for_particle_diameter_less_than_1um_measured_by_HRAMS StdtoVol_AMS_60s, m3 sm-3, Conversion_factor_from_std_to_ambient_volume_and_pressure IceFlag_AMS_60s, unitless, Datapoints_suspected_to_be_impacted_by_artifacts_due_to_ice_impaction_on_the_inlet AmmBalance_lt_1um_AMS_60s, unitless, Ammonium_Molar_Balance_for_non_refractory_inorganic_species_less_than_1um_measured_by_HRAMS Density_lt_1um_AMS_60s, g cm-3, Estimated_aerosol_density_assuming_internally_mixed_aerosol_for_particle_diameter_less_than_1um_measured_by_HRAMS OADensity_lt_1um_AMS_60s, g cm-3, Estimated_density_of_the_organic_aerosol_fraction_assuming_internally_mixed_aerosol_for_particle_diameter_less_than_1um_measured_by_HRAMS O_C_lt_1um_AMS_60s, unitless, O/C_atomic_ratio_of_the_organic_mass_fraction_of_the_aerosol_for_particle_diameter_less_than_1um_measured_by_HRAMS H_C_lt_1um_AMS_60s, unitless, H/C_atomic_ratio_of_the_organic_mass_fraction_of_the_aerosol_for_particle_diameter_less_than_1um_measured_by_HRAMS OA_OC_lt_1um_AMS_60s, unitless, Organic_aerosol_to_organic_carbon_ratio_of_the_organic_mass_fraction_of_the_aerosol_for_particle_diameter_less_than_1um_measured_by_HRAMS OSc_lt_1um_AMS_60s, unitless, Estimated_average_oxidation_state_of_carbon_of_the_organic_mass_fraction_of_the_aerosol_for_particle_diameter_less_than_1um_measured_by_HRAMS f43_lt_1um_AMS_60s, unitless, Fractional_contribution_of_m/z_43_to_total_organic_mass_for_particle_diameter_less_than_1um_measured_by_HRAMS f44_lt_1um_AMS_60s, unitless, Fractional_contribution_of_m/z_44_to_total_organic_mass_for_particle_diameter_less_than_1um_measured_by_HRAMS f57_lt_1um_AMS_60s, unitless, Fractional_contribution_of_m/z_57_to_total_organic_mass_for_particle_diameter_less_than_1um_measured_by_HRAMS f60_lt_1um_AMS_60s, unitless, Fractional_contribution_of_m/z_60_to_total_organic_mass_for_particle_diameter_less_than_1um_measured_by_HRAMS f82_lt_1um_AMS_60s, unitless, Fractional_contribution_of_m/z_82_to_total_organic_mass_for_particle_diameter_less_than_1um_measured_by_HRAMS f91_lt_1um_AMS_60s, unitless, Fractional_contribution_of_m/z_91_to_total_organic_mass_for_particle_diameter_less_than_1um_measured_by_HRAMS fC2H3O_lt_1um_AMS_60s, unitless, Fractional_contribution_of_C2H3O+_to_total_organic_mass_for_particle_diameter_less_than_1um_measured_by_HRAMS fCO2_lt_1um_AMS_60s, unitless, Fractional_contribution_of_CO2+_to_total_organic_mass_for_particle_diameter_less_than_1um_measured_by_HRAMS fC4H9_lt_1um_AMS_60s, unitless, Fractional_contribution_of_C4H9+_to_total_organic_mass_for_particle_diameter_less_than_1um_measured_by_HRAMS fC2H4O2_lt_1um_AMS_60s, unitless, Fractional_contribution_of_C2H4O2+_to_total_organic_mass_for_particle_diameter_less_than_1um_measured_by_HRAMS fC5H6O_lt_1um_AMS_60s, unitless, Fractional_contribution_of_C5H6O+_to_total_organic_mass_for_particle_diameter_less_than_1um_measured_by_HRAMS fC7H7_lt_1um_AMS_60s, unitless, Fractional_contribution_of_C7H7+_to_total_organic_mass_for_particle_diameter_less_than_1um_measured_by_HRAMS OrgNitr_Fraction_lt_1um_AMS_60s, unitless, Estimated_organic_nitrate_fractional_contribution_to_total_aerosol_nitrate_mass_by_HRAMS 1 Some EMI interference on this flight, samples affected have been removed. 