41, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor based on LIF ATom 1, 1 2016, 08, 22, 2017, 06, 06 0 Start_UTC, seconds, seconds since takeoff's midnight UTC 5 1, 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since takeoff's midnight UTC Mid_UTC, seconds, seconds since takeoff's midnight UTC OH_pptv, pptv, OH mixing ratio in pptv HO2_pptv, pptv, HO2 mixing ratio in pptv OHR_Hz, Hz, OH reactivity in Hz 0 22 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom I: Science Flight #10 -- SFJ - MSP ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 with Laser Induced Fluorescence; OH reactivity with discharge flow DATA_INFO: Units are pptv for OH and HO2; Hz for OHR. UNCERTAINTY: Normaly HOx absolute accuracy is estimated to be +/- 32% at two sigma confidence. Please see comments below. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Semi-Final Data. Calibrating ATHOS with the new OH scavenging inlet is proving to be difficult. Until we complete more tests, OH uncertainty above 6 km estimated to be a factor of 2, 2 sigma confidence HO2 uncertainty for all altitudes estimated to be a factor of 1.6, 2 sigma confidence. OHR uncertainty estimated to be 15%, 2 sigma confidence, with 0.3 s^-1 zero uncertainty. OHR correction for NO appears to work for conditions with ambient NO<=~5 ppbv; OHR data are not reported for higher NO conditions. REVISION: R1 R1: Final Data Start_UTC, Stop_UTC, Mid_UTC, OH_pptv, HO2_pptv, OHR_Hz 46386, 46415, 46400, -9999.000, 25.359, -9999.000 46416, 46445, 46430, 0.040, 25.221, 0.947 46446, 46475, 46460, 0.040, 22.934, -0.261 46476, 46505, 46490, 0.101, 22.397, 1.046 46506, 46535, 46520, 0.101, 21.860, 1.313 46536, 46565, 46550, 0.025, 16.316, 0.517 46566, 46595, 46580, 0.025, 16.291, 0.472 46596, 46625, 46610, 0.058, 13.871, 0.857 46627, 46656, 46641, 0.058, 11.443, 0.600 46657, 46686, 46671, 0.067, 11.120, 0.941 46687, 46716, 46701, 0.067, 10.445, 0.226 46717, 46746, 46731, 0.038, 10.259, 1.306 46747, 46776, 46761, 0.038, 10.072, 1.259 46777, 46806, 46791, 0.045, 9.029, 0.555 46807, 46836, 46821, 0.045, 7.989, 1.931 46837, 46866, 46851, 0.041, 6.949, 1.883 46867, 46896, 46881, 0.041, 5.905, 1.205 46897, 46926, 46911, 0.040, 6.940, 2.129 46927, 46956, 46941, 0.040, 5.640, 1.525 46957, 46986, 46971, 0.053, 5.864, 1.555 46987, 47016, 47001, 0.053, 6.091, 0.236 47017, 47046, 47031, 0.024, 5.127, 0.269 47047, 47076, 47061, 0.024, 4.833, 0.705 47077, 47106, 47091, 0.065, 4.952, 0.594 47108, 47137, 47122, 0.065, 5.070, -0.488 47138, 47167, 47152, 0.086, 5.127, -0.512 47168, 47197, 47182, 0.086, 4.722, 0.226 47198, 47227, 47212, 0.112, 5.682, 0.428 47228, 47257, 47242, 0.112, 6.642, -0.012 47338, 47367, 47352, 0.106, 11.953, -9999.000 47368, 47397, 47382, 0.106, 10.274, 1.472 47398, 47427, 47412, 0.120, 9.950, 0.741 47428, 47457, 47442, 0.120, 9.627, 0.226 47458, 47487, 47472, 0.127, 9.966, 