47, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2018, 05, 21, 2019, 05, 24 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 29 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom IV: Science Flight #12 -- ANC - PMD ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 35% (actually a multiplicative factor of 1/1.35 to 1.35), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R3 R3: Final Data (see OTHER_COMMENTS) R2: Final Data (see OTHER_COMMENTS) R1: Final Data (see OTHER_COMMENTS) R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 60428, 60457, 60443, -9999.000, -9999.000 60458, 60487, 60473, -9999.000, -9999.000 60488, 60517, 60503, -9999.000, -9999.000 60518, 60547, 60533, -9999.000, -9999.000 60549, 60578, 60564, 0.022, 6.858 60579, 60608, 60594, 0.022, 3.306 60609, 60638, 60624, 0.037, 4.927 60639, 60668, 60654, 0.037, 4.956 60669, 60698, 60684, -0.026, 4.985 60699, 60728, 60714, -0.026, 0.839 60729, 60758, 60744, -0.026, 1.219 60759, 60788, 60774, 0.021, 1.600 60789, 60818, 60804, -0.006, 1.982 60819, 60848, 60834, -0.006, 2.363 60849, 60878, 60864, -0.006, 2.744 60879, 60908, 60894, -0.002, 3.124 60909, 60938, 60924, -0.002, 3.505 60939, 60968, 60954, 0.022, 3.094 60969, 60998, 60984, 0.007, 5.325 60999, 61028, 61014, 0.007, 4.808 61029, 61058, 61044, 0.007, 4.291 61059, 61088, 61074, -0.007, 3.863 61089, 61118, 61104, -0.007, 6.215 61119, 61148, 61134, 0.054, 5.958 61149, 61178, 61164, 0.054, 5.702 61179, 61208, 61194, 0.028, 5.023 61209, 61238, 61224, 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