18 PI_CONTACT_INFO: Jose-Luis Jimenez, jose.jimenez@colorado.edu, Address: University of Colorado UCB 216; CIRES Bldg., Boulder, CO 80309-0216, phone +1-303-492-3557, fax +1-303-492-1149 PLATFORM: NASA DC-8 Aircraft LOCATION: Airports serving as home base on this deployment: PMD, ANC, KOA, NAN, CHC, PUQ, ASI, TER, THU, ANC, PMD ASSOCIATED_DATA: N/A INSTRUMENT_INFO: AMS_Type=V; Ionization_type=EI; AMS_SamplingTime: 46 s; AMS_SamplingCycle: Fast Mode, 6 s closed and 46 s open (+5 s PToF, reported under a different DataID) , 1 min synchronization clock; AMS_LensType=standard; AMS_LensPressure=1.50 Torr (actively controlled); AMS_FlowRate=92.5 sccm; AMS_PrsTempFlowCal: 273K, 1 bar; AMS_STPConversionFactor=StdtoVol_AMS; AMS_IEOverAB=7.14e-13; AMS_Calibrations: AN mass Calibration (400 nm particles) after every flight; Chloride and sulfate RIE, as well a PSL size calibration (100-900 nm), at regular intervals; AMS_FilEmmCurr = 1.4 mA (actively controlled); AMS_DAQType = ADQ_1600; AMS_RIENH4=3.66; AMS_RIESO4=1.46; AMS_RIEChl=1.85 (based on in-field calibrations); AMS_CE: Calculated using the algorithm from Middlebrook et al, AS&T, 46, 258–271, 2012 using 1 min data; AMS_PMCut= ~1 um vacuum aerodynamic, based on in-field calibration; AMS_InletRH: < 50%; AMS_PieberCorr=1% (as discussed in Pieber et al, ES&T 50 (19), pp 10494–10503 (2016)); AMS_HuCorr=0.36% (as discussed in Hu et al, AS&T, in press, 2017) DATA_INFO: Only brief explanations are provided here. Please refer to http://tinyurl.com/FAQ-AMS-Data for additional topics and more detailed explanations, and contact the PIs if in doubt. Both that web page and this header are updated regularly in response to questions from data users and/or new information about the instrument and data interpretation. All concentration data is reported under STP (273 K & 1013 mb); use provided conversion factor to calculate under ambient temperature and pressure. Note that several other definitions of standard conditions are in use by others in the community, and some groups and models report under ambient and not standard conditions--check carefully before comparing!! Data was taken on a 1 min clock with 6 s background and 46 s ambient measurements, reported in 60 s increments. The remaining time was either instrument overhead or was spent taking particle size segregated data (reported in a separate data id). Time base is corrected for inlet lag (about 0.4 s in the BL). Latitude, Longitude and GPS Altitude are provided (inlet lag adjusted) from the instruments' own GPS datafeed. IMPORTANT: All reported data in this file is derived by analyzing the averaged raw data at 60 s resolution, it is NOT an arithmetic average of the data reported under the AMS Id. Hence it has higher S/N than the simple average and should be preferentially used for longer timescales. All reported data (including the individual f_x marker fractions) are derived from fitting individual HR ions using PIKA 1.17C, and NOT by using the unit mass resolution (UMR) signal (“Squirrel” in AMS parlance). Unlike the aerosol species concentrations (extensive properties), all the variables (intensive properties) detailing the chemical composition of the organic fraction were thresholded for the organic detection limit to avoid averaging artifacts; the thresholded data should be averaged to slower time resolutions with OA mass weighting. Reported aerosol density is estimated for non-refractory material assuming an internally mixed aerosol, following the method of Salcedo et al, ACP 6, 925–946, 2006; the density of the organic fraction is estimated with the expression provided in Kuwata et al ES&T, 46, 787-794, 2012. Only species above DL are included in the density calculation. Atomic O/C, H/C and OA/OC ratios are reported using the new calibration proposed by Canagaratna, Jimenez et al. ACP 15, 253-272, 2015, which results in, on average, 28% higher O/C and 