0.840 47488, 47517, 47502, 0.127, 10.525, -0.241 47518, 47547, 47532, 0.150, 10.000, 0.124 47548, 47577, 47562, 0.150, 9.477, 0.588 47578, 47607, 47592, 0.105, 9.155, 0.237 47608, 47637, 47622, 0.105, 10.796, -0.125 47638, 47667, 47652, 0.085, 9.823, 0.388 47668, 47697, 47682, 0.085, 8.849, 0.443 47699, 47728, 47713, 0.091, 11.609, 0.337 47729, 47758, 47743, 0.091, 10.417, -0.159 47759, 47788, 47773, 0.117, 9.646, 0.065 47789, 47818, 47803, 0.117, 8.876, 0.310 47819, 47848, 47833, 0.070, 10.544, 0.516 47849, 47878, 47863, 0.070, 9.928, 1.524 47879, 47908, 47893, 0.125, 10.532, -0.450 47909, 47938, 47923, 0.125, 11.135, 1.583 47939, 47968, 47953, 0.061, 11.652, 0.204 47969, 47998, 47983, 0.061, 11.271, -0.140 47999, 48028, 48013, 0.064, 12.079, -0.475 48029, 48058, 48043, 0.064, 12.887, 0.640 48059, 48088, 48073, 0.114, 13.514, 0.913 48089, 48118, 48103, 0.114, 12.700, 0.511 48119, 48148, 48133, 0.084, 10.899, 0.030 48149, 48178, 48163, 0.084, 9.104, -0.743 48179, 48208, 48193, 0.097, 9.072, 1.519 48210, 48239, 48224, 0.097, 9.535, 0.494 48240, 48269, 48254, 0.067, 10.091, 0.450 48270, 48299, 48284, 0.067, 10.646, -0.434 48300, 48329, 48314, 0.079, 11.318, 0.474 48330, 48359, 48344, 0.079, 12.391, 1.435 48360, 48389, 48374, 0.072, 12.233, 0.429 48390, 48419, 48404, 0.072, 12.076, 1.719 48420, 48449, 48434, 0.095, 12.673, 0.904 48450, 48479, 48464, 0.095, 13.852, 0.747 48480, 48509, 48494, 0.066, 15.404, 0.735 48510, 48539, 48524, 0.066, 16.946, -0.017 48540, 48569, 48554, 0.065, 14.666, 1.671 48570, 48599, 48584, 0.065, 17.722, 0.915 48600, 48629, 48614, 0.056, 19.998, 0.466 48630, 48659, 48644, 0.056, 22.267, -0.413 48660, 48689, 48674, 0.040, 27.143, 1.080 48690, 48719, 48704, 0.040, 23.717, -0.126 48806, 48835, 48820, 0.095, 16.003, -9999.000 48836, 48865, 48850, 0.095, 13.992, 1.101 48866, 48895, 48880, 0.091, 20.000, 0.331 48896, 48925, 48910, 0.091, 22.271, -0.332 48926, 48955, 48940, 0.044, 22.088, 1.254 48956, 48985, 48970, 0.044, 21.905, 2.286 48986, 49015, 49000, 0.068, 22.102, 1.510 49016, 49045, 49030, 0.068, 22.307, -0.649 49047, 49076, 49061, 0.063, 19.615, 1.948 49077, 49106, 49091, 0.063, 16.942, 1.586 49107, 49136, 49121, 0.073, 14.175, 2.607 49137, 49166, 49151, 0.073, 15.582, 1.665 49167, 49196, 49181, 0.050, 13.759, 1.063 49197, 49226, 49211, 0.050, 11.949, 1.035 49227, 49256, 49241, 0.108, 10.961, -0.750 49257, 49286, 49271, 0.108, 11.285, 0.846 49287, 49316, 49301, 0.097, 10.040, 0.705 49317, 49346, 49331, 0.097, 8.803, 0.875 49347, 49376, 49361, 0.073, 10.790, 0.649 49377, 49406, 49391, 0.073, 10.961, 0.592 49407, 49436, 49421, -0.004, 10.238, 1.035 49437, 49466, 49451, -0.004, 9.520, 0.535 49467, 49496, 49481, 0.100, 10.075, 0.848 49497, 49526, 49511, 0.100, 10.598, 0.374 49527, 49556, 49541, 0.111, 9.517, 0.340 49557, 49586, 49571, 0.111, 8.435, 0.915 49587, 49616, 49601, 0.407, 8.917, 0.571 49617, 49646, 