The NASA GISS Research Scanning Polarimeter (RSP) is a passive, downward-facing polarimeter that makes total radiance and linear polarization measurements in nine spectral bands ranging from the visible/near-infrared (VNIR) to the shortwave infrared (SWIR). The band centers are: 410 (30), 470 (20), 550 (20), 670 (20), 865 (20), 960 (20), 1590 (60), 1880 (90) and 2250 (130) nm where the full width at half maximum (FWHM) bandwidths of each channel is shown in parenthesis. Noise is minimized in the SWIR channels by cooling the detectors to less than 165K using a dewar of liquid nitrogen. The RSP measures the degree of linear polarization (DoLP) with an uncertainty of <0.2%. The polarimetric and radiometric intensity measurement uncertainties are each <3%. A full set of RSP’s design parameters are shown in Table 1 and more details on design and calibration can be found in Cairns et al. (1999) and Cairns et al. (2003).
 
The RSP is an along track scanning instrument that can make up to 152 measurements sweeping ± 60° from nadir along the aircraft's track every 0.8 seconds with each measurement having a 14 mrad (~0.8°) field-of-view. Each scan includes stability, dark reference and calibration checks. As the RSP travels aboard an aircraft, the same nadir footprint is viewed from multiple angles. Consecutive scans are aggregated into virtual scans that are reflectances of a single nadir footprint from multiple viewing angles. This format comprises the RSP’s Level 1C data.
 
RSP’s high-angular resolution and polarimetric accuracy enables numerous aerosol, cloud and ocean properties to be retrieved. These are Level 2 data products. A summary of the primary L2 aerosol, cloud and ocean data products retrieved by the RSP are shown in Table 3.
 
The RSP’s data archive is publicly available and organized by air campaign, each of which contain ReadMe files provided by the RSP team for their Level 1C and Level 2 data products, including important details about biases and uncertainties that data users should consult.

The RSP data archive is available at: https://data.giss.nasa.gov/pub/rsp/
 
A visualizer showing the times and locations of NASA Airborne Campaigns the RSP has taken part in is available at: http://rsp.apam.columbia.edu:3000
 

The UNHMERC instrument provides detailed information on atmospheric mercury. Measurements of total gaseous mercury (TGM) and gaseous elemental mercury (Hg°) are performed simultaneously with one minute time resolution using a custom four-channel atomic fluorescence spectrometer. The relative amount of reactive gaseous mercury (RGM = HgCl2 + HgBr2+ HgOBr + …) will be assessed through careful examination of the difference between TGM and Hg°. TGM is defined as the sum Hg° + RGM. Targeted aerosol sampling will also be conducted for particulate-phase mercury (HgP).

TOGA measures volatile organic compounds (VOCs). TOGA was deployed with an Agilent quadrupole mass spectrometer from 2006 through 2018. Since 2019, the TOGA has been equipped with a TOFWERK high-resolution time-of-flight (HR-TOF) mass spectrometer detector (TOGA-TOF). Specific data will be obtained for radical precursors, tracers of anthropogenic and biogenic activities, tracers of urban and biomass combustion emissions, tracers of ocean emissions, products of oxidative processing, precursors to aerosol formation, and compounds important for aerosol modification and transformation. TOGA measures a wide range of VOCs with high sensitivity (low to sub-ppt), frequency (2 minutes or better), accuracy (20% or better), and precision (<3%). Over 100 species are routinely measured throughout the troposphere and lower stratosphere from the surface to 16 km or higher. See table for list of VOCs that have been quantified using TOGA and TOGA-TOF. The TOGA-TOF is contained in a dual extended HIAPER rack, weighs approximately 225 kg and consumes ~1 kW of power. The major components of the instrument are the inlet, cryogenic preconcentrator, gas chromatograph, time-of-flight mass spectrometer detector, zero air/calibration system, and the control/data acquisition system. All processes and data acquisition are computer controlled.

The UC Berkeley thermal-dissociation laser-induced fluorescence (TD- LIF) instrument detects NO2 directly and detects total peroxynitrates (ΣPNs ≡ PAN + PPN +N2O5 + HNO4. . .), total alkyl- and other thermally stable organic nitrates (ΣANs), and HNO3 following thermal dissociation of these NOy species to NO2. The sensitivity for NO2 at 1 Hz is 30 pptv (S/N=2) with a slope uncertainty of 5%. The uncertainties for the dissociated species are 10% for ΣPNs and 15% for ΣANs and HNO3.

PTR-MS is a chemical ionization mass spectrometry technique that allows for fast measurements of organic trace gases. In combination with the CHARON inlet, it measures the organic composition of submicrometer aerosol particles.