7% higher H/C ratios than using the Aiken et al ES&T 42, 4478–4485, 2008 method. Oxidation State of OA provided according to the approximate formula of Kroll et al, Nature Chemistry, 3, 133-139, 2011 using the new calibration described in Canagaratna, Jimenez et al. 2015. The molar ion balance of the inorganic species (“Ammonium Balance”) is provided as a rough proxy for aerosol acidity; we also provide a modeled pH product (reported in the final data) that is in general more meaningful. An IceFlag (based on AMS measurements of particulate water and Zinc) is included to identify periods when artifacts due to ice impaction on the inlet (not shared with the other aerosol instruments on the plane) were observed; in general, AMS data seems to be impacted to a much lesser extent by these artifacts than other instruments, but extra caution should be exercised when using data from these periods. An organic nitrate fraction is included as an experimental product (1 min resolution due to the lower signal-to-noise of this product), see Fry et al, ACP 13, 8585-8605, 2013 for details; organic nitrate fraction data is not reported during elevated dust or sea salt episodes that lead to significant interferences. In some cases the measured nitrate might also include nitrite, although the presence of nitrite in submicron aerosols is very unusual in our experience (see Guo et al., JGR 121, 10355-10376, 2016). UNCERTAINTY: Accuracy estimate (2sdev): Inorganics +/-34%, Organics +/-38%, dominated by uncertainty in particle collection efficiency due to particle bounce, and absolute and relative ionization efficiency, as estimated in Bahreini et al. JGR 114, D00F16, 2009. doi:10.1029/2008JD011493 (Supp. Info.). Precision error (1sdev) for each species is provided as a separate variable. Continuous detection Limits are estimated based on the method of Drewnick et al, AMT 2, 33-46, 2009 and were corrected by comparison with frequent, periodic blanks. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: -9999, -9999, -9999, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888, -8888 DM_CONTACT_INFO: Pedro Campuzano Jost, Pedro.CampuzanoJost-1@colorado.edu, Address: University of Colorado UCB 216; CIRES Bldg., Boulder, CO 80309-0216, phone +1-303-492-9599, fax +1-303-492-1149 PROJECT_INFO: NASA ATom-2 Mission, January 2017 STIPULATIONS_ON_USE: Final data. Data users are encouraged to consult with the PI for proper data interpretation. OTHER_COMMENTS: N/A REVISION: R1 R1: Final Data; R0: Preliminary Data. For in-field use only. AMS_Starttime_60s, AMS_Stoptime_60s, AMS_MidPointTime_60s, AMS_LAT_60s, AMS_LON_60s, AMS_ALT_60s, OA_lt_1um_AMS_60s, OA_lt_1um_AMS_prec_60s, OA_lt_1um_AMS_DL_60s, Sulfate_lt_1um_AMS_60s, Sulfate_lt_1um_AMS_prec_60s, Sulfate_lt_1um_AMS_DL_60s, Ammonium_lt_1um_AMS_60s, Ammonium_lt_1um_AMS_prec_60s, Ammonium_lt_1um_AMS_DL_60s, Nitrate_lt_1um_AMS_60s, Nitrate_lt_1um_AMS_prec_60s, Nitrate_lt_1um_AMS_DL_60s, Chloride_lt_1um_AMS_60s, Chloride_lt_1um_AMS_prec_60s, Chloride_lt_1um_AMS_DL_60s, StdtoVol_AMS_60s, IceFlag_AMS_60s, AmmBalance_lt_1um_AMS_60s, Density_lt_1um_AMS_60s, OADensity_lt_1um_AMS_60s, O_C_lt_1um_AMS_60s, H_C_lt_1um_AMS_60s, OA_OC_lt_1um_AMS_60s, OSc_lt_1um_AMS_60s, f43_lt_1um_AMS_60s, f44_lt_1um_AMS_60s, f57_lt_1um_AMS_60s, f60_lt_1um_AMS_60s, f82_lt_1um_AMS_60s, f91_lt_1um_AMS_60s, fC2H3O_lt_1um_AMS_60s, fCO2_lt_1um_AMS_60s, fC4H9_lt_1um_AMS_60s, fC2H4O2_lt_1um_AMS_60s, fC5H6O_lt_1um_AMS_60s, fC7H7_lt_1um_AMS_60s, OrgNitr_Fraction_lt_1um_AMS_60s 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