49631, -9999.000, -9999.000, -0.298 49647, 49676, 49661, -9999.000, -9999.000, 0.047 49678, 49707, 49692, -9999.000, -9999.000, 0.582 49708, 49737, 49722, -9999.000, -9999.000, 0.834 49738, 49767, 49752, -9999.000, -9999.000, -0.330 49768, 49797, 49782, -9999.000, -9999.000, -0.301 49798, 49827, 49812, -9999.000, -9999.000, 1.335 49828, 49857, 49842, -9999.000, -9999.000, 0.366 49858, 49887, 49872, -9999.000, -9999.000, -0.260 49888, 49917, 49902, -9999.000, -9999.000, 0.613 49918, 49947, 49932, -9999.000, -9999.000, 0.339 49948, 49977, 49962, -9999.000, -9999.000, 0.665 49978, 50007, 49992, -9999.000, -9999.000, 0.929 50008, 50037, 50022, -9999.000, -9999.000, 0.541 50142, 50171, 50156, -9999.000, -9999.000, 1.203 50172, 50201, 50186, -9999.000, -9999.000, 0.175 50202, 50231, 50216, -9999.000, -9999.000, 0.124 50232, 50261, 50246, -9999.000, -9999.000, 0.515 50262, 50291, 50276, -9999.000, -9999.000, 0.436 50292, 50321, 50306, -9999.000, -9999.000, 0.712 50322, 50351, 50336, -9999.000, -9999.000, 0.395 50352, 50381, 50366, -9999.000, -9999.000, 0.456 50382, 50411, 50396, -9999.000, -9999.000, 0.458 50412, 50441, 50426, -9999.000, -9999.000, -0.288 50442, 50471, 50456, -9999.000, -9999.000, 0.807 50472, 50501, 50486, -9999.000, -9999.000, 0.668 50502, 50531, 50516, -9999.000, -9999.000, 1.264 50532, 50561, 50546, -9999.000, -9999.000, 0.516 50562, 50591, 50576, -9999.000, -9999.000, 0.727 50592, 50621, 50606, -9999.000, -9999.000, 0.566 50622, 50651, 50636, -9999.000, -9999.000, 0.648 50652, 50681, 50666, -9999.000, -9999.000, -0.095 50682, 50711, 50696, -9999.000, -9999.000, 1.105 50712, 50741, 50726, -9999.000, -9999.000, 0.177 50743, 50772, 50757, -9999.000, -9999.000, 1.087 50773, 50802, 50787, -9999.000, -9999.000, 0.474 50803, 50832, 50817, -9999.000, -9999.000, 0.521 50833, 50862, 50847, -9999.000, -9999.000, 0.576 50863, 50892, 50877, -9999.000, -9999.000, 0.760 50893, 50922, 50907, -9999.000, -9999.000, -0.291 50923, 50952, 50937, -9999.000, -9999.000, 0.373 50953, 50982, 50967, -9999.000, -9999.000, 1.179 50983, 51012, 50997, -9999.000, -9999.000, 1.256 51013, 51042, 51027, -9999.000, -9999.000, 0.655 51043, 51072, 51057, -9999.000, -9999.000, 0.560 51073, 51102, 51087, -9999.000, -9999.000, 1.229 51103, 51132, 51117, -9999.000, -9999.000, -0.022 51133, 51162, 51147, -9999.000, -9999.000, 0.053 51163, 51192, 51177, -9999.000, -9999.000, 0.819 51193, 51222, 51207, -9999.000, -9999.000, 0.739 51223, 51252, 51237, -9999.000, -9999.000, -0.111 51254, 51283, 51268, -9999.000, -9999.000, 1.195 51284, 51313, 51298, -9999.000, -9999.000, 0.391 51314, 51343, 51328, -9999.000, -9999.000, 0.699 51344, 51373, 51358, -9999.000, -9999.000, 0.509 51374, 51403, 51388, -9999.000, -9999.000, 0.959 51404, 51433, 51418, -9999.000, -9999.000, 0.415 51434, 51463, 51448, -9999.000, -9999.000, 0.519 51464, 51493, 51478, -9999.000, -9999.000, 0.569 51494, 51523, 51508, -9999.000, -9999.000, 0.592 51524, 51553, 51538, -9999.000, -9999.000, 1.479 51554, 51583, 51568, -9999.000, -9999.000, 0.319 51584, 51613, 51598, -9999.000, -9999.000, 0.831 51614, 51643, 51628, -9999.000, -9999.000, 0.962 51644, 51673, 51658, -9999.000, -9999.000, 0.265 51674, 51703, 51688, -9999.000, -9999.000, 0.099 51704, 51733, 51718, -9999.000, -9999.000, 0.397 51734, 51763, 51748, -9999.000, -9999.000, 0.392 51764, 51793, 51778, -9999.000, -9999.000, 0.657 51794, 51823, 51808, -9999.000, -9999.000, 1.398 51824, 51853, 51838, -9999.000, -9999.000, 1.102 51855, 51884, 51869, -9999.000, -9999.000, 0.652 51885, 51914, 51899, 0.694, -9999.000, 0.381 51915, 51944, 51929, 0.694, 8.841, 1.050 51945, 51974, 51959, 1.114, 10.577, 0.553 51975, 52004, 51989, 1.114, 7.423, 0.216 52005, 52034, 52019, 0.782, 6.676, 0.337 52035, 52064, 52049, 0.782, 5.927, 0.195 52065, 52094, 52079, 1.041, 7.078, 1.109 52095, 52124, 52109, 1.041, 5.463, 0.788 52125, 52154, 52139, 0.830, 4.843, 0.162 52155, 52184, 52169, 0.830, 4.223, 0.333 52185, 52214, 52199, 0.458, 4.232, 0.428 52215, 52244, 52229, 0.458, 4.010, 0.635 52245, 52274, 52259, 0.528, 4.074, 0.088 52275, 52304, 52289, 0.528, 4.137, 0.619 52305, 52334, 52319, 0.471, 3.509, 0.858 52335, 52364, 52349, 0.471, 4.274, 1.234 52365, 52394, 52379, 0.457, 4.169, 0.210 52395, 52424, 52409, 0.457, 4.064, 0.567 52425, 52454, 52439, 0.627, 4.062, 0.111 52456, 52485, 52470, 0.627, 4.154, 0.420 52486, 52515, 52500, 0.433, 3.736, 0.587 52516, 52545, 52530, 0.433, 3.318, 0.909 52546, 52575, 52560, 0.400, 5.068, 0.175 52576, 52605, 52590, 0.400, 4.203, -0.059 52606, 52635, 52620, 0.394, 4.278, 0.327 52636, 52665, 52650, 0.394, 4.352, 0.174 52666, 52695, 52680, 0.418, 5.677, 0.475 52696, 52725, 52710, 0.418, 5.333, 0.823 52726, 52755, 52740, 0.552, 5.236, 0.255 52756, 52785, 52770, 0.552, 5.139, 0.556 52786, 52815, 52800, 0.514, 3.513, 0.513 52816, 52845, 52830, 0.514, 5.245, 0.381 52846, 52875, 52860, 0.440, 4.874, 0.366 52876, 52905, 52890, 0.440, 4.503, 0.491 52906, 52935, 52920, 0.442, 4.829, -0.073 52936, 52965, 52950, 0.442, 4.393, -9999.000 52966, 52995, 52980, 0.573, 7.140, 0.491 52996, 53025, 53010, 0.573, 9.888, -0.255 53026, 53055, 53040, 0.187, 13.275, 0.172 53057, 53086, 53071, 0.187, 15.118, 0.656 53087, 53116, 53101, 0.147, 13.308, -0.001 53117, 53146, 53131, 0.147, 11.498, -0.195 53147, 53176, 53161, -9999.000, -9999.000, -0.479 53177, 53206, 53191, 0.261, 13.673, -0.287 53207, 53236, 53221, 0.283, 13.214, 0.464 53237, 53266, 53251, 0.283, 12.755, 0.509 53267, 53296, 53281, 0.142, 12.578, 0.445 53297, 53326, 53311, 0.142, 13.392, -0.111 53327, 53356, 53341, 0.119, 12.162, 0.763 53357, 53386, 53371, 0.119, 10.929, 0.247 53387, 53416, 53401, 0.203, 11.454, 1.347 53417, 53446, 53431, 0.203, 11.985, 0.929 53447, 53476, 53461, 0.250, 11.547, 0.551 53477, 53506, 53491, 0.250, 11.107, -0.294 53507, 53536, 53521, 0.292, 12.001, 0.565 53537, 53566, 53551, 0.292, 16.565, 1.420 53567, 53596, 53581, 0.185, 15.474, 0.615 53598, 53627, 53612, 0.185, 14.375, 2.088 53627, 53656, 53641, 0.259, 16.802, -0.117 53657, 53686, 53671, 0.259, 15.894, 1.350 53688, 53717, 53702, 0.207, 16.018, 0.826 53718, 53747, 53732, 0.207, 16.140, 2.000 53748, 53777, 53762, 0.316, 19.928, 1.962 53778, 53807, 53792, 0.316, 19.166, 1.448 53808, 53837, 53822, 0.221, 19.758, 3.871 53838, 53867, 53852, 0.221, 20.349, 2.087 53868, 53897, 53882, -9999.000, -9999.000, 2.126 53898, 53927, 53912, -9999.000, -9999.000, 1.602 53928, 53957, 53942, -9999.000, -9999.000, 1.539 53958, 53987, 53972, 0.495, 20.516, 2.762 53988, 54017, 54002, -9999.000, -9999.000, 1.868 54018, 54047, 54032, -9999.000, -9999.000, 1.572 54048, 54077, 54062, -9999.000, -9999.000, 0.917 54078, 54107, 54092, -9999.000, -9999.000, 1.573 54108, 54137, 54122, -9999.000, -9999.000, 1.277 54138, 54167, 54152, -9999.000, -9999.000, 2.017 54168, 54197, 54182, 0.267, -9999.000, 1.092 54198, 54227, 54212, 0.267, 15.683, 0.772 54229, 54258, 54243, 0.306, 18.025, 1.184 54259, 54288, 54273, 0.306, 18.332, 1.765 54289, 54318, 54303, 0.303, 17.535, 0.865 54319, 54348, 54333, 0.303, 16.738, 2.672 54349, 54378, 54363, 0.171, 15.828, 1.390 54379, 54408, 54393, 0.171, 15.069, 0.751 54409, 54438, 54423, 0.231, 14.398, 2.115 54439, 54468, 54453, 0.231, 13.727, 1.832 54469, 54498, 54483, 0.251, 13.833, 1.100 54499, 54528, 54513, 0.251, 13.100, 1.882 54529, 54558, 54543, 0.048, 12.519, 0.519 54559, 54588, 54573, 0.048, 11.938, 0.369 54589, 54618, 54603, 0.120, 11.525, 0.612 54619, 54648, 54633, 0.120, 11.315, 0.463 54649, 54678, 54663, 0.176, 9.802, 0.537 54679, 54708, 54693, 0.176, 8.284, 0.854 54709, 54738, 54723, 0.161, 8.892, 0.752 54739, 54768, 54753, 0.161, 10.084, 0.881 54769, 54798, 54783, 0.197, 10.059, 1.417 54799, 54828, 54813, 0.197, 10.034, 0.061 54830, 54859, 54844, 0.336, 11.976, 0.050 54860, 54889, 54874, 0.336, 12.872, 0.737 54890, 54919, 54904, 0.242, 12.103, -0.396 54920, 54949, 54934, 0.242, 11.332, 0.491 54950, 54979, 54964, 0.458, 10.596, 1.296 54980, 55009, 54994, 0.458, 10.044, 0.827 55010, 55039, 55024, 0.370, 9.891, 0.744 55040, 55069, 55054, 0.370, 9.739, 0.154 55070, 55099, 55084, 0.426, 10.890, 0.652 55100, 55129, 55114, 0.426, 11.036, 0.618 55130, 55159, 55144, 0.474, 10.266, 0.287 55160, 55189, 55174, 0.474, 9.498, -0.007 55190, 55219, 55204, 0.790, 8.025, -0.164 55220, 55249, 55234, 0.790, 7.184, 0.917 55250, 55279, 55264, 0.722, 6.858, -0.172 55280, 55309, 55294, 0.722, 6.530, 0.634 55310, 55339, 55324, 0.373, 4.892, 0.734 55340, 55369, 55354, 0.373, 5.646, -9999.000 55370, 55399, 55384, 0.465, 5.016, 0.466 55400, 55429, 55414, 0.465, 4.387, 0.471 55430, 55459, 55444, 0.346, 4.927, 0.274 55460, 55